Nomenclatura y conversiones de unidades de concentracin en la ABSORCION y DESORCION de un

componente.

Prof. Gregorio Zacahua Tlacuatl

FASE GASEOSA:

Fraccin molar (1): = = = = 1+ [=] . 01
+

Relacin molar: = =
= 1 [=]

0

Fraccin peso: = = 1+ = [=] 01
+(1 ) .

Relacin molar: = 1
[=]

0

Presin total: = +
.
Densidad molar: = ( ) = ( ) = [=] 3 [=] 3
. . .

, .
Densidad total: = = . = = (0.08205

3 )(,)
[=] 3
.

Densidad parcial: = = = = ( )

= ( )

= ( ) [=] 3
.
.
= = [=]
3.

Densidad masa: = ( ) = [=] 3
.

Fraccin molar (2): = = [=] 01
. .

Fraccin peso (2): = [=] . 01

%mol: 102

%peso: 102

ppm : 106
6 3
10
= ( 3 ) ( 1 ) (103.

) [=]
. . .

:
ppm 106
FASE LIQUIDA:

PM mezcla: = + (1 ) [=]

106
ppm : = ( ) ( . ) ( ) [=]
. . 1 .

Fraccin molar (2): = [=] . 01
.

= =
1
. 1 103 .
Densidad molar: = ( ) ( .
) (
) ( 3
1 .
) [=] 3
. .

= ( ) = =

Densidad masa: = ( 3
.
) ( ) [=] 3
.

Densidad parcial: = = = ( )

=( ) [=] 3
.

= ( )
:

En la interfase: =

1 = 1 o 2 = 2

1 =( ) 1

= =

En el equilibrio: 1 = 1 o 1 = 1

2 = 2 o 2 = 2

= [] = [= 3
]
3

Recuperaciones: = ( )
1

Gastos: 1 = 1 = ( ) 1 = (1 + 1 )

2 = (1 + 2 )
2 = (1 ) 1
 2 = (1 + 2 )
2 = 2 2

Balance de masa: = (1 2 ) = (1 2 ) = , (1 2 )

Velocidades de transferencia A o flujos molares de A:

Pesos moleculares: 2 = (2 ) + (1 2 )

Flujos molares especficos de A o velocidades de transferencia de masa de A:

= ( )( ) = ( )( ) = ( )( )

= ( )( ) = ( ) ( ) = ( )( ) = ( ) ( )
1 1

= ( )( ) = ( ) ( ) = ( )( ) = ( )( )



= ( )( ) = ( )( ) = ( )( ) = ( ) ( )


= ( ) ( ) = ( )( ) = ( )( )

= ( )( ) = ( )(

) = ( )( )

= ( )( ) = ( )(

) = ( ) ( )

COEFICIENTES DE TRANSFERENCIA DE MASA:

= ( ) =


= ( ) =

= ( )(1 )(1 )

= ( )


= ( ) = = = = ( )
( ) ( )( )

=


= ( )(1 )(1 ) =


( )( )
=

= ( )( ) = ( ) ( )( )

=


=


= ( ) = [ ] ( )

= ( )

= ( ) (1 )(1 ) = ( ) ( ) =

= ( ) = ( )

Para soluciones diluidas:

= = ( )

3
Donde = 0.7302

= + 460

1
= = ( )( ) = ( ) ( ) = ( )


RESISTENCIAS

= +
1 1
= +

1 1
= +

 1 1
= +

1 1 1
= +
( )
= +
1 1 1
= +

1 1 1 1 1
= + = ( )

1 1 1
= +

Entonces

1= +

Donde

= = , = = [=] Absorcin

= [=] Absorcin


= = = [=] Desorcin

= [=] Desorcin

Para la resistencia gaseosa:

1 1 1
[ ] [ ] [ ]

= = = =
[ 1 ] 1 1
[ ] [ ]

1 1
[ ] [ ( )]

= = =
=
1 1 ( )
[ ] [ ]

Para la resistencia lquida:

1
[ ] [ ]

= = =
[ 1 ] 1
[ ]

1
[ ] [ ]

= = = =
1 1
[ ] [ ]

En la interfase: =

En el equilibrio: =
Flujos molares especficos de A o velocidades de transferencia de masa de A:

= ( )( ) = ( )( )

COEFICIENTES DE TRANSFERENCIA DE MASA:

= = =

RESISTENCIAS

= +
1 1
= +

1 1
= +

1 1 1
= +
( )
= +
1 1 1
= +

1 1 1
= +

Entonces

1= +

Donde
Para la resistencia gaseosa:
1 1 1
[ ] [ ] [ ]

= = = =
[ 1 ] 1 1
[ ] [ ]

1 1
[ ] [ ( )]

= = =
=
1 1 ( )
[ ] [ ]

Para la resistencia lquida:

1
[ ] [ ]

= = =
[ 1 ] 1
[ ]

1
[ ] [ ]

= = = =
1 1
[ ] [ ]