AP Chemistry Chemistry I Review Assignment

Nomenclature
1. Name these binary compounds of two nonmetals.
IF7 iodine heptafluoride
N2O5 dinitrogen pentoxide
XeF2 xenon difluoride
N2O4 dinitrogen tetroxide
As4O10 tetrarsenic decoxide
SF6 sulfur hexafluoride
PCl3 phosphorous trichloride
S2Cl2 disulfur dichloride

2. Name these binary compounds with a fixed charge metal.

AlCl3 aluminum chloride
MgO magnesium oxide
BaI2 barium iodide
KI potassium iodide
SrBr2 strontium bromide
Na2S sodium sulfide
CaF2 calcium fluoride
Al2O3 aluminum oxide

3. Name these binary compounds of cations with variable charge.

CuCl2 copper (II) chloride
Fe2O3 iron (III) oxide
SnO tin (II) oxide
PbCl4 lead (IV) chloride
Cu2S copper (I) sulfide
HgS mercury (II) sulfide
AuI3 gold (III) iodide
CoP cobalt (III) phosphide

4. Name these compounds with polyatomic ions.

Fe(NO3)3 iron (III) nitrate
NaOH sodium hydroxide
Cu2SO4 copper (I) sulfate
Ca(ClO3)2 calcium chlorate
KNO2 potassium nitrite
NaHCO3 sodium hydrogen carbonate
NH4NO2 ammonium nitrite
Cu2Cr2O7 copper (I) dichromate

5. Name these binary acids

HCl(aq) hydrochloric acid
HI(aq) hydroiodic acid

6. Name these acids with polyatomic ions.

HClO4 perchloric acid
H2SO4 sulfuric acid
HC2H3O2 acetic acid
H3PO4 phosphoric acid
HNO2 nitrous acid
H2CrO4 chromic acid
H2C2O4 dichromic acid
H2CO3 carbonic acid

7. Name these compounds appropriately.

CO carbon monoxide
NH4CN ammonium cyanide
HIO3(aq) iodic acid
NI3 nitrogen triiodide
AlP aluminum phosphide
OF2 oxygen difluoride
LiMnO4 lithium permanganate
HClO(aq) hypochlorous acid
HF(aq) hydrofluoric acid
SO2 sulfur dioxide
CuCr2O7 copper(II) dichromate
K2O potassium oxide
FeF3 iron(III) fluoride
KC2H3O2 potassium acetate
MnS manganese(II) sulfide

8. Write the formulas.

Tin (IV) phosphide Sn3(PO4)4
Copper (II) cyanide Cu(CN)2
Magnesium hydroxide Mg(OH)2
Sodium peroxide Na2O2
Sulfurous acid H2SO3
Lithium silicate Li4SiO4
Potassium nitride K3N
Chromium (III) carbonate Cr2(CO3)3
Gallium arsenide - GaAs
Cobalt (II) chromate CoCrO4
Zinc fluoride ZnF2
Dichromic acid H2Cr2O7

Solubility rules
9. Review solubility rules and identify each of the following compounds as soluble or insoluble in water.
Na2CO3 Sol. CoCO3 Insol. Pb(NO3)2 Sol.
K2S Sol. BaSO4 Sol. (NH4)2S Sol.
AgI Insol. Ni(NO3)2 Sol. KI Sol.
FeS Insol. PbCl2 Insol. CuSO4 Sol.
Li2O Sol. Mn(C2H3O2)2 Sol. Cr(OH)3 Insol
AgClO3 Insol. Sn(SO3)4 Insol. FeF2 Insol.

10. Predict whether each of these double replacement reactions will give a precipitate or not based on the solubility of the
products. If yes, identify the precipitate.
silver nitrate and potassium chloride Yes, AgCl
AgNO3 + KCl AgCl + KNO3
magnesium nitrate and sodium carbonate Yes, MgCO3
Mg(NO3)2 + Na2CO3 MgCO3 + 2NaNO3
strontium bromide and potassium sulfate Yes, SrSO4
SrBr2 + K2SO4 2KBr + SrSO4
cobalt (III) bromide and potassium sulfide Yes, Co2S3
2CoBr3 + 3K2S Co2S3 + 6KBr
ammonium hydroxide and copper (II) acetate Yes, Cu(OH)2
2NH4OH + Cu(C2H3O2)2 Cu(OH)2 + 2NH4C2H3O2
lithium chlorate and chromium (III) fluoride Yes, Cr(ClO3)3
3LiClO3 + CrF3 Cr(ClO3)3 + 3LiF

Balancing Equations
11. Balance the following equations with the lowest whole number coefficients.
S8 + 12O2 8SO3
C10H16 + 8Cl2 10C + 16HCl
4Fe + 3O2 2Fe2O3
2C7H6O2 + 15O2 14CO2 + 6H2O
2KClO3 2KCl + 3O2
2H3AsO4 As2O5 + 3H2O
V2O5 + 6HCl 2VOCl3 + 3H2O
3Hg(OH)2 + 2H3PO4 Hg3(PO4)2 + 6H2O
 Stoichiometry and Limiting Factor
12. Given the equation below, what mass of water would be needed to react with 10.0g of sodium oxide?
Na2O + H2O 2NaOH

1 mol Na 2 O 1 mol H 2 O 18 g H 2 O
10 g Na 2 O 2.9 g H 2 O
62 g Na 2 O 1 mol Na 2 O 1 mol H 2 O

13. 2NaClO3 2NaCl + 3O2

What mass of sodium chloride is formed along with 45.0 g of oxygen gas?
1 mol O 2 2 mol NaCl 58.44 g NaCl
45.0 g O 2 54.8 g NaCl
32 g O 2 3 mol O 2 1 mol NaCl

14. 4NH3 + 5O2 4NO + 6 H2O

What mass of water will be produced when 100.0 g of ammonia is reacted with
excess oxygen?
1 mol NH 3 6 mol H 2 O 18 g H 2 O
100.0 g NH 3 158 g H 2 O
17 g NH 3 4 mol NH 3 1 mol H 2 O

15. If the reaction in #14 is done with 25.0g of each reactant, which would be the
limiting factor?
1 mol NH 3 4 mol NO
25.0 g NH 3 1.47 mol NO
17 g NH 3 4 mol NH3
1 mol O 2 4 mol NO
25.0 g O 2 0.62 mol NO
32 g O 2 5 mol O 2
Thus, the O2 is the limiting reagent

16. Na2S + 2AgNO3 Ag2S + 2NaNO3

If the above reaction is carried out with 50.0g of sodium sulfide and 35.0g of silver
nitrate, which is the limiting factor?
1 mol Na 2S 1 mol Ag 2S
50.0 g Na 2S 0.641 mol Ag 2S
78.04 g Na 2S 1 mol Na 2S
1 mol AgNO 3 1 mol Ag 2S
35.0 g AgNO 3 0.103 mol Ag 2S
169.87 g AgNO 3 2 mol AgNO 3
Thus the AgNO3 is the limiting reagent

What mass of the excess reactant remains?

1 mol Na 2S 78.04 g Na 2S
0.103 mol Ag 2S consumed 8.04 g Na 2S consumed
1 mol Ag 2S 1 mol Na 2S
Thus, (50.0 8.04) = 41.96 g Na2S are left

What mass of silver sulfide would precipitate?

0.103 mole Ag2S would precipitate, thus 25.5 g Ag2S would precipitate

17. 6NaOH + 2Al 2Na3AlO3 + 3H2

What volume of hydrogen gas (measured at STP) would result from reacting 75.0g of sodium
hydroxide with 50.0g of aluminum?

1 mol NaOH 3 mol H 2 22.4 L of H 2 @ STP

75.0 g NaOH 21.0 L of H 2 @ STP
40 g NaOH 6 mol NaOH 1 mol H 2