Calculado de polinomio en Fig 1

t Ca dCa/dt = rA ln(-rA) ln(Ca)

0 10.00 -13.25 2.58 2.30
12.00
0.1 8.82 -10.46 2.35 2.18
0.2 7.89 -8.35 2.12 2.07 10.00
f(x) = 5.5261318423x^4 - 13.6687359557x^3 + 15.9187
0.3 7.13 -6.80 1.92 1.96 R = 0.9999994002
8.00
0.4 6.51 -5.67 1.73 1.87
6.00
0.5 5.99 -4.82 1.57 1.79

Ca
0.6 5.54 -4.14 1.42 1.71 4.00
0.7 5.16 -3.48 1.25 1.64 2.00 Permite encontr
0.00
ESTIMACION LINEAL 0 0.1 0.2 0.3 0.4 0.5
m b 2.01 -2.03
t
se_m se_b 0.02 0.03
r2 sey 1.00 0.01
F df 12569.04 6.00
ss_reg ss_resid 1.50 0.00
3.00
alfa = 2.008 (la pendiente) 2.50 f(x) = 2.008100243x
k= 0.131 (Exponencial del intercepto) 2.00 R = 0.9995228644

ln(-dCa/dt)
1.50

1.00

0.50
Perm
0.00
1.50 1.60 1.70 1.80 1.90
ln(C
- 13.6687359557x^3 + 15.9187265952x^2 - 13.2537722558x + 9.9994620641

Permite encontrar dCa/dt

0.2 0.3 0.4 0.5 0.6 0.7 0.8
t

f(x) = 2.008100243x - 2.029052012

R = 0.9995228644

Permite encontrar k y alfa

.60 1.70 1.80 1.90 2.00 2.10 2.20 2.30 2.40

ln(Ca)
t Ca t (interpolado) Ca (interpolado) dCa/dt = rA ln(-rA) ln(Ca)
0 10.00
0.1 8.82 0.05 9.41 -11.82 2.47 2.24
0.2 7.89 0.15 8.35 -9.32 2.23 2.12
0.3 7.13 0.25 7.51 -7.54 2.02 2.02
0.4 6.51 0.35 6.82 -6.22 1.83 1.92
0.5 5.99 0.45 6.25 -5.22 1.65 1.83
0.6 5.54 0.55 5.77 -4.45 1.49 1.75
0.7 5.16 0.65 5.35 -3.83 1.34 1.68

ESTIMACION LINEAL
m b 1.995 -2.003
se_m se_b 0.000 0.001
r2 sey 1.000 0.000
F df 35132884.065 5.000
ss_reg ss_resid 0.981 0.000

alfa = 1.995 (la pendiente)

k= 0.135 (Exponencial del intercepto)
 3.00

2.50
f(x) = 1.9953427815x - 2.003205513
R = 0.9999998577
2.00
ln(-dCa/dt)

1.50

1.00

0.50 Permite encontrar k y alfa

0.00
1.50 1.60 1.70 1.80 1.90 2.00 2.10 2.20 2.30
ln(Ca)
t Ca (1/Ca - 1/Cao)
0 10.00 0.00
0.1 8.82 0.01
0.2 7.89 0.03
0.3 7.13 0.04
0.4 6.51 0.05 0.10
0.5 5.99 0.07 f(x) = 0.134x + 1.96261
0.08
R = 1
0.6 5.54 0.08

l(1/Ca - 1/Cao)
0.06
0.7 5.16 0.09
0.04
ESTIMACION LINEAL 0.02
m b 0.134 2.775558E-17
0.00
se_m se_b 2.3059E-17 9.646083E-18
0 0.1 0.2
r2 sey 1 1.494365E-17
F df 3.3771E+31 6
ss_reg ss_resid 0.00754152 1.339875E-33

k= 0.134
.10
f(x) = 0.134x + 1.96261557335472E-17
.08
R = 1
.06

.04

.02 Permite encontrar k

.00
Se asumi alfa = 2
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
t
 Calculados
t (real) Ca (Real) Ca (calculado) error k= 0.13394087
0 10.00 10.00 3.16E-30 alfa = 2.00021096
0.1 8.82 8.82 1.03E-09
0.2 7.89 7.89 9.36E-10 Utilice el Solver para variar k y alfa y minim
0.3 7.13 7.13 1.91E-10
0.4 6.51 6.51 8.69E-11
0.5 5.99 5.99 1.18E-09
0.6 5.54 5.54 3.49E-09
0.7 5.16 5.16 6.81E-09

suma 1.37E-08
er para variar k y alfa y minimizar el valor de la suma de errores
Spreadsheets that help to find kinetic parameters
Alejandro Molina
Facultad de Minas
Oct-14
Rev.
March April 2015. Correction of the equation of concentration by Jhon Marcos Zapata Zapata

Actualizado Sep. 2016 para hacerlo ms fcil de entender para los estudiantes