T PS1 PS2 P1 P2 PT

77.925 1.341 1.000 0.000 1.000 1.000

69.851 1.050 0.719 0.315 0.685 1.000
64.778 0.894 0.579 0.471 0.528 0.999
61.535 0.804 0.502 0.559 0.441 1.000
59.430 0.750 0.457 0.612 0.388 1.000

58.114 0.717 0.431 0.645 0.356 1.001

57.312 0.698 0.415 0.665 0.335 1.001

56.858 0.687 0.407 0.676 0.324 1.000
56.676 0.683 0.403 0.682 0.318 1.000
56.658 0.683 0.403 0.682 0.318 1.000
56.729 0.684 0.404 0.679 0.321 1.000
56.832 0.687 0.406 0.673 0.327 1.000
56.921 0.689 0.408 0.665 0.335 1.000
56.959 0.690 0.409 0.655 0.345 1.000
56.930 0.689 0.408 0.645 0.355 1.000
56.845 0.687 0.406 0.636 0.364 1.000
56.766 0.685 0.405 0.631 0.369 1.000
56.858 0.687 0.407 0.635 0.365 1.000
57.520 0.703 0.419 0.658 0.342 1.000
59.842 0.760 0.466 0.729 0.270 1.000
68.300 1.000 0.673 1.000 0.000 1.000

T-X1Y1
80
 T-X1Y1
80

75

70

65
T

60

55

50
0 0.25 0.5

X1Y1
 X1 Y1 X2 Y2 1 2
0.000 0.000 1.000 1.000 6.821 1.000
0.050 0.315 0.950 0.685 5.994 1.003
0.100 0.471 0.900 0.528 5.269 1.014
0.150 0.559 0.850 0.441 4.635 1.033
0.200 0.612 0.800 0.388 4.081 1.061
3.598 1.101
0.250 0.645 0.750 0.356

0.300 0.665 0.700 0.335 3.177 1.154

0.350 0.676 0.650 0.324 2.812 1.224
0.400 0.682 0.600 0.318 2.495 1.315
0.450 0.682 0.550 0.318 2.221 1.433
0.500 0.679 0.500 0.321 1.985 1.587
0.550 0.673 0.450 0.327 1.782 1.788
0.600 0.665 0.400 0.335 1.608 2.054
0.650 0.655 0.350 0.345 1.461 2.412
0.700 0.645 0.300 0.355 1.337 2.900
0.750 0.636 0.250 0.364 1.234 3.581
0.800 0.631 0.200 0.369 1.151 4.554
0.850 0.635 0.150 0.365 1.086 5.987
0.900 0.658 0.100 0.342 1.039 8.167
0.950 0.729 0.050 0.270 1.010 11.611
1.000 1.000 0.000 0.000 1.000 17.288

T-X1Y1
T-X1Y1

0.5 0.75 1

X1Y1
Ytotal
1.000
1.000 N-HEXANO ETANOL
0.999 A 4.00139 5.33675
1.000 B 1170.875 1648.22
1.000 C 224.317 230.918

1.001 T.B. [C] 69 78

1.001 A12 A21

1.000 1.92 2.85
1.000
1.000 P [atm] 1
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1
 T PS1 PS2 P1
77.9215 1.3408500073 0.9998458581 0
69.6116 1.0419668937 0.7118102914 0.3216537564
64.3633 0.8819268632 0.5687038437 0.4809022553
61.026 0.7906704835 0.490996899 0.5692438003
58.9178 0.7369751331 0.4466975012 0.6213137815
57.619 0.7053567672 0.4211293443 0.6521156128
56.8981 0.688274864 0.4074804333 0.6699448968
56.5722 0.6806624071 0.4014356414 0.6790004753
56.4706 0.6783020663 0.3995661444 0.6809316829
56.5373 0.6798496672 0.400791659 0.6784742315
56.6718 0.6829810784 0.4032743359 0.6723775244
56.8104 0.6862203593 0.4058467135 0.6636330087
56.9072 0.6884900416 0.4076516386 0.6532208174
56.9353 0.6891496317 0.4081765556 0.6422309689
56.8926 0.6881458585 0.4073777994 0.632035697
56.8123 0.6862635794 0.4058810642 0.6245411425
56.7844 0.6856120565 0.4053633246 0.62268975
57.002 0.690717714 0.4094251745 0.6316369562
57.8769 0.711547485 0.4261045768 0.6620503689
60.4194 0.7749139598 0.477885108 0.74245793
68.2998 0.9999913023 0.6734739882 0.9999913023

80

75
 80

75

70

65
T

60

55

50
0 0.25
 P2 PT X1 Y1 X2
0.9998458581 0.9998458581 0 0 1
0.6783311814 0.9999849378 0.05 0.32165 0.95
0.5186551945 0.9995574499 0.1 0.4809 0.9
0.4307127448 0.9999565452 0.15 0.56924 0.85
0.3791220114 1.0004357929 0.2 0.62131 0.8
0.3480845622 1.000200175 0.25 0.65212 0.75
0.3303649561 1.000309853 0.3 0.66994 0.7
0.3216991555 1.0006996308 0.35 0.679 0.65
0.3190391095 0.9999707924 0.4 0.68093 0.6
0.3214565022 0.9999307336 0.45 0.67847 0.55
0.327494049 0.9998715734 0.5 0.67238 0.5
0.3361677661 0.9998007748 0.55 0.66363 0.45
0.3465275244 0.9997483417 0.6 0.65322 0.4
0.3574963637 0.9997273326 0.65 0.64223 0.35
0.3677076543 0.9997433513 0.7 0.63204 0.3
0.3752446864 0.9997858289 0.75 0.62454 0.25
0.3771435372 0.9998332872 0.8 0.62269 0.2
0.3682314489 0.9998684051 0.85 0.63164 0.15
0.3378019269 0.9998522958 0.9 0.66205 0.1
0.2572171244 0.9996750544 0.95 0.74246 0.05
0 0.9999913023 1 1 0

T-X1Y1
 T-X1Y1

5 0.5 0.7

X1Y1
 Y2 1 2 Ytotal
0.9998458581 6.9587509706 1 0.9998458581
0.6783311814 6.1739726734 1.00312 0.9999849378
0.5186551945 5.4528586822 1.01333 0.9995574499
0.4307127448 4.7996716052 1.03202 0.9999565452
0.3791220114 4.2152967825 1.0609 1.0004357929
0.3480845622 3.6980753181 1.10207 1.000200175
0.3303649561 3.2445608185 1.15821 1.000309853
0.3216991555 2.8501667462 1.23288 1.0006996308
0.3190391095 2.5096919085 1.33077 0.9999707924
0.3214565022 2.2177263402 1.45828 0.9999307336
0.327494049 1.9689492011 1.62418 0.9998715734
0.3361677661 1.7583352839 1.84069 0.9998007748
0.3465275244 1.5812884668 2.12514 0.9997483417
0.3574963637 1.43372005 2.50239 0.9997273326
0.3677076543 1.312088313 3.00874 0.9997433513
0.3752446864 1.2134135458 3.69808 0.9997858289
0.3771435372 1.1352807759 4.65192 0.9998332872
0.3682314489 1.0758408049 5.99591 0.9998684051
0.3378019269 1.0338192973 7.92768 0.9998522958
0.2572171244 1.0085437916 10.7648 0.9996750544
0 1 15.0293 0.9999913023
0.75 1
 N-HEXANO ETANOL
A 4.00139 5.33675
B 1170.875 1648.22
C 224.317 230.918
T.B. C 69 78
A12 A21
1.94 2.71

P 1
 PARA DIAGRAMA TXY
T PS1 PS2 P1 P2 PT X1 Y1 X2 Y2 1 2 12 21 Ytotal
76.2304 964.9631 691.8995 0.0000 760.0497 760.0497 0.0000 0.0000 1.0000 1.0001 8.8293 1.0985 0.2803 0.0939 1.0001
67.7941 744.8554 486.3472 252.7352 507.2963 760.0315 0.0500 0.3325 0.9500 0.6675 6.7862 1.0980 0.2770 0.0868 1.0000 N-HEXANO ETANOL MEZCLA

63.6878 653.1010 406.2542 352.4572 407.6505 760.1076 0.1000 0.4638 0.9000 0.5364 5.3967 1.1149 0.2754 0.0834 1.0001 V. MOLAR cm3/mol 131.61 58.68
61.4305 606.5997 367.0842 402.5651 357.2658 759.8309 0.1500 0.5297 0.8500 0.4701 4.4243 1.1450 0.2745 0.0816 0.9998 a12 cal/mol a21 cal/mol 320.36
60.1115 580.6638 345.6802 431.8728 328.1601 760.0330 0.2000 0.5683 0.8000 0.4318 3.7188 1.1866 0.2740 0.0805 1.0000 320.36 2189.29 2189.29
59.2898 564.9565 332.8776 450.5401 309.4862 760.0264 0.2500 0.5928 0.7500 0.4072 3.1899 1.2396 0.2737 0.0798 1.0000 A 6.91058 7.5867
58.7601 555.0092 324.8337 463.2186 296.6687 759.8873 0.3000 0.6095 0.7000 0.3904 2.7820 1.3047 0.2735 0.0794 0.9999 B 1189.64 1281.59
58.4226 548.7439 319.7930 472.4382 287.5576 759.9958 0.3500 0.6216 0.6500 0.3784 2.4598 1.3834 0.2733 0.0791 1.0000 C 226.78 193.768
58.2005 544.6510 316.5109 479.3153 280.6964 760.0118 0.4000 0.6307 0.6000 0.3693 2.2001 1.4781 0.2732 0.0790 1.0000 TB c 69 78
58.0457 541.8133 314.2405 484.4828 275.2036 759.6865 0.4500 0.6375 0.5500 0.3621 1.9871 1.5923 0.2732 0.0788 0.9996 P 760.0000 mmHg
57.9644 540.3288 313.0544 488.9284 270.9830 759.9114 0.5000 0.6433 0.5000 0.3566 1.8097 1.7312 0.2731 0.0788 0.9999 R 1.9872 cal/mol k
57.9164 539.4525 312.3548 492.6008 267.3705 759.9713 0.5500 0.6482 0.4500 0.3518 1.6603 1.9022 0.2731 0.0787 1.0000
57.8961 539.0821 312.0592 495.8263 264.1596 759.9859 0.6000 0.6524 0.4000 0.3476 1.5329 2.1163 0.2731 0.0787 1.0000
57.8994 539.1429 312.1077 498.8512 261.1342 759.9854 0.6500 0.6564 0.3500 0.3436 1.4235 2.3905 0.2731 0.0787 1.0000
57.9256 539.6206 312.4890 501.9211 258.0446 759.9657 0.7000 0.6604 0.3000 0.3395 1.3288 2.7526 0.2731 0.0787 1.0000
57.9780 540.5756 313.2516 505.3372 254.5223 759.8595 0.7500 0.6649 0.2500 0.3349 1.2464 3.2501 0.2731 0.0788 0.9998
58.0594 542.0648 314.4415 509.4388 249.8023 759.2411 0.8000 0.6703 0.2000 0.3287 1.1748 3.9722 0.2732 0.0788 0.9990
58.2713 545.9534 317.5544 516.3909 243.1804 759.5713 0.8500 0.6795 0.1500 0.3200 1.1128 5.1053 0.2733 0.0790 0.9994
58.7429 554.6893 324.5758 529.3545 230.6837 760.0382 0.9000 0.6965 0.1000 0.3035 1.0604 7.1072 0.2734 0.0794 1.0001
60.1322 581.0649 346.0088 562.8053 197.3055 760.1107 0.9500 0.7405 0.0500 0.2596 1.0196 11.4047 0.2740 0.0805 1.0001
68.4525 760.4623 500.3204 760.4623 0.0000 760.4623 1.0000 1.0006 0.0000 0.0000 1.0000 23.5816 0.2773 0.0874 1.0006

T-X1Y1
80

75

70

65
T

60

55

50
0 0.25 0.5 0.75 1

X1Y1

15
 T C T K PS1 PS2 P1 P2 PT X1 Y1 X2 Y2 1 2 12 21 r1 Ytotal
-24.8060 248.1940 10.4837 1.0037 0.0000 3.0010 3.0010 0.0000 0.0000 1.0000 2.9625 1.0000 0.9972 0.0084 0.0059 1.0144 1.0010
-29.0296 243.9704 7.8472 0.6414 0.3924 2.5886 2.9810 0.0500 0.3873 0.9500 2.5554 1.0000 0.9972 0.0086 0.0060 1.0132 1.0000 N-HEXANO ETANOL

-32.5472 240.4528 6.1061 0.4339 0.6106 2.3311 2.9417 0.1000 0.6028 0.9000 2.3012 1.0000 0.9972 0.0087 0.0061 1.0120 1.0000 A 6.91058 7.5867
-35.4775 237.5225 4.9198 0.3092 0.7380 2.1563 2.8943 0.1500 0.7285 0.8500 2.1287 1.0000 0.9971 0.0088 0.0061 1.0109 1.0000 B 1189.64 1281.59
62.2436 335.2436 623.0378 380.8162 124.6076 382.6142 507.2217 0.2000 123.0084 0.8000 377.7040 1.0000 0.9980 0.0063 0.0043 1.0068 428.6388 C 226.78 193.768
62.1807 335.1807 621.7548 379.7399 155.4387 381.4879 536.9266 0.2500 153.4439 0.7500 376.5922 1.0000 0.9980 0.0063 0.0043 1.0060 439.6623 T.B. C 69 78
62.1075 335.1075 620.2623 378.4887 186.0787 380.1867 566.2654 0.3000 183.6907 0.7000 375.3077 1.0000 0.9980 0.0063 0.0043 1.0052 450.4799 A12 A21
62.0114 335.0114 618.3089 376.8528 216.4081 378.5008 594.9089 0.3500 213.6309 0.6500 373.6434 1.0000 0.9980 0.0063 0.0043 1.0045 460.8622 0 0
61.9232 334.9232 616.5202 375.3564 246.6081 376.9543 623.5624 0.4000 243.4433 0.6000 372.1168 1.0000 0.9980 0.0063 0.0044 1.0038 471.3619 B12 B21
61.8335 334.8335 614.7044 373.8388 276.6170 375.3868 652.0038 0.4500 273.0671 0.5500 370.5694 1.0000 0.9980 0.0063 0.0044 1.0032 481.8082 2.0966 1.4571
61.7427 334.7427 612.8715 372.3085 306.4357 373.8064 680.2421 0.5000 302.5032 0.5000 369.0093 1.0000 0.9980 0.0063 0.0044 1.0027 492.2095 C12 C21
61.6509 334.6509 611.0219 370.7659 336.0620 372.2138 708.2758 0.5500 331.7493 0.4500 367.4371 1.0000 0.9980 0.0063 0.0044 1.0022 502.5656 0 0.47
61.5584 334.5584 609.1638 369.2178 365.4983 370.6158 736.1141 0.6000 360.8078 0.4000 365.8596 1.0000 0.9980 0.0063 0.0044 1.0017 512.8834 P 1.013
61.4650 334.4650 607.2902 367.6585 394.7386 369.0064 763.7451 0.6500 389.6729 0.3500 364.2709 1.0000 0.9980 0.0063 0.0044 1.0013 523.1559
61.3703 334.3703 605.3975 366.0849 423.7783 367.3829 791.1611 0.7000 418.3398 0.3000 362.6682 1.0000 0.9980 0.0063 0.0044 1.0010 533.3790
61.2743 334.2743 603.4826 364.4946 452.6119 365.7426 818.3545 0.7500 446.8035 0.2500 361.0489 1.0000 0.9980 0.0063 0.0044 1.0007 543.5491
61.1769 334.1769 601.5430 362.8857 481.2344 364.0836 845.3181 0.8000 475.0587 0.2000 359.4113 1.0000 0.9980 0.0063 0.0044 1.0004 553.6630
61.0778 334.0778 599.5771 361.2566 509.6405 362.4046 872.0451 0.8500 503.1002 0.1500 357.7538 1.0000 0.9980 0.0063 0.0044 1.0002 563.7180
60.9672 333.9672 597.3879 359.4449 537.6491 360.5428 898.1919 0.9000 530.7494 0.1000 355.9159 1.0000 0.9980 0.0063 0.0044 1.0001 573.5200
60.8621 333.8621 595.3144 357.7309 565.5487 358.7789 924.3275 0.9500 558.2909 0.0500 354.1746 1.0000 0.9980 0.0063 0.0044 1.0000 583.3986
60.7649 333.7649 593.4001 356.1504 593.4001 357.1484 950.5485 1.0000 585.7849 0.0000 352.5650 1.0000 0.9980 0.0063 0.0044 1.0000 593.4001

T-xy diagram for A/B

T-X1Y1 79
78 x 1.0133 bar
80
77 y 1.0133 bar

76
75
75
74
73

72
70
71
70
Temperature, C

69
65
68
T

67
66
60
65

64
63
55
62
61
60
50
0 0.25 0.5 0.75 1
59

58
X1Y1
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00
Liquid/vapor mole fraction, A

16
 T PS1 PS2 P1 P2 PT
64.50 0.89 0.57 #DIV/0! 0.57 #DIV/0!
2.00 0.07 0.02 0.00 0.02 0.02
1.00 0.06 0.02 0.00 0.02 0.02
1.00 0.06 0.02 0.00 0.01 0.01
1.00 0.06 0.02 0.00 0.01 0.01
1.00 0.06 0.02 0.00 0.01 0.01
1.00 0.06 0.02 0.00 0.01 0.01
1.00 0.06 0.02 0.00 0.01 0.01
1.00 0.06 0.02 0.00 0.01 0.01
1.00 0.06 0.02 0.00 0.01 0.01
400.00 133.64 530.07 0.00 265.04 265.04
1.00 0.06 0.02 0.00 0.01 0.01
1.00 0.06 0.02 0.00 0.01 0.01
1.00 0.06 0.02 0.00 0.01 0.01
1.00 0.06 0.02 0.00 0.01 0.01
1.00 0.06 0.02 0.00 0.00 0.00
1.00 0.06 0.02 0.00 0.00 0.00
1.00 0.06 0.02 0.00 0.00 0.00
10000.00 7706.75 149847.03 0.00 14984.70 14984.70
1.00 0.06 0.02 0.00 0.00 0.00
1.00 0.06 0.02 0.00 0.00 0.00

T-xy diagram for A/B

79
78 x 1.0133 bar
77 y 1.0133 bar

76
75
74
73
72
71
Temp eratu re, C

70
69

68
67
66
65
64
63

62
61
60
59

58
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00
Liquid/vapor mole frac tion, A
 X1 Y1 X2 Y2 ln g1 ln g2
0.00 #DIV/0! 1.00 0.01
0.05 0.00 0.95 0.00
0.10 0.00 0.90 0.00
0.15 0.00 0.85 0.00
0.20 0.00 0.80 0.00
0.25 0.00 0.75 0.00
0.30 0.00 0.70 0.00
0.35 0.00 0.65 0.00
0.40 0.00 0.60 0.00
0.45 0.00 0.55 0.00
0.50 0.00 0.50 2.62
0.55 0.00 0.45 0.00
0.60 0.00 0.40 0.00
0.65 0.00 0.35 0.00
0.70 0.00 0.30 0.00
0.75 0.00 0.25 0.00
0.80 0.00 0.20 0.00
0.85 0.00 0.15 0.00
0.90 0.00 0.10 147.89
0.95 0.00 0.05 0.00
1.00 0.00 0.00 0.00

x 1.0133 bar
y 1.0133 bar

85 0.90 0.95 1.00

1 2 1 2 1 2
#DIV/0! 1.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0!
1.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0!
1.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0!
1.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0!
1.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0!
1.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0!
1.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0!
1.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0!
1.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0!
1.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0!
1.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0!
1.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0!
1.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0!
1.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0!
1.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0!
1.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0!
1.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0!
1.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0!
1.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0!
1.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0!
1.00 #DIV/0! #DIV/0! #DIV/0! #DIV/0!
12 21 Ytotal
1.00 1.00 #DIV/0!
1.00 1.00 0.00 T.B. C
1.00 1.00 0.00 P Kpa
1.00 1.00 0.00
1.00 1.00 0.00
1.00 1.00 0.00 R cal/molK
1.00 1.00 0.00
1.00 1.00 0.00 A
1.00 1.00 0.00 B
1.00 1.00 0.00 C
1.00 1.00 2.62
1.00 1.00 0.00
1.00 1.00 0.00
1.00 1.00 0.00
1.00 1.00 0.00
1.00 1.00 0.00 Z
1.00 1.00 0.00
1.00 1.00 0.00
1.00 1.00 147.89
1.00 1.00 0.00
1.00 1.00 0.00
 N-HEXANO ETANOL
69 78
101.325
A12 A21

1.9872

4.00139 5.33675
1170.875 1648.22
224.317 230.918

r1 r2

q1 q2

10
L1 L2
 T-xy diagram for A/B
79
78 x 1.0133 bar
77 y 1.0133 bar

76
75

74
73
72
71
Temp eratu re, C

70
69
68
67
66
65

64
63
62

61
60
59
58
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00
Liquid/vapor mole fraction, A
 x 1.0133 bar
y 1.0133 bar

80 0.85 0.90 0.95 1.00

T(K) T(C) x1 y1 VL M
351.45 80.45 0 0
77.925 77.922
349.15 78.15 0.01 0.095 3.240212932 3.244902074
346.35 75.35 0.02 0.193
340.55 69.55 0.06 0.365
339.05 68.05 0.08 0.42
334.95 63.95 0.152 0.532
332.55 61.55 0.245 0.605
331.85 60.85 0.33 0.63 3.48703072 3.489375291
331.5 60.5 0.452 0.64
331.25 60.25 0.588 0.65
331.15 60.15 0.67 0.66
331.4 60.4 0.725 0.67
331.6 60.6 0.765 0.675
332.3 61.3 0.898 0.71
333.35 62.35 0.955 0.745
336.65 65.65 0.99 0.84
339.85 68.85 0.994 0.935 3.733848508 3.733848508
341.85 70.85 1 1
68.300 68.3
W NRTL UNIQUAC UNIFAC
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3.5024423472 2.8301886792 2.979651163 2.830188679

68.9 68.8 68.9
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