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3.1 INTRODUCTION
The distillation process has very large time constant and it is not economically
feasible to implement a new control strategy on an industrial process. It is
often desirable to test the strategy using dynamic computer simulations of the
process. The mathematical models facilitate the evaluation of alternative
process, tuning of controllers, determining the dynamic effects of
disturbances, optimizing plant operation and investigating potential safety
problems without disturbing the actual process [162]. The simulated models
can also be used to rearrange the manipulated and controlled variable pairing
of the process. Dynamic mathematical models are thus essential, efficient and
powerful tools for simulation study of distillation process. In order to represent
realistic operation of the actual continuous distillation process a rigorous non
linear model is required. Such a model is developed using dynamic material
balance, energy balance and enthalpy equations, supported by vapor liquid
equilibrium and physical properties. Luyben [155] used rigorous models for
design and dynamic control of various reactive distillation systems. The
rigorous models are solved with the help of MATLAB programs or ASPEN
technology simulation software. Several other researchers [48][8][28][80] have
also used the mathematical models, developed in ASPEN software, for
design, modeling, simulation and control of distillation processes.
49
means thermal equilibrium is achieved much faster than phase equilibrium.
The detailed mathematical models, modeling assumptions and the simulation
algorithms of these processes are discussed below.
Overhead Vapor
QC
Condenser
Reflux=400 lb-mol/h
15
Reflux
Drum
Distillate
D=200 lb-mol/h
XD= [1.74e-02 9.82 e-01 8.24 e-05 4.93 e-05 6.59 e-10]
NF=5
F=1000 lb-mol/h
Column
]
ZF
XF YF
0.05 0.40
0.60 0.53 3
0.01 0.02
0.30 0.05 2
0.04 0.00 VB
1
Reboiler
50
consideration (figure 3.1) is a hypothetical model [156] having 15 trays and 5th
tray is used as the feed tray. The reboiler heat input to the process is
5.275*109 Joule (5.0*106 Btu) and reflux flow rate is 181.6 kg-mol/h (400.0 lb-
mol/h). The liquid and vapor feed rate is 363.2 kg-mol/h (800 lb-mol/h) and
90.8 kg-mol/h (200 lb-mol/h) respectively. The other column and mixture
details are given in table 3.1. The initial conditions of the distillation process
are given in table 3.2.
51
Table 3.2 Initial conditions for multicomponent mixture
Initial Liquid flow Component concentrations (mole fractions)
Tray No. temp. rate
1 2 3 4 5
( F) (kg-mol/h)
Base-
201.58 0.00 0.00 7.25 e-03 4.88 e-02 8.36 e-1 1.08 e-1
Component
1 154.90 336.00 9.99e-12 1.10e-01 2.40e-01 6.07e-01 4.33e-02
2 132.60 369.74 1.56e-09 2.86e-01 2.02e-01 4.73e-01 3.93e-02
3 120.20 404.97 1.82e-07 4.57e-01 1.31e-01 3.76e-01 3.59e-02
4 114.00 435.88 1.33e-05 5.72e-01 8.03e-02 3.14e-01 3.33e-02
5 108.40 447.64 7.60e-04 6.34e-01 4.96e-02 2.84e-01 3.25e-02
6 101.20 145.28 1.12e-03 8.18e-01 8.66e-02 9.42e-02 1.74e-06
7 98.20 173.38 1.29e-03 9.10e-01 4.46e-02 4.40e-02 7.76e-07
8 96.90 185.95 1.36e-03 9.53e-01 2.38e-02 2.18e-02 3.71e-07
9 96.20 192.34 1.40e-03 9.75e-01 1.28e-02 1.10e-02 1.81e-07
10 95.80 195.76 1.42e-03 9.86e-01 6.94e-03 5.63e-03 8.93e-08
11 95.50 195.58 1.43e-03 9.92e-01 3.74e-03 2.86e-03 4.40e-08
12 95.30 198.62 1.44e-03 9.95e-01 1.99e-03 1.45e-03 2.16e-08
13 95.10 199.17 1.44e-03 9.97e-01 1.04e-03 7.18e-04 1.04e-08
14 94.90 199.53 1.45e-03 9.98e-01 5.19e-04 3.42e-04 4.84e-09
15 94.20 199.12 1.75e-03 9.98e-01 2.36e-04 1.49e-04 2.05e-09
Reflux
77.26 181.60 1.74e-02 9.82 e-01 8.24 e-05 4.93 e-05 6.59 e-10
Drum
52
(v) Murphree stage efficiency based on vapor phase is valid.
(vi) A total condenser and a partial reboiler are assumed to be used. The
reflux drum and reboiler holdups are considered to be well-mixed
pools.
(vii) Metal walls and trays have negligible heat capacity i.e. enthalpy of
metal is considered to be negligible.
(viii) There is a definite relationship between the concentration of a
component in the vapor and liquid leaving each tray and is given by
bubble point calculation.
The mass and energy balance equations are derived by applying
conservation laws to each tray, reboiler and condenser.
The schematic block diagram of condenser is shown in figure 3.2. The rate of
change of reflux drum-level is zero at steady state condition i.e. , this
implies that at any instant the distillate flow is the difference of vapor from last
tray and reflux flow and is given by equation (3.1).
yNT,j
VNT
HNT
R
yNT,j MD
hD
VNT D xD j
HNT
(3.1)
Component material balance for condenser is given by
53
for (3.2)
where
= No. of trays
= No. of components
= Liquid molar holdup in the reflux drum, lb-mol
= Distillate flow rate, lb-mol/h
= Liquid fraction of component in reflux drum, %mole fraction
= Vapor fraction of component leaving tray , %mole fraction
= Total liquid flow rate entering the tray from reflux drum, lb-mol/h
= Total vapor flow rate leaving the tray , lb-mol/h
The schematic block diagram of general tray is shown in figure 3.3 and the
component material balance for tray is given by
Vi Li+1
yi,j xi+1,j
Hi
hi+1
hFi Fi xFi
Mi
Vi-1 Li
xi,j
yi-1,j
Hi-1 hi
(3.3)
for
where
= Molar liquid holdup on tray , lb-mol
= Liquid fraction of component leaving the tray , %mole fraction
= Total liquid flow rate leaving tray , lb-mol/h
54
= Total vapor flow rate leaving tray , lb-mol/h
= Total feed flow rate injected to tray , lb-mol/h
= Liquid fraction of component in feed on tray , %mole fraction
where
= Length of the weir, ft
= Net area of the tray, ft2
= Height of the weir, ft
= Average molar density of liquid on tray , lb-mol/ft3
= Liquid flow rate from tray , lb-mol/h
The schematic diagram of reboiler is shown in figure 3.4. The rate of change
of reboiler holdup is zero at steady state condition i.e. , that is, at any
instant t, the bottom product rate will be the difference of liquid entering from
first tray and vapor leaving the reboiler and is given by
(3.6)
Component material balance for reboiler is given by
for (3.7)
55
where
= Liquid molar holdup in reboiler, lb-mol
= Total liquid flow rate from tray 1 entering to reboiler, lb-mol/h
= Liquid fraction of component in bottom product, %mole fraction
= Total vapor flow rate leaving reboiler, lb-mol/h
= Vapor fraction of component leaving reboiler, %mole fraction
= Total bottom product rate, lb-mol/h
Tray-1
L1 , x1,j
HB h1
VB, yB,j
MB Reboiler
QB B , hB, xB,j
for (3.9)
where
= Total molar holdup on tray , lb-mol
= Total liquid flow rate leaving tray , lb-mol/h
= Total liquid flow rate entering tray , lb-mol/h
56
= Total vapor flow rate leaving tray , lb-mol/h
= Total vapor flow rate entering tray , lb-mol/h
= Total feed flow injected on tray , lb-mol/h
The enthalpy is defined as the total internal energy and is given by the
product of pressure and volume. The energy dynamics is assumed to be so
rapid that the enthalpy balance reduces to an algebraic equation. This means
that thermal equilibrium is attained much faster than phase equilibrium. Using
the definition, the enthalpy balance for condenser is given by
(3.10)
where
= Total molar enthalpy of vapor leaving the last tray, kJ/lb-mol
= Total molar enthalpy of liquid leaving the reflux drum, kJ/lb-mol
= Condenser duty, kW
The enthalpy balance for general tray i is given by the following equation.
(3.11)
for
where
Total molar enthalpy of liquid leaving tray , kJ/lb-mol
Total molar enthalpy of vapor leaving tray , kJ/lb-mol
The enthalpy balance for reboiler is given by the equation given below.
(3.12)
where
57
Reboiler duty, Btu/h
Total molar enthalpy of liquid leaving reboiler, kJ/lb-mol
Total molar enthalpy of vapor leaving reboiler, kJ/lb-mol
Enthalpies of liquid and vapor on tray are calculated by mixing rule and are
given by
(3.13)
(3.14)
where and represent pure component enthalpies of component on
tray in liquid and vapor phase respectively.
A tray is said to be in equilibrium, when the tray temperature satisfy bubble
point relation, and calculated using equations (3.15a), (3.15b) and (3.15c) as
follows. Using Raoults law the component vapor pressure is given by
(3.15a)
where
= Vapor pressure of component on tray , kPa
= Constants for component on tray
Tray temperature of be calculated, F
The vapor fraction is related to liquid fraction using component vapor pressure
and total pressure by following equation.
(3.15b)
where
= Total vapor pressure on tray , kPa
= Liquid fraction of component on tray , %mole fraction
(3.15c)
where
= Vapor fraction of component on tray , %mole fraction
The bubble point relationship is satisfied by an iterative procedure.
58
3.3 SIMULATION FLOWCHART FOR MULTICOMPONENT DISTILLATION
PROCESS
Input Data
(column size, components,
physical properties, feeds etc.)
Compute derivatives of
component continuity equations
59
Arfaj and Luyben [155][28][29]. The reversible exothermic liquid-phase
reaction is given as:
The vapor liquid equilibrium is assumed to be ideal. The relative volatilities of
the reactants and product components are considered to be constant and the
reactants are intermediate boiling between the two product components. The
volatilities of the different components are given as , ,
and . The heat of reaction is -10000 cal/mol and heat of vaporization is
6944 cal/mol. The forward and reverse reaction rates are specified as 0.008
kmol s1 kmol1 and 0.004 kmol s1 kmol1 at 366 K.
Nr = 5
Nrx = 9
Ns = 5
R P
P = 8 bar
Vs = 28.82mol/s 356.5K
RR = 2
ID = 0.797m
Nr
387.6 K D
FOB=12.6mol/s
D = 12.6 mol/s
XD,A = 0.0417
Nrx XD,B = 0.0083
XD,C = 0.9500
394.5 K XD,D = 0.0000
FOA=12.6mol/s
Ns
431.5 K
B = 12.6 mol/s
XB,A = 0.0083
Vs XB,B = 0.0417
XB,C = 0.0000
XB,D = 0.9500
Figure 3.6 Schematic diagram of reactive distillation process with complete details
60
The control objective for the distillation process is to obtain 95% purity in the
product. There are 5 trays in stripping section, 9 trays in reactive section and
5 trays in rectifying section of the column. The column is fed with two pure
reactants fresh feed streams: and . The light reactant A is fed to the
bottom tray of the reactive zone (tray 6), while the heavy reactant B is
introduced at the top of the reactive section (tray 14). The light product C
leaves in the distillate, while the heavy product D is removed in the bottoms.
Reactive tray holdup is 1000 mol, reflux flow rate is 32.78 mol/s and column
operates at a pressure of 8 bar.
Tray A B C D
1 0.00164 0.04839 0 0.9499
2 0.051 0.051 0 0.898
3 0.128 0.069 0 0.803
4 0.24 0.079 0 0.681
5 0.375 0.075 0.004 0.546
6 0.478 0.057 0.01 0.455
7 0.529 0.038 0.02 0.413
8 0.387 0.079 0.032 0.502
9 0.29 0.14 0.045 0.525
10 0.225 0.23 0.065 0.48
11 0.17 0.336 0.081 0.413
12 0.124 0.45 0.099 0.327
13 0.087 0.562 0.12 0.231
14 0.051 0.667 0.13 0.149
15 0.04 0.731 0.15 0.079
16 0.057 0.688 0.212 0.043
17 0.09 0.553 0.347 0.01
18 0.1 0.347 0.547 0.004
19 0.089 0.164 0.732 0
20 0.064 0.064 0.872 0
21 0.04839 0.00164 0.9499 0
61
physical properties and vapour-liquid equilibrium parameters are given in
table 3.4 to table 3.6.
Composition A B C D
(mol fraction)
Distillate 0.04755 0.00246 0.94999 0.00000
Bottoms 0.00164 0.04839 0.00000 0.94999
62
Table 3.6 Steady state temperatures of the column
The net reaction rate for component j on tray i in the reactive zone is given by
63
(3.16)
for
where
= No. of trays
= No. of components
= Rate of reaction on the tray for component , mol/s
= Stoichiometric coefficient of component
= Molar holdup on tray , mol
= Forward specific reaction rate on tray , kmol s-1 kmol-1
= Backward specific reaction rate on tray , kmol s-1 kmol-1
= Mole fraction of component A on tray
= Mole fraction of component B on tray
= Mole fraction of component C on tray
= Mole fraction of component D on tray
The forward and backward specific reaction rates on tray are as follows:
(3.17)
(3.18)
where
= Activation energy for forward reaction, cal/mol
= Activation energy for backward reaction, cal/mol
= Temperature on tray i, K
= Universal gas constant, cal/(mol K)
= Rate constant for forward reaction
= Rate constant for backward reaction
64
therefore, the vapor rate increases up through the reactive trays and the liquid
rate decreases down through the reactive trays.
for (3.19)
for (3.20)
where
= Vapor flow rate at tray , mol/s
= Liquid flow rate at tray , mol/s
= Heat of vaporization, cal/mol
= Heat of reaction, cal/mol
for (3.21)
where
= Liquid fraction of component in reflux drum, %mole fraction
= Liquid molar holdup in the reflux drum, mol
= Vapor flow rate at tray , mol/s
= Vapor fraction of component j leaving tray , %mole fraction
= Distillate flowrate, mol/s
= Reflux ratio
(3.22)
for
where
= Liquid fraction of component leaving tray , %mole fraction
= Liquid molar holdup on tray mol
65
= Liquid flow rate leaving tray , mol/s
= Vapor flow rate leaving tray , mol/s
Vapor fraction of component leaving tray , %mole fraction
(3.23)
(3.24)
where
= Input feed flow rate on feed tray , mol/s
= Liquid fraction of component in feed on tray , % mole fraction
(3.25)
where
= Liquid molar holdup in reboiler, mol
= Total liquid flow rate from tray 1 entering to reboiler, mol/s
= Liquid fraction of component in bottom product, %mole fraction
= Total vapor flow rate leaving reboiler, mol/s
= Vapor fraction of component leaving reboiler, %mole fraction
= Bottom flow rate, mol/s
(3.26)
where
= Antione constant for component
66
= Antione constant for component
= Pressure in the column, bar
= Relative volatility for component
With the equimolal overflow mentioned above, the vapor flow rates in the
stripping section are equal to and liquid rates equal to . Analogously,
and are the vapor flow rates and liquid flow rates respectively in rectifying
section. With pressure and tray liquid composition known at each point
in time on each tray, the temperature and the vapor composition can be
calculated. This bubble point calculation can be solved by a Newton-Raphson
iterative convergence method.
(3.27)
(3.28)
where
= Pure vapor pressure of component
Liquid fraction of component leaving tray , %mole fraction
Vapor fraction of component leaving tray , %mole fraction
67
Input Data
(column size, components,
physical properties, feeds etc.)
Compute derivatives of
component continuity equations
68
(generally in minutes). As the time constant of distillation process is large, a
fast and efficient controller is needed so that the overall time constant of the
system is not reduced further. The time shown in the results (in seconds) is
the time taken by PC for simulation. A second in the simulation may be
considered nearly equivalent to minutes in a real time process.
0.8
X1 (lit)
X2 (lit)
X3 (lit)
mole fraction
0.6 X4 (lit)
X5 (lit)
X1 (sim)
0.4 X2 (sim)
X3 (sim)
X4 (sim)
0.2 X5 (sim)
0 5 10 15
tray number
160
literature
simulated
150
140
tray temperature (deg. F)
130
120
110
100
90
0 5 10 15
tray number
69
1
X1(lit)
0.9 X2(lit)
X3(lit)
0.8 X4(lit)
X1(sim)
0.7 X2(sim)
X3(sim)
0.6
mole fraction
X4(sim)
0.5
0.4
0.3
0.2
0.1
0
0 2 4 6 8 10 12 14 16 18 20
tray number
440
420
400
temperature(K)
380
360
TEMPERATURE(Reference)
340 TEMPERATURE(Simulated)'
320
300
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19
tray number
70
the process models are validated. The results also show that component X2 is
obtained in distillate and X4 is obtained in bottom in case of multi component
distillation process. In the reactive distillation process X3 (component C) is
obtained in distillate and X4 (component D) is obtained in bottom. The
simulation data thus obtained is used by soft sensors to model the input-
output behavior of the system. It is also found that the composition and
temperature profiles of the two processes are highly nonlinear. Hence there is
a need of highly robust and efficient controllers to achieve the desired control
objective.
3.7 CONCLUSION
INTERNET
SWITCH
The present work uses the semirigorous models of the distillation processes.
The mathematical models of the processes are simulated in MATLAB and the
dynamic issue of the distillation process is also discussed. The developed
models are validated against the results available in literature. The artificial
intelligent techniques are used in the composition measurements as well as
control of distillation processes, the results obtained are discussed in the next
chapter.
71
72