1

NATIONAL JUNIOR COLLEGE

SH2 PRELIMINARY EXAM
Higher 2

CANDIDATE
NAME

SUBJECT REGISTRATION
CLASS NUMBER

CHEMISTRY 9647/01
Paper 1 Multiple Chi!e
Thu 19 Sep 201!
A""iti#al Material$% Multiple Chi!e A#$&er Sheet
1 h"u#
Data B'let

REA$ THESE INSTRUCTIONS %IRST

(rite i# $)t pe#!il*

D #t u$e $taple$+ paper !lip$+ highlighter$+ glue r !rre!ti# )lui"*

(rite ,ur #a-e+ $u./e!t !la$$ a#" regi$trati# #u-.er # the A#$&er Sheet i# the $pa!e$
pr0i"e" u#le$$ thi$ ha$ .ee# "#e )r ,u*

There are 40 ue$ti#$ # thi$ paper* A#$&er &'' ue$ti#$* r ea!h ue$ti# there are )ur
p$$i.le a#$&er$ A+ (+ C a#" $*

Ch$e the ")e ,u !#$i"er !rre!t a#" re!r" ,ur !hi!e i# *"+ pe),-' # the $eparate
A#$&er Sheet*

Re&. he -)*#u,-")* ") he A)*e# Shee e# ,&#e+u''

Ea!h !rre!t a#$&er &ill $!re #e -ar'* A -ar' &ill #t .e "e"u!te" )r a &r#g a#$&er*
A#, rugh &r'i#g $hul" .e "#e i# thi$ .'let*

This paper consists of 19 printed pages and 0 blank page.

Se,-") A

NJC/H2 Che3/01/201! Tu#) "e#

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r ea!h ue$ti# there are )ur p$$i. le a#$&er$ A+ (+ C+ a#" $* Ch$e the #e ,u
!#$i"er t .e !rre!t*

1 (hi!h #e ) the )l l&i#g repre$e#t$ the ! #)igurati# ) the thr ee ele!tr#$ )

highe$t e#erg, )r the gru#" $tate ) a# ele-e#t i# grup III3

A 1$2 2$1
( 1$1 2$1 2p1
C 2$1 2p2
$ 4$2 4p1

2 The rst ionisation energies of twenty successive elements in the Periodic

Table are represented in the graph.
The letters given are not the normal symbols for these elements.

)ir$t i#i$ati#
e#erg,
8'J -l1

(hi!h $tate-e#t a.ut the ele-e#t$ a#" their !-pu#"$ i# thi$ graph i$ )" true3

A O5i"e a#" h,"r5i"e ) ele-e#tM are a-phteri!*

( O5i"e ) ele-e#t % ha$ a gia#t !0ale#t latti!e $tru!ture*

C Ele-e#t$ (+ J a#" R are i# Grup 6 ) the Peri"i! Ta.le*

$ The $e!#" i#i$ati# e#erg, ) 5 i$ larger tha# the $e!#" i#i$ati# e#erg, ) L*

! I# a# e5peri-e#t+ a .ea- ) prt#$ &a$ pa$$e" thrugh a# ele!tri! )iel" ) !#$ta#t

$tre#gth* A#al,$i$ ) the "e)le!ti# !!urri#g at the ele!tri! )iel" regi# re0eale" a#
a#gle ) "e)le!ti# ) 127 t&ar"$ the #egati0e plate*

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 !

prt#$

12

U#"er i"e#ti!al !#"iti#$+ a .ea- ) parti!le$+ + ea!h ha0i#g 24 ti-e$ the -a$$ ) a
prt#+ &a$ "e)le!te" ., a# a#gle ) 1 t&ar"$ the p$iti0e plate*

(hat i$ the 0erall !harge # a parti!le ) 3

A 92
( 9:
C ;:
$ ;2

4 Use of the Data Booklet is relevant to this question.

A t,pi!al $li" )ertili$er )r u$e &ith hu$ehl" pla#t$ a#" $hru.$ !#tai#$ the ele-e#t$
N+ P+ a#" < i# the rati ) 1= g % :6 g % 1= g per 166 g ) )ertili$er* The re!--e#"e"
u$age ) )ertili$er i$ 14 g ) )ertili$er per = "-: ) &ater*

(hat i$ the !#!e#trati# ) #itrge# at-$ i# thi$ $luti#3

A 6*6: -l "-;:
( 6*6= -l "-;:
C 6*42 -l "-;:
$ 6*>= -l "-;:

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5 0.200 mol of a hydrocarbon undergo complete combustion to give 35.2 g of

carbon dioide and !"." g of water as the only products.

#hat is the molecular formula of the hydrocarbon$

A C2H4
( C2H?
C C4H4
$ C4H@

6 The i#$ P:;+ S2; a#" Cl; ha0e ra"ii 6*212#-+ 6*1@4#- a#" 6*1@1#- re$pe!ti0el,*

(hi!h #e ) the )ll&i#g !rre!tl, e5plai#$ the "e!rea$e$ i# ra"iu$ gi#g )r- P :; t
Cl;3

A A# i#!rea$e i# .th the ttal #u-.er ) ele!tr#$ a#" the #u!lear !harge
( A# i#!rea$e i# the ttal #u-.er ) ele!tr#$ &ith the #u!lear !harge re-ai#i#g
!#$ta#t
C A !#$ta#t ttal #u-.er ) ele!tr#$ a#" a# i#!rea$e i# the #u!lear !harge
$ A "e!rea$e i# the ttal #u-.er ) ele!tr#$ &ith the #u!lear !harge re-ai#i#g
!#$ta#t

7 (hi!h ) the )ll&i#g $pe!ie$ "e$ )" ha0e a .#" a#gle ) 126 aru#" the !e#tral
at-$3

A AlCl:
( CH:9
C PH:
$ N2O4

I# &hi!h pr!e$$ are h,"rge# .#"$ .r'e#3

A 2H2Ol 2H2g 9 O2g

( CH:CH2OHl CH:CH2OHg
C NH:a 9 H2Ol NH49a 9 OH%a

$ CH:COOHa 9 NaOHa CH:COONaa 9 H2Ol

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9 The euati# .el& repre$e#t$ the !-.i#ati# ) ga$eu$ at-$ ) ##-etal X a#"
) h,"rge# t )r- ga$eu$X2H? -le!ule$*

2 Xg 9 ? Hg X2H?g H F ;2>>= 'J -l;1

The .#" e#erg, ) a#X;H .#" i$ := 'J -l;1*

(hat i$ the .#" "i$$!iati# e#erg, ) a# X;X .#"3

A ;46=*6 'J -l;1

;1
( ;262*= 'J -l
C 9262*= 'J -l;1
$ 946=*6 'J -l;1

10 (hi!h ) the )ll&i#g $tate-e#t$ a.ut latti!e $tru!ture$ i$ ,"##e,3

A The latti!e e#erg, ) a# i#i! !r,$tal te#"$ t .e large i) the $ie$ ) the t& t,pe$
) i#$ i#0l0e" are $-all*
( The parti!le$ !!up,i#g latti!e $ite$ -a, .e at-$ r i#$ .ut #t -le!ule$*
C The )r!e$ hl"i#g the latti!e tgether are $ $tr#g that the parti!le$ !!up,i#g
latti!e $ite$ are hel" $tati#ar,*
$ The latti!e e#erg, ) a# i#i! !r,$tal i$ al&a,$ larger tha# that ) a -etal*

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11 The "iagra- $h&$ the Br#Ha.er !,!le )r the )r-ati# ) -ag#e$iu- )luri"e*

Mg$ 9 2g Mg2$

H1 H2

Mg29g 9 2g

Hat- % E#thalp, !ha#ge ) at-iati# I*E % I#i$ati# e#erg,

E*A % Ele!tr# A))i#it, B*E % B#" e#erg,

(hi!h ) the )ll&i#g repre$e#t$ the !rre!t e#erg, !ha#ge$+ H1 a#" H23

H1 H2

A Hat- ) Mg 9 1 a#" 2 E
$t #"
*A)Mg 2 Hat- ) 2 9 21$t I*E )

( Hat- ) Mg 9 1 $t a#" 2#"I *E)Mg 2B*E) 2 9 21$t E*A )

C Hat- ) Mg 9 1$t a#" 2I*E

#"
) Mg 2 Hat- ) 2 9 21$t I*E )

$ Hat- ) Mg 9 1 $t a#" 2#" I*E ) Mg B*E ) 2 9 21$t E*A )

12 2= ) a $luti# ) etha#i! a!i" &a$ !#0erte" t etha#ate i#$ ., rea!ti# &ith

$"iu- h,"r5i"e $luti# at 2= C*

(hat i$ the <a ) etha#i! a!i" at 2= C gi0e# that the pH ) the $luti# &a$ )u#" t
.e 4*2@3

A 1*=> 16%4
( 1*:1 16%=
C 1*>= 16%=
$ =*24 16%=

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1! The $lu.ilit, ) ir#II !ar.#ate i# &ater at 2= C i$ =*= 16%? -l "-%:*

(hat i$ the #u-eri!al 0alue ) the $lu.ilit, pr"u!t )r ir# II !ar.#ate &he#
"i$$l0e" i# a 6*61 -l "-%: $luti# ) ir#II !hlri"e at 2= C3

A =*= 16%@
( =*= 16%16
C :*12 16%
$ :*12 16%11

14 The )ll&i#g "ata i$ .tai#e" "uri#g the )ir$t r"er ther-al "e!-p$iti# )
2Ag (g 9 C$
at !#$ta#t 0lu-e a#" te-perature*

Ti-e Ttal pre$$ure i# Pa$!al

At the e#" ) 16 -i#ute$ ) rea!ti# ?66
A)ter !-pleti# ) rea!ti# 466

(hat i$ the rate !#$ta#t )r thi$ rea!ti# i# -i#13

A !a##t .e "eter-i#e" "ue t i#$u))i!ie#t "ata

( 6*6:4?
C 6*6?:
$ 6*1:@

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18 The !ur0e Y a#" the 0alue Ea repre$e#t the "i$tri.uti# ) e#ergie$ ) the -le!ule$
a#" the a!ti0ati# e#erg, )r a# u#!atal,$e" ga$eu$ rea!ti#*

(hat i$ a p$$i.le ut!-e i) the rea!ti# i$ !atal,$e"3

A The "i$tri.uti# ) e#ergie$ &ill .e gi0e# ., !ur0e Y a#" the a!ti0ati# e#erg, .,
0alue :*
( The "i$tri.uti# ) e#ergie$ &ill .e gi0e# ., !ur0e Y a#" the a!ti0ati# e#erg, .,
0alue ;*
C The "i$tri.uti# ) e#ergie$ &ill .e gi0e# ., !ur0e X a#" the a!ti0ati# e#erg, .,
0alue ;*
$ The "i$tri.uti# ) e#ergie$ &ill .e gi0e# ., !ur0e < a#" the a!ti0ati# e#erg, .,
0alue :*

16 Duri#g the ele!trl,$i$ ) -lte# alu-i#iu- 5i"e t pr"u!e alu-i#iu-+ u$i#g graphite
!ar.# ele!tr"e$+ t& !#$e!uti0e rea!ti#$ !!ur at the a#"e+ ea!h pr"u!i#g a
"i))ere#t ga$*

H& "e$ the 5i"ati# #u-.er ) 5,ge# !ha#ge i# the$e rea!ti#$3

A "e!rea$e$ ., 2+ the# i#!rea$e$ ., 2

( i#!rea$e$ ., 2+ the# "e!rea$e$ ., 2
C i#!rea$e$ ., 2+ the# "e!rea$e$ ., 4
$ # !ha#ge+ the# "e!rea$e$ ., 2

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17 E1+ E2 a#" E: are the e-) 0alue$ ) the three gal0a#i! !ell$ I+ II a#" III re$pe!ti0el,*

Cell I K# K#29 1 -l "-: 88 Cu29 6*1 -l "-: Cu

Cell II K# K#29 1 -l "-: 88 Cu29 1 -l "-: Cu
Cell III K# K# 6*1 -l "- 88 Cu29 1 -l "-: Cu
29 :

All the $tate-e#t$ are true e5!ept

A The e-) ) the three !ell$ are ) the r"er % E: E2 E1

( The plarit, ) the !pper ele!tr"e i$ p$iti0e #l, i# !ell II a#" III*

C The !lur ) the $luti# )a"e$ i# #e ) the !-part-e#t$ ) ea!h !ell*

$ Ele!tr#$ )l& )r- the i#! ele!tr"e t the !pper ele!tr"e i# all the three
!ell$*

1 The i#)r-ati# relate$ t ele-e#t <*

< i$ i# Peri" : ) the Peri"i! Ta.le*

< ha$ a l&er ele!tri!al !#"u!ti0it, tha# Mg*
A < at- ha$ a hal))ille" $u.$hell i# it$ gru#" $tate*
< )r-$ a# a!i"i! 5i"e # e5p$ure t air*

(hat i$ <3

A Na

( Si

C P

$ Cl

19 Sul)ur i$ !#0erte" t S? ., )luri#e+ t SCl2 ., !hlri#e a#" t S 2Br2 ., .r-i#e*

(hi!h tre#" "e$ thi$ i#)r-ati# .e$t pr0i"e e0i"e#!e )r3

A the tre#" i# .#" e#erg,% Cl2 Br2 2

( the tre#" i# ele!tr#egati0it,% Cl Br

C the tre#" i# )ir$t i#i$ati# e#erg,% C l Br

$ the tre#" i# 5i"i$i#g a.ilit,% 2 Cl2 Br2

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20 An en zym
e is compl
etel
y denat
uredat50 C. A xed con
cen
tr
ati
onoft his enzym
e is
added to a xed concent
rat
i
on of it
s su bst
r
ate. The t
i
me take
n f or co
mplet
i
on of het
react
i
on is measu
red at di
er
ent t
emperat
ures.

Whi
chgr
ap
h sho
ws he
t resu
l
t
s?

21 O#e ) the rea!ti#$ ta'i#g pla!e i# a !atal,ti! !#0erter i# a !ar e5hau$t $,$te- i$
.et&ee# #itrge# 5i"e a#" !ta#e u#.ur#e" petrl* The pr"u!t$ ) thi$ rea!ti# are
##t5i!*

(hi!h i$ the !rre!t euati# )r the rea!ti#3

A C@H1? 9 1? NO @ CO 9 @ N 2 9 @ H2O
( C@H1? 9 24 NO @ CO2 9 12 N2 9 @ H2O
C C@H1@ 9 1> NO @ CO 9 @ N2 9 H2O
$ C@H1@ 9 2= NO @ CO2 9 12 N 2 9 H2O

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22 The pr"u!t$ .tai#e" ., !ra!'i#g a# al'a#e+ M+ are -etha#e+ ethe#e a#" prpe#e*
The -le )ra!ti# ) ethe#e i# the pr"u!t$ i$ 6*=*
(hat i$ the i"e#tit, ) M3
A C?H14
( C@H1@
C CH26
$ C11H24

2! (hat i$ the ttal #u-.er ) i$-er$ i#!lu"i#g $terei$-er$ )r a# rga#i! !-pu#"+

C4H3
A :
( 4
C =
$ ?
24 #hat causes carbonyl groups& '()& to react by a nucleophilic mechanism
while alkene groups& '('& react by an electrophilic mechanism$

A 5,ge# i$ -re rea!ti0e tha# !ar.#

( the "i))ere#t le#gth$ ) the "u.le .#"$

C the relati0e $tre#gth$ ) the "u.le .#"$

$ the ele!tr#egati0it, "i))ere#!e .et&ee# the !ar.# a#" 5,ge# at-$ i# the
!ar.#,l grup

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28 C#$i"er the )ll&i#g )ur !-pu#"$*

1 2#itrphe#l
2 .e#i! a!i"
! 2!hlr.e#i! a!i"
4 !,!lhe5a#l

(hat i$ the relati0e r"er ) "e!rea$i#g a!i"it, ) the$e !-pu#"$3

M$ta!i"i! Lea$ta!i"i!

A :241
( :214
C 2:41
$ 2:14

26 A pr"u!t P i$late" )r- a #aturall,;!!urri#g $ur!e i$ e$ta.li$he" a$ ha0i#g a

-le!ular )r-ula ) C@HNO:* It p$$e$$e$ a !hiral !e#tre a#" it )r-$ a &itteri#*
(hi!h #e ) the )ll&i#g $tru!ture$ !ul" .e P3
NH2

A HO CH
COOH

OH

( O2N CH
CH:

HO CH 2NH2
C
COOH

H2N CH2OH
$

COOH

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27 Sa#t#i# i$ a "rug that &a$ #!e &i"el, u$e" t e5pel para$iti! &r-$ )r- the .",*

$a#t#i#

(he# $a#t#i# i$ )ir$t treate" &ith &ar- "ilute H 2SO4+ )ll&e" ., !l" a!i"i)ie" <M#O4+
X i$ .tai#e"*

H& -a#, at-$ ) h,"rge# i# ea!h -le!ule ) X !a# .e "i$pla!e" &ith $"iu-
-etal3

A 2 ( 4 C = $ *

2 (he# a# i$-er % ) -le!ular )r-ula C 4HBr u#"erge$ h,"rl,$i$ i# aueu$ al'ali

t )r- a# al!hl C4HOH+ the rate ) rea!ti# i$ )u#" t .e u#a))e!te" ., !ha#ge$ i#
the !#!e#trati# ) OH; i#$ pre$e#t*

(hi!h i$ the -$t li'el, -le!ular $tru!ture ) %3

A CH:CH2CH2CH2Br
( CH:CH2CHBrCH:
C CH:2CHCH2Br
$ CH::CBr

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29 The )ir$t $tage i# the $,#the$i$ ) a#tip,ri#e+ a "rug u$e" i# re"u!i#g )e0er+ i$ the
rea!ti# .et&ee# !-pu#" P a#" phe#,lh,"rai#e*

CH :COCH2CO2CH2CH: 9 NHNH 2 6

P phe#,lh,"rai#e

(hat i$ the $tru!ture ) 3

NHN
C
A
CH:COCH2CO NHNH2
CH:CCH2CO2CH2CH:

$
( CH
NHCH :COCH
2CO 2CONH
2CH2CH :

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!0 The rea!ti# !#"iti#$ )r )ur "i))ere#t tra#$)r-ati#$ are gi0e# .el&*

(hi!h tra#$)r-ati# &ill !!ur u#"er the gi0e# !#"iti#$3

OH OCOCH :
CH:COOHAl+ !#! H2SO4

A heat

t CH:
CH:
Br2Aa+ eBr:
Br
(
:6C

OH NaA$ O
Al Br
Br
C
Br

<CN+ H2SO4Aa
$ CH:CH2Br heat CH:CH2CN

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 16

Se,-") (

r ea!h ) the ue$ti#$ i# thi$ $e!ti#+ #e r -re ) the three #u-.ere" $tate-e#t$ 1 t
! -a, .e !rre!t* De!i"e &hether ea!h ) the $tate-e#t$ i$ r i$ #t !rre!t ,u -a, )i#" it
help)ul t put a ti!' agai#$t the $tate-e#t$ that ,u !#$i"er t .e !rre!t*

The re$p#$e$ A t $ $hul" .e $ele!te" # the .a$i$ )

A(C$

1+2+ a#" ! are 1 a#" 2 #l, are 2 a#" ! #l, are 1 #l, i$ !rre!t
!rre!t !rre!t !rre!t

N ther !-.i#ati# ) $tate-e#t$ i$ u$e" a$ a !rre!t re$p#$e*

!1 (hi!h ) the e#thalp, !ha#ge$ ) the )ll&i#g rea!ti#$ !a# #l, .e .tai#e" .,
appli!ati# ) He$$ La&3

1 The h,"rati# ) a#h,"ru$ !pper $ul)ate t )r- !r,$tal$ ) CuSO4*=H2O*

2 The )r-ati# ) -etha#e )r- it$ ele-e#t$*
! The !-.u$ti# ) glu!$e+ C ?H12O?*

32 Str#tiu- -etal !a# .e .tai#e" ., the ele!trl,$i$ ) -lte# $tr#tiu- .r-i"e+

SrBr2+ u$i#g the apparatu$ $h&# i# the "iagra-*

$teel ele!tr"e

graphite ele!tr"e

#hich statements concerning the electrolysis are true$

1 1: !ul-.$ ) ele!tri!it, are #ee"e" t "ep$it 1 16 : -l ) $tr#tiu- at-$

at the a#"e*
2 The regi# aru#" the graphite ele!tr"e tur#$ ,ell& ; ra#ge*
! #ithout the atmosphere of argon& strontium oide would be formed.

33 (he# light i$ $h#e )r a )i5e" peri" i#t a $luti# ) CH 2I CH2I a#" I2 i#

tetra!hlr-etha#e at 166C+ the )ll&i#g rea!ti# !!ur$%

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CH2ICH2I CH2FCH2 9 I2

Relati0e i#itial !#!e#trati# Relati0e i#itial

Relati0e light
e5peri-e#t rate ) )r-ati#
C2H4I2 I2 i#te#$it,
) I2
1 2 1 4 2
2 2 1 1 1
: 1 1 4 1
4 1 2 4 1

#hat conclusions about the reaction can be drawn from the data in the
table$

1 The r
ate of f
ormat
ion of i
odi
ne i
s p
r
opor
ti
onal t
o i
ni
ti
al co
nc
Ce
2n
Ht
4r
Ia
2t
*i
on of
2 The r
ate of f
ormat
ion of i
odi
ne i
s p
r t
opori
(l
o
in
ga
hl
tti
o
ntens
it
y).
! I"i#e i$ #t i#0l0e" i# the rate "eter-i#i#g $tep*

34 I# .la!' a#" &hite phtgraphi! )il-+ light !#0ert$ $il0er !hlri"e i#t -etalli! $il0er*
A)ter the )il- ha$ .ee# "e0elpe"+ the u#e5p$e" $il0er !hlri"e i$ re-0e" .,
rea!ti# &ith $"iu- thi$ul)ate t pr"u!e a )i5e" #egati0e*

The pr
oce
ss ca
n b
e e
rpr
ese
nt
ed by he
t o
fl
l
owi
ng t
wo r
eact
i
ons:

2AgCl 2Ag l+ 2 C
AgCl 9 2Na2S2O: 4Na9 9 Cl ; 9 AgS2O:2Q:;

(hi!h $tate-e#t$ a.ut the rea!ti#$ are !rre!t3

1 Bth rea!ti#$ i#0l0e a !ha#ge ) 5i"ati# #u-.er*

2 The rle ) $"iu- thi$ul)ate i$ t -a'e the $il0er i#$ $lu.le*
! +oth reactions have positive , values.

!8 C#$i"er the $pe!ie$ i# the )ll&i#g euati#*

TiH2O4Cl2Q9a 9 2H2Ol TiH2O?Q:9a 9 2Cl;a

(hi!h $tate-e#t$ are !rre!t3

1 (ater a!t$ a$ a Le&i$ .a$e*
2 The !-ple5 i#$ are .th !tahe"ral*
! The TiH2O?Q:9 i# !a# a!t a$ a Br#$te";L&r, a!i"*

The re$p#$e$ A t $ $hul" .e $ele!te" # the .a$i$ )

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 1

A(C$
1+2+ a#" ! are 1 a#" 2 #l, are 2 a#" ! #l, are
1 #l, i$ !rre!t
!rre!t !rre!t !rre!t

N ther !-.i#ati# ) $tate-e#t$ i$ u$e" a$ a !rre!t re$p#$e*

!6 Sli"$ ;+ X+ Y a#" < are !-pu#"$ ) t& "i))ere#t Grup II -etal$* S-e ) their
appli!ati#$ are "e$!ri.e" .el&*

C-pu#" ; i$ u$e" a$ a re)ra!tr, li#i#g -aterial i# 'il#$*

C-pu#" X i$ u$e" a$ a .uil"i#g -aterial* It !a# al$ .e heate" i# a 'il# t )r-

!-pu#" Y*

(he# Y i$ h,"rate"+ it )r-$ !-pu#" < &hi!h i$ u$e" agri!ulturall, t treat $il$*

(hi!h $tate-e#t$ a.ut the$e !-pu#"$ are !rre!t3

1 Mre a!i" i$ #eutrali$e" ., 1 g ) ; tha# ., 1 g ) X*

2 The -etalli! ele-e#t i# ; rea!t$ &ith &ater -re ui!'l, tha# the -etalli!
ele-e#t i# Y*
! A""i#g < t a $il "e!rea$e$ the pH ) the $il*

37 'yanohydrins are useful intermediates in organic syntheses. They can be

made by reacting carbonyl compounds with hydrogen cyanide.

#hich statements are correct about the reaction of propanal and hydrogen
cyanide$

1 Prpa#al rea!t$ &ith HCN at a )a$ter rate tha# prpa##e*

2 Prpa#al rea!t$ &ith HCN t gi0e a ra!e-i! -i5ture*

! The pr"u!t .tai#e" )r- the rea!ti# !a# .e "i$ti#gui$he" )r- prpa#al .,
&ar-i#g &ith NaOHa*

! (hi!h pair$ ) reage#t$ &ill rea!t tgether i# a re"5 rea!ti#3

1 CH4 9 Cl2

2 CH:CH2CHO 9 ehli#g$ reage#t

! CH:CH2COCH: 9 Tlle#$ reage#t

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 19

!9 The !-pu#" $h&# i$ a hr-#e pr"u!e" "uri#g preg#a#!, t $uppre$$ 0ulati#*

CH:
C O
CH:

CH:

HO
(hi!h $tate-e#t$ are !rre!t3

1 (he# rea!te" &ith al'ali#e aueu$ i"i#e+ a ,ell& pre!ipitate i$ .$er0e"*

2 (he# rea!te" &ith LiAlH4+ the pr"u!t )r-e" ha$ : !ar.# at-$ !#0erte"
)r- $p2 h,.ri"i$e" t $p: h,.ri"i$e"*
! (he# rea!te" &ith a# e5!e$$ ) ht a!i"i)ie" < 2Cr2O>+ the pr"u!t )r-e" "e$
#t "e!luri$e aueu$ .r-i#e*

40 (hi!h rea!ti#$ pr"u!e a# rga#i! pr"u!t !#tai#i#g 1@O at-3

1 O 1@
H2 O
CH:CH2C
OCH2CH: i# a!i" -e"iu-
&ar-

2 O
CH:CH2C ;
CH:CH2NH2
1@ O H
! O
!#! H2SO4
CH:CH2 C CH:CH2OH
1@ heat
O H
E#" ) Paper;

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SH2 P#e'-3 P&pe# 1 A)*e#*

1 D 11 D 21 D !1 B
2 B 12 C 22 B !2 C
! D 1! D 2! C !! A
4 A 14 C 24 D !4 C
8 D 18 A 28 B !8 A

6 C 16 B 26 A !6 D
7 C 17 B 27 D !7 A
B 1 C 2 D ! B
9 D 19 D 29 A !9 D
10 A 20 C !0 C 40 B

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