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Supplier : Sigma-Aldrich
3050 Spruce Street
SAINT LOUIS MO 63103
USA
Telephone : +1 800-325-5832
Fax : +1 800-325-5052
Emergency Phone # (For : (314) 776-6555
both supplier and
manufacturer)
Preparation Information : Sigma-Aldrich Corporation
Product Safety - Americas Region
1-800-521-8956
2. HAZARDS IDENTIFICATION
Emergency Overview
OSHA Hazards
Target Organ Effect, Toxic by inhalation., Toxic by ingestion, Toxic by skin absorption, Irritant, Corrosive, Mutagen
Target Organs
Kidney, Central nervous system, Liver, Pancreas, Spleen.
Other hazards which do not result in classification
Vesicant., Rapidly absorbed through skin.
GHS Classification
Acute toxicity, Oral (Category 4)
Acute toxicity, Inhalation (Category 3)
Acute toxicity, Dermal (Category 5)
Skin corrosion (Category 1B)
Serious eye damage (Category 1)
Germ cell mutagenicity (Category 2)
Specific target organ toxicity - repeated exposure (Category 2)
Acute aquatic toxicity (Category 3)
Chronic aquatic toxicity (Category 3)
GHS Label elements, including precautionary statements
Pictogram
3. COMPOSITION/INFORMATION ON INGREDIENTS
Synonyms : Lactophenol Anilin Blue
Lactophenol Cotton Blue
Phenol
CAS-No. 108-95-2 Acute Tox. 3; Skin Corr. 1B; 20 - 30 %
EC-No. 203-632-7 Muta. 2; STOT RE 2; Aquatic
Index-No. 604-001-00-2 Chronic 3; H301 + H311 +
H331, H314, H341, H373,
H412
L-(+)-Lactic acid
CAS-No. 79-33-4 Skin Irrit. 2; Eye Dam. 1; 20 - 30 %
EC-No. 201-196-2 H315, H318
For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16
5. FIREFIGHTING MEASURES
Conditions of flammability
Not flammable or combustible.
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special protective equipment for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Hazardous combustion products
Hazardous decomposition products formed under fire conditions. - Carbon oxides
Remarks Central Nervous System impairment Upper Respiratory Tract irritation Lung damage Substances for
which there is a Biological Exposure Index or Indices (see BEI section) Not classifiable as a
human carcinogen Danger of cutaneous absorption
TWA 5 ppm USA. OSHA - TABLE Z-1 Limits for Air Contaminants -
19 mg/m3 1910.1000
Skin notation
Eye protection
Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved
under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin and body protection
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the
concentration and amount of the dangerous substance at the specific workplace.
Hygiene measures
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.
no data available
Carcinogenicity
IARC: 3 - Group 3: Not classifiable as to its carcinogenicity to humans (Phenol)
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
no data available
Teratogenicity
no data available
IMDG
UN number: 2821 Class: 6.1 Packing group: II EMS-No: F-A, S-A
Proper shipping name: PHENOL SOLUTION
Marine pollutant: No
IATA
UN number: 2821 Class: 6.1 Packing group: II
Proper shipping name: Phenol solution