Class 12 th

Chemistry
MCQ
1) What type of solid is sodium chloride?
a) Ionic b) Molecular c) Covalent d) Metallic
2) The melting points of ionic solids are
a) Very high b) Normal c) Very low d) Abnormal
3) What type of solid is quartz?
a) Ionic b) Molecular c) Covalent d) Metallic
4) What type of crystal structure is of silver metal?
a) Fcc b) Simple cube c) bcc d) Metallic
5) What is the percentage packing efficiency of simple cube?
a) 53.26 b) 68.0 c) 74.0 d) 52.36
6) How many times is the number of octahedral voids as compared to tetrahedral
voids?
a) 4 b)8 c)2 d)0.5
7) What is the number of atoms in the unit cell of body centred cube?
a) 2 b) 1 c) 4 d) 6
8) What is the number of atoms in face centred cube?
a) 2 b) 1 c) 4 d) 6
9) In which of the following compounds Schottky defect is present?
a) NaCl b) ZnS c) SiO2 d) SrCl2
10) In which of the following Frenkel defect is present?
a) NaCl b) ZnS c) KBr d) SrCl2
11) Which of the following compouds shows metal deficiency defect?
a) Fe0.95O b) Fe2O3.6 c) Fe3O4 d) FeS1.6
12) Which of the following elements is a semiconductor?
a) Na b) Al c) Fe d) Ge
13) Which kind of semiconductor is obtained by doping Si with B?
a) N-type b) p-type c) pnp-type d) npn-type
14) With which element, the conductivity of ReO3 is matching?
a) Copper b) Zinc c) Iron d) Aluminium
15) Which of the followingwill be paramagnetic?
a) O22- b) Cr3+ c) Na+ d) Cu+
16) Which theory is useful in explaining electrical conductivity in conductors and
semiconductors?
a) Paulis principle b) Avogadros theory c) Band theory d) Hybridisation
theory
17) Which unit of concentration value is changed with change in temperature?
a) Normality b) Molarity c) % V/V d) all of these
18) Which type of solution is petrol?
a) Solid-liquid b) liquid-liquid c) gas-liquid d) all of these
19) What is the concentration of solution in ppm when 2 10 gram CO2 is dissolved
-6

in10 ml solution?
a) 2 b) 0.2 c) 200 d) 2 10-6
20) Which of the following gas has highest solubility in ethyl alcohol?
a) H2S b) NH3 c) N2 d) CO2
21) Which of the following substance has the highest solubility in water?
a) Ethanol b) ethylene glycol c) glycerine d) propanol
22) On increasing temperature, the solubility of gaseous solute in liquid solvent
a) Increase b) Decrease c) Remains constant d) Uncertain
23) On increasing temperature the value of Henrys constant
a) Decrease b) Increase c) Remains constant d) Uncertain
24) Which solution has the highest effect of temperature on its vapour pressure?
a) Sugar solution b) NaCl solution c) BaCl2 solution d) Aqueous H2S
25) Which of the following aqueous solution has the highest boiling point having
concentration 0.02m?
a) Urea b) NaCl C) Na2SO4 d) K4[Fe(CN)6]
26) 0.05 M glucose solution is iso-osmotic with which of the following solutions?
a) 0.10 M NaCl b) 0.05 NaCl c) 0.025 M NaCl d) 1 M NaCl
27) What is the value of vant Hoff factor for dilute FeCl3 (aqueous) solution?
a) 1 b) <1 c) >1 d) zero
28) What is the value of vant Hoff factor when acetic acid is dissolved in benzene?
b) 1 b) <1 c) >1 d) zero
29) What is the molarity for 10% W/W NaoH(aq) solution?
a) 2.778 b) 2.5 c) 10 d) 5
30) For which solution the value of Vant Hoff factor is one?
a) NaCl b) KNO3 c) glucose d) CH3COOH
31) For which solution the value of Vant Hoff factor is not 1?
a) Glucose b) Sugar c) Fructose d) Acetic acid
32) The real vapour pressure for non-ideal solution is-------------- than by Raoults law
a) More b) less c) equal d) both (a) and (b)
33) Which of the following solution is hypotonic?
a) 0.1 M NaCl b) 0.1 M sugar c) 0.1 M Na2SO4 d) 0.1 M FeCl3
34) The total pressure for the volatile components A and B is 0.02 bar at equilibrium.
If the mole fraction of component A is 0.2, then what will be partial pressure of
component B?
a) 0.02 bar b) 0.04 bar c) 0.016 bar d) 0.2 bar
35) Which of the following solution is hypertonic?
a) 0.1 M FeCl3 b) 0.1 M NaOH c) 0.1 M Urea d) 0.1 M Na2SO4

36) Which reaction takes place in electrochemical cell?

a) Oxidation b) Reduction c) Redox d) All the given
37) Which of the following reaction is for Danell cell?
a) Cu2+(aq) + Fe(s) Fe2+(aq) + Cu(s) c) Zn2+(aq) + Mg (s) Zn(s) + Mg2+(aq)
b) Cu2+(aq) + Zn(s) Zn2+(aq) + Cu(s) d) All of these
38) Which cell differs from principle point of view?
a) Storage cell b) Electrolytic cell c) Fuel cell d) Leclanche cell
39) Which phenomenon does not occur in Daniel cell?
a) Increase in weight of plate Cu c) The conduction of electricity takes place
by salt bridge
b) Increase in weight of plate Zn d) There is no change in colour of ZnSO 4
solution
40) The electrochemical cell stops working after sometime. Why?
a) Increase of temperature
b) The difference of cell potential of both electrodes become zero
c) By reversing the direction of reaction taking place in the cell
d) Due to change in concentration
41) What is used for the measurement of accurate potential of electrochemical cell?
a) Galvanometer b) Ammeter c) Voltmeter d) Potentiometer
42) If M, N, O, P and Q are in the increasing order of their standard potentials in
standard conditions of their standard half cells, then by combination of which two
half cells maximum cell potential will be obtained?
a) M and N b) M and Q c) M and P d) M and O
0
43) E red =
a) E0oxi b) -E0red c) -E0oxi d) E0redox
44) What will be the symbolic representation of the cell for the given following
reaction
Fe(s) + Cd2+(aq) Fe2+(aq) + Cd(s)
a) Fe(s) I Fe2+(1M) II Cd(s) I Cd2+(1M)+ c) -Cd(s) I Cd2+(1M) II Fe2+(1M) I Fe(s)+
b) -Cd(s) I Cd2+(1M) II Fe(s) I Fe2+(1M)+ d) Fe(s) I Fe2+(1M) II Cd2+(1M) I
Cd(s)+
45) The solution of silver nitrate becomes coloured when pieces of nickel are added
to solution of silver nitrate because
 a) Nickel is oxidized c) Nickel is reduced
b) b) Silver is oxidized d) Silver is precipitated
46) The value of standard reduction potential of X, Y and Z metal are 0.34 V, 0.80 V
and -0.45 V. Mention their order of strength as reducing agent
a) Z > Y > X b) Z > X > Y c) X > Y > Z d) Y > Z > X
47) If one mole elctrons are passed through solution of MgSO4, AgNO3 and AlCl3 in
what mole ration the metals Mg, Ag and Al will be deposited at the electrodes?
a) 1 : 1 : 1 b) 1 : 2 : 3 c) 2 : 1 : 3 d) 3 : 6 : 2
48) What will be obtained at cathode and anode obtained respectively when
electrolysis aqueous solution of concentrated NaCl, out between graphite
electrodes?
a) Cl2 and Na metal b) H2 and O2 c) Cl2 and H2 d) H2 and Cl2
49) The resistance of any uniform conductor is
a) In inverse proportion to its length
b) In direct proportion to its length
c) in direct proportion of the area of its cross section
d) in the inverse proportion of the square of its area
cross section
50) Which is more corroded when the iron plates of steamers are connected with
block of Zn metal and kept in contact of sea water?
a) Iron b) Zinc c) Both d) Neither of the
metal
51) Which is the device used for measurement of electrical resistance?
a) Voltmeter b) Wheatstone bridge c) Galvanometer d) Ammeter
52) At which temperature ceramic materials are known as superconductor?
a) 0 K b) 200 K c) 150 K d) 15 K
53) l = length, R = resistance, A = area of cross section, then.
a) R l/A b) R A/l c) R 1/Al d) R lA

54) How many groups are there in p-block element?

a) 3 b) 4 c) 5 d) 6
55) What is the molecular formula of chilie salt petre?
a) KNO3 b) NaNO3 c) Ca(NO3)2 d) Ba(NO3)2
56) For the presence of which of the following ions, ring test is useful?
a) NO- b) NO-3 c) NO2 d) N2O
57) Which of the following groups of four elements is called chalcogens?
a) Nitrogen, phosphorus, arsenic and antimony
 b) Oxygen, Sulphur,selenium and tellurium
c) Fluorine, chlorine, bromine, iodine
d) Helium, neon, argon, kripton
58) Which of the following electronic configuration is the general electronic
configuration of elements of group 16?
a) ns2np3 b) ns2np4 c) ns2np6 d) ns2np5
59) Which of the following oxoacids of chlorine is most stable?
a) HCIO3 b) HCIO c) HCIO4 d) HCIO2
60) Which of the following orders with reference to stability is correct?
a) HF > HBr > HCl > HI c) HI < HCl < HBr < HF
b) HF > HCl > HBr > HI d) HF > HI > HCl > HBr
61) Which of the following is the interhalogen compound?
a) XeF4 b) IF7 c) NaCl d) CaF2
62) What is the molecular formula of oleum?
a) H2SO3 b) H2SO5 c) H2S2O7 d) H2S2O8
63) In which of the following oxides of nitrogen, the oxidation state of nitrogen
element is (+4)?
a) N2O3 b) N2O4 c) N2O5 d) N2O

64) In haloalkane-------------------------- bond is formed between carbon and halogen.

a) Onic b) van der Waals c) Covalent d) Hydrogen
65) In haloarene compounds, halogen combines with carbon having which
hybridization?
a) Sp2 b) sp3 c) sp d) dsp2
66) In haloalkane, carbon in C-X bond possesses which partial electric charge?
a) Chargeless b) Positive c) Negative d) Anionic
67) Which of the following is vinyl halide?
a) CH2Cl2 b) CH2=CH-Cl c) CHCH-Cl d) CH-CH
I I
Cl Cl
68) What is B in R-OH + PX5 R-X + B + HX?
a) HPOX3 b) H3PO3 c) POX3 d) H3PO2
69) Which catalyst is used in preparation of bromobenzene by bromination of
benzene?
a) FeBr3 b) HBr c) AlBr3 d) Br2
70) By which name the reaction CH3-Br + Ag-F CH3F + AgBr is known?
a) Grignard b) Wurtz c) Fittig d) Swartz
71) What are nucleophilic reagents according to Lewis theory?
a) Acid b) Base c) Neutral molecules d) Positive ions
72) On which of the following factors the stability of carbocation depends?
a) Resonance b) Temperature c) Transition state d) Reaction rate
73) What is called an optically active substance?
a) Which reflects polarized light
b) Which rotates the plane of polarized light
c) Which increases rate of polarized light
d) Which absorbs polarized light
74) Arrange giving the sequence order to Br, Cl, F and H combined with asymmetric
carbon.
a) H, Cl, Br, F b) H, Cl, Br, F c) Br, Cl, F, H d) H, F, Br, Cl
75) 2C6H5-X + 2Na Dry ether A+ 2NaX. What will be the product A obtained in the
reaction?
a) C6H5Cl b) C12H10 c) C6H5-C6H5 d) C6H5Na
76) Which substance is inflammable?
a) DDT b) Freon c) CHI3 d) CHCl3

77) Which general formula is that of alcohol?

a) R1-O-R2 b) Ar-OH c) R-OH d) Ar1-O-Ar1
78) Which formula is tertiary alcohol?
a) CH3OH b) (CH3)2CHOH c) (CH3)3COH d) CH3CH2OH
79) Which order from the following is true for boiling points?
a) Chloroethane < ethane < ethanol c) Ethanol < ethane < chloroethane
b) Ethane < chloroethane < ethanol d) ethane > chloroethane > ethanol
80) Which substance from the following is reducing agent?
a) Potassium permanganate c) Chromic acid
b) Lithium aluminium hydride d) Pyridinium chloro chromate
81) What will be formed after oxidation reaction of 20 alcohol with chromic acid?
a) Aldehyde b) Ketone c) Carboxylic acid d) Ester
82) In which from the following intermolecular hydrogen bond is not present?
a) alcohol-alcohol b) alcohol-water c) ether-ether d) ether-water
83) Which species from the following is nucleophilic reagent?
a) E b) E+ c) E- d) E
84) Whichh statement from the following is true?
a) During dehydration reaction H2O molecule is added to reactant
b) Lucas test is used for detection of ethers
c) During esterification OH- from acid molecule and H+ from alcohol are removed
d) During esterification H+ from acid molecule and OH- from alcohol are removed
85) Which substance from the following is unsymmetrical ether?
 a) CH2-O-CH2 b) C2H5-O-CH2CH3 c) CH3-O-C2H5 d) CH3-O-CH3
86) Alcohol and ether are---------------------- isomers.
a) Chain b) Position c) Functional group d) Optical
87) What is C-O-H bond angle in alcohol?
a) 108 b) 109.5 c) 108.5 d) 111.7
88) The aqueous solution of alcohol is of which type?
a) Acidic b) Basic c) Neutral d) Amphoteric
89) Common name of Propane 2 ol is-------------------------
a) Propanol b) Butanol c) Isopropyl alcohol d) None of these
90) Which oxidizing reagent used to oxidise trialkyl borane in presence of aq. Sodium
hydroxide?
a) LiAIH4 b) (BH3)2 c) H2O2 d) All of these

91) What is not correct at normal temperature and pressure?

a) P4O10 is a white solid c) SO3 is a colourless gas
b) SO2 is a colourless gas d) NO2 is a brown coloured gas
92) Which of the following have P-O-P bond?
a) Hypophosphorous acid c) Pyrophosphoric acid
b) Phosphorous acid d) Orthophosphoric acid
93) Continuous use of which fertilizer increase the acidity of soil?
a) Urea b) Phosphate of lime c) Ammonium sulphate d) None
94) Which allotropes of phosphorous is most stable?
a) Yellow P b) Red P c) Black P d) White P
95) Which of the strongest oxidizing agent?
a) Br2 b) I2 c) F2 d) Cl2
96) Sulphur atom of which oxo acid have non bonding electron pair?
a) Disulphuric acid b) Sulphuric acid c) Sulphurous acid d) pyrosulphuric acid
97) An acyl halide is formed when PCl5 reacts with
a) Amide b) alcohol c) acid d) ester
98) Which of the following is a nucleophilic substitution reaction?
a) HI b) SO2 c) HNO3 d) H2O
99) Which branched chain isomer of the hydrocarbon with molecular mass 72 u gives
only one isomer of mono substituted alkyl halide?
a) Isohexane b) Noehexane c) Neopentane d) None
100) What is DDT among the following?
a) Fertilizer c) Non-biodegradable pollutant
b) Biodegradable pollutant d) Green house gas