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BOARD OF INTERMEDIATE EDUCATION
JUNIOR INTER CHEMISTRY
MODEL PAPER (ENGLISH VERSION)
e t
TIME: 3 HOURS
. n
MAX.MARKS: 60

SECTION - A
h a
I. i) Very Short Answer Type questions.
i b
ii) Answer ALL questions.

a t 10 2 = 20
1.
ii) Each question carries TWO marks.

p r
What is 'Critical Temperature'? Give its value for CO2.
2.

d u
Calculate Oxidation Number of S, Cr in H2SO5 and Cr2O7-2
3.
4.
n a
Boron is unable to form BF6-3 ion. Explain.
What is "Common ion effect"?
5.
e e
Give the formulae of

.
6.
w w
a) Borax b) Colemanite
Why crude NaCl absorbs moisture from atmosphere?
e t
7. w
Give two uses of Caustic soda.
. n
8. What is PAN? What is the ill effect caused by it?

h a
9.
10.
How is Ozone formed in Stratosphere?
Give the Principle of Chromatography?
i b
a
SECTION - B t
II. i) Short Answer Type questions.

p r
ii) Answer any SIX questions.

d u
iii) Each question carries FOUR marks. 6 4 = 24
11.
n a
Calculate RMS, Average and most probable velocities of CO2 at 27C.
12.
Cr2O
-2 e
Balance the following redox reaction by ion electron method in acid medium

.e - -
+ NO2 Cr+3 + NO3

ww
7
13. State and explain Hess's Law of Constant heat summation.
14.
w
Derive the relation between Kc and Kp for the equilibrium reaction
2 SO2 (g) + O2 (g) 2 SO3 (g)
15. Write a short note on
a) Silicones b) Fullerenes

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16. Explain the terms "Hard water" and "Soft water". How hardness of water can be removed by Calgon
method?
17. Which type of compounds react with Ozone? Explain the reaction of Ozone with one aliphatic and one

18.
aromatic compound.
What do you understand about Geometrical isomerism? Write E, Z isomers for CHCl = CFBr.
e t
SECTION - C
. n
III. i) Long Answer Type questions.
h a
ii) Answer any TWO questions.

i b 2 8 = 16
19.
iii) Each question carries EIGHT marks.
EXplain
a t
a) Heisenberg's uncertainty Principle.

p r
b) de Broglie's Principle.

d u
c) What is nodal plane? How many nodal planes are possbile for 2p and 3d orbitals.
20.
n a
What are first and second ionistation enthalpy? Why IE2 > IE1. Explain 4 factors influencing it.
21.

.e e
a) Explain the formation of Coordinate covalent bond with 2 examples.
b) Explain sp3d hybridization with one example.

w w e t
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ANSWERS
SECTION - A
1.
A:
What is 'Critical temperature? Give its value for CO2.
The temperature above which a gas can not be liquified by appliying any pressure.
e t
Tc for CO2 = 30.98C.
. n
2. Calculate Oxidation number of S, Cr in H2SO5 and Cr2O7-2.
O -2
h a

A: H - O - S - O - O - H
i b
+l -2 -1 -1 +1
O-2
a t
Cr2O7-2

p r
x- 6=0
x = +6
d u
O.No. of S = +6

n
2x + 7 (-2) = -2 a
.e e 2x = -2 + 14 = 12
x = +6

3.
w w
O.No. of Cr = +6
Boron is unable to form BF6-3 Explain.
e t
A: w
B = 1s2 2s2 2px1 (ground state)
. n
B = 1s2 2s1 2px1 2py1 2pz0 (1st excited state)

h a
i b
In the valency shell only 4 orbitals are avaialble to take electrons. The maximum covalency of B is 4.
Due to non-avaiability of d orbitals, boron is unable to expand its octet to form BF6-3.
4. What is "Common ion effect"?

a t
A:
r
The phenomenon of suppression of solubility of a weak electrolyte by the addition of strong electrolyte
having common ion with it.
p
u
e.g.: Suppression of ionisation of CH3COOH when CH3COONa is added (due to common ion CH3COO-)

d
5. Give the formulae of
a) Borax
n a
b) Colemanite
A:

e e
a) Borax - Na2B4O7. 10 H2O

.
ww
b) Colemanite - Ca2B6O11.5 H2O
6. Why crude NaCl absorbs moisture from atmosphere?
A:
w
Crude NaCl is contaminated with CaCl2 and MgCl2. As they are deliquescent, they absorb moisture
from atmosphere.
7. Give two uses of Caustic Soda.
A: It is used in the manufacture of soap, paper.
It is used in the purification of bauxite.

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8. What is PAN? What is the ill effect caused by it?
A: Peroxy Acetyl Nitrate is called PAN. It is formed when O3 reacts with unburnt hydrocarbons in air in
O

presence of NO2. Its formula is H3C - C - O - O - NO2. It is powerful irritant of eyes.
e t
9. How is Ozone formed in the Stratosphere?
. n
A: In Stratosphere O2 absorbs ultra violet radiation to form O3.

h a
3 O2
u.v.
2 O3

i b
10.
A:
Give the Principle of Chromatography?

a t
The Principle of adsorption is used to separate the substances of a mixture over the stationary phase with
the help of mobile phase. It involves

p r
Adsorption & Retention of a mixture.

d u
Elution: Recovery of substances in the mixture.

n a
Qualitative & Quantitative analysis of eluted substances.

.e e SECTION - B
11.
w
Calculate RMS, Average and most probable velocities of CO2 at 27C.

w
3 8.314 300 1000
e t
A:
w
URMS =
3RT
=
M
= 4.12 102 m/sec
44

. n
UAverage = 0.9213 RMS speed = 0.9213 4.12 102
= 3.8 102 m/sec.
h a
Ump = 0.8166 RMS speed = 0.8166 4.12 102
i b
= 3.36 102 m/sec

a t
12.
-2 -
Cr2O7 + NO2- Cr+3 + NO3
p r
Balance the following redox reaction by ion-electron method in acid medium.

A:
-
NO2 NO3
OXIDATION
-
a du REDUCTON
Cr2O7-2 Cr+3
-
NO2 + H2O NO3
e
-
n Cr2O7-2 2 Cr+3
-

e
NO2 + H2O NO3 + 2 H+

.
-
Cr2O7-2 2 Cr+3 + 7 H2O

ww
- -
NO2 + H2O NO3 + 2 H+ + 2 e- Cr2O7-2 + 14 H+ 2 Cr+3 + 7 H2O
- -
3 (NO2 + H2O NO3 + 2 H+ + 2e- Cr2O7-2 + 14 H+ + 6 e- 2 Cr+3 + 7 H2O

w - -
3 NO2 + 3 H2O 3 NO3 + 6 H+ + 6e-
By adding both the L.H.S. and R.H.S. of 2 Half reactions separately

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3 NO2- + 3 H2O + Cr2O7-2 + 14 H+ + 6 e- 3 NO3- + 6 H+ + 6 e- + 2 Cr+3 + 7 H2O
-
3 NO2-+ Cr2O7-2 + 8 H+ 3 NO3 + 2 Cr+3 + 4 H2O
13. State and explain Hess's Law of Constant heat summation.
A:
e
Hess's law: The total change in enthalpy of a reaction is same whether the reaction takes place in t
single step or several steps.
1
Path I: C (graphite) + O2 (g) CO (g) H = -110.5 KJmol-1
. n
1
2
2 Steps CO (g) + O2 (g) CO2 (g)
h
H = -283 KJmol-1
a
2
Path II: C (graphite) + O2 (g) CO2 (g)
i b
H = -393.5 KJmol-1
1 step

a t
14.
2 SO2 (g) + O2 (g) 2 SO3 (g)
p r
Derive the realtion between Kc and Kp for the equilibrium reaction

[SO3]

2

d u
A: Kc =
[SO2]2 [O2]
n a
2

.
PSO
e
2

e
PSO
Kp = 3

. PO PV = nRT

w w
=
2 2
[SO3]2 [RT]2 n
P = RT = CRT
e t
w [SO2]2 [RT]2, [O2] [RT]
= Kc. (RT)2 - (2 + 1)
v

. n
Kp = Kc (RT)-1
h a
15. Write a short note on

i b
(a) Silicones
b) Fullerenes
a t
A:
p r
a) Silicones: Organosilicon polymers having repeating unit ( R2 SiO )n in which alkyl or phenyl

d u
groups occupy the remaining positions. They are prepared from hydrolysis of dialkyl dichloro silane
and polymerisation.

n CH3 a CH3

.e e Cu

570 K

+ 2 H2O
2 CH3Cl + Si Cl - Si - Cl HO -
-2 HCl

Si -OH

ww
CH3 CH3

w CH3

CH3

H] O - Si - O H + HO - Si - O [H
-H2O
Polymerisation
(
CH3

Si - O

)
n
CH3 CH3 CH3
They are used as sealant, grease, water proofing of fabrics.

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b) Fullerenes: It is made by heating graphite in presence of noble gas like He. They are purest forms
of Carbon. C60 molecule is cage like (Soccer ball shaped) molecule.

e t
The sturucture of C60 Buckminster fullerene

. n
It contains 20 six membered rings and 12 five membered rings. They undergo sp2 hybridisation. Due to

a
presence of free electrons it has aromatic character. It has C - C single bonds (143.5 pm) and

h
16.
double bonds (138.3 pm)

i b
Explain the terms "hard water" and "soft water". How hardness of water can be removed by
calgon method?

a t
A:

r
Soft water: The water that gives good lather easily with soap water.

p
Hard Water: The water that does not give lather readily with soap water due to presence of

u
Ca+2, Mg+2, Cl, SO4-2, HCO-3 ions.

d
n a
Calgon method: Sodium hexa meta phosphate is called calgon. ('cal' means Calcium 'gon' means gone.)
When hard water containing Ca+2 or Mg+2 ions is passed through calgon, Na+ ions are released.

17.
[ ( e )] [ (
Na2 Na4 PO3 6 + 2 Ca+2 Na2 Ca2 PO3 6 + 4 Na+

.e )]
Which type of compounds react with Ozone? Explain the reaction of Ozone with one aliphatic and

w w
one aromatic compound.

e t
A:
w n
Unsaturated compounds like alkenes, alkynes, C6H6 react with O3 to form respective Ozomides. Which
on hydrolysis gives carbonyl compounds.
.
Reactoin with aliphatic compound:

h a
H - C = C - H + O3
H O
C C
H
Zn
2 HCHO + H2O2
i b

H H
H H H2O Methanal
O-O
a t
Reaction with aromatic compund.

p r
Zn
C6H6 + 3 O3 C6H6O9 3
CHO

H2O CHO
d u
+ 3 H2O2

18.
n a
gly oxal
What do you understand about geometrical isomerism? Write E, Z isomers for CHCl = CFBr.
A:
e e
Compounds having same molecular formula and same structural forumula but differ in the special

.
arrangement of atoms or groups around C = C are called geometrical isomers and this phenomenon is

w
H
ww
called geometrical isomerism. When similar gropus are on the same side of C = C, it is called "cis"
isomer and on opposite side of C = C, it is called 'trans' isomer.
F H Br
C = C C = C
Cl Br Cl F
Z - isomer E - isomer

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SECTION - C
19. Explain:
a) Heisenberg's uncertainty Principle.
b) de Broglie's principle
e t
.
c) What is nodal plane? How many nodal planes are possible for 2p and 3d orbitals.
n
A:
a
a) Heisenberg's uncertainty Principle: It is impossible to determine simultaneously and accurately

h
x. p
h
i b
both the position & momentum of a tiny moving sub atomic particle like electron.

4
when x is very small, p will be very large.
a t
Where x = Uncertainty in position
p r
h = Planck's Constant = 6.626 10-34 JS
d u
p = Uncertainty in momentum = m v

n a
b) de Broglie's Principle: All tiny particles like electron moving with high velocity possess both the

e e
particle nature and wave nature.

.
w w
E = h (Planck's theory) ..............(1)
E = mc2 (Einstein's theory) .........(2)
e t
w
from (1) & (2)

. n
h = mc2

h a
c h h
h = h = mc2 or = or =
mc p

i b
electron in this plane is Zero.
a t
c) Nodal Plane: The plane that passes through nodal point is called nodal plane. The density of

no. of nodal planes for any orbital = l

p r
d u
no. of nodal planes for 2 P = 1 ( ... l = 1)
no. of nodal planes for 3d = 2 ( ... l = 2)
20.
n a
What is first and second ionisation enthalpy?

A:
. e
Why IE2 > IE1. Explain 4 factors influencing it.

e
The minimum amount of energy required to remove an electron from an isolated gaseous atom (M) in

ww
its ground state is called first ionisation enthalpy (I.E1)

w
M (g) M+ (g) +e-
The energy required to remove an electron from unipositive gaseous atom, is called second ionisation
enthalpy (I.E2)
M+ (g) M+2 (g) + e-

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Unit of ionisation enthalpy is K.J./mole
Due to increase in effective nuclear charge, the magnitude of the force of attraction between the
nucleus and valence electrons also increases.
So I.E2 I.E1
FACTORS:
e t
. n
a) Atomic radius: As atomic radius increases, the distance between nucleus and valence electron

h a
increases, attractive force decreases. Hence it requires less amount of energy to remove electron i.e.
I.E. decreases in a group. In a period, I.E. increases from left to right due to decrease in atomic radius.
1
I.E.
Atomic radius
i b
a t
b) Nuclear Charge: As the nuclear charge increases, the attractive force between the nucleus and

1
p r
valence electron increases. I.E. also increases as it requires more energy to remove an electron.

I.E.
nuclear charge

d u
n a
c) Screening effect: In multi electron atoms, valence electrons are screened from the nucleus by inner
electrons. Therefore the outer most electron feel less attraction, can be removed easily.

e e
I.E.

.
1
Screening effect

w w
atom with more stable electronic configuration has greater ionisation enthalpy.
e t
d) Electronic configuration: Atoms having half filled or completely filled shells are more stable an

w e.g.: N = 1s2 2s2 2px1 2py1 2pz1 (Half - filled orbitals)

. n
Ne = 1s2 2s2 2px2 2py2 2pz2 (Completely filled orbitals)

h a
21.
b
a) Explain the formation of coordinate covalent bond with 2 examples.
b) Explain sp3d hybridization with one example.
i
A:

a t
a) Coodiate covalent bond: Convalent bond formed between electron pair donor atom and electron

p r
pair acceptor atom or ion is called coordinate covalent bond or dative bond. It is represented by ""
Where donor atom possess lone pair of electrons. Acceptor species possess empty orbital.
+
e.g.: NH4 , H3O+

d u +

[ ]
a
H H

en

H+
..

H-N + H - N -H

H
.e
H

ww
"N" donates electron pair to H+ and shares with it to form a dative bond.

w [ ]
.. . . +
H+ H - O - H
..

H-O +

H H
"O" donates electron pair to H+ and shares with it to form a dative bond.

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b) sp3d hybridization: The phenomenon of inter mixing of one s, three p and one d orbitals to form five
identical sp3d hybrid orbitals is called sp3d hybridization.
e.g.: PCl5 Cl
Cl

e t
Cl
P
Cl
. n
Cl
h a
i b
Phosphorous in its 1st excited state has 3s1 3px1 3py1 3pz1 3d1 configuration and undergoes sp3d
hyrbridization. Five sp3d orbitals or Phosphorous overlap with five p orbitals of Chlorine to give

a t
trigonal bipyramidal geometry for PCl5. The bond angles are 120 & 90.

p r Writer: A.N.S. Sankara Rao

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