Académique Documents
Professionnel Documents
Culture Documents
www.elsevier.com/locate/jfoodeng
Abstract
Air-drying of banana slabs has been investigated and the inuence of experimental parameters such as temperature, relative humidity
and slab thickness has been studied. This was in part re-investigated because of inconsistencies in previous studies, particularly in relation
to derived water diusion coecients. In addition, it is shown that harvest season and hence initial moisture content has a very marked
inuence on the drying kinetics. By contrast banana maturity (ripeness) has little inuence on the kinetics despite there being signicant
dierences in morphology and chemical composition between green and ripe bananas. The eect of these two variables on the drying
kinetics has not previously been studied.
2006 Elsevier Ltd. All rights reserved.
0260-8774/$ - see front matter 2006 Elsevier Ltd. All rights reserved.
doi:10.1016/j.jfoodeng.2006.01.063
M.-H. Nguyen, W.E. Price / Journal of Food Engineering 79 (2007) 200207 201
porosity decreased as sample temperature increases. These drying of banana has been reported by several authors
authors (Krokida, Tsami, & Maroulis, 1998) also examined using Ficks law of diusion (Garcia, 1988; Mowlah
the eect of drying conditions on color change during con- et al., 1983; Sankat et al., 1996).
ventional and vacuum drying those fruits. Rate of color Most studies (Garcia, 1988; Mowlah et al., 1983; Mulet
changes was found to increase as temperature increased et al., 1989) of dehydration of banana have focused on the
and air humidity decreased. Other workers (Robinson, validation of a particular model, under a limited range of
1980) investigated the improvement of banana dehydration drying conditions. The eect of temperature on the drying
and used the results in designing a commercial banana dry- kinetics was of most interest in these studies. In addition,
ing plant. there were some inconsistencies in the derived diusion
Generally, drying of foods is characterised by two sepa- coecients (Mowlah et al., 1983). Although our prime
rate phases: the constant rate and the falling rate periods. interest has been the eect of pre-treatments such as osmo-
For a high-moisture food, prior to drying, the surface of tic dehydration on subsequent air-drying (Nguyen and
the food is saturated with water. The drying rate is thus Price, unpublished data) the gaps and inconsistencies in
constant for a period of time until the migration of mois- the current literature as far as understanding drying kinet-
ture to the surface is not sucient to keep it in a saturated ics of banana, led us to re-investigate the matter. In partic-
state, assuming the composition of the drying air does not ular, it was hoped that a simple model with a single falling
change. The constant rate period ends and the moisture rate period giving a good t to experimental data for a wide
content at this point is referred to as the critical moisture range of conditions could be obtained. Therefore the aim
content. The falling rate period then starts, and the drying of the current work was to investigate the eect of drying
rate falls monotonically to the end of the process. Fruit conditions on the drying kinetics over a wide temperature
with a high amount of free water and fruit with a skin such range (3070 C) and to look at the eect of slab thickness.
as plum, grape, apple, apricot, peach, and pear usually In addition, the inuence of banana maturity, and dierent
undergo a constant rate period during drying if the drying harvesting seasons was also studied to conrm the eect of
temperature is not too high. morphology on the drying kinetics.
The drying rate during the falling rate period is caused
by the concentration gradient of moisture inside the food 2. Experimental method
matrix. The internal moisture movement results from a
number of mechanisms such as liquid diusion, capillary 2.1. Materials
ow, ows due to shrinkage and pressure gradients (Lyder-
son, 1983). Fresh Cavendish banana were bought from commercial
Due to the complexity of food, drying can occur simul- sources in Wollongong, Australia. They were grown in
taneously by dierent mechanisms. Therefore, modelling North Queensland, Australia from a single supplier. Bana-
the drying process, and predicting the drying behavior nas were stored at room temperature. Ripe bananas (bright
under dierent conditions is necessary to have a better yellow) and green bananas were used in drying studies.
understanding of the mechanisms of drying at play. Ficks Experiments were repeated in dierent months from Janu-
law of diusion has been used to describe the drying kinet- ary to November in order to examine the eect of various
ics of fruit during the falling rate period. Modelling the harvesting seasons on drying kinetics.
water in
temperature controller
electronic balance
water out
transmitter box
heater
fan
tray
temp/rh probe
drying chamber
insulated wall control valve
ct
-1.2 60 C
zero, i.e., when dW/dt = 0. The values of equilibrium mois- 70 C
-1.5
ture contents were determined by the point on the plots of
-1.8
dW/dt versus W when the graph cuts the moisture axis.
-2.1
This approach can be applied as the drying occurred over
-2.4
a long time, when equilibrium could be approached. This
method was the best available within the time constraints Fig. 2. Plots of ln Wr versus time for 1 cm slabs banana versus time at
of the project. More time-consuming isotherm measure- dierent drying temperatures. (Initial moisture content = 72.6% wet basis,
ments were outside the scope of the work. It is interesting velocity = 1 m/s.)
to see that the results obtained in this study were very sim-
ilar to results reported by Sankat et al. (1996) with the same ln Wr versus time indicate that D was independent of mois-
range of RH% at each drying condition. ture content (R2 = 0.99 for all temperatures). Increased D
with increased temperature was observed. Values of con-
3.3. Estimated parameters of diusion model stant rates and diusion coecients obtained from dierent
drying conditions are summarized in Table 3. The temper-
The equilibrium moisture contents for all drying condi- ature dependence of the moisture diusivity was described
tions obtained in this study are summarized in Table 2. The with an Arrhenius type equation:
results of equilibrium moisture contents agreed well with
data in the literature (Brekke & Pointing, 1970; Sankat D D0 expEa =RT 6
et al., 1996). Applying Eq. (3) by plotting the natural log- where Ea is activation energy (kJ/mol).
arithm of removal moisture ratio (Wr) versus time, the
value of rate constant (K), and thus the diusion coecient Table 3
D could be determined from the slope of the straight line. Values of rate constants and of diusion coecients of bananas dried at
dierent dying conditions (ripe banana of 1 cm slabs)
Slope P2 D=4L2 K 5 Drying temperatures (C) K (h1) D (m2/s) 1010
30 0.046 1.3
where L = the thickness of the slab, if drying occurred only
40 0.083 2.1
on one large face. In this study, drying occurred on two 50 0.111 3.2
faces, as slabs were placed on a mesh tray. In this case 60 0.208 5.1
L = half thickness. 70 0.277 7.8
Fig. 2 shows the plots of ln Wr versus time for banana In all cases, the standard deviations in the mean K, and D were between
(1 cm) dried at dierent temperatures. The linear plots of 1% and 2% for three replications.
204 M.-H. Nguyen, W.E. Price / Journal of Food Engineering 79 (2007) 200207
Values of ln D at dierent temperatures were plotted ver- drying time to a particular moisture content between the
sus 1/T for slabs of 1 and 2 cm. Good linearity was model and experimental data was 1015 min or less for
obtained in both cases. From the slope of these lines, acti- all drying temperatures from 30 C to 70 C.
vation energy was derived. The values of Ea were 39.8 In summary, the diusion model gave the good t with
(4.6) kJ/mol, and 34.7 (0.073) kJ/mol for 1 cm, and the experimental data. The values of moisture diusion
2 cm slabs, respectively. coecients or constant rates, which were yielded from this
model, were useful to explain the eects of dierent drying
3.4. Testing and evaluation of the model conditions on drying behaviors of banana. There are sev-
eral signicant advantages in a simple model with few var-
In order to evaluate this model for predicting drying iable parameters, over previous reports (Sankat et al.,
behavior of banana, experimental drying curves of banana 1996) to model the drying of fresh banana. Not least of
at 30 C, 50 C, 60 C, and 70 C for 1 cm slabs were com- these is that for the temperature range used here, it was
pared with those obtained by the diusion model. In the possible to use only one falling rate period of drying to
model, the tted values of D, K for the semi-log plots were describe the process.
used to generate the model drying curves. The two curves
were compared statistically across the entire drying period. 3.5. Eect of drying temperature on drying kinetics
Fig. 3 represents the comparison of the changes of experi-
mental and predicted moisture content during drying at Bananas were dried at 10 C intervals from 30 C to
60 C. At all temperatures studied the deviation between 70 C to investigate the inuence of temperature on drying
experiment and predicted moisture content was generally kinetics. The eect of temperature on drying rate was seen
12% at any time point. clearly from the results of water diusivity in Table 3.
These results and the deviations of D and K show that Increasing temperature resulted in signicant improvement
the diusion model can be used successfully to predict of rate of mass loss, especially the initial rate. Total drying
the mass transfer during the falling rate period of drying time was reduced signicantly with increasing temperature.
banana for a wide range of drying temperatures. An extre- The initial drying rate and the drying time needed to obtain
mely good t was obtained for drying at 60 C and 70 C. a 70% mass loss (wet basis) at dierent drying temperatures
This agreed with expectations, because at high tempera- are shown in Table 4. The drying time of banana at 70 C
ture, the rate of moisture loss was very rapid at the begin- was twice as fast as that at 60 C, three times compared to
ning. At this stage the evaporation of moisture from the 50 C, four times that at 40 C and 10 times that at 30 C.
surface controlled the rate of drying. The faster the surface Decreased drying time of around 10 h with increasing
moisture was deleted, the sooner the drying rate was con- 10 C was observed within this temperature range, except
trolled predominantly by internal diusion. for the large dierence for case of drying at 30 C.
The drying time at all temperatures also agreed very well
between predicted and experimental data. The dierence in 3.6. The inuence of sample thickness on kinetics of
drying banana
Comparison of Predicted and Experimental Moisture
Contents during Drying Banana at The drying rate in the falling rate period, which is
60 oC, 1 cm mainly inuenced by the moisture gradient in food
2.5
(Strumillo & Kudra, 1986), is also thickness dependent.
Moisture Content
Model
1.5 thickness on the kinetics of drying. Table 5 shows the
1.0 Experiment results of rate constants and diusion coecients calcu-
0.5 lated from the diusion model for 1 cm and 2 cm slabs
0.0 dried at dierent temperatures. From Table 5, the thickness
0 3 6 9 12 15 18 21 24 27 30 and temperature dependence of D can be seen clearly. The
Drying Time (hours) D values for 2 cm slabs were nearly three times greater than
Fig. 3. Comparison between experimental and predicted moisture content those for 1 cm slabs at all temperatures. This was not sur-
changes. prising, because the diusion model assumed that diusion
Table 4
Comparison of initial drying rates (kg H2O/kg DM*h) and drying times to 70% mass loss for drying bananas (1 cm slabs) at dierent temperatures
T (C) 30 40 50 60 70
Initial drying rate (kg H2O/kg DM*h) 0.17 0.3 0.39 0.54 0.73
Drying time (min) to 70% mass loss 6000 95 2520 60 1850 75 1320 60 660 60
In all cases, the standard deviations in the mean initial drying rates were between 2% and 4% for three replications. Errors quoted for the drying times are
the standard deviations of the mean for three replications.
M.-H. Nguyen, W.E. Price / Journal of Food Engineering 79 (2007) 200207 205
0.20
70 C
(kgH2O/kg DM *h)
0.15 Table 7
60 C Drying times and initial drying rates of bananas harvested in January and
0.10 March
50 C
Temperature 40 C 60 C
0.05
Month January March January March
0.00 Initial drying rate 0.53 0.34 0.95 0.63
0 400 800 1200 1600 (kg H2O/kg DM*h)
-0.05 Drying time (min) 1575 74 1800 46 1020 30 1050 45
Time (min)
In all cases, the standard deviations in the mean initial drying rates were
Fig. 4. The dierence in drying rates between 1 cm and 2 cm banana slabs between 2% and 3% for three replications. Errors quoted for drying time
at various drying temperatures. are the standard deviations of the mean for three replications.
206 M.-H. Nguyen, W.E. Price / Journal of Food Engineering 79 (2007) 200207
understandable, because the higher the initial moisture drying time was very similar for all drying temperatures
content the greater the concentration gradient established and slab thickness. The values of K, and D (calculated from
and thus, a higher driving force for mass transport would the diusion model) of green and ripe samples under dier-
result. ent drying conditions are presented in Table 8. The values of
From Table 7, it can be seen that dierent initial mois- K and D are not very dierent between green and unripe
ture contents resulted in longer drying times for samples samples indicating little net inuence of maturity and hence
dried at 40 C, whereas drying times were nearly the same fruit morphology on the drying rate.
for two samples dried at 60 C, despite their being a greater
initial drying rate for the banana with the higher moisture 4. Conclusion
content. The increase of water diusivity with increased
moisture content has been reported elsewhere (Saravacos Using a simple solution to Ficks diusion equation for
& Raonzeous, 1984; Sokhansanj & Jayas, 1987). Thus, an innite slab it was possible to model the drying kinetics
higher initial moisture content in food resulted in a higher of drying banana slabs. The deviation between predicted
drying rate, as expected. This led to a rapid decrease in and experimental moisture contents during drying was
moisture content in the fruit, and resulted in the same dry- small and extremely good ts to experimental data was
ing time for both January and March samples at 60 C. obtained at all drying temperatures. Perhaps, under these
Moreover, high temperature (60 C) accelerated the drying conditions, very little non-moisture loss was
evaporation of moisture near the surface better than low observed.
temperature (40 C), thus drying time could be reduced. Temperature dependence of diusivity followed an
The results of drying at 60 C agreed with the reports of Arrhenius type equation with a high correlation coecient
Sabarez et al. (1997, 2001) for drying plum of dierent ini- (R2 = 0.99), and the apparent moisture diusivity obtained
tial moisture contents at 70 C. The authors reported that in this work agreed with data reported in the literature.
at this temperature, there was very little dierence in drying The dierence in drying rates for banana slabs of dier-
time between samples with dierent initial moisture con- ent thickness showed that drying banana followed mainly
tents. Perhaps, strong temperature dependent diusivity the internal moisture transfer of the falling rate period, in
of water in banana led to the dierence between the two which water diusivity depended upon both temperature
temperatures. and distance.
Initial moisture content varied with bananas of dierent
3.8. The inuence of maturity of banana on drying kinetics harvesting seasons. The large dierence in initial moisture
content (over 5% wet basis) could strongly aect drying
There have been reports of changes in structure (intercel- rates. However, this eect was only clearly observed at
lular space, cell wall) (Charles & Tung, 1973; Marriot, 1980; low temperature (40 C). At a higher drying temperature
Prabha & Bhagyalakshimi, 1998), permeability of mem- this was not seen, since temperature dependence of diusiv-
brane, chemical composition (including starch, sugar and ity was stronger than the concentration dependence.
water) (Ketiku, 1973; Ni & Eads, 1993; Prabha & Bhagyal- Mass loss under all drying conditions between green and
akshimi, 1998; Wills, Lim, & Greeneld, 1984) between ripe banana was very similar. This showed that mass loss
green and ripe banana. It was therefore of interest to inves- was not inuenced much by fruit morphology. However,
tigate the drying kinetics of banana of dierent maturity. chemical changes, especially signicant rise in the amount
Green banana and ripe ones of the same hand (given six of sugar in ripe banana may contribute to reducing the rate
days more to mature) were dried under the same drying con- of mass loss of ripe banana. This would compensate for the
ditions (temperature, thickness, and humidity and air veloc- more open structure of ripe banana which be expected to
ity). Mass loss of green and ripe bananas as a function of favor an increased drying rate for ripe banana. It is possi-
ble these two competing eects counter-balance each other.
Table 8
Rate constants and diusion coecients of green and ripe banana dried
under dierent drying conditions
References
1 2 10
Drying conditions K (h ) D (m /s) 10 Beck, R. A., & Zapsalis, C. (1985). Water in foods, physical and chemical
50 C, 1 cm Green 0.14 3.81 phenomena. Food chemistry and nutritional biochemistry. New York:
Ripe 0.11 3.21 MacMillan.
Bowrey, R. G., Buckle, K. A., Hamey, I., & Pavenayotin, P. (1980). Use of
60 C, 2 cm Green 0.13 14.75
solar energy for banana drying. Food Technology in Australia, 32(6),
Ripe 0.14 15.87
290291.
70 C, 1 cm Green 0.30 8.5 Brekke, J. E., & Pointing, J. D. (1970). Oso-vac dried bananas. Hawaii
Ripe 0.28 7.8 Agric. Exp. Station Research Report 182.
Brennan, J. G., Butters, J. R., Cowell, N. D., & Lilly, A. E. V. (1976).
70 C, 2 cm Green 0.18 20.15 Food engineering operations. London: Applied Science Publishers.
Ripe 0.202 22.74 Charles, R. J., & Tung, M. A. (1973). Physical, rheological and chemical
In all cases, the standard deviations in the mean K, D were between 2% properties of banana during ripening. Journal of Food Science, 38,
and 3% for three replications. 456459.
M.-H. Nguyen, W.E. Price / Journal of Food Engineering 79 (2007) 200207 207
Crank, J. (1975). The mathematics of diusion. Oxford: Clarendon Press. Ratti, C., & Mujumdar, A. S. (1996). Drying of fruits. In L. P. Somogyi,
Garcia, R. (1988). Drying of bananas using microwave and air ovens. H. S. Ramaswamy, & Y. H. Hui (Eds.). Processing fruits: science and
International Journal of Food Science and Technology, 23, 7380. technology, biology, principles and applications (Vol. 1). California:
Iglesias, H. A., & Chirife, J. (1982). Handbook of food isotherms. New Technomic Publishing.
York: Academic Press. Robinson, A. A. (1980). Research design and development of banana
Ketiku, A. O. (1973). Chemical composition of unripe and ripe plantain dehydration process. Food engineering. Sydney, UNSW, Australia.
(Musa paradisiaca). Journal of the Science of Food and Agriculture, 24, Sabarez, H., Price, W. E., Back, P. J., & Woolf, L. A. (1997). Modelling
703707. the kinetics of drying of DAgen Plums (Prunus domestica). Food
Krokida, M. K., Karathanos, V. T., & Maroulis, Z. B. (1998). Eect of Chemistry, 60(3), 371382.
freeze-drying conditions on shrinkage and porosity of dehydrated Sabarez, H. T., & Price, W. E. (1999). A diusion model for prune
agricultural products. Journal of Food Engineering, 35(4), 369380. dehydration. Journal of Food Engineering, 42(3), 167172.
Krokida, M. K., & Maroulis, Z. B. (1999). Eect of microwave drying on Sabarez, H. T., & Price, W. E. (2001). Eect of processing conditions on
some quality properties of dehydrated products. Drying Technology, the physico-chemical changes during dehydration of prunes. In
17(3), 449466. International symposium on fruit, nut and vegetable production engi-
Krokida, M. K., Tsami, E., & Maroulis, Z. B. (1998). Kinetics of color neering, Potsdam, Germany, ATB.
change during drying of some fruits and vegetables. Drying Technol- Sadler, M. J. (1993). Bananas and plantains. In R. MacRae, M. Sadler, &
ogy, 16(35), 667685. R. Robinson (Eds.), Encyclopaedia of food science, technology and
Lomauro, C. J., Bakshi, A. S., & Labuza, T. P. (1985). Evaluation of food nutrition. London: Academic Press.
moisture sorption isotherm equations: Part I Fruit, vegetable and meat Sankat, C. K., Castaigne, F., & Maharaj, R. (1996). The air drying
products. Lebensmittel-Wissenschaft und-Technologie, 18, 111117. behaviour of freshly and osmotically dehydrated banana slices.
Lyderson, A. L. (1983). Mass transfer in engineering practice. New York: International Journal of Food Science and Technology, 31, 123135.
John Wiley and Sons. Saravacos, G. D., & Raonzeous, G. S. (1984). Diusivity of moisture in air
Marriot, J. (1980). Bananasphysiology and biochemistry of storage and drying of starch gels. In B. M. McKenna et al. (Eds.). Engineering and
ripening for optimum quality. CRC Critical Reviews in Food Science food (Vol. 1, pp. 499507). London and New York: Elsevier Applied
and Nutrition(September), 4188. Science Publishers.
ce:given-name>G.Mowlah Takano, K., Kamoi, I., & Obara, T. (1983). Sokhansanj, R. S., & Jayas, D. S. (1987). Handbook of industrial drying.
Water transport mechanism and some aspects of quality changes New York: Marcel Dekker.
during air dehydration of bananas. Lebensmittel-Wissenschaft und- Strumillo, C., & Kudra, T. (1986). Drying principles, applications and
Technologie, 16, 103107. design. New York: Gordon and Breach.
Mulet, A., Berna, A., & Rossello, C. (1989). Drying kinetics of some fruits. Wang, Z. H., & Chen, G. (1998). Heat and mass transfer during low
Drying Technology, 15(5), 13991418. intensity convection drying. Chemical Engineering Science, 24(17),
Ni, Q. X., & Eads, T. M. (1993). Analysis by proton NMR of changes in 38993908.
liquid-phase and solid-phase components during ripening of banana. Wills, R. B. H., Lim, J. S. K., & Greeneld, H. (1984). Changes in
Journal of Agricultural and Food Chemistry, 41, 10351040. chemical composition of cavendish banana (Musa acuminata) during
Perry, R. H., & Green, D. W. (1997). Perrys chemical engineers ripening. Journal of Food Biochemistry, 8, 6977.
handbook. New York: McGraw-Hill. Wills, R. B. H., Lim, J. S. K., & Greeneld, H. (1986). Composition of
Prabha, T. N., & Bhagyalakshimi, N. (1998). Carbohydrate metabolism in Australian foods 31: tropical and sub-tropical fruits. Food Technology
ripening banana fruit. Phytochemistry, 48(6), 915919. in Australia, 38(3), 118123.