Académique Documents
Professionnel Documents
Culture Documents
Heterocylics
Polysaccharides
Synthetic Precursors
Current Strategies in Polymer Synthesis
Composition
Stereochemistry
2. Versatility
Synthetic Methods
Mw/Mn 1
4. Ziegler-Natta (Metal-Coordinated)
Polymerization
Stereochemical Control
Polydisperse products
Mw/Mn 1.05
Monodisperse in MW
Monodisperse in Composition
Sequentially Uniform
Stereochemically Pure
H3C
CH3 H3C
H3C
H3C
C
H2 CH3
H3C
CH3
H3C
CH3
Temperature Program
Hours
POLY(VINYL CHLORIDE) SUSPENSION PROCESSES
Conditions 8 hr at 52C 8 hr
at 40C
Suspending Media
Hydrocarbon solvents
Long Chain Alcohols
Freons
Supercritical CO2
Monomer
Polymer
Monomer
Droplet
500-2000 A
Monomer Micelle 20 -30 A
Monomer Droplet
10,000 A (1 )
Stages of Emulsion Polymerization
Phase I Phase II Phase III
Conversion
Rate, P/t
time
Disadvantages:
Polymer surface contaminated by surface active agents
Coagulation introduces salts Poor electrical properties
(CH3)2N-C-S- Na+
or HO OH
S
Add antioxidants and antiozonants
Two step coagulation
20 % NaCl Cream
5% H2SO4 Crumb
Chemistry of Initiation
.
HOCH2SO 2- Na+ Fe++ RO -OH
Fe+++
RO . +
OH-
HOCH2SO 2- Na+ Versene complex
M
RO -M .
xM
RSH ROMxM.
RS . ROMxMH
xM
RS -M. RSMxM.