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SANCHEZ DELGADO ALAN

Sistema 2,2,4,6,6-pentametilheptano y n-hexadecano @ 294 1K

R=8.314E+07 ; T=294K

x1 (mN/m) ln x1 (mN/m)
0.0000 27.3 - - -
0.1261 25.9 -2.0707 0.694 1.1367
0.2449 25.3 -1.4069 1.347 1.2824
0.4087 24.3 -0.8948 2.248 1.5146
0.5620 23.8 -0.5763 3.091 1.7698
0.7036 23.1 -0.3515 3.870 2.0436
0.8368 22.5 -0.1782 4.602 2.3397
1.0000 21.8 0.0000 5.500 2.7616

Fuente: Density, Viscosity, Speed of Sound, Bulk Modulus, Surface Tension,and Flash Point of Direct Sugar to Hydrocarbon Diesel (DSH-76) and
Binary Mixtures of NHexadecane and 2,2,4,6,6-Pentamethylheptane. Dianne J. Luning Prak,*, Robert E. Morris, Jim S. Cowart, Leonard J.
Hamilton, and Paul C. Trulove

La funcin p vs ln x esta descrita por la ecuacin:


s= 2.215E-10 mol/cm2
y = 5.5ex
Se toman 3 datos en x de saturacin:
ln x1 (mN/m) Obteniendo b con x=1:
= 1.7616
0.0000 5.500
-0.0100 5.445
-0.0300 5.337 Obteniendo b a partir de todos los datos:
Donde d/d(lnx) = sRT = 5.4144 = 1.8348

vs ln x
6.000

5.000

4.000

3.000
y = 5.4144x + 5.4998

2.000

1.000

0.000
-2.1000 -1.6000 -1.1000 -0.6000 -0.1000
Determinacin de


3.0000

2.5000

y = 1.8348x + 0.818
2.0000

1.5000

1.0000

0.5000

0.0000
0 0.2 0.4 0.6 0.8 1 1.2