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PERATURAN PEMARKAHAN
KIMIA
Kertas 2
H
a I}NTUK KEGUNAAN PEMERIKSA SAIIAJA
AMARAN
Peraturan pemarkahan ini SULIT dan Hak Cipta Bahagian Pendidikan Menengah
MARA. Kegunaannya khusus unhrk pemeriksa yang berkenaan sahaja. Sebarang
maklumat dalam peraturan pemarkahan ini tidak boleh dimaklumkan kepada
sesiapa.
[Lihat sebelah
454112 @zotz Hut Clpta Bahagian Pendidikan Menengah MARA
SULIT
,,
SULIT 4s4il2{PP)
MAB|I(ING S,,IiIDEIINES
Symbol Meaning
_ or bold keyword
a. accept
r. reject
of
Question Mark
Mark Scheme
No Sub Total
t(o) (i) Xe /l Xenon 1 1
(v) The outermost shell of xenon atom is fully filled with electrons l/ I 1
(ii) 800c 1 1
Mark
Question Mark Scheme
No Sub .Total
2(a) (i) Chemical formula that shows the simplest whole number ratio of
atoms of each element in a compound 1 i
a: without whole number
(ii) Element Zn o
Mass (g) 30.5-24.0:6.5 32.1-30.5:1.6 1
Number of
mole of 6.5/65= 0.1 1.6/16:A.1
atoms
Simplest
ratio of 1 1 1
moles
(iii) t
Ionic compound 1 I
t
(iv) Yellow to white // I I
Yellow when hot and white when cold
TOTAL 9
Mark
Question lllark Scheme
No Sub Total
3(a) (i) 7 1 i
(i i) Sodium chloride 1 i
(iii) P1 No.ofmoleHCl:1.0 x 20
1000
:0.02 mol 1
3(b) (i) Add/ Dissolve/Pour/ Put baking soda powder / lime water/ CaAl I 1
CaCOr
acidic water
(iii) the higher the concentration of hydrogen ions, H*, the lower the
pH value, 1
Or
The iower the concentration of hydrogen ions, H*, thc higher the
pH value
TOTAL 10
halarnan sebelah
SULIT 6 4y1/z{PP)
(ii)
lr
HH
C- C
ll
HH
1 2
46
- 0.1 mol
surroundings
TOTAL 10
(iii )
Experim
ent
.'
(v) P1 Experiment IL 1
I
TOTAL 11
halaman sebelah
SULIT 4s4u2(PP\
Question Mark
Mark Scheme Sutr Total
No
6 (a) (i) Pl : Exothermic reaction. 1
ZHz+ Oz ) ZHzO
P2. Balance 1 2
(iii)
Energy
2Hz+ Oz
(b) pl
(ii) 1 rnoi of hydrogen released 282kJ beat I
na
iL 25 mol of hydrogen released:2-5 x 282 k.)
1
TOTAL 11
https://cikguadura.wordpress.com/ Mark
Question Mark Scheme
No Sub Total
7 (a)
half equation
half equation
1 10
P 10: Diagram of electron arrangement
fadp: atom]
7 (c)
CHa NaF
The boiling point of CHc is The boiling point of NaF is 1+l
lower higher
CHa rnolecules are athacted There are Na* ion and F- ion
by a rveak Van der Waals that are attracted to each bY a 1+1
forces/ intermolecular fo rces. shong electrostatic forces
TOTAL 2A
of copper atoms
P7. The atorns/layers of atoms cannot slide easily over each
other when force is applied 1
Question Mark
Mark Scheme
No Sub Total
8(d) P1 Neutralize the SOz release I
2
P2 with CaO/ Ca(OH)z/ CaCO: 1
(e) 1
P2: It has a lower thermal expansion coefiicient //
High resistant to heat// more resistant to chemical attack.
1
P3: Polyvinyl chloride 1 4
P4: It does not rust a: Light
TOTAL 20
https://cikguadura.wordpress.com/ Mark
Question Mark Scheme Sub
No Total
9 (a) P1 Transition element ll groap3-12 1
(ii) Materials:
Small pieces of Y and Z, filter paper, water.
1
Apparatus:
Knife. forceps. water trough,&asin. fi1ter paper.
1
Procedure:
1 . Fill the rvater trough rvith rvater.
TOTAL 2A
Question Mark
No
l!{ark Scheme Sub Total
10 (a) (i) Acid : Hydrochloric aci d/sul phuric acidlnitric acid/ethanoic acid I
a: any dilute acid
Metal : Magnesium/zinCaluminium
(Any one acid and one metal) I 2
higher
P2. The water and sugar molecules gain higher kinetic energy 1
molecule forces. I J
halaman sebelah
SULIT t4 454U2(PP.)
Mark
Question Mark Scheme
No Sub Total
containing water.
'l'0't'AL 2tJ
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1| i,'n
NIAI(TAB ITENDATI SAINS MARA
PERATURAN PEMARI(A.HAN
KI]\T IA
F.ertas i
Satu jam tiga puluh nr init
AMAIL{N
Peraturzin peinarkahan
ini sl,rl,IT cian Hak cipta penciiclikan
MARA' Kegr'rnaannya khusus unruk pemerikia Bahagiarr r4crcngah
1'ang bir.k.,ru*,
-boleh sahaja. Sebarans
daiam peraturan p.,ro.kulr*r ini
tidak
::[Y" dimak]umkan t"pa.ti
[-ihat .srllclalr
t{5'i l,/-l ,ejirl _sr..LrT
.: ;ir,;: l.iIr: II}ralriir pcncrrjiirrr llcrrrrr:rir
i,1ili_,i
454 1i3{}'P)
l\'{ark Scherne
1 (a) Ahle to stsle ofie inference corr,:t:tlit
Slrilpic ansu,cr:
1\{ethyl cthanoate// eth1,1 propano:ite,,i1propr{ methanoate// Liquid u,hic!.r
iess dense ihan waier is produceril F-sier is pr 116ugg(.
f i,!rpi__L:!lti,.f Cr:
Perfuure is firrned li tiquicl fk-rat on the sr.rr{hcc of water,i/ Proc1ucti
substance rvhich less dense than u,ater is produced /,i
Sample arlswer':
Esterr'Orqanic
compound
i I \{ethvl ethanoate
-1
Ethvl propanoate
Propyl methanoate
Ester/ Organic
Alcohol Carboxylic acid compound
Able to state eny ttw variobles carrectly // One varioble correctly and
two ideas 2
S;rnpli:_lrrrs.ri u'
Ilexaner'alkane,/saturaierJ hyclrocarbo6 canlot react \.jjth
broiline 1,atei.
B'hile hexener'alkene/uirsati-irateri h,r.drocarhc,n cair ieact rviti:
broprine
\\'ater
OR
Sql1plqq4s",cI
Hexene/alkene,iunsaturated hydrocarbon can react wrth bromine
water il
Hexaneialkane/ saturated hydrocarbon carmot react rvith bromine
u,ater
I I Hexenel alkenelunsaturated hydrocarbon
can react rvith aci di il ed
potassium man gan ate(\rll) soiuti on /I{exa,ei alkaneisaturatetl
hydrocarbon cannot react *'ith acidi fi eri potassiur-r-:, an ganate(v
I I)
solution /z'
Hexane,'alkanc,/saturaierl hl.drocarooi'r cio ,ot chailue tire colour
of.
l-.rourine u,at cr i ac id i li eci po trss rum ilt an gan alte( \,, ,I 1 _so luti
) orr
iiH ex eneialken e,.unsaturateri hydrcicarbon cl ecoioun ses the co lour
of
bromine r,vatcr /acidifi ed iro tassium rltirnganete(\,,1) sol u ti on,
)
.lblt to.\'tat( tlt(,itleu ol hy1rt,,7l1er;,
fuul-r-lq--,rnruql
b( 12)
F1 . % of c;irhon by ilass in hexane = .,it7rrt{(1) r 1007b lt E3.7291,
sauul-siuslsr
P1 . oA of carbon by mass 100o/o ll 83 -12 or'a
oA
Pi. of carbon by mass iu hexauc - IA0o/o ll 85.71 %
OR
&r:u]ria!-igsr
Dj lfercrrt substancelhyclrocarbon producc ciilferenl sooi ,/,i
'l'ire number of'hydrogen atours per molecule of hvrirocarLrorr
in lrr:rane
is !:l'e atr:r theLlt rn hexene .
Sct i: i 8 V
Set2: 1.1 V -1
fui:urlqiuuyrtr
Sct l: L8 2
Set 2: 1.1
Set 3: 0.;1
Sarn!lc- unsrvcr
Magnesium electrode becomes thinner/l
(loppcr electrode bccomes ihicker,ii -1
.S,liut]S.ltlrU r.:i
I,iag:esi Lrnt e:l ectroii e tiisso I ve.s,,/ I
\,1g corrode
I
lr
'l
I
I
I
Mark scheme
-l (c.l 4ble to state the correct opttrationsl de-iinition.fttr redox resclioil irt
Set III y,ith the J'ollox,ing aspects'
ANI)
Z, \\4rat is observed
It,o[tmeter needle deflected/ the y,ohagc i.s 0.411
Sanrnlc arlfrrerl
1. Wlten copper dipped into copper(ll) sulphate and silver dipped into
silver nitlate solution. the voltmeter needle deilectedi the voltaqe rs 0..,iV
OR
l. \\'lrat rs ol'rscn,cd
lvitltnletr:r needle tie/lectedi lhe "',oltdgi: i.t l) 1l')
Sqrxpig_anslv_ql
lledox reaction is an oxidation and reduction hai:1-.ens at the sure tjr.ne r'
I
sinruItaneouslv i,'
I \\ .- .-'-r.'(ll) :-:1.1tliC ,,r.i ril'
i-,^,- r.()l-.1)i,': 11l1.1r1rl iiii . _'r ail;, ,,r :;1rrr
I
I
'IltIc to gin: ,, ,,,, i,!,,:u u{tln,' ,tpt'ruti:onu!,1t,finitiott.
i
S4i_rI!e 91.:tt._ru
i
l
I . it4i:"a1 tirl;peti irri.r.i si,l iri.itrii.
I
I
1
h'o respon"'? 0r x,rlng $tls,l+'ef 0-
i-_
Qucstion
I
S-a-ti:p19-eqs_lgt
.
1 Rusting of ir.rin occur' ,ii
2. Iie + Fe2* + Zell
3. lron atoi.n donates ttr,o eiectrons 1o ftrnl iron (ll) ion ii
r+ 'l'he iron
nail crorrodes ,,,'
5. I'he iltrn ltail dissolves ,',r
(r. 'l'he iron nail oxidizes r,'
i. Ircrn donates electrons i'r
8. iron rs rnore eiectropositive I reaclive ll
9. Silver is less electropositive/ reactive i'l
10. 1'he position of iron is higher than silver //
1 l.
'fhe position of iron is higher in Electrochemical
Series /i
12. I'he position of silver is lorver in Electrochemical Series
Salnpic an.,;n.u
1. Fe=2cgFc'
2. Fe2- + 2e ) Fe
3 The iron nail changed.
4. I'i-ic presence of iron(li) ion
5. The pcrsition oi-iron is lor'.,ei"than siiier in Electl.ochentical
trr r_ie < i,ul Sl i
Scr-ies i
Able ta stfite tlre chunge ot'intensity o.f the blue spot tyith time less
correctlv
S arnl;lc*ansrvcr
2
intelrsit1, of blue spitt irrcrease/ bi ggeri highcr
' (c)
.4hle to classift' ull fir,e raactonts into reducing and oxidizing agert
correctly. J
L Corrcel. heedings
2. List of reducing md o:,.idizing agents
'!1uu]-q.:::sroq
#Score l: ifreverse
3 (a) Able to state the problem statfient o.f the experiment correcii';
San:p& aus.,r,'er
Sample answefi
1. Carbonate and sulphate are different //
2. Different salts have different rcaetion ll I
S,.:t.ltllqi:rsu:ct:
,!.!:Ul.:i!r:[ci
\\/hen calciurn cai-bonate rs heateri. sas released tunts the
]j41c r1-rilcr
qlgUdI u,hiie- r,hen calciuir-r sulphate is irer:ed. tlre lirne u,nlcr rcmains
unchanged.
OR
Sq,!p]g ili5,el
1. when calsium carbcrnater carbonate sart is heated, a colourless
gas released fums the lirnc r.r'ltcr- clttLrclv //
2. when caicium sulphatei sulphate salt is heated. the iime rvarcr
rernaills unchangeci,',/
3, Gas released tun"rs lhe lirric:rr atcf_liCgil u,hen calcium
car'bonate,'cari:onatc sait is heatcd rvhile the lirle *.att:r r.r:nrains
unciranged *'hen calciuni -sLrllrhnte, suiphate salt is heatecl ,. 1
Siilnltle altsi\'ai"
fui:n,,;rlll:*,vqr
fl-lcatingl
Materials: L-alcium earbonate, caleium sulphate. lirne lvater.
Apparatus: Boilirig tube, test tube. ie*st tube holder, ul1sen burner,
stopper and delir,ery fr-rbc,
--1
OR
IAcid]
Matetials: Calcium carbonate" caicium sulpirate. f any narned acidl
Apparatus: Boiling tube, test hrbe, iest tube holder, stopper and
delivery tube.
Materials : any named carbonate salt (except NazCOr and KzCO:), any
2
named suiphate salt, lirne r.vater
Apparatus: Boiling tube, test tube, Bunsen bumer. stopper and delivery
tube
-Sample answer: 1
Mark Scheme
S_rtUuL:_lAUri
U_lg4ti!'r I
OR
IAcid]
l, i'uvplace 1 spatula (2-5g) of carcium carbonate into a boiring
tube.
Add HCI into the boiling tube
J. Stoppered with a delivery tube dipped into lime water ll
bubble/flou'ichamel//pass through the gas produced into rime
u,ater (by using delivery tube).
4. Observe and rccor.d anv changes.
5. Repeat step i until 3 by replacing calcium carbonate rvith calciurn
sulphate.
Mark Scherne
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,4ble to tsbul&te the dalq u,ith the follotting aspacts
I /-^.--^^. +:+l ^-
2. Co;npieic iisi cf saiisi ci;ii-ip;i:u;il1s
,cilt!-tl-c- orutlgt
Calcium carbonate
Calcium sulphate
Observaiion
Calcium carbonate
Calcium sulphate
la : formula]
Sarnirle aiis-w*r
T-ype of salts
'I-1pe
ol salts
OR
--_t
I
I
t*_ I
ia: ionni-ilal