k = Ae-Ea/RT

Soal Latihan Ea 1 1
ln(k2/k1) = ( )
1. Cl2 + M Cl. + Cl. k1 Initiation R T2 T1
Cl. + H2 H. + HCl k2 Propagation
H. + Br2 Cl. + HCl k3 Propagation
Cl. + Cl. + M Cl2 + M k4 Termination
H. + O2 + M .HO2 + M k5
Cl. + O2 + M .ClO2 + M k6

Tunjukan Hukum lajunya seperti dibawah :

2.

3. The following mechanism is proposed for a reaction:

(1) 2NO N2O2
(2) 2(H2 2H)
(3) N2O2 + H N2O + HO
(4) H + N2O HO + N2
(5) 2(HO + H H2O)
(a) Write a balanced equation for the overall reaction
(b) Determine the molecularity of each step.
(c) Write the rate law for each step.

4. Propose a reasonable mechanism for each of the following reactions:

(a) 2NO2(g) + F2(g) 2NO2F(g); Rate = k[NO2][F2]
(b) 2NO(g) + O2(g) 2NO2(g); Rate = k[NO]2[O2]
5. Given the following elementary steps:
Step 1: NO + NO N2O2; (fast)

Step 2: N2O2 + O2 2NO2; (slow)

Write the net equation and derive the rate law for the overall reaction.

6. For the reaction: 2 N2O5(g) 4NO2(g) + O2(g)

the following rate constants, k, are obtained at different temperatures:

Temp. oC: 45.0 50.0 55.0 60.0

k, s-1 : 4.8 x 10-4 8.8 x 10-4 1.6 x 10-3 2.8 x 10-3

Calculate the activation energy (Ea) for this reaction.

7. It has been proposed that the conversion of ozone into O2 proceeds by a two-step
mechanism:
O3 (g) O2 (g) + O(g)
O3 (g) + O(g) 2 O2 (g)
(a) Describe the molecularity of each elementary reaction in this mechanism.
(b) Write the equation for the overall reaction.
(c) Identify the intermediate(s).

8. For the reaction of hydrogen with iodine, the rate constant is 2.45 x 10-4 L/mol s at 302
C and 0.950 L/mol s at 508 C.
a) Calculate the activation energy and the frequency factor for this reaction.
b) What is the value of the rate constant at 400 C?

9. At 552.3 K, the rate constant for the decomposition of S02Cl2 is 6.09 x 10-5 min-1 . If the
activation energy is 210 kj/mol, calculate the frequency factor and the rate constant at
600 K.
10. The decomposition of ethyl bromide in the gas phase is a first-order reaction. The data
are :
Temperature 800 K 900 K
Rate constant 0.0361 s-1 1.410 s-1

What is the activation energy for the reaction ?

11.

12.