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NAME:.. CLASS:
962/3
CHEMISTRY
1 hour
TINGKATAN 6 ATAS
CHEMISTRY (KIMIA)
Instructions to candidates:
1
Section A
Four suggested answers labelled A, B, C and D is given for each question in this section. Choose one
correct answer.
1. Which of the following is not correct about the type of hybridisation of the carbon atoms
in the following molecule?
A. 1-butene
B. 2-butene
C. 1, 2-dichloropropene
D. 1-bromo-1-chloroethane
4. Propanone has the formula, CH3COCH3. Which of the following species is expected to
attack the carbon atom in the carbonyl group (C=O) in propanone?
A. Br2 B. CN- C. H+ D. Cl+
5. A mixture containing a little ethane and a large quantity of bromine gas is exposed to
ultraviolet light. Which of the following bromoalkanes is the principle product of reaction?
A. CH3CH2Br C. CBr3CBr3
B. BrCH2CH2Br D. CH3CHBr2
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7. Benzene reacts with a mixture of concentrated nitric(V) acid and concentrated
sulphuric(VI) acid at 55 oC to form a yellow oil. When heated to 90 oC, compound X is formed.
Compound X could be
A NO2 B NO2 C NO2 D NO2
NO2
NO2
NO2
8. An aromatic compound P has the molecular formula C8H9Cl. When P is heated with
acidified potassium manganate(VII) solution, the compound C8H6O4 is formed.
P could be
A B CH3 CH2Cl
CH2CH2Cl
C C2H5 Cl D Cl CH3
CH3
9. Benzene reacts with a mixture of concentrated nitric acid and concentrated sulphuric acid to
produce nitrobenzene according to the following equation.
C6H6 + HNO3 C6H5NO2 + H2O
10. Which compound reacts with chlorine following the mechanism for free radical and electrophilic
substitution?
11. Which of the following pairs of organic compounds contain substituition groups that are
ortho and para directing?
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12. A monosubstituted benzene has the formula C6H5X. When C6H5X reacts with an
electrophile, Y, a trisubstituted benzene, Z is formed. Which of the following statement is
correct?
14. Which of the following reaction takes place especially through S N1 mechanism?
A. CH3CH(NH2)CH3 C. CH3CH2CH2CH2NH2
B. (CH3)2CHCH2NH2 D. CH3CH2CH(CH3)NH2
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Name :____________________________ Class : _______________________
Section A [ 15 marks]
No. Answer No. Answer No. Answer No. Answer No. Answer
1. 4. 7. 10. 13.
2. 5. 8. 11. 14.
3. 6. 9. 12. 15.
16. (a) The compound C5H12 exhibits isomer pentane, 2-methylbutane and 2,2-
dimethylpropane. The table below shows the boiling point of the isomers.
Compound pentane 2-methylbutane 2,2-dimethylpropane
(b) pKa values of some compounds are given as follows. pKa values: 15.5, 10.0 and 4.74
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17. Photochemical smog is a type of air pollution which is formed from the reaction of
gases from internal combustion of engines of vehicles, in the atmosphere in the
presence of sunlight.
(a) Name the gases formed from the internal combustion of engines of vehicles
which contribute to the formation of photochemical smog. [2 marks]
(b) A measure taken to reduce these pollutant gases is to install catalytic converter in
vehicles.
(ii) State the type of catalyst which takes place in the catalytic converter. [1 mark]
(iii) Write two equations of reactions involved in the catalytic converter. [2 marks]
(c) Suggest two other ways to decrease air pollution from internal combustion of engines
of vehicles. [2 marks]
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(ii) Draw the structural formulae of all the isomers of the hydrocarbon. [4 marks]
(iii)If one of the isomers shows stereoisomerism, draw and name the stereoisomer.
[2 marks]
(c ) Polychlorinated methanes are useful solvents. Dichloromethane is a component of
many paint-stripping solvents. Can the chloroform formed from dichloromethane?
Explain it. [2 marks]
(ii) Give an example of addition reaction involving bromine, and describe the
mechanism involved. [3 marks]
(b) Describe the mechanism when 1-iodomethane is boiled under reflux with aqueous
sodium hydroxide. [4 marks]
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