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Copyright 

C Blackwell Publishing 2005


Scandinavian Journal of Metallurgy 2005; 34: 340352
Printed in Singapore. All rights reserved SCANDINAVIAN
JOURNAL OF METALLURGY

Physical modeling simulations of refining processes


in Brazilian Steel Industry
Varadarajan Seshadri1 , Carlos Antonio Silva2 and Itavahn Alves Da Silva2
1 Department of Metallurgical Engg. and Materials, Universidade Federal de Minas Gerais, Belo Horizonte, Brazil; and 2 Department of Metallurgical
Engineering, Universidade Federal de Ouro Preto, Ouro Preto, Brazil

In this work, the techniques of physical modeling for op- cesses or suggesting alternative techniques for improved
timization, control and improvement of metallurgical pro- efficiency.
cesses, such as RH degassing, continuous casting, IR-UT,
etc with special reference to Brazilian steel plants such as Key words: continuous casting, IRUT process, physical
Usiminas, CST, Belgo-Mineira etc. are discussed. Many of modelling, RH degassing.
these have been industry-sponsored projects, involving de-
velopment of physical models of laboratory scale, consid- 
C Blackwell Publishing, 2005
ering similarity principles and carrying over the results of
experiments to the industrial unit, for optimizing the pro- Accepted for publication 1 February 2005

During the last 25 years there has been increasing ten- nomena principles, there are basically two difficulties,
dency with respect to application of quantitative meth- the analysis of the problem and the solution of the differ-
ods of modeling for the solution of the problems of de- ential equations with defined boundary conditions. Be-
sign, operation and control of the industrial processes. fore the advent of computers there was great difficulty
As the processes become more complex, models have in this respect and hence models were simplified to get
to be developed for each stage of the process for effec- analytical solutions. However, in the last 1015 years the
tive control of the operation or automation for obtain- developments in the field of computers have been phe-
ing better productivity and quality of products as well nomenal and this problem does not exist any more [1,
as decreasing the production costs. The techniques of 2]. Now there are also available several software based
physical and mathematical modeling of processes are on the several techniques of numerical analysis for the
useful in the development of new processes and tech- resolution of models of transport phenomena in 2 or 3
nologies besides improving the control and efficiency of dimensions. With the use of powerful computers, it has
the existing processes. become possible to decrease the time of computation
The mathematical modeling of a process may involve facilitating the use of very precise and complex models
a system of algebraic or differential equations or appli- for control of processes. This situation should be favored
cation of statistics that represent quantitatively several now by the fall of the hardware prices and availability of
stages of the process and involves, in addition to un- sophisticated software in the market for complex math-
derstanding of the basic principles of the actual pro- ematical models. Artificial intelligence is another field
cess, several knowledge areas such as thermodynamics, where significant developments have taken place. De-
kinetics, transport phenomena, mathematics and com- velopment of software on this basis has been used for
puter science. The degree of sophistication of a model process control. Computer control has been successfully
for simulation of an industrial process depends on tak- applied in the fields of agglomeration, iron making, steel
ing into consideration fundamental principles of mass, making, rolling, foundry etc using such soft wares.
heat and momentum transfer and other related phenom- The physical modeling of a process consists essen-
ena, formulation of the model, practical verification and tially of its representation in a reduced scale in the lab-
improvement of the same. For simulation of a process oratory using the similarity principles and materials
through a mathematical model involving transport phe- at low temperatures in order to analyze the effect of

340
Physical modeling simulations

several variables of the process, facilitating the visual- propriate tracers such as sodium chloride, potassium
ization and measurement of specific aspects in a con- chloride. Plug flow and other considerations can be
venient way and low cost. It is important to point out made depending on the process and RTD curves can
that a modern research methodology and development be obtained suiting well-known techniques adopted ex-
of new processes as well as improvement of the exis- tensively in various investigations [4].
tent processes, require the use of techniques of both In Brazil, the departments of Metallurgical Engineer-
mathematical and physical modeling first in the labo- ing of UFMG and UFOP have maintained a strong inter-
ratory and then in experiments in pilot plants or pro- action with several steel companies, such as USIMINAS,
totypes or a combination of both using the knowhow ACESITA, CST, CSBM. This program not only imparted
obtained in the first stage to achieve the defined ob- continuing education to the several engineers in terms
jectives. For accomplishing the simulation of industrial of masters degree program in several areas of the met-
processes through these techniques a good technical col- allurgy but also carried out research programs of inter-
laboration between those specialized in fundamentals est to the industry with the active cooperation of the
and experts with practical knowledge of the process is university. In this context several research projects have
very essential. This collaboration would greatly influ- been taken up with the sponsorship of the steel industry,
ence the successful development of a realistic model of which were simultaneously masters or doctorate theses
the process. also. This contribution gives details regarding some of
The key point of the physical modeling is the realis- the projects completed successfully of this industry by
tic representation of the process to be analyzed in terms the authors under the university research program in the
of the important variables that influence the same and field of physical modeling over the years. This program
develop a correlation between the dimensionless num- covered several areas such as RH degassing, continuous
bers constituted by these variables derived by apply- casting tundish and mold, blast furnace, agglomeration,
ing similarity principles such as Buckhingham theorem, flux powder injection in melts etc [521].
Rayleighs method of indices etc. and carrying out ex-
periments with the model at ambient temperature vary-
ing different parameters of the process. The correlations Examples of application of physical
developed in this way are valid for the model as well as modelling of processes
the prototype. Similarity between model and prototype Analysis of installation of process RH of usiminas
is not only with respect to geometry, but also dynamic in function of several operational conditions [13]
parameters such as velocity, force, density, concentra- It is well known that the productivity of the process
tion, temperature and thermal aspects [3]. Through anal- degasification with RH process depends on the rate of
ysis of general equations of momentum, heat and mass circulation of the steel, which in turn is determined by
balance, such as the NavierStokes equation one can the number of uplegs, nozzle locations and injection
arrive at the dimensionless numbers important in the rate of gas in it. The circulation rate influences signifi-
process. The experimental results of the physical model cantly descarburization, deoxidation, removal of hydro-
itself can be verified by applying the above balance gen and nitrogen from the melts as well as mixing and
and solving the differential equations, with simplifi- homogenization in the ladle. Hence, optimization of the
cations for unidimensional, bidimensional or tridimen- process can be achieved through a better understanding
sional considerations and other aspects of the process. of the variables that affect this parameter.
Once the geometric and dynamic similarities between During 19781979 USIMINAS installed a RH de-
the model and the prototype are established, in general gassing unit with a capacity of 86 tonnes. With the ob-
the model is constructed in acrylic material assuming jective stated previously, a cold model was built in the
a geometric scale and dynamic similarity principles are scale 1:5.3 considering similarity principles. Through a
established between model and prototype using the di- dimensional analysis it was shown that
mensionless numbers. Hence, various parameters such
 b
as liquid and gas fluxes, concentration gradients etc are NF r = C[(NVa )]a (NRe )2 . (1)
determined for use in the cold model experiments. Sub-
sequently, the influence of the variables of the process The parameters C, a and b were determined through
on parameters determining the efficiency of the process experimental work with the physical model, using water
are determined for optimizing the process. Tracer tech- and injecting nitrogen in the upleg (1080 l/min) under
niques are used extensively for concentrationtime (C vacuum; NaCl was the tracer. A saturated solution of
T) diagrams. Conductivity and other measurements are NaCl was injected upleg and the variation of the con-
made continuously for simulating the process with ap- centration in the downleg end was evaluated through

341
Seshadri et al.

lowing equation resulted relating flow in the model and


prototype.

Qm 0.279Q p . (4)

Visualization techniques such as the use of video cam-


era, for measuring and recording the flow pattern and
speed was made, and camphor particles (whose den-
sity of 0.99 g/cm guaranteed the absence of gravita-
tional flow) in the feeding circuit served as a tracer. This
enabled analysis of turbulence levels and formation of
vortexes, depth of penetration of flow and the speed
Fig. 1. Circulation rate as a function of gas flow rate for physical model and measurement of ascending and descending flows.
industrial unit of Usiminas. Figures 24 show that the speed of the descending flow,
its depth and penetration are functions of the liquid ve-
locity and angle of inclination of the exit holes of the
continuous measurement of the electric conductivity at nozzle. This information was useful in the nozzle design
this location. From the CT diagram, circulation rate was and optimisation of flow and consequently diminishing
evaluated and the following correlation resulted for the inclusions etc in the casting.
model through regression analysis. In general the optimum condition was characterized
by a smaller depth of penetration of the flow of steel
NF r = 0.057NVa NRe .
0.192 0.33
(2)
and lower level of turbulence, which are obtained with
The rate of circulation in the industrial installation a submerged nozzle system with an exit angle so as
was evaluated using the correlation above. Fig. 1 repre- not to generate disturbances on the surface of the steel
sents the variation of the circulation rate with the argon solidifying.
flow rate and this is in agreement with the results of
other publications in the literature. The correlation be-
tween the rate of circulation and argon flow rate is given
by the equation

Tc = 5.89Q0.33 , (3)

where Tc is the rate of circulation in t/min and Q is the


gas flow NI/min.

Study of flow through submerged nozzle system in


the continuous casting unit of USIMINAS [14]
Liquid steel is fed into the continuous casting mould Fig. 2. Depth of penetration of flow as a function of water flow in the model
for mold thickness of 950mm for various inclination of exit nozzle.
through a submerged nozzle system with lateral exits.
This system is used for the protection of steel against ox-
idation and the generation of flow that favours the flota-
tion of the inclusions and its absorption by the mould
fluxes at the surface. Simulation of the flow in the mould
with submerged nozzle of the continuous casting unit of
USIMINAS was carried out for the analysis of the influ-
ence of the diameter, inclination of the submerged noz-
zle openings and of the operational parameters such as
width of the plate, casting speed depth of the submerged
nozzle system on the flow patterns in the mould using a
physical model built of acrylic on the scale 1:1.667. Use
of water as liquid dynamic similarity parameters was
evaluated using the Froude and Reynold criteria opting
for an equality of Reynolds number to guarantee the
same flow regime in the model and prototype. The fol- Fig. 3. Flux lines in the mold and level of turbulence.

342
Physical modeling simulations

Fig. 4. Velocity of descendant water flux in the mold (nozzle angle 0 ).


Fig. 5. Relation between Froude number and relative height, N Rh = ladle
(H)/ingot(h).

Analysis of flow of steel in indirect casting of steel Physical model for evaluation of mixing time
ingots in USIMINAS through cold modeling [15] during injection of gas through lance in the steel
In the indirect casting of steel ingots, the steel from ladle (project sponsored by COSIPA steel Co. Sao
the ladle flows into the vertical channel and distributes Paulo [16]
the same via horizontal channels for feeding the ingot The process of injection of gas and powders such as
molds. It is essential that the metal is fed in a manner CaSi and lime are used extensively to carry out effi-
minimising the problems generated by the impact of the cient desulphurization, dephosphorization etc, as this
jet of steel on the base plate as well as avoiding high cast- process improves the efficiency of interaction between
ing speed which can sometimes lead to the flow from metal and flux or slag. Injection is normally done
the top of the mold. Hence, the flow has to be optimised through a lance system or porous plug at the bottom
for improving production efficiency and final quality of of the ladle. The gas serves to homogenise the effect, ef-
products with respect to inclusions etc. For simulating ficient mixing, and promotes efficient degasification of
the indirect casting process, a water model was built at the melts, and the fine powder flux serves to improve
a scale of 1:1.887. efficiency of the refining reactions. One of the variables
Applying dimensional analysis to the process it can that is intrinsically linked to the hydrodynamic perfor-
be shown that mance is the efficiency of mixing and this is a function
of lance depth, diameter and design of the lance system
N f r = K (NRe )a (NRh )b . (5) such as 2 exits or 3 exits and the exit angle as well as gas
velocity.
In this equation, the Froude number represents the re- A study of the effect of these variables on time of mix-
lationship among inertial forces defined by the speed of ing was done using a physical model in the laboratory.
the jet in a free fall and the forces opposed to the same, Correlations obtained were extrapolated for the indus-
namely column of liquid in the ingot mold. N Re defines trial installation. Through a dimensional analysis, it can
the relationship between the forces of inertia and viscos- be shown that Froud and Reynold numbers as well as a
ity for flow through the channels. N Rh gives the height proportionality number relating gas and liquid flow are
relationship H/h, which represents the effect of energy important in the process.
contained in the jet starting from the decreasing height The model was built (acrylic ladle) at a scale of 1:5
(H) of metal in the ladle and that of the of the resistance (Fig. 6) using a group of lances for the injection of air
of the liquid column (h) ascending in the ingot mold. For in the water in the ladle and the following variables
the determination of the actual correlation between the are considered: (a) gas flow, (b) lance position (hori-
above dimensional numbers several experiments were zontal and vertical displacement); (c) lance type (two
carried out varying (H) of the level of water in the ladle three holes); (d) type of exit of the lance (horizontal
and (h) of the ingot mold. Through a regression analysis and inclined) and diameter of the lance hole. The time
the following correlation resulted; see Fig. 5 of mixing is defined as the requested time so that the
concentration of the tracer in a certain place reaches
NF r = 0.0812(NRh )0.387 (NRe )0.20 . (6) 95% concentration of the stationary regime after the

343
Seshadri et al.

for the nozzle in the model and in the prototype.


Dm = 0.40Dp . (10)

The time of mixing is the time necessary for the ho-


mogenisation of the tracer solution (15% NaCl) deter-
mined by the measurement of conductivity. This time
was evaluated in the static condition of the bath and af-
ter the establishment of the flow regime. As the time of
mixing is highly dependent on the viscosity, it is neces-
sary to introduce the proportion of viscosities between
water and liquid iron in the model (m) and prototype
(p), respectively in the computations
m 1
= = . (11)
p 5.56
This correlation was also applied in eq. (9) to correct
the value of Q m . Starting from experiments on the cold
model by varying the height of the lance, a mean value
was calculated (50 W/t). This value was used to develop
a correlation between T mix measured for different con-
ditions (flow variation, position of the lance and lances
with two or three holes) using regression analysis. The
Fig. 6. Lance positions in the physical model. results are for the static condition of the bath represented
in Table 1. The following observations can be made: (a)
the displacement and the penetration of the lance in the
addition of the tracer at another reference point. This bath decrease the time of the mixing, the former has
time is related to agitation intensity, defined by the work more influence than the latter, Figs. 7 and 8; (b) the time
that the gas accomplishes during the residence time in
the liquid phase (M tons) for unit of time due to ex- Table 1. Lance positions in the physical model
pansion caused by heating of liquid to temperature (T), # Central # Intermediate # Far left
expansion during its ascension in the bath and buoy-
1 Above ref. point 4 Above ref. point 7 Above ref. Point
ancy work. Considering all these, one can arrive at the 2 Ref. point 5 Ref. point 8 Ref. point
following expression for the total energy (E). 3 Below ref. point 6 Below ref. point 9 Below ref. Point
     
0, 006183 Q S
E= T 4, 60 log 1 + + 1 298 ,
M 144
(7)
and for the physical model
     
0, 006183 Q S
E= T 4, 60 log 1 + + 1 298 ,
M 1033
(8)
where S is the bath height above the hole of the lance
(cm).
The flow of air to be used in the model (Q m ) was eval-
uated equalling the flow number for the model and the
prototype and considering expansion of gas (17 times)
and flow in the real system (750 Nl/min).

Qm = 0.32Q p . (9)

The diameter of the hole of the lance in the model (D m ) Fig. 7. Variation of time of mixing with gas flow through Lance (type 3T
was arrived at equalling the modified Froude numbers ( = 7,0mm).

344
Physical modeling simulations

Fig. 9. Scheme for the nozzle locations and blockage.

level in the vacuum vessel amounted to 65 mm. These


are basic data for standard operation. Most of them have
been varied during the experiments in order to assess
their influence upon the operation.
Fig. 8. Variation time of mixing with gas flow through Lance (type 2T, = Nozzle blockage inside the upleg is frequent in indus-
5, 0 mm) and positions. trial practices. Blockage itself is not critical if circulation
rates can be kept at a safe level by further gas injec-
of mixing corresponding to the central deep position and tion. As will be shown the more important factor here
the use of 2T type of lance should improve the efficiency is not the number of nozzles blocked, rather it is the
of the process and avoid overflow risks. gas distribution. The location of the nozzles (diameter =
3 mm) in the upleg is given in Fig. 9. The distance be-
Physical modeling study of RH degassing process tween the two levels of injection amounted to 45 mm in
of CST to assess the effect of nozzle blockage, the physical model. Symmetrical (four nozzles at each
bottom injection in ladle and decarburization [18] injection level, uniformly distributed) and nonsymmet-
A physical model based on similarity principles was rical (four nozzles at each injection level, facing ladle
constructed for simulating the RH degasser of CST wall) locations of nozzles were blocked and the circula-
(Companhia Siderurgica Tubarao, Vitoria, ES, Brazil) tion rates were studied for different gas flow rates. For
to evaluate the circulation rate of the metal which es- symmetrical nozzle blockage, inside upleg, a small neg-
sentially defines the degree of exposure of the metal to ative change in the circulation rate was observed. It is
vacuum in the chamber and thus the refining rate. The apparent that a trend of lowering the circulation rate
circulation rate, on the other hand, will influence the de- with higher gas flow rates. This is probably due to a
carburisation rate and removal of dissolved gases like decrease in the liquid flow rate caused by higher frac-
nitrogen and hence it is essential to optimise this param- tion gas in the plume. In the case of nonsymmetrical
eter to get maximum refining efficiency with the mini- blockage, a lowering of 50% in the liquid flow rate was
mum refining times, thus improving the productivity of observed (Fig. 10). These changes were also observed in
the secondary refining process. the visualization of the flux with aniline additions.
The water model of the RH unit of the CST was Mixing characteristics in the ladle and circulation
fabricated (acrylic) with scale factor of 1:5 considering were evaluated by pulse tracer addition using conduc-
the geometric and dynamic similarity criteria based on tivity meters located at the downleg as well as at several
Reynolds (NRe) Froude (NFr) numbers as well as pro- locations in the ladle (see Fig. 11).
portional flow of gas and liquid in the system (Nva) The conductivity probes have been located close to
and modified Froud number (NFrm) for nozzle design the wall at three different levels; atthe bottom, at the
as in the case of the RH unit of USIMINAS reported in medium level and close to the liquid top. To assess the
reference 13. influence of the angular position they have been placed
Operational and geometrical parameters of the phys- in front of thesnorkels, by the down snorkel and the up
ical model were arrived at from the prototype applying snorkel. The results are not substantially different. The
similarity principles as mentioned earlier. The vacuum upper curve is for measurements made at downleg and
vessel is equipped with two snorkels and 16 nozzles in the lower curves are for conductivity data taken at dif-
the upleg (two levels). Air was used for injection through ferent levels inside the ladle. The fact that there is no
the nozzles. The upleg and downleg diameters were remarkable discrepancy between data derived from the
150 mm, snorkel immersion depth was 60 mm and liquid conductivity meters located at the ladle is an indication

345
Seshadri et al.

Fig. 10. Effect of the nozzle blockage on the circulation rate, without gas Fig. 12. Kinetics of degassing (with and without gas injection through
injection through porous plug as determined for the water model. porous plug). The abscissa axis is for gas injection through the upleg only.

where, C is the concentration of CO 2 [mol/l], Co is the


initial concentration of CO 2 , [mol/l]; A is the liquidgas
interfacial area [m2 ]; V is the volume of the liquid [l]; t
is the time [s]; K is the mass transfer coefficient for the
gasliquid interface.
It can be seen from Fig. 12 that increased degassing
rates result in increasing injection rate through nozzles
as well as rate of gas injection through a porous plug, as
these factors also increase the circulation rates.
To confirm if injection from the bottom can replace
injection through the nozzles as far as degassing is con-
Fig. 11. Rate of mixing vs rate of circulation. cerned, more experiments are necessary. It should be
remembered that degassing is also enhanced by higher
vacuum. Data for circulation with and without auxiliary
of the good state of mixing. However, the circulation gas injection, gas flow rate and apparent degasification
time inferred from data collected with the probe located parameters have been combined in order to highlight
inside the downleg, about half of the mixing time result- the influence of the circulation rate. The main objective
ing from probes inside the ladle; i.e. circulation rates, are was to assess if the same circulation rate would guar-
twice as higher. antee the same degasification. As shown in Fig. 13, the
Additional gas injection can be made through a degassification level is not the same even if the circula-
porous plug located under the upleg in order to improve tion rate is kept constant for different combinations of
and/or restore circulation just in case one or more noz- gas injection through the porous plug and upleg. For ex-
zles happen to be blocked. Experiments on the kinetics ample, a circulation rate of 10.5 [kg/s] can be achieved
of degasification CO 2 adsorption- desorption process in by different gas flow rates through the upleg nozzles
sodium hydroxide solution as circulating fluid and the
effect of, bottom gas flow rate in this case was also eval-
uated. This technique relies on the hypothesis that in
caustic solutions equilibrium among the species H 2 O (l),
H+ , OH , H 2 CO 3 aq, HCO 3 , CO 3 = , CO 2 aq e Na+ can be
achieved quickly, when the solution contacts a gaseous
phase containing CO 2 (g) and/or air. For a limited range
of pH (in this case 6 to 7), the reaction is predominantly
desorptionadsorption (CO 2(g) = CO 2aq ). Changes in the
pH values are then related to CO 2aq concentration. Thus
a macroscopic kinetic model can be proposed, assuming
perfect mixing. Accordingly,
Fig. 13. Effect of circulation rate upon degasification (for different rates of
LnC/Co = (K .A/V).t (12) gas injection through porous plug) as determined for the water model.

346
Physical modeling simulations

given in Fig. 14 and CAS-OB are examples of such reac-


tors. Their performance is dependent upon geometrical
characteristics as well as operational conditions, which
determine the flow field inside the vessel. A physical
model of the IR-UT process of the CST, a steel plant lo-
cated in Serra, Espirito Santo, Brazil, was developed to
assess the features of the flow field and its influence on
metallurgical behaviour. Results of the physical model
were used to optimize the process parameters in the in-
dustrial unit.
The principle of conducting alloy addition and blow-
ing oxidant within a slag-free space provided by a
snorkel is used for IR-UT processing. It utilizes a re-
fractory snorkel as a means to facilitate additions to the
ladle and to protect molten steel from uncontrolled re-
actions with the slag. Liquid steel can be homogenized,
Fig. 14. Schematic view of IR-UT.
alloyed, heated or cooled if necessary, by adding small
scrap pieces. Process control software are available for
Table 2. Comparison of degasification rates with and without auxiliary the process. The IR-UT heating is based on the chemical
injection reaction of aluminium with oxygen gas blowing on the
Injection metal surface. Inert gas stirring may continue for some-
conditions Working formula K.A/(2.303 V) time after reheating to ensure that the alumina particles
no auxiliary 0.0331 e0.2557Q 0.4851 formed during reheating are removed by flotation.
auxiliary 20 lpm 0.0116 Q2 + 0.4122 Q 2.5854 0.4638 The physical model of CST (Brazil), IR-UT, was built
auxiliary 33 lpm 0.0042 Q2 + 0.2089 Q 1.3353 0.3951 using plexiglass at a scale factor of 1:5. Water was used
for simulating liquid steel and compressed air was used
only or with some auxiliary gas plug injection. For this in place of argon. Air flow rate was monitored and
circulation rate and considering the working formulas controlled using mass flow meters (Omega Engineer-
from Table 2, a comparison can be made. ing, Inc., USA) and a range was chosen to cover the
To conclude, a physical model simulating the RH de- presumed operational conditions. The main parameter
gassing practice in the CST was satisfactory in verifying used for flow characterization was macroscopic mixing
the findings of the earlier works in the field such as the time as given by conductivity probes. Mixing time is
increase of circulation rates with increasing gas injection taken as the time required to have concentration sta-
rates in the upleg. The bottom gas injection practice, un- bilised within 5% of nominal concentration. Mixing time
der the upleg, improved the circulation rates. This effect is also a function of reactor geometrical parameters such
was more significant for low snorkel gas flow rate. A as number and degree of inclination of the agitation
nonsymmetrical nozzle blockage has been shown to be lance injection nozzles, relative to the position of the
deleterious to the process performance. A drop in circu- agitation lance with regard to the snorkel/vessel walls,
lation rate of approximately 50% was noted. However, snorkel dimension and depth of immersion, in addition
these effects were not important for symmetrical nozzle to gas flow rate. As far as the liquid flow is concerned,
blockage. Increasing circulation rates by bottom injec- dynamic similarity must be ensured. A common ap-
tion are followed by increasing degassing rates. The re- proach is to take the interaction between gas and liquid
sults were carried over to the prototype to optimize the as the driving force behind the flow field. The present
process. authors have assumed that the main characteristics of
liquid flow field of the prototype would be reproduced
Physical modelling of Injection Refining-Up by taking into consideration the Froude group and tur-
Temperature Process of theCompanhia Siderurgica bulent Reynolds group. That is, the momentum con-
de Tubarao, Brazil) [19] servation equation for isothermal flow and the constant
Steel refining reactors based on chemical heating are be- properties remain valid. Thus, an equation for turbulent
ing used as an alternative to ladle furnaces. They show viscosity characteristic of a liquid stirred by gas injection
a high degree of flexibility with respect to the heating can be introduced as part of the definition of turbulent
rate in addition to carrying out refining reactions such as Reynolds number. Proper manipulation leads to Q m =
de-S, inclusion removal, alloying etc. IR-UT process as 2.5 Q p .

347
Seshadri et al.

Fig. 15. Main features of the flow field, determined by laser sheet visualiza-
tion.

Laser sheet visualization was used for a first appraisal Fig. 16. Relationship between mixing times and gas flow rate determined
of the flow field. Particles of resin (S6H from Goodyear, with physical model for nominal conditions.
specific gravity 1040 kg/m3 ) were dispersed in water. A
plane of light was produced by making a beam impinge
on a glass rod. Then the path of those particles moving
on the plane was recorded by a digital domestic cam-
era (Sony). The movies could then be produced with
a domestic fame grabber (PCVision). Figure 15 shows
a schematic view for the flow observed in the vertical
plane defined as longitudinal axis and the stirring lance.
It makes apparent that the snorkel works for diverging
the main flow, which would otherwise be directed to the
metal surface. This main feature is not present at a regu-
lar ladle and is expected to show remarkable influence. Fig. 17. Optimal positioning of snorkel as function of gas flow rate.
A series of experiments were designed in order to assess
the influence of snorkel (with, without), snorkel depth
of immersion, snorkel diameter, distance between lance relationship between the specific energy of stirring, ,
and bottom of the ladle, and gas flow rate. and the mixing time, .
Preliminary experiments have shown that the gas
blown at the surface would not affect the mixing times = a . n , (13)
very much. Flow phenomena induced by chemical re- which would be specific for each class of reactor as they
actions or splashing due to shear stresses are obviously are defined by different geometry and arrangement of
important but cannot be promptly be simulated with stirring elements. Thus one should be able to evalu-
this kind of experiment. Thus, this work did not take ate the proper values of a and n for each combination
their possible effects into consideration. One can assume of ladle geometry, snorkel geometry, depth of immer-
that the very presence of the snorkel acting as a physical sion, number, shape and location of nozzels for a given
barrier would reduce the influence of the oxygen blast IR-UT.unit. As far as evaluating the specific stirring en-
at steel-free surface (contained inside the snorkel). Two ergy is concerned the present authors have chosen
kinds of representation were used to highlight the effects    
of many parameters. One of them shows mixing time as 8, 32 TI 9, 81 H
= TS 1 + ln 1 + Q, (14)
function of gas flow rate, other parameters being kept 22, 4M TS PA
constant (see Figs. 16 and 17). The present experiments where is the specific stirring energy, W/kg; M is the
with the physical model of IR-UT show a strong snorkel mass of liquid, kg; Q is the gas flow rate, STP, dm3 /s;
influence. As shown in Fig. 17, an optimum value of T S is the temperature of steel, K; T I is the temperature
depth of immersion of the snorkel seems to exist. For this of gas, K; is the liquid specific gravity, kg/m; H is the
value, the mixing time is minimum, which is, however, depth of injection, m; P A is the ambient pressure, Pa.
dependent on the gas flow rate. Mixing time curves flat Some relevant equations for gas flow up to 200 lpm
out when the gas flow rate increases, suggesting that for are as follows:
a given specific stirring energy small snorkel positioning 1. Influence of snorkel diameter, 4 cm immersion.
errors should not be significant. That would character-
ize a robust modus operandi. The other [22] employs a ln no = 0.3144 ln + 2.453, (15)

348
Physical modeling simulations

ln 34 = 0.3144 ln + 2.453, (16) Table 4. Predicted mixing times as a function of the distance between the
lance and bottom of the ladle

ln 45 = 0.3144 ln + 2.453, (17) Distance lance to bottom of the ladle [cm] [w/kg]

where the subscripts refer to no snorkel, 34 cm snorkel 4 6 8 10


[s] 42 42 42 44 0.040
and 45 cm snorkel.
[s] 46 47 47 50 0.028
2. Influence of the lance to the bottom of the ladle
distance. blockage has been reported in some cases. Because the
ln 4 = 0.2936 ln + 2.7813, (18) lance is positioned far from the reactors longitudinal
axis, a nonsymmetrical flow field could result and this
ln 6 = 0.3243 ln + 2.6843, (19) may pose a problem. A nonsymmetrical flow field is not
a problem by itself. In fact it is usually more efficient for
ln 8 = 0.3071 ln + 2.7588, (20) mixing purposes as shown by trial experiments with the
model. However, some combinations of nozzle block-
ln 10 = 0.3714 ln + 2.5804. (21) age, i.e. number and sequence, can be very detrimental
in this respect.
The relationship arrived at can be used to make es-
timations for the industrial unit under different condi- Assessment of the performance of the tundish of a
tions or to forecast variations if not absolute values. For 6-strand continuous casting unit of Companhia
getting specific absolute values, experiments must be Siderurgica Belgo-Mineira, Brazil using physical
conducted in the plant, which is rather difficult. Prelim- modeling [21]
inary calculations have indicated specific stirring energy This work described the characterization of the perfor-
values around 0.04 0.06 W/kg for the industrial unit. If mance of the tundish of a 6-strand continuous casting
one takes into consideration the above-mentioned val- unit of the Companhia Siderurgica Belgo Mineira, Joao
ues of stirring energy then a model gas flow rate close to Monlevade, Brazil, using physical modelling. Perma-
200 Nl/min would be required to match the model and nent and transient conditions, due to ladle metal com-
the prototype. At this level the mixing time differences position changes, were considered. For transient con-
would not be significant. As a matter of fact they are not ditions, due to ladle change, the degree of intermixing
important for flow rates higher than 50 Nl/min. and the minimum residence time are determined with a
Mixing times are shown for two snorkel diameters view to optimizing the process. Reduction of the effect
and for no snorkel present in Table 3. Mixing times of ladle change requires different approaches. During
are shorter without a snorkel acting as a flow bar- ladle changeover the level of metal inside the tundish
rier. Although mixing is more effective for no snorkel decreases to a minimum and then is restored to regu-
or snorkels of increasing diameters the difference may lar levels usually by increasing the pouring rate to the
not be important at relatively high flow rates. The maximum allowed by the ladle/gate assembly. The re-
same kind of conclusion is reached with respect to the filling period is characterized by a metal stream of high
positioning of the stirring lance. Skulls or premature kinetic energy, impinging on the slag layer. Partial emul-
lining failure could make it difficult to assess the true sification of the slag happens during this process. Also,
distance lance/bottom of the ladle. This can be an impor- in some instances, vortex formation is significant. These
tant factor mainly at low gas flow rates. At higher flow conditions can lead to slag being drawn into the mold
rates, the flow behavior as evaluated by the mixing time resulting in a product of low internal soundness. A in-
is not remarkably affected by even deliberate misposi- termix product is the natural result of sequential casting
tioning of the lance. Again, a robust operation almost of different grades. Decreasing the incidence of stream
insensitive to regular fluctuations can be expected (see break-up as well as that of air-molten steel contact
Table 4). would be fundamental to reducing the levels of metal
The availability of a lance designed for powder injec- reoxidation during ladle changeover operations. Other-
tion is an important feature of IR-UT. However, nozzle wise macro cleanness and mechanical properties will be
adversely affected in addition to resulting in possibly
Table 3. Comparison of predicted mixing times at different snorkel diam- smaller aluminium residual contents and higher nitro-
eters gen contents. Slag entraining is also a factor contribut-
(s) no snorkel 45 cm snorkel 34 cm snorkel [w/kg] ing to mold metal contamination because a heavy slag
cover can result in the tundish during sequential cast-
31,97 38.66 41.52 0.04
ing. Experiments suggested that the thermal gradient is

349
Seshadri et al.

the cause of flow reversal when high-temperature steel


from a new ladle interacts with the cold metal of the
previous ladle. This behaviour is also dependent upon
the combination of buoyancy forces, inertial forces and
geometrical parameters and has been the object of many
investigations. The problems cited during the transients
can be resolved to some extent by increasing the tundish
working volume if there is a possibility. Generally, loss of
material quality is ascribed to inclusions resulting from
free pouring and excessive refilling rates and also to in-
termix produced by a slow transition between different
grades. Increasing the working volume should normally
enhance inclusion entrapment and intermix generation.
Ideally, a product mix should allow one to reduce or Fig. 18. Parameters for evaluating flow performance.
eliminate the transitional plate (or bloom, or billet). For
some applications the inclusion counting can be not Table 6. Values for transient isothermal ladle change
quite important. So an optimal design is to be aimed Average each pair of strands
at by each plant and the results of physical modelling 13 tons; 2Q o #1, # 6 # 2, # 5 #3, # 4
T min (s) 91.71( 10) 62.68(4) 11.54(1)
can make important contributions in this respect. The fo- intermix (ton) 2.48( 0.38) 1.05( 0.39) 0.38(0,04)
cus of this work was to generate a relationship between (ton/min) 0.34 0.34 0,.4
geometry/operational parameters and the metallurgi- Average for each pair of strands
17,8 tons, 2Q o #1, #6 #2, #5 #3, #4
cal behaviour of a 6-strand billet casting machine. The T min (s) 167.75(17) 89.36(12) 24.04(4)
acceptable conditions for a steady-state operation were Intermix(ton) 3.32(0,52) 1.72(0,17) 0.50(0,08)
determined by a comparison between a tundish without (ton/min) 0.34 0.33 0.34
Average for each pair of strands
any sort of flow modifiers and a tundish with modifiers.
13 tons, 3Q o #1, #6 #2, # 5 #3, #4
The recommended configuration can then be applied Tmin (s) 81.86(9) 45.33(4) 8.40(1)
to transient experiments related to ladle changeover. In intermix (ton) 2.21(0.22) 1.27(0.13) 0,25(0,05)
addition to geometry the effects of the rate of refilling, (ton/min) 0.34 0.34 0.34
Average values for each pair of strands
minimum level of metal, thermal gradient and casting 17,8 tons, 3Q o #1, #6 #2, #5 # 3, # 4
rate have also been assessed. T min (s) 112.39(13) 50.11(6) 13.64(1)
A 1:3 plexiglass model of the tundish of the 6-billets intermix (ton) 4.19(0,65) 1.96(0.43) 0.93(0.11)
(ton/min) 0.34 0.34 0.34
continuous casting machine of Belgo Mineira SA, Joao
Monlevade, Brazil was built using similarity criteria. It
is a tee-shaped tundish, with 28 tons of nominal capac-
The working level is recovered by refilling at refilling ra-
ity operating at 2.10 tons/min. The experimental set up
tios of 2 or 3, as compared with the nominal throughput.
includes flow meters for cold and hot inflow streams
The graph presented here is an idealized one; the actual
as well as at each strand; conducivity measurements at
curves can show a short circuit, especially if flow rever-
each strand in the cold model. Data acquisition is made
sal is present as in the case for some nonisothermal tran-
through an A/D board. Similarity criteria for isothermal
sients. The reference time, zero, for the experiment was
flow are presented in Table 5. As far as nonisothermal
taken to be the instant when the inflow is stopped. From
flow is concerned the similarity criterion T.) steel =
then on, the liquid level decreases during a time interval
T.) water was obeyed.
called draining interval, t D , from the nominal working
A step tracer addition technique has been adopted
volume V T to a minimum V MIN . V MIN is reached at t =
and S-type cumulative curves have arisen (see Fig. 18).
t D when refilling starts at refilling ratio f ,
As shown the liquid volume is allowed to decrease to

13 tons or 17.8 tons from the working volume of 28 tons. Q0 = f. Qi . (22)

Parameters and time interval used for flow character-


Table 5. Similarity criteria for isothermal flow ization were defined from t = t D . A minimum residence
Ratios for model/prototype conversion time, t 2%, was defined as the time interval required for
Dimension Area Volume Velocity Flow Time a 2% level of transition to be reached from t D . The mix-
ing of steel from ladles cast sequentially should be the
2 3 1/2 5/2 1/2
cause of intermix production. Twenty percent and 70%

350
Physical modeling simulations

transition measured at the normalized concentration Internal strands:


curve have been set as lower and upper boundary for the
intermix production. Time intervals are, respectively, t ID t2% = 181.003 57.04 f + 19.66VMIN r 2 = 70, (34)
and t FD . The intermix was evaluated as

Di = (tF D tI D )Qi . (23) D = 3.99 + 0.967 f + 0.081VMIN r 2 = 81. (35)

The average values for the transient isothermal (i.e. for Comparison between isothermal and nonisothermal
a hypothetical operation where there would be no tem- data shows a smaller degree of confidence for intermedi-
perature difference between the incoming and outgoing ate strands t 2% estimates. Flow reversal was observed in
ladles) simulations are presented in Table 5 (figures in some nonisothermal experiments and that was charac-
parenthesis are for 95% confidence interval). terized by short circuit at strands 3 and 4, which should
The effects of refilling ratio, throughput, working vol- result in a certain degree of uncertainty of minimum
ume, minimum level during ladle changeover, and ge- residence time at these strands.
ometry were assessed as follows. Minimum residence With respect to the minimum residence time during
times are (much) smaller for transient conditions as com- ladle change-over transient it is necessary to remember
pared with steady-state operations. Minimum residence that in some cases the free stream of steel impinging over
times are smaller for the higher refilling rate and the the slag cover could promote slag emulsification. In this
smaller minimum level of liquid. Transition for the in- case the issue is not inclusion flotation but rather the
ternal strands is sharper than transition for the external dispersing of the emulsion. In that sense larger values
strands. The level of influence varies according to the of minimum residence time are favourable.
strand location and each should be analysed separately. The optimisation of internal design parameters of
Stepwise multiregression resulted in following corre- tundish should lead to maximizing the minimum res-
lations for transient isothermal. idence time; that would improve the efficiency of inclu-
External strands: sion flotation or emulsification dispersion. Minimizing
intermix production would also be a goal.
t2% = 25.70 33.20 f + 11.10VMIN r 2 = 71, (24) The effects of flow obstacles geometry vary according
to the strands, especially in the tee-shaped tundish.
D = 2.45 + 0.383 f + 0.295VMIN r 2 = 51. (25) The transition for internal strands was sharper than
the transition for external strands; the relationships be-
Intermediate strands: tween minimum residence time and minimum level of
t2% = 86.70 29.80 f + 3.24VMIN r 2 = 71, (26) liquid, refilling rate were evaluated.

D = 0.87 + 0.189 f + 0.125VMIN r 2 = 35. (27)


Conclusions
The use of a physical or cold model to simulate processes
Internal strands: of high temperatures is attractive as it can be done with
t2% = 4.73 6.57 f + 1.68VMIN r 2 = 82, (28) ease and at low cost using principles of similarity. Ex-
periments can be conducted with great flexibility vary-
ing many important parameters of the process. Low re-
D = 1.17 + 0.167 f + 0.081VMIN r 2 = 63. (29)
search cost and noninterference in the operation rhythm
Experimental data were also available for nonisother- of the industrial installation are additional advantages.
mal transient conditions, T = 20 C. Stepwise multiple Even a mathematical model simulating the operation
regression results in the following correlations. at an industrial scale can be first tested in the physical
External strands: model.. The examples cited above were the fruit of ac-
tive collaboration between industry and university in
t2% = 98.78 8.44 f + 1.87VMIN r 2 = 59, (30) the field of modelling, where both parties have gained;
the industry in terms of improving and optimising ex-
D = 1.78 + 0.84 f + 0.166VMIN r 2 = 75. (31) isting process parameters and the university in terms of
academic contributions.
Intermediate strands:

t2% = 155.93 9.61 f + 0.742VMIN r 2 = 36, (32) Acknowledgements


We would like to thank the respective steel compa-
D = 4.183 + 0.551 f + 0.205VMIN r = 81.
2
(33) nies in Brazil for sponsoring the projects and also

351
Seshadri et al.

financing institutions such as CNPq and FAPEMIG in 16. Bentes MAG, Seshadri V. In: Proceedings 3rd beneficiation
Brazil. and Agglomeration 1991, Bhubaneswar, India, 93110.
17. Viera UA, Seshadri V. In: Proceedings of the International
Congress on Iron and Steel Technology in Developing
References Coutries (ISTDEC-91), St. Augustine Trinaidad-Tobago
1991: 95106.
1. Franks RGE. Mathematical Modeling in Chemical Engi- 18. da Silva CA, da Silva IA, EM de Castro Martins, Seshadri
neering. John Wiley and Sons, New York, 1967: 125. V, Perim CA, Filho GAV. Ironmaking and Steelmaking.
2. Szekeley J. Met Trans B, 1988: 19B: 525539. London 2004: 31: 3742.
3. Johnstone RE, Thring MW. Pilot plants and scale up meth- 19. da Silva CA, da Silva IA, Seshadri V, da Silva CMG, de
ods in chemical engg. McGraw-Hill, New York, 1977: 130. Paula Alves M, Fracalossi Jr EC, Perim CA, Barao CD.
4. Levienspiel O. Chemical reaction engineering 3rd edn. In: Proceedings of Yazawa International Symposium Met-
John Wiley & sons, New York, 1999: 257361. allurgical and Materials Processing: Principles and Tech-
5. Miwa EK. Metalurgia A.B.M. 1984: 40: 611627. nologies. TMS 2003: 2: 715728.
6. Miwa EK, Barbosa JC, Gomes AJ, Seshadri V. Metalurgia 20. da Silva CA, da Silva IA, Seshadri V, Perim CA, Gandra
A.B.M. 1986: 42: 95101. CA. International Conference on Advances in Materials
7. Miwa EK, Seshadri V. IPT-UFMG. Maio 1989: II: 1290. and Materials Processing (ICAMMP 2002) Tata McGraw
8. Seshadri V, Preira RO. In: Proceedings of the International Hill Publishing Company Limited New Delhi, India, 561
Symposium on Agglomeration Iron and Steel Soc. 1985: 567.
729744. 21. Silva MSS, da Mota EG, Fracalossi Jr EC, da Silva CA, da
9. Seshadri V, Preira RO. Trans. Iron and Steel Inst of Metals Silva IA, da Costa Neto JG, Seshadri V. Proceedings of
of Japan 1986: 26: 604610. Yazawa International Symposium Metallurgical and Ma-
10. Ribeiro WJ, Seshadri V. Modelo Matematico de lingota- terials Processing, TMS 2003: 2: 729739.
mento contnuo de tarugos de aco. Anais do 46 Congresso 22. Nakanishi K, Fujii T, Szekely J. Ironmaking and Steelmak-
Anual da ABM, Sao Paulo, S.P., 1991: 3: 379399. ing 1975: 3: 193197.
11. Seshadri V, Silva CA, Silva IA, d Von Kruger. ISIJ Inter-
national 1997: 37: 2130.
12. Seshadri V, da Silva CA, da Silva IA. Materials and Man-
ufacturing Processes 2002: 17(5): 693713.
13. Seshadri V, Costa SLS. Trans of Iron and Steei Inst of Japan Address:
1986: 26: 135138. Varadarajan Seshadri
14. Sidmei O, Costa de Andrade MJ, Mundim, Seshadri V. Department of Metallurgical Engg and Materials
Metalurgia ABM 1986: 42: 401405. Universidade Federal de Minas Gerais
15. de Oliveira RNB, Costa SLS, Seshadri V, Analise do Fluxo Rua Espiritosanto 35
de aco no lingotamento indireto atraves de modelamento Belohorizonte
a frio. Anais do XIL Congresso Anual da ABM. Sao Brazil
Paulo/SP. 1986: 473484. E-mail: seshadri@demet.ufmg.br

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