Académique Documents
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ON
PRESENTED BY
NAME ANURAG SINGH
SESSION - 2017-2018
SEMINAR CO-ORDINATOR
Prashant Chauhan
JSS MAHAVIDYAPEETHA
JSS ACADEMY OF TECHNICAL EDUCATION, NOIDA
DEPARTMENT OF MECHANICAL ENGINEERING
JSS MAHAVIDYAPEETHA
JSS ACADEMY OF TECHNICAL EDUCATION
DEPARTMENT OF MECHANICAL ENGINEERING
CERTIFICATE
Date:
Hydrogen powered vehicles have been in development from the past decade. While the
attention to hydrogen fuel cell vehicle is increasing. Hydrogen internal combustion
engines may prove to be the most effective solution for the immediate future. Over
various research carried out in comparison of hydrogen as fuel to gasoline, hydrogen
was the most efficient for performance and utilization. But the finalized development
and releasing for public use may take over long period of time.
TABLE OF CONTENTS
1. Introduction
1.1. Motivation for use of hydrogen as transport fuel
1.1.1. Hydrogen
1.1.1.1 Chemical properties of Hydrogen
1.2. Introduction to hydrogen fuel vehicles
1.3. Applications
1.3.1. Automobiles
1.3.1.1 Buses
1.3.1.2 Bikes
1.3.1.3 Airplanes
1.3.1.4 Fork Trucks
1.3.1.5 Rockets
1.4.1 Advantages
1.4.2 Disadvantages
1.5 Hydrogen Production
1.6 Hydrogen storage
1.7 Hydrogen technology development in India
2. Literature survey
3. Objectives
4. Methodology
4.1. Working of hydrogen fuel cell
5. Conclusions
6. References
LIST OF FIGURES
SL no Title Page no
1. Hythane vehicle by Volvo, Multi Fuel 3
7. Reforming of Biomass 9
A vehicle using hydrogen as its fuel for power generation is known as hydrogen vehicle.
Automobiles considering various transportation vehicle like cars, buses, bikes and
cycles, as well as space rockets using hydrogen fuelled termed as hydrogen vehicle.
The main process of utilizing this energy is by converting the chemical energy of
hydrogen molecules to mechanical energy either by burning hydrogen in an internal
combustion engine by reacting hydrogen with oxygen in a fuel cell to run the electric
motors. The proposed hydrogen fuel vehicle in commercial use over worldwide is due
to ease of hydrogen for fuelling transportation as key element. Hydrogen acts as a good
energy carrier and it can be produced by using renewable sources. As of 2014, 95% of
hydrogen is made from methane. The low cost of producing the hydrogen is from
electrolysis of water. Although evolving hydrogen is an expensive process to use, this
process can help us to save the fossils fuels for future fulfilling the future demand and
supply without stock out.
Hydrogen FCVs are a potential option for reducing emissions from the transportation
sector. Combusting fossil fuels to power conventional vehicles releases GHG (Green
House Gas like Water vapor, Carbon dioxide, Methane, Nitrous oxide, Ozone,
Chlorofluorocarbons) emissions and other pollutants from the vehicle exhaust system
(i.e., tailpipe emissions). In addition, there are also emissions associated with
producing petroleum-based fuels (i.e., upstream emissions), notably emissions from
oil refineries. FCVs emit no tailpipe GHGs or other pollutants during vehicle operation,
and depending on how hydrogen is produced, there can be substantially lower upstream
GHG emissions associated with producing hydrogen fuel. One kilogram of hydrogen is
roughly equal to one gallon of gasoline (on an energy level).
1.1 Motivations for use of hydrogen as a transport fuel
Of all the potential applications for hydrogen it is perhaps its potential for use as a
transport fuel that has provoked the greatest interest around the world. There are a
number of social and political motivations for a transition to hydrogen as a transport
fuel, from decarbonizing the transport sector to reducing dependency on imported oil.
The key motivations are summarized below
1.1.1 Hydrogen
Simplest element in the universe one proton and one electron
Occurs naturally as a gas
Can be used to create energy through combustion or use in fuel cells
Most hydrogen is bonded to oxygen in the form of water (H2O)
Can be produced through the use of nuclear, solar, wind, and other renewable
sources
Diversity of sources make hydrogen available alternative fuel
Steam methane reforming (CH4 )
Hydrogen has long been considered as the wonder-fuel of the future.
Huge number of companies are in process to develop technologies that might efficiently
exploit the potential of hydrogen energy for use in motor vehicles with better output.
As of November 2013 there are demonstration fleets of hydrogen fuel cell vehicles
undergoing field testing including the Chevrolet Equinox Fuel Cell, Honda FCX
Clarity, Hyundai ix35 FCEV and Mercedes-Benz B-Class F-Cell. There are three
main options for hydrogen vehicles, presenting differing degrees of technical challenge.
These options are as follows:
Mazda realized the potential benefits of hydrogen at an early stage, and has since been
engaged in development of hydrogen vehicles. In February 2006, Mazda became the
first company in the world to commercialize a hydrogen rotary engine vehicle, when it
began commercial leasing of the RX-8 Hydrogen RE in Japan. Since then, Mazda has
delivered RX-8 Hydrogen RE vehicles to national and local government authorities as
well as private enterprises. The main motto for introducing hydrogen fuel vehicle by
this company was to reduce the global warming as 20% of global warming is caused by
transportation sector.
Fig: Hydrogen fuel cell vehicle by Toyota
In Lexus RX450h designed by Toyota motor company, the front wheels are driven by
electric motor generated by chemical reaction in the hydrogen-powered fuel cell stack
located under the floor of the Mirais passenger compartment and the remaining layout
was same as normal. Water vapour was the only emission, some of which is recycled
to humidify the process.
1.3 Applications
1.3.1 Automobiles
Although there are currently no fuel cell cars available for commercial sale, over 20
FCEVs prototypes and demonstration cars have been released since 2009. Automobiles
such as the;
Fuel cell electric vehicles have driven more than 3 million miles, with more than 27,000 re-
fuelling.
1.3.1.1 Buses
There are also demonstration models of buses, and in total there are over 100 fuel cell
buses deployed around the world today.
Most of these buses are produced by UTC Power, Toyota, Ballard, Hydrogenics, and
Proton Motor.
UTC buses have already accumulated over 970,000 km (600,000 mi) of driving.
Fuel cell buses have a 30-141% higher fuel economy than diesel buses and natural gas
buses.
In 2005 the British firm Intelligent Energy produced the first ever working hydrogen
run motorcycle called the ENV (Emission Neutral Vehicle).
The motorcycle holds enough fuel to run for four hours, and to travel 160 km (100 mi)
in an urban area, at a top speed of 80 km/h (50 mph).
Hydrogen fuel cell vehicle
The Suzuki Burgman received "whole vehicle type" approval in the EU.
1.3.1.3 Airplanes
The Fuel Cell Demonstrator Airplane, as it was called, used a Proton Exchange
Membrane (PEM) fuel cell/lithium-ion battery hybrid system to power an electric
motor, which was coupled to a conventional propeller.
In 2003, the world's first propeller driven airplane to be powered entirely by a fuel
cell was flown.
The first production HICE forklift truck based on the Linde X39 Diesel was
presented at an exposition in Hannover on May 27, 2008. It used a 2.0 litre, 43 kW
(58 hp) diesel internal combustion engine converted to use hydrogen as a fuel with
the use of a compressor and direct injection.
Hydrogen fuel cell vehicle
A fuel cell forklift (also called a fuel cell lift truck or a fuel cell forklift) is a fuel
cell powered industrial forklift truck. In 2013 there were over 4,000 fuel cell
forklifts used in material handling in the US.
1.3.1.5 Rockets
Many large rockets use liquid hydrogen as fuel, with liquid oxygen as an oxidizer.
Advantage of hydrogen rocket fuel is the high effective exhaust velocity compared
to kerosene/LOX (Liquid - Oxygen combination) or UDMH
(Unsymmetrical Dimethyl hydrazine) /N2O4 (Nitrogen tetroxide) engines.
According to the Tsiolkovsky rocket equation, a rocket with higher exhaust velocity
needs less propellant mass to achieve a given change of speed. Before combustion,
the hydrogen runs through cooling pipes around the exhaust nozzle to protect the
nozzle from damage by the hot exhaust.
1.4.1 Advantages
1) Created from water, can be recycled to produce more hydrogen
2) Cleanest fuel available when combusted produces carbon monoxide, carbon
dioxide, or hydrocarbon emissions
3) Hydrogen fuel cell vehicles (FCVs) have a significant potential to reduce emissions
from the transportation sector, because they do not emit any greenhouse gases
(GHGs) during vehicle operation. Their lifecycle GHG emissions depend on how
the hydrogen fuel is made.
4) Leaks/spills will quickly evaporate and do not pose any threats to the environment
5) Several major hurdles to commercial deployment must be overcome before any
environmental benefits from FCVs are realized. These challenges include the
production, distribution, and storage of hydrogen; fuel cell technology; and overall
vehicle cost.
6) Domestic production will allow for energy independence
Hydrogen fuel cell vehicle
1.4.2 Disadvantages
1) Conceptually, replacing the current oil-based infrastructure with hydrogen would
cost billions, maybe trillions, of dollars.
2) Although abundant in the universe, hydrogen is fairly rare in our atmosphere,
meaning that it has to be extracted (for example through electrolysis, as explained
above) and currently, the process is cost prohibitive and inefficient.
3) It is a very flammable gas (think of the Hindenburg), which further adds to the on-
board storage problems. Its production at energy plants creates excessive carbon
dioxide.
4) Low energy content per unit volume
5) The large investment in infrastructure that would be required to fuel vehicles.
"heliostats"
Using waste heat from advanced nuclear reactors
Hydrogen storage in present context of development is the biggest problem for research
workers. According to the January 2003 Office of Technology Policy report, fuel Cell
Vehicles is race to a new automotive future. The needs of consumers in a fuel cell
vehicle are un-fulfilled due to inadequate hydrogen storage system. The difficult raised
for storage of hydrogen is because of its low density.
Existing and proposed technologies for hydrogen storage include;
cylinders. Compressed gas storage in such tanks has been marked at a pressure of
34 MPa with a mass of 32.5 kg and volume of 186 L, sufficient for a 500-km range.
However, this tank volume is about 90% of a 55-gallon drum, rather large for
individual automobiles.
2) Liquid storage (cryogenic storage): While having potential weight and volume
advantages, cryogenic method with activated carbon as adsorbent requires liquid
nitrogen temperatures and 2 MPa to hold the physically adsorbed hydrogen.
3) Carbon Nanotube and Related Storage Technologies: It is still unclear about the
status of using advanced carbon materials for the storage of hydrogen. Reviewing
the status of single walled, double walled, graphite nanofiber stack storage and other
carbon-based storage technologies that have been proposed include alkali-doped
graphite, fullerenes, and activated carbon, high surface area and abundant pore
volume in the nanostructured materials make these especially attractive as potential
absorption storage materials.
5) Some others storage system like underground storage system and line storage
system.
2. LITERATURE SURVEY
Fuel cells are more an evolutionary technology than a revolutionary one. Originally
invented in the early 1800s, the technology was developed gradually before being given
a boost through use in the NASA Apollo space program in the late 1960s and early
1970s. During this period the first fuel cell car was demonstrated by General Motors
and was followed by several other early Fuel cell Electric Vehicle demonstrations, all
based on alkaline fuel cell technologies similar to those developed for NASA. Fuel cells
using proton exchange membranes, the type now used in fuel cell electric vehicle, were
first developed in 1958 but it took until 1993 for the technology to become viable
enough for vehicle demonstrations.
3. OBJECTIVES
1) Alternative for the existing exhausting fuels and reduced pollution with good energy
economy and concentrating on Hydrogen fuel cell vehicle
4) Determine the benefits, if any, of adapting HICEs now, rather than waiting for fuel
cells to become available
5) Comparing the performance of hydrogen fuel cell vehicle with others competing
technology
6) Availing the safety and public acceptance profit if HFV introduced as infrastructure
Hydrogen fuel cell vehicle
4. Methodology
4.1 Working of hydrogen fuel cell
1) Hydrogen is chaneed through field flow plates to anode on one side of the fuel cell
while oxygen from the air is chaneled to the cathode on the other side of the cell.
2) At the anode ,a platinum catalyst causes the hydrogen to split into positive hydrogen
ions (protons) and negatively charged electrons.
3) The Polymer Electrolyte Membrane (PEM) allows only the positively charged ions
to pass through it to the cathode .The negatively charged electrons must travel along
an external circuit to the cathode , creating an electrical current.
4) At the cathode , the electons and positively cahrged hydrogen ions combine with
oxygen to form water, which flows out of the cell
Hydrogen fuel cell vehicle
A fuel cell vehicle (FCV) or fuel cell electric vehicle (FCEV) is a type of vehicle which
uses a fuel cell to power its on-board electric motor. Fuel cells in vehicles create
electricity to power an electric motor, generally using oxygen from the air and
compressed hydrogen. A fuel cell vehicle that is fueled with hydrogen emits only water
and heat, but no tailpipe pollutants, therefore it is considered a zero-emissions vehicle.
Depending on the process, however, producing the hydrogen used in the vehicle may
create pollutants. Fuel cells have been used in various kinds of vehicles including
forklifts, especially in indoor applications where their clean emissions are important to
air quality, and in space applications. The first commercial production fuel cell
automobiles are being sold in California by Toyota and leased on a limited basis by
Hyundai, with additional manufacturers planning to enter the market. Furthermore, fuel
cells are being developed and tested in buses, boats, motorcycles and bicycles, among
other kinds of vehicles.
planned, particularly in California. New stations are also planned in Japan and
Germany. Critics doubt whether hydrogen will be efficient or cost-effective for
automobiles, as compared with other zero emission technologies, such as the battery
electric vehicle.
5. Conclusions
1) Hydrogen Fuel cell vehicles are currently being researched for their feasibility of
widespread usage in automobiles and other forms of transportation.
2) Hydrogen fuel does not occur naturally on Earth and thus is not an energy source,
but is an energy carrier. Currently it is most frequently made from methane or other
fossil fuels.
3) However, it can be produced from a wide range of sources (such as wind, solar, or
nuclear) that are intermittent, too diffuse or too cumbersome to directly propel
vehicles.
Hydrogen fuel cell vehicle
6. References