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Acid-Base Theories
2. Arrhenius
Arrhenius acids are compounds that contain hydrogen that ionize to
yield hydrogen (H+) ions in aqueous solution.
H O
I II
H-C-C-O-H ethanoic acid (C CH3COOH)
I
H
The structural formula shows that the three hydrogens are in weakly
polar bonds.
3. BrØnsted-Lowry
A Bronsted-Lowry acid is defined as a hydrogen-ion donor, while a
Bronsted-Lowry base is a hydrogen-ion acceptor.
6. Ionization of H2O
Water shows a very small conduction. That was the result from self-
ionization or autoionization, a reaction in which two like molecules
react to give ions.
Kc = [H+][OH-]
[H20]
[H2O]K = [H+][OH-], and the value of the constant is called the ion-
product constant for water (Kw). At 25º C, the value of Kw is 1.00 x 10-14.
pOH = -log[OH-]
pH + pOH = 14
pH = 14 – pOH
pOH = 14- pH
8. Indicators
An indicator (In) is a weak acid or base that undergoes dissociation
in a known pH range. In this range, the acid or base is a different color
from its conjugate bases or acid.
Acid neutral Base
[H+]
100 10-1 10-2 10-3 10-4 10-5 10-6 10-7 10-8 10-9 10-10 10-11 10-12 10-13 10-14
(mol/L)
pH
pH 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14
range
pH 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 pH
9. Buffers
Buffer is a solution characterized by the ability to withstand changes
in pH when limited amounts of acid or base are added to it.
Most buffers contain a weak acid and its conjugate base, or a weak
base and its conjugate acid.
10.Neutralization
Neutralization is a reaction in which an acid and a base react in an
aqueous solution to produce a salt and water.
Examples:
HCl (aq) + NaOH (aq) → NaCl (aq) + H2O (l)
H2SO4 (aq) + 2KOH (aq) → K2SO4 (aq) + 2H2O (l)
1.1.1.Titration
The amount of acid or base in a solution can be determined
by carrying out a neutralization reaction. An appropriate acid-
base indicator is used to show when neutralization has occurred.
Phenolpthalein is often the indicator for acid-base neutralization
reactions. Solutions that contain this indicator turn from colorless
to deep pink as the pH of the solution is changed from acidic to
basic. Neutral solutions are very faintly pink.
Steps in Titration
1.A measured volume of the unknown concentration is added
to the flask.
2.The indicator is added to the solution.
3.Measured volumes of a base known concentration are mixed
into the acid until the indicator barely changes color.
1.1.2.Equivalents
One equivalent is the amount of an acid (or base) that will
give one mole of hydrogen (or hydroxide ions).
1.1.3.Normality
An older unit sometimes used to express the equivalents of an
acid and base is normality. Normality of a solution is the
concentration expressed as the number of equivalents of solute
in 1 L solution.
A solution containing 1.0 equiv of an acid or base per liter has
a normality of 1.0
N1V1=N2V2
Actetates
AgC2H3O2 -- 2 x 10-3
Bromides Cr(OH)3 -- 4 x 10-38
AgBr -- 5 x 10-13 Fe(OH)2 -- 1 x 10-15
PbBr2 -- 5 x 10-6 Fe(OH)3 -- 5 x 10-38
Mg(OH)2 -- 1 x 10-11
Carbonates Zn(OH)2 -- 5 x 10-17
BaCO3 -- 2 x 10-9
CaCO3 -- 5 x 10-9 Iodides
MgCO3 -- 2 x 10-8 AgI -- 1 x 10-16
PbI2 -- 1 x 10-8
Chlorides
AgCl -- 1.6 x 10-10 Sulfates
Hg2Cl2 -- 1 x 10-18 BaSO4 -- 1.4 x 10-9
PbCl2 -- 1.7 x 10-5 CaSO4 -- 3 x 10-5
PbSO4 -- 1 x 10-8
Chromates
Ag2CrO4 -- 2 x 10-12 Sulfides
BaCrO4 -- 2 x 10-10 Ag2S -- 1 x 10-49
PbCrO4 -- 1 x 10-16 CdS -- 1 x 10-26
SrCrO4 -- 4 x 10-5 CoS -- 1 x 10-20
CuS -- 1 x 10-35
Fluorides FeS -- 1 x 10-17
BaF2 -- 2 x 10-6 HgS -- 1 x 10-52
CaF2 -- 2 x 10-10 MnS -- 1 x 10-15
PbF2 -- 4 x 10-8 NiS -- 1 x 10-19
PbS -- 1 x 10-27
ZnS -- 1 x 10-20
Hydroxides
Al(OH)3 -- 5 x 10-33
If you would add silver nitrate, the product of the [Ag+] and
[Cl ] would be greater than Ksp. Applying Le Chatelier’s principle,
-
Properties of Salts
Salts are characterized by ionic bonds, relatively high melting
points, electrical conductivity when melted or when in solution, and a
crystalline structure in solid state.