CAPTULO 1

1. = ln
1 1
2. ln (1 ) = (
1
)
2 2
2 2
3. +2 +
+2 +
0.5

4. =
1+

2 2
2( +2 + )
5. +2 +
+ 2 +
2 2
6. =1 = 0 = 1, ,
[ ] [ ] = 0
7.
()(1)
8. = =1
[ ] = [ ] [ ]
9.
()(1)
[ ] [ ] [ ] = 0
10.
()()(1)
11. [ ][ ] = 0

12. [ ] [ ] = 0
13. = = [ ]

2 1 0 1
4 0 2 0
1 4 1
14. 3 = 1 1 0 = [ ]
0 3 1
3 4 3 4 0
2 3 2 3 0
( 2 ) ( 0 2 1 )
15. = = [ ] = 8 3 = 5
11 21 31 41 51
12 22 32 42 52
13 23 33 43 53
1 0 1 1 0 3 2 0
24 34 44 54
16. [ ] [ ] = 0 (0 2 4 1 3 4 3 2) 14 25 35 45 55 = 0
15
1 0 1 0 1 0 0 1 16 26 36 46 56
17 27 37 47 57
(18 28 38 48 58 )
17. = 1 = = 0
1 0 0 1 1 1 3 2 0
18. (0 2 3) (2 ) = (4) , (1) , (4) , (3) , (2)
1 0 1 3 1 0 0 0 1
=3 =4 =6 =7 =8
 1 0 0 1 1 1 3 2 0
13 9 1
19. (0 1 0 ) (2 ) = (2 ) , (2 ) , ( ) , ( ) , ( )
2 2 2
0 0 1 5 0 1 3 2 1
=3 =4 =6 =7 =8
20. + 22 4
21. + 22 + 3
22. 3 + 13/2 2 3 4 + 33
23. 2 + 9/2 2 2 3 + 23
24. 3 2 + 1/2 2
25. 4 + 3
26. 3 + 1/2 2 3 4
27. 23 4 + 1/2 2 32 3
0
30. =
=

31. = 0 +
32. = 0 + =1

33. =
1 0 0
34. ==
=

35. = 0 +
36. = 0 + =1
0
37. = 0
0
=
0

38. = 0
= 0
R
i=1 vij Xi R
i=1 vij i
39. Xj = =
nj0 Cj0
R
40. nj = i=1 nij Xi
T
41. [nj ] = [vij ] [Xi ]
T
42. [ik ]T [vij ] [Xi ] = 0
43. [ik ]T [ni ] = 0
44. n invariantes independientes = Rango[ik ] = S R max
45. [ik ]T [ci ] = 0
n1
n2
n3
1 0 1 1 0 3 2 0 n
4
46. [ik ]T [ni ] = 0 [0 2 4 1 3 4 3 2] =0
n5
1 0 1 0 1 0 0 1
n6
n7
[n8 ]
47. n1 + n3 + n4 + 3n6 + 2n7 = 0
2n2 + 4n3 + n4 + 3n5 + 4n6 + 3n7 + 2n8 = 0
n1 + n3 + n5 + n8 = 0
48. n10 + n30 + n40 + 3n60 + 2n70 = n1 + n3 + n4 + 3n6 + 2n7
2n20 + 4n30 + n40 + 4n60 + 3n70 + 2n80 = 2n2 + 4n3 + n4 + 3n5 + 4n6 +
3n7 + 2n8
n10 + n30 + n50 + n80 = n1 + n3 + n5 + n8

49. n10 = n1 + n3 + n4 + 3n6 + 2n7

2n20 = 2n2 + 4n3 + n4 + 3n5 + 4n6 + 3n7 + 2n8
n10 = n1 + n3 + n5 + n8

50. A+B R+S

A + B 2T + U

51. cA cB = cA0 cB0

cR cS = cR0 cS0
cT 2cU = cT0 2cU0
cA cR cU = cA0 cR0 cU0

dX
52. R= dt
1 dX
53. r = V dt
d
54. r= dt
1 dnj
55. rj =
V dt
dnj
56. R j = rj dV = rj V = dt
dnj dX
57. = vj
dt dt
dnj
58. = vj R
dt
1 dnj
59. R=v
j dt
60. R j = vj R
61. R j = Ri=1 vij R i
62. rj = vj r
dcj
63. rj = = Ri=1 vij ri
dt
1 dnj 1 d(cj V) 1 dcj cj dV
64. r= = = ==v +=
V vj dt Vvj dt j dt vj V dt

65. r= k cA cB cC cD
E/RT
66. k= Ae
67. N2 O5 NO2 + NO3 k1 , k1
NO2 + NO3 NO2 + NO + O2 k2
NO + N2 O5 3NO2 k3

68. O3 + M O2 + O + M k1 , k1
O2 + O3 2O2 k2
 dcN2 O5
69. rN2 O5 = = k1 cN2 O5 + k1 cNO2 cNO3 k 3 cNO cN2 O5
dt
70. rN2 O5 = k1 cN2 O5 k1 cNO2 cNO3 + k 3 cNO cN2 O5
dcNO3
71. rNO3 = = k1 cN2 O5 k1 cNO2 cNO3 k 2 cNO2 cNO3 = 0
dt
dcNO
72. rNO = = k 2 cNO2 cNO3 k 3 cNO cN2 O5 = 0
dt
k1 c N2 O 5
73. cNO3 = k +k
1 2 cNO2
k2 cNO2 cNO3
74. cNO = k3 c N 2 O 5
k1 k2
75. cNO = k
3 (k1 +k2 )
k c N2 O 5 k1 k2
76. rN2 O5 = k1 cN2 O5 k1 cNO2 k +k
1
+ k3 k cN2 O5
1 2 cNO2 3 (k1 +k2 )
2k1
39. rN2O5 = c
(k1 +k2 ) N2 O5

40. 2N2 O5 4NO2 + O2

k1 k2
41. rN2O5 =-2r r = c
(k1 +k2 ) N2 O5

42. = k 2 3

43. r1= k1` ( 3 - k1 / k1 2 ) 0

k1 3
44. =
k1
2

k1 k2 23
45. =
k1
2

46. 2 O3 3O2

2k1 k2 23
47. rO3 =-2r
k1
2

48.
 CAPITULO 2
1. + + + +

2. = = =1
3. + + + +

4. = =1 `
=1

5. = =1(0 + ) `
=1(0 + )


`
=1(0 + ) `
=1 ,
6. = = =

=1(0 + )
=1 ,

7. = (=1 ) (`
=1 )


8. = (=1 ) = (`
=1 )/=1 ,


9. = (=1 ) = ` `
=1 , = =1 ln ((, )) =

`
=1 ()
,

,
10. = (0, + , , ) = ,


11. = (=1 ) =1 (` `
=1 ) =1


12. 0


13. = 0 (1 ) 0

1 1
14. = 2 ( 0 (1 ) 0 ) = 2 ( )
1
15. = 2

( )

16. = = =


+
17. = exp ( ) = exp ( ) = exp ( ) ( )

18. =

19. = ( ) > 0

20. |=0 = = > 0

21. | = = ( ) < 0

22. =
( )
1

23. =
( )
1

24. =

25. =
 21 2+1
26. | = = para =
21 2

27. =
28. ln = ln + ln
29. = /(1 + )2

1
30. = =

31. =

32. ln = ln + ln + ln + ln

33. = = ( )

34. =

35. =

+ +
36. = ( ) = ( ) =

37. = ,0 ,0

38. = ( ,0 ) ,0 = ,0

39. = =

40. =
1
41. =

42. =
1
43. =

1 1
44. =

45. ,0 = 0 = 0 +
=1 0
46. = 0

47. = 0 (1 + )
1 1 [,0 (1+ )] 0
48. = =
0 (1+ ) (1+ )
 0
49. (1+ )
= 0 (1+ = 0

) 0

ln(1 + ) =
0

50. 0 = 0 = 0 ( )

51. ln = ln 0 +
52. = 1 ( )
1 1
53. 0 2 = 0 =
,0

0 (1 )2 1+
54. = ,0 2 (1+ )2
0 (1 2
=
(1+ ) )

(1 + )
0 ln(1 ) = ,0
0 1

55. 0: 1/2 = 2,0

ln 2
56. 1: 1/2 =

1
57. 2: 1/2 =
,0

58. = = + = +


59. = ,0
,0

60. = ,0 + = ,0 + (,0 ) = ,0 + ,0 = ,0 ( + )

61. = (1 ) ( + )

, ,0 (+, ) 1,
62. = = = = +
, ,0 (1, ) ,

+1
63. = + (, )
,

+1 +1
64. 0 = + 0 ln (1 ) = +
, , , ,

65. =

66. = ,0
,0

. = = ; = ; =

71. =
+


72. [ + ] =


73. = [( ) + ( )]

74. = +

75. = [( ( ) + ( ) ]

/
76. = +

77. = =


78. = [( )]

79. =

80. = ( ) = ( ) ( ) =

/ /
81. = [ ( ) ]

/
82. =

/ /
83. = ( ) = ( )/ ( ) =

84. = =

85. =


86. = ( ) = [ ( ) ]

CAPITULO 3.
19. = = 42

20. = 4 2 ( ) = 4 = 42
(1 )

21. = [1 + (1 ) ( )]

22. = 2
1+( 2 )( )+( )(1 )

 42
23. = = 2 1 1
( 2 )( )+ (1 )+( )

24. = .

25. = =

4
26. = . = 3 3

27. = = 42

42 42
28. 2
=
1 1
( 2 )( )+ (1 )+( )

29. = 2
1 1
( 2 )( )+ (1 )+( )

2 1 1
30. [(2 ) ( ) + ( ) (1 ) + ( )] = 0

31. =
1


32. = = 1 =

1


33. = = 1 =

2 2
34. = (1 ) {1 + 3 [( ) + ( ) + 1] + [( + 1) 2 ( ) ]}
6

4 4
3 3 3
35. = =3 4
3
= 1 ( ) = (1 )1/3
3
3

36. = (1 ) {1 + 3 [(1 )2/3 + (1 )1/3 + 1] + [(1 )1/3 + 1
6
2(1 )2/3 ]}

2 2
37. = (1 ) {1 + 3 [( ) + ( ) + 1] + 6 [( + 1) 2 ( ) ]}

2
38. = + 3 + 6 = .. + .. + ...

39. 1 = .. + .. + ...

40.

41. = = 42
 42
42. = 42 =
1

43. = (1 ) = [1 (1 )3 ]

44. =

1

45. = 1 = 1 (1 )3 = 1

46. 0
47. = = 4 2
42
48. = 4 2 ==

3
49. = 3 [1 ( ) ] = 3

2 2
50. 3 [( ) + ( ) + 1] 1 + [( + 1) 2 ( ) ]
6

51. = 3

3
52. = 1 ( ) = 1 = 1

53. 0
4
54. = =
(1 )

CAPTULO 4
1. pAi = HA cAi
2. NA = k AG (pA pAi )
3. NA = k AL (cAi cA )
4. NA = k AG (pA pAi ) = k AL (cAi cA )
kAG PA+ kAL cA
5. cAi = kAL +kAG HA
PA cA HA
6. NA = 1 H
+ A
kAG kAL

1 1 HA
7. =k +
KA AG a kAL a
PA cA HA
8. NA.a = 1 H
+ A
kAG .a kAL .a
kAL .a P
9. NA.a = ( ) (PA cA HA ) = k AL . a (HA cA ) = k AL (cAi cA )
HA A
10. NA.a = k AG . a(PA cA HA ) = k AG . a(PA cA HA ) = k AG . a(pA pAi )
DAF
11. K AF =
 AG D
12. k AG = RT
G
DAL
13. k AL = L

AF D
14. k AF = 2

15. k AF = 2DAF . S
d2 cA
16. DAL + rA = 0
dx2
17. cA = cAi for x = 0
18. cA = cA for x = L
cA 1 k k c k
19. = {senh [L D xD ] + c A senh [xD ]}
cAi senh (L
k
) AL AL Ai AL
DAL

maxima conversin posible en la pelcula lquida kCAi L L 2 k

20. Ha2 = mximo transporte por difusin a travs de la pelcula lquida = DAL =
(cAi 0) DAL
L
DAL k
21. Ha = kAL

dc DAL c Ha
22. NA = DAL ( dxA )x=0 = (cAi coshAHa)(tanh Ha)
L

NA en presencia de reaccin qumica

23. E= kAL (cAi cA )

DAL
24. Ha > 2 NA = c Ha = kDAL cAi
L Ai
D
25. Ha < 0.3 NA = AL (cAi cA ) = k AL (cAi cA )
L
26. NA = k AG (pA pAi ) = k AL (cAi cA )E

kAG pA +EkAL cA
27. pAi = EkAL
kAG +
HA
pA HA cA
28. NA = 1 H
+ A
kAG EkAL
v
29. b = vB
A
30. r = kcA cB
d2 cA
31. DAL kcA cB = 0
dx2
d2 cB
DBL bkcA cB = 0
dx 2

32. cA = cAi x=0

cB = cB x = L
cA = cA x = L

dcB
=0 x=0
dx
volumen de lquido
k
33. Al = volumen de reactor
volumen de pelcula lquida = a = aDAL
L AL
volumen de reactor

34. NA = k AG (pA pAi )

NA = k AL (cAi 0)
NB = k BL (cB 0)

DAL
35. k AL = L
DBL
k BL =
L

36. DAL = k AL L = kAL r kAL = k AL ( L )
r
L
DBL = k BL L = kBL (L r ) kBL = k BL ( )
L r

37. NA = bNB

kAL D
38. = DAL
kBL BL

L
39. r = DBL cB HA
[1+ ]
DAL bpAi

D c k
pA BL B AL
DAL bkAG
40. pAi = kAL
1+
kAGH
A

D c H
DAL DBL cB pA + BL B A
DAL b
41. NA = cAi (1 + bD )= 1 H
AL cAi + A
kAG kAL

kAL DBL cB HA DBL cB

42. NA = (pA + ) = k AL cAi (1 + D )
HA DAL b AL bcAi

kAL (cAi 0) L L D c DBL cB HA
r
43. E Ei = = = 1 + bDBL cB = 1 +
kAL cAi r AL Ai bDAL pAi
 D c H k c H
1+ BL B A 1+ BL B A
DAL bpA kAL bpA
44. Ei = DBL cB kAL = k c
1 1 BL B
DAL bpA kAG kAG bpA

NB kBL L
45. NA = k AG (pA 0) = = (cB cBi )
b b L r

bkAG pA
46. NA = k AG pA para cB kBL

kBL cB kBL cBi kBL cB

47. k AG pA = k AG pA
b b b

48. NA = k AG (pA pAi ) = Ek AL (cAi 0)

p
49. NA = 1 AHA
+
kAG kAL E

E E
Ha i
Ei 1
50. E= E E
tanh(Ha i )
Ei 1

kc cB L kDAL cB DAL kcB

51. Ha2 = DALAi = Ha =
(cAi 0) k2AL kAL
L

52. E Ha

53. NA . a = k AG . a(pA pAi ) = Ek AL . a(cAi cA ) = kcA cB

pA
54. NA . a = 1 HA H
+ + A
kAG .a kAL .aE kcB

Ha2
55. E= 1+ 3

pA
56. NA . a = HA H
+ A
kAL .aE kcB

57. NA . a = k AG . a(pA pAi ) = k AL . a(cAi cA ) = kcA cB

pA
58. NA . a = 1 H H
+ A + A
kAG .a kAL .a kcB

pA
59. NA . a = HA H
+ A
kAL .a kcB

60. =
61. = ( ) =

62. =1+ = 1 + . 2

CAPTULO 5

1 = 4

2.1 +
2.2 , = , (1 )

2.3 , = ,

2.4 , = , , = , (1 ) ,

2.5 , (1 ) = ,

2.6 = 1+

,
,
,
2.7 = = exp ( ) exp( )
,

,
2.8 , = ,
,
2.9 = =
,

2.10
= = 1

2.11 =
=
(1 )

2.12 2 + 2 2

2.13 , = , ( 2 2
) , ( )

, 1 2 1 1
2.14 = = ( ) = ( )2 = (1 )2
,

2.15 =
= 1+

2.16 2 + 2

2.17 , = , 2
,
,
2.18 = = 2
= 2 = 2
, ( ) (1 )
 2
2.19 =
= 1+ 2

2.20 + 2 2

2.21 , = , ( 2
) ,

, 1 1 1
2.22 = = 2 =
=
)
, ( 2 (1 2
)

1

2.23 =
=
2.24 . (1 )
1
2.25 = ()

3.1 + +

3.2 =


3.3 =

)
3.4 , = , (

3.5 =


3.6 = = ( )

)
3.7 = (

,
3.8 , = ,

3.9 = , = [ ] .
,

, ( )
3.10 , =

3.11 = [ ]

3.12 = [ ] = [ ] =

3.13 0 = + +
3.14 = , = = , =

3.15 = , ( ) = (
) = , = ( )

0 ( )
3.16 = 1 1 1 1
1+

1
1+
[( + )+( +
+ ) +( + ) ]
, , , ,

3.17 + , = , (1 )


3.18 + , = , ( )

(1
3.19 + + = )

3.20 + , = , ( )

1
3.21 =

3.22 0 = 1 + + +

3.23 = = = , = , (1 )

3.24 ( ) 0

3.25 ( ) 0

( )2
3.26 (1
) 0
=
=

0
3.27 =
1+ + +

3.28 ,= , (1 ) = , (1 ) = , ( )

, 0 (1 )

3.29 =
(1+ + + )

3.30 = = = , = , ( )

3.31 ( ) 0

( )2
3.32 (1
) 0
=
=

3.33 0 = 1 + + + = +
+ = (1 + +
+ )

0
3.34 =
1+ + +

3.35 = , ( ) = , ( ) = , ( )

, 0 ( )

3.36 =
(1+ + + )

(
3.37 = = = =
)

3.38 0 = 1 + + + = + + + = (1 + + +
+ )

3.39 = 1+ + 0
+

2
2 2
3.40 = ( ) = ( ) = ( )

3.41
=

2 ( )

3.42 = (1+ +
2
+ )

3.43 = = = , = , ( )

( )2

3.44 (1 ) 0
=
=

0
3.45 = 1+ +
+

3.46 = , ( ) = , ( ) = , ( )


, ( )

3.47 = 1+ +
+

3.48 I +M E + ` = ` (1
)



3.49 =

3.50 = + +

3.51 ( ) 0 = 1

= 1

3.52 = + + = + + = (1 + + )
1 1

3.53 =
(1+ + )
1

3.54 = , ( ) = , ( ) = , ( )
1 1

, ( )

3.55 =
+ +

( )
3.56 = = = =

3.57 = + + = ( + + )

3.58 = (1+
+ )

( ( ( ) =
3.59 = )

= )

=

( )

 ( )


3.60 = (+
+ )

(
3.61 = = = , = )

3.62 ( ) 0

3.63 = (1+
+ 1 )

3.64 = , ( ) = , ( 1 ) = , ( 1 )


( )

3.65 = +
+

2
2

3.66 + 2 2() = ( )

3.67 =
2
3.68 + 2 2(2 ) = ( )

2
3.69 =
( )( )
3.70 = ( )

2 ( 1 )

3.71 =
(1+1 1 + + )2

3.72 + , = , ( )

1
3.73 + + = (
)



3.74 + , = , ( 1 )

3.75 +
, = , ( )

3.76 = 1+

3.77 =
1+1 1

3.78 =


3.79 = 1+

=
3.80

=
3.81

3.82 = (
) (
)
 ),
(
5.4.71 =

5.4.72 + + = 1

3 3
5.4.73 =

=
3
0 2 3 2

5.5.1 , = ( )

5.5.2 , = , = ( )

5.5.3 , (, , ) = ( )

5.5.4 , (, , ) = ,
5.5.5 , (, , ) = ,
,
5.5.6 , =
, + ,

5.5.7 ( ) = +, , = ,
,
1 1 1
5.5.8 =+
,
5.5.9 = ( )
5.5.10 = ( )
5.5.11 ( ) = ( )
,
5.5.12 =

5.5.13 =
,

5.5.14 =

5.5.15 =
=
=
2 2/3
,
5.5.16 = 3 = ( )( )
,
0,72
5.5.17 = 1,1068 (para Re < 10)
5.5.18 = 0,4548 0,4069 (para Re > 10)

5.5.19 =


5.5.20 =
2 2/3

5.5.21 = 3
= (

) (
)

)
) = (
5.5.22 ( ) = (
, (, , )
)
5.5.23 ( ) = (


,
5.5.24 = ( ) = ( ) (, , )

2/3

5.5.25 , = ( ) ( ) ( )
,
2/3

5.5.26 = ( ) ( )

, 1 2/3

5.5.27 = ( )

2/3
5.5.28 = = ( ) (, , )


5.5.29 = =
(, , )
 , ,
5.5.30 < 0,1
,
5.5.31 ( ) = , (, , ) = ( )
5.5.32 ( ) = , (, , ) = ,
,
5.5.33 , =
, + ,
,
5.5.34 ( ) = , = , = ,
, +
1
5.5.35 = 1
+
,

5.5.36 = +
,

5.5.37 = +
,
( ) ( )
5.5.38 = ,
= (
)
( )
5.5.39 = (, , )

5.6.1 = , , + = , , + = , , +
. ( . )
. . = = =

,
. . = ; = , ( )
,

, ,
5.6.4 =

5.6.5 = = =


5.6.6 = =

5.6.7 = = . . = =


= =

5.6.9 = ( + ) +
. . =
5.6.11 , = =

5.6.12 = .
, .

, ,
5.6.13 = . = .
=

, . .

, ,
5.6.14 =


,

() ()
5.7.1 = = ()
= = , ,
5.7.2 = (, ) = ,

5.7.3 = =

()
5.7.4 =
. ,

() () +
5.7.5 = ()
= ( )
, ,

5.7.6 (, ) = ,

5.7.7 = =

() +
5.7.8 = ( )
, ,

()
5.7.9 = +
, ,

() () ()
5.7.10 = ()
= ()
( ,
) =
, ,()

()(,)
,
, , ()

()(,)
5.7.11 = ,
, , ()
() ,
5.7.12 = ()
, , , (,) ,

() , ,()
5.7.13 = ,(,) , ()
, , ,

| |()
5.7.14 < =

/
() () ()
5.7.15 ( ) <1
,

5.7.16
() ()( )
| |<
, ,
 ()
5.7.17 < ||
, ,

()
5.7.18 (+) <
, ,
5.7.19 || < ,

,, ()
5.7.20 =
, ,

()()
5.7.21 =
||()
5.7.22 = < ,


5.7.23 = =

5.7.24 < ,
,
( ) ,
5.7.25 = <
, ,
( ) +,
5.7.26 < | |(+,)
, ,
,
5.7.27 | + , | <

5.7.28 ( ) = , , = ( ) ,

,
5.7.29 ( ) = , , =

, =

, , =
, =

, +
5.7.30 = = ( ) ( )

5.7.31 ( ) = , = , ,

5.7.32 , = ( /)

5.7.33 ( ) = = ,
(+)
, ,
5.7.34 ( ) = , = ,
= , =
(+)
, (+) ,

(+) (+)
,
5.7.35 ( ) =
=
, =
,
(+) ,

5.7.36 ( ) = , ,

5.7.37 ( ) = , ( ) = ( )

5.7.38 ( )

 , , ,
5.7.39 , = ( ) , = ( )( ) , ,


, , , ,
5.7.40 ( ) , = ( )

, , , , ,
, ,

5.7.41 ( ) ( ) =
,

5.7.42 =
5.7.43 ( ) = = , = ,

,
5.7.44 ( ) = ,

5.7.45 , = =

,
5.7.46 ( ) = , = , = ( , )

5.7.47 ( )

5.7.48 ( )

5.7.49 , =

5.7.50 ( )

5.8.

5.8.1 = = ()

5.8.2 = ()()( , , , , , , )

cR cR ,0 cA,0 M c A,0 X A c A,0 ( M X A )

39.
r kcA,0 (1 X A )(M X A )
40.
dX A
kcA,0 (1 X A )( M X A )
41. dt
M XA
In kcA,0 (M 1) t
M (1 X A )
42.
43. 2 A B r1 k1c A2
44. 2 A H B H r2 k2c A2 cH
XA
2cA,0 (k1 k2ch ) t 2c A,0 k 1t
45. 1 X A

46. r kc A cb
A B

v v
r kcA B cB k B cA2
47. vA vA
v
cB cB 0 B ( c A 0 c A )
48. vA

1 d v
cA0 (1 X A ) k cA0 (1 xA ) cB B cA0 X A
49. vA dt vA

dx A
v A kdt
v
(1 X A )(cBO B c A0 X A )
50. vA

vB
cB 0 c A0 X A
vA v
In v A cB 0 B c A0 kt
cB 0 1 X A vA
51.

52. A B r1 k1cA
53. A D r2 k2cA
dcA
54. k1 k2 c A
dt
dc
55. B k1c A
dt
dc
56. D k2 cA
dt
C A dc
0 dt cA cA.0 exp k1 k2 t
1
A.0 cA A
k1 k 2
57.

58. IncA IncA.0 (k1 k2 )t

dcB
k1cA,0 exp k1 k2 t
59. dt
 dcB k1cA,0 exp k1 k2 t dt
cB
B.0 0

kc
cB cB ,0 1 A,0 1 exp (k1 k2 )t
60. k1 k2

1 exp k k t
k2cA,0
cD cD,0
k1 k2
1 2
61.

cB ,0 cB k1
S
cD ,0 cD k2
62.

63. S

k1 A1 exp Ea ,1 RT A
1 exp

Ea ,1 Ea ,2


k2 A2 exp Ea ,2 RT A2
RT

64. A B r1 k1cA

65. A D r2 k2c A2

k1c A,0 e k ,1
66. cA
k1 k2 c A,0 1 e k ,1

k1 1 k2cA,0 1 e
k ,1

67. cB In k1
t
k2 k1e k ,1

k1 1 k2 c2,0 1 e
k1 1
k1c A,0 e k ,1
68. cD cA,0 In k t
k1 k2 c A,0 1 e k ,1 k1 K1e k11
1

dcB dcB dt rB
69. S (t )
dcD dcD dt rC

r1 k1c A k1 1
70. S (t )
r2 k2 c A2 k2 c A
71. A B r1 k1cA

72. A D r2 k2cB

dc A
73. k1c A
dt

dcB
74. k1c A k2 cB
dt

dcD
75. k 2 cB
dt

dcA
cA

c A ,0 c
k1 dt c A c A,0 exp(k1t )
0
76. A

dcB
77. k2 cB k1cA,0 exp k1t
dt
k1cA,0
k1 k2 cB exp(k , t ) exp(k2t ) cB,0 exp(k2t )
Si k2 k1

k1 k2 cB (k1ca ,0t cb ,0 ) exp(k , t )

Si

c A,0 cB,0 cD,0 c A cB cD