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3. Saltwater boils at
a. slightly higher than 100C
b. 100C
c. slightly lower than 100C
d. ???
5. Buffer solution resists changes in acidity. If an acid is added to a buffer solution, the ______
remains the same
a. pH
b. concentration
c. ???
d. ???
Refer to handbook for nos. 6-8
6. specific volume of compressed air at 150 bars and 160K
9. An ideal gas in a piston at 5,000 psia expands isothermally against a resisting pressure of 500 psia
until its volume is doubled. Find the work done.
3. 41.6 g of aluminum is mixed with HCl. The hydrogen gas liberated from this reaction is passed
with copper oxide. How much copper is formed from this reaction?
4. A 32 g of compound X is mixed with 450 g CCl4. Find the molecular weight of the compound if the
boiling point rise is 6.210C. K6 = 5.03
4. How many milliliters of 6.0M HCl is needed to prepare 250ml of 1.2M HCl?
5. 184 g of ethanol is mixed with 1-gmol glycerol. What is the vapor pressure of the
resulting solution if the vapor pressure of ethanol at the working temperature is 200 mmHg?
Assume that glycerol is nonvolatile.
6. How much heat is required to raise 4000g of methanol from 2 to 220C. (Cp of methanol is 0.6
cal/g0C)
7. At equilibrium, a 1-L PCl5 is found to contain (in mole/L)
PCl5 = 7.05
PCl3 = 0.54
Cl2 = 0.54
Find the equilibrium constant.
10. Naming:
H2C = C - C = C
.................l
................CH3
a. isoamylene
b. isoprene
c. ???
d. ???
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2. A carbonyl compound is
a. One carbon and one oxygen bounded by a double bond.
b. One carbon and one oxygen bounded by a single bond.
c. One carbon and two oxygen bounded by one single and one double bond.
d. One carbon and two oxygen bounded by two double bonds.
3. Water flows down at 1000 gal/min. If 80% of the energy produced can light 100 75-W bulbs for 60
seconds, what is the height of the pipe through with the water flows?
a. 49.73 ft.
b. ???
c. ???
d. ???
4. The best indicator to be used in the filtration of a weak acid by a strong base is
a. phenolphthalein
b. methyl orange
c. ???
d. ???
5. It required 82 ml of H2SO4 to neutralize 12.0g NaOH. What is the molarity of the H2SO4?
6. A 620 mg ideal gas occupies 175 cc at STP. What is the molecular weight of the ideal gas?
a. 79
b. ???
c. ???
d. ???
7. A 0.1 M acetic acid is found to contain 1.32 x 10-3 mol/L of H+ at equilibrium. What is the
ionization constant?
8. A 2-L flask is filled with 0.2 mol of HI. It is allowed to reach equilibrium at high temperature. If at
equilibrium the flask was found to contain 0.078M HI, what is the Kc?
4. An atom is __________
a. Electrically positive spherical species with a neutral center and negatively charged electron.
b. An electrically positive spherical species with a positive center and negatively charged electron
c. An electrically neutral spherical species with a neutral center and negatively charged electron.
d. An electrically negative spherical species with a positively charged center and negatively charged
elections.
6. The electrons of metals are free to move in a solid. This explains why
a. metals are unstable
b. metals can be easily molded
c. metals have high reflectivity
d. metals have high conductivity
7. A 4.256 grams compound is dissolved in 100 grams toluene. What is the molecular weight (MW)
of the compound if the vapor pressure of the solution in 28.209? The vapor pressure of toluene at the
working temperature is 28.829 mmHg. Assume that the compound is a nonvolatile, non-dissociating
solute.
8. A flue gas is analyzed to contain (dry basis): 11.6% CO2, 6.8% O2, 0.5% CO and leaves the boiler at
5380K. The inlet air is at 2870K and the fuel contains 29.4% C. What is the amount of heat carried
by the flue gas per kg of fuel burnt? The mean heat capacity of the flue gas is 1.005 kJ/kg 0K.
2. A compound is found to contain by mass: 22.79% C, 1.42% H and 75.9% Br. What is the molecular
formula of the compound if its molecular weight is 422?
a. C4H6Br4
b. C2H3Br2
c. ???
d. ???
9. 19.6 grams of Carbon Disulfide is reacted with excess oxygen to form carbon dioxide and sulfur
dioxide. What is the amount of sulfur dioxide formed?
a. 32 grams
b. ???
c. ???
d. ???
10. The ionization constant of NH4 OH is 1.8 x 10-5. What is the formality of a solution of NH4OH
which is 1.3% ionized?
a. 0.10
b. ???
c. ???
d. ???