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Definitions
Pre-balancing Skills
2 Pre-Balancing Practice
Answer Key
Practice can help students develop fluency with balancing chemical equations.
This chemistry workbook provides ample practice:
This chemistry workbook isnt just for students. Anyone who enjoys math or
science puzzles may enjoy balancing chemical reactions in the spirit of solving
puzzles.
1 How to Balance Chemical Reactions
Definitions
An example of a chemical change is when carbon (C) and diatomic oxygen gas
(O2) get together to form a new gas called carbon dioxide (CO2). At the
molecular level, two oxygen atoms are bound to each carbon atom in carbon
dioxide. The composition of carbon dioxide is thus different from that of
separate carbon and oxygen atoms.
The reactants of a chemical reaction are the initial substances. They react
together to produce new substances with different compositions.
The products of a chemical reaction are the final substances. They are the new
substances that are produced by the reaction.
For example, in photosynthesis, plants combine water (H2O) and carbon dioxide
(CO2) to form carbohydrates, such as glucose (C6H12O6), and diatomic oxygen
gas (O2). Water and carbon dioxide are the reactants (these substances react
together), while glucose and diatomic oxygen gas are the products (these
substances are formed by the reaction).
The terms of a chemical reaction are separated by plus (+) and yield () signs.
The above chemical equation consists of 4 terms: FeS, 2 HCl, FeCl2, and H2S.
A chemical reaction is said to be balanced when there are the same number of
each type of atom on both sides of the chemical equation.
There are 4 copper (Cu) atoms on each side, 2 sulfur (S) atoms on each side, and
6 oxygen (O) atoms on each side (since 3 2 = 6 on the left and 2 + 2 2 = 6 on
the right). When every element has the same number of atoms on each side of
the reaction, the equation is balanced. (Well learn how to count atoms later in
this chapter.)
According to the law of conservation of mass, atoms are neither created nor
destroyed during a chemical reaction. This is why chemical reactions need to be
balanced: to ensure that the reaction has the same number of each type of atom
on both sides of the chemical equation. The law of conservation of mass applies
to ordinary chemical reactions.[*]
The Significance of Balancing Reactions
2 Na + F2 2 NaF
According to the above chemical equation, 2 sodium (Na) atoms react with one
diatomic fluorine molecule (F2) to yield 2 sodium fluoride (NaF) molecules.
Because the proportions are the same at any scale, the same chemical equation
tells us that 2 moles of sodium react with one mole of diatomic fluorine gas to
yield 2 moles of sodium fluoride, for example.
Pre-balancing Skills
Before we learn how to balance a chemical reaction, let us first consider how to
count atoms in various terms, using subscripts, parentheses, and coefficients.
After all, a chemical equation is basically balanced by counting atoms while
inserting coefficients as needed to make the numbers the same on both sides.
A coefficient multiplies the numbers of all atoms in the same term. (Recall the
words coefficient and term defined earlier in this chapter.) If there is no
coefficient, there is one molecule. When there are two or more molecules, a
coefficient is used.
When two or more terms are added together (with + signs in between), first treat
each term separately and then add all of the atoms together.
Goal: Add coefficients to each term, as needed, such that the total number of
each atom on both sides of the chemical equation matches up exactly.
Begin by counting the number of each type of atom on each side of the
chemical equation.
Insert one coefficient at a time, attempting to balance one element at a
time.
Work with elements that appear in compounds like NaCl or H2O before
working with elements that appear isolated like N2 or Al.
Work with elements that appear only once on each side of the equation
before dealing with elements that appear two or more times on the same
side.
Its generally better to save H and O for last.
Realize that you may need to change inserted coefficients over the course
of balancing a chemical reaction.
Use trial and error. Its okay to make a mistake. If something doesnt work
out, you can always go back and change it, and try something else instead.
If you find yourself needing to insert a fractional coefficient at the end,
multiply every coefficient by the denominator of that fraction. (See
Example 10 at the end of this chapter.)
Check: When you finish balancing a chemical equation, add up the total number
of each atom on each side to make sure they are the same on both sides.
Balancing Examples (with Math and Explanations)
The following examples illustrate the strategy for balancing chemical reactions.
The examples start out simple and grow progressively more challenging.
H2 + Cl2 HCl
H2 + Cl2 2 HCl
H2 + O2 H2O
H2 + O2 2 H2O (unbalanced)
2 H2 + O2 2 H2O
N2 + F2 NF3
When you see subscripts of 2 and 3 on the same element, its often helpful to
make 6 of each by multiplying 2 by 3 and multiplying 3 by 2 (since 2 3 and 3
2 both equal 6).
In this case, this happens to balance N at the same time. (But things dont always
turn out so easy.)
N2 + 3 F2 2 NF3
Si + O2 SiO2
You dont need to do anything to balance the equation, but you should show
your work by counting atoms on each side and stating that its already balanced
(because an instructor might penalize you for leaving an exercise blank).
Si + O2 SiO2
Example 5. Balance the following reaction.
Mg + HCl MgCl2 + H2
Mg + 2 HCl MgCl2 + H2
Although the guidelines suggest saving H and O for last, in this case it turns out
to be easier to work with O first.
Note that O2 is on the left and O3 is on the right. Lets try the trick from Example
3. (That trick doesnt always work, but its worth testing it out when you see a
subscript of 2 on one side and a subscript of 3 on the other side attached to the
same element.)
In this case, this happens to also balance N and H at the same time. (But things
dont always turn out so easy.)
We still need more H atoms on the right. Changing the coefficient from a 2 to a 3
wont work because we wont be able to make 3 O atoms on the left (since you
cant multiply O2 by an integer to make 3 O atoms).
We now need 2 more H atoms and 2 more O atoms on the left-hand side. We can
achieve this by inserting a coefficient of 2 before H2O2.
Al + Pb(NO3)2 Pb + Al(NO3)3
With 2 N on the left and 3 N on the right, we can use the trick from Example 3 to
balance N: Insert a coefficient of 3 before Pb(NO3)2 and a coefficient of 2 before
Al(NO3)3. The reasoning behind this is that 3 2 and 2 3 both equal 6.
Now N and O are both balanced, but Al and Pb are no longer balanced.
2 Al + 3 Pb(NO3)2 3 Pb + 2 Al(NO3)3
The guidelines suggest dealing with Mg and P before working with H and O.
F2
Note: The answers are tabulated at the back of the book. Use device navigation
to check the answer key. Look for Chapter 2 Answers.
Exercise 2. How many atoms of each kind are there in the following expression?
CH4
Exercise 3. How many atoms of each kind are there in the following expression?
Al2O3
Exercise 4. How many atoms of each kind are there in the following expression?
C2H5OH
Exercise 5. How many atoms of each kind are there in the following expression?
Pb(NO3)2
Exercise 6. How many atoms of each kind are there in the following expression?
Hg3(PO4)2
Exercise 7. How many atoms of each kind are there in the following expression?
(NH4)2SO4
Exercise 8. How many atoms of each kind are there in the following expression?
3 N2
Exercise 9. How many atoms of each kind are there in the following expression?
4 Na2O
Exercise 10. How many atoms of each kind are there in the following
expression?
6 H2SO4
Exercise 11. How many atoms of each kind are there in the following
expression?
5 C12H22O11
Exercise 12. How many atoms of each kind are there in the following
expression?
2 Al2(CO3)3
Exercise 13. How many atoms of each kind are there in the following
expression?
4 Sn(NO3)2
Exercise 14. How many atoms of each kind are there in the following
expression?
5 (NH4)2S
Exercise 15. How many atoms of each kind are there in the following
expression?
2 Fe + 3 Cl2
Exercise 16. How many atoms of each kind are there in the following
expression?
2 C6H14 + 19 O2
Exercise 17. How many atoms of each kind are there in the following
expression?
Al2(SO4)3 + 3 Ca(OH)2
Exercise 18. How many atoms of each kind are there in the following
expression?
4Pb(CH3COO)2 + 4H2S
3 Basic Structure with 3 Terms or Less
Exercise 1. Balance the following reaction.
N2O4 NO2
Note: The answers are tabulated at the back of the book. Use device navigation
to check the answer key. Look for Chapter 3 Answers.
O2 O3
C6H6 C2H2
C6H12O6 CH2O
C + O2 CO2
C + O2 CO
H2 + F2 HF
Xe + F2 XeF6
C + F2 CF4
U + F2 UF6
CH4 C + H
Ca + O2 CaO
Mg + N2 Mg3N2
NO + O2 NO2
P + Cl2 PCl3
H2 + O3 H2O
SO2 + O2 SO3
H2O H2 + O2
Co + F2 CoF3
Na + Cl2 NaCl
Fe + C Fe3C
HgO Hg + O2
Br2 + F2 BrF3
Mg + O2 MgO
Al + Cl2 AlCl3
SO3 SO2 + O2
NaN3 Na + N2
P4 + O2 P4O6
P + F2 PF5
N2O5 NO2 + O2
H2 + O2 H2O
P4 + O2 P4O10
Zn + S8 ZnS
Br2 + F2 BrF5
FeO + O2 Fe2O3
Cr + O2 Cr2O3
Al2O3 Al + O2
PH3 P4 + H2
B + O2 B2O3
Li + N2 Li3N
Fe + O2 Fe2O3
P4 + Br2 PBr3
Al + O2 Al2O3
V2O5 V + O2
Zn + HCl ZnCl2 + H2
Note: The answers are tabulated at the back of the book. Use device navigation
to check the answer key. Look for Chapter 4 Answers.
CH4 + H2O CO + H2
WO3 + H2 W + H2O
CO2 + H2 CO + H2O
H2O + F2 HF + O2
TbF3 + Ca Tb + CaF2
Al + HCl AlCl3 + H2
NH3 + O2 NO + H2O
NH3 + NO N2 + H2O
PBr3 + H2 P4 + HBr
N2O + NO2 NO
Note: The answers are tabulated at the back of the book. Use device navigation
to check the answer key. Look for Chapter 5 Answers.
C2H4 + H2 C2H6
C + H2 C5H12
KClO3 KCl + O2
H2SO3 + O2 H2SO4
Na2SO3 + S8 Na2S2O3
C12H22O11 C + H2O
6 Intermediate Structure with 4 Terms
Exercise 1. Balance the following reaction.
NO2 + O3 N2O5 + O2
Note: The answers are tabulated at the back of the book. Use device navigation
to check the answer key. Look for Chapter 6 Answers.
Al + Fe2O3 Fe + Al2O3
Fe2O3 + C Fe + CO
Fe2O3 + CO Fe + CO2
C + As2O3 CO2 + As
Fe + H2O Fe3 O4 + H2
I2O5 + CO I2 + CO2
C2H4 + F2 CF4 + HF
Fe2O3 + S Fe + SO2
Na + Fe2O3 Fe + Na2O
Cr2O3 + Si Cr + SiO2
Al + Fe3O4 Fe + Al2O3
Na + H2O NaOH + H2
K + H2O KOH + H2
Fe + CuSO4 Cu + Fe2(SO4)3
Fe + H2O + O2 Fe(OH)3
Fe2O3 + P Fe + P4O10
Note: The answers are tabulated at the back of the book. Use device navigation
to check the answer key. Look for Chapter 7 Answers.
NH4NO3 H2O + N2 + O2
C + H2 + O2 C2H5OH
Note: The answers are tabulated at the back of the book. Use device navigation
to check the answer key. Look for Chapter 8 Answers.
C7H5N3O6 CO + C + H2 + N2
C8H10N4O2 + O2 CO + H2O + NO
Note: The answers are tabulated at the back of the book. Use device navigation
to check the answer key. Look for Chapter 9 Answers.
#1) F2
2 F
#2) CH4
1 C
4 H
#3) Al2O3
2 Al
3 O
#4) C2H5OH
2 C
6 H
1 O
#5) Pb(NO3)2
1 Pb
2 N
6 O
#6) Hg3(PO4)2
3 Hg
2 P
8 O
#7) (NH4)2SO4
2 N
8 H
1 S
4 O
#8) 3 N2
6 N
#9) 4 Na2O
8 Na
4 O
#10) 6 H2SO4
12 H
6 S
24 O
#11) 5 C12H22O11
60 C
110 H
55 O
#12) 2 Al2(CO3)3
4 Al
6 C
18 O
#13) 4 Sn(NO3)2
4 Sn
8 N
24 O
#14) 5 (NH4)2S
10 N
40 H
5 S
#15) 2 Fe + 3 Cl2
2 Fe
6 Cl
#16) 2 C6H14 + 19 O2
12 C
28 H
38 O
2 Al
3 S
18 O
3 Ca
6 H
4 Pb
16 C
32 H
16 O
4 S
Chapter 3 Answers
#2) 3 O2 2 O3
#6) 2 C + O2 2 CO
#7) H2 + F2 2 HF
#8) Xe + 3 F2 XeF6
#9) 2 Fe + O2 2 FeO
#10) C + 2 F2 CF4
#11) U + 3 F2 UF6
#12) CH4 C + 4 H
#13) 2 Ca + O2 2 CaO
#14) 3 Mg + N2 Mg3N2
#15) 2 NO + O2 2 NO2
#17) 3 H2 + O3 3 H2O
#20) 2 H2O 2 H2 + O2
#21) 2 Co + 3 F2 2 CoF3
#23) 3 Fe + C Fe3C
#24) 2 HgO 2 Hg + O2
#26) 2 Mg + O2 2 MgO
#30) 2 NaN3 2 Na + 3 N2
#31) P4 + 3 O2 P4O6
#32) 2 P + 5 F2 2 PF5
#34) 2 H2 + O2 2 H2O
#35) P4 + 5 O2 P4O10
#36) 8 Zn + S8 8 ZnS
#40) 4 Cr + 3 O2 2 Cr2O3
#41) 2 Al2O3 4 Al + 3 O2
#42) 4 PH3 P4 + 6 H2
#43) 4 B + 3 O2 2 B2O3
#44) 6 Li + N2 2 Li3N
#45) 4 Fe + 3 O2 2 Fe2O3
#47) 4 Al + 3 O2 2 Al2O3
#48) 2 V2O5 4 V + 5 O2
#49) 16 Rb + S8 8 Rb2S
Chapter 4 Answers
#12) 2 H2O + 2 F2 4 HF + O2
#3) 5 C + 6 H2 C5H12
#9) Ni(CO)4 Ni + 4 CO
#5) Fe2O3 + 3 C 2 Fe + 3 CO
#25) 4 C + 6 H2 + O2 2 C2H5OH
#31) 2 C7H5N3O6 12 CO + 2 C + 5 H2 + 3 N2
As a physics teacher, Dr. McMullen observed that many students lack fluency in
fundamental math skills. In an effort to help students of all ages and levels
master basic math skills, he published a series of math workbooks on arithmetic,
fractions, and algebra called the Improve Your Math Fluency Series. Dr.
McMullen has also published a variety of science books, including introductions
to basic astronomy and chemistry concepts in addition to physics textbooks.
Dr. McMullen is very passionate about teaching. Many students and observers
have been impressed with the transformation that occurs when he walks into the
classroom, and the interactive engaged discussions that he leads during class
time. Dr. McMullen is well-known for drawing monkeys and using them in his
physics examples and problems, applying his creativity to inspire students. A
stressed-out student is likely to be told to throw some bananas at monkeys,
smile, and think happy physics thoughts.
Author, Chris McMullen, Ph.D.
Improve Your Math Fluency
This series of math workbooks is geared toward practicing essential math skills:
www.improveyourmathfluency.com
www.chrismcmullen.com
Dr. McMullen has published a variety of science books, including:
Chris McMullen enjoys solving puzzles. His favorite puzzle is Kakuro (kind of
like a cross between crossword puzzles and Sudoku). He once taught a three-
week summer course on puzzles.
pattern recognition
visual discrimination
analytical skills
logic and reasoning
analogies
mathematics
Chris McMullen has coauthored several word scramble books. This includes a
cool idea called VErBAl ReAcTiONS. A VErBAl ReAcTiON expresses word
scrambles so that they look like chemical reactions. Here is an example:
2 C + U + 2 S + Es S U C C Es S
The left side of the reaction indicates that the answer has 2 Cs, 1 U, 2 Ss, and 1
Es. Rearrange CCUSSEs to form SUCCEsS.
If you enjoy anagrams and like science or math, these puzzles are tailor-made for
you.
[*] However, the law of conservation of mass doesnt hold true for all types of reactions. For example, in
nuclear reactions such as 233U 229Th + 4He, the atoms themselves may change identity.