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Conversion Calculation
r A=k
XA
dx A
t=CaO
0
k
t x
= A
Ca O k
zero order
250
200
f(x) = 718.87x - 246.42
R = 0.97
150
X
100
50
0
0.46 0.48 0.5 0.52 0.54 0.56 0.58 0.6 0.62
t/Cao
r A=kCao ( 1 X )
XA
dx A
t=CaO
0 kCao(1 X)
ln( ( 1 X ))
1
t=
k
t X -Ln(1-X)
10 0.48 0.65392
6
11.42857 0.5 0.69314
7
16 0.58 0.86750
1
20 0.61 0.94160
9
First oder
1
0.9 f(x) = 0.03x + 0.36
0.8 R = 0.98
0.7
0.6
0.5
t
0.4
0.3
0.2
0.1
0
8 10 12 14 16 18 20 22
-Ln(1-X)
r A=kCao2 ( 1X )2
XA
dX
t=Cao
0 kCao2(1X )2
1
X
kCao
t=
(1 X)2
Xt*Cao X/(1-X)^2
1 1.77514792
9
1.1428571 2
43
1.6 3.28798185
9
2 4.01051939
5
Second order
2.5
2
f(x) = 0.43x + 0.26
R = 0.99
1.5
t*Cao
0.5
0
1.5 2 2.5 3 3.5 4 4.5
X/(1-X)^2
Since second order assumption gives more linearity than other orders. It suits with the literature
that second order is applied for this saponification reaction
Slope = 0.426
Rate = k * Ca02*(1-X)2