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Pgina 1 de 12 11/12/2017 20:36:51 Tabla B-1

Tabla B-1.- PARAMETROS DE FUERZA INTERMOLECU

Parametros de
Lennard-Jones
PESO
SUBSTANCIA MOLECULAR /K Tc Pc
(-A-) (-K-) (K) (atm)
(-M-)

Elementos
Ligeros
H2 2.02 2.915 38.0 33.3 12.8
He 4.00 2.576 10.2 5.26 2.26
Gases
Nobles
Ne 20.18 2.789 35.7 44.5 26.9
Ar 39.94 3.418 124.0 151.0 48.0
Kr 83.80 3.498 225.0 209.4 54.3
Xe 131.30 4.055 229.0 289.8 58.0
Sustancias
Poliatomicas
sencillar
Aire e
28.97 e
3.617 97.0 132.0 36.4
N2 28.02 3.681 91.5 126.2 33.5
O2 32.00 3.433 113.0 154.4 49.7
O3 48.00 0.000 0.0 268.0 67.0
CO 28.01 3.590 110.0 133.0 34.5
CO2 44.01 3.996 190.0 304.2 72.9
NO 30.01 3.470 119.0 180.0 64.0
N2O 44.02 3.879 220.0 309.7 71.7
SO2 64.07 4.290 252.0 430.7 77.8
F2 38.00 3.653 112.0 0.0 0.0
Cl2 70.91 4.115 357.0 417.0 76.1
Br2 159.83 4.268 520.0 584.0 102.0
I2 253.82 4.982 550.0 800.0 0.0
Hidrocarburos
CH4 16.04 3.822 137.0 190.7 45.8
C2H2 26.04 4.221 185.0 309.5 61.6
C2H4 28.05 4.232 205.0 282.4 50.0
C2H6 30.07 4.418 230.0 305.4 48.2
Pgina 2 de 12 11/12/2017 20:36:51 Tabla B-1

C3H6 42.08 0.000 0.0 365.0 45.5


C3H8 44.09 5.061 254.0 370.0 42.0
n-C4H10 58.12 0.000 0.0 425.2 37.5
i-C4H10 58.12 5.341 313.0 408.1 36.0
i-C5H12 72.15 5.769 345.0 469.8 33.3
i-C6H14 86.17 5.909 413.0 507.9 29.9
i-C7H16 100.20 0.000 0.0 540.2 27.0
i-C8H18 114.22 7.451 320.0 569.4 24.6
i-C9H20 128.25 0.000 0.0 595.0 22.5
ClicloHexano 84.16 6.093 324.0 553.0 40.0
C6H6 78.11 5.270 440.0 562.6 48.6
Otros
Compuestos
CH3Cl 50.49 3.375 855.0 416.3 65.9
CH2Cl2 84.94 4.759 406.0 510.0 60.0
CHCl3 119.39 5.430 327.0 536.6 54.0
CCl4 153.84 5.881 327.0 556.4 450.0
C2N2 52.04 4.380 339.0 400.0 59.0
COS 60.08 4.130 335.0 378.0 61.0
CS2 76.14 4.438 488.0 552.0 78.0
Pgina 3 de 12 11/12/2017 20:36:51 Tabla B-1

INTERMOLECULAR Y CONSTANTES CRITICAS

Constantes Criticas b,c,d

Vc Uc Kc
(cm .g-mol-1)
3 (gcm-1sec-1 x 106) (calsec-1cm-1K-1x 106)

65.0 34.7 0.0


57.80 25.4 0.0

41.7 156.0 79.2


75.2 264.0 71.0
92.2 396.0 49.4
118.8 490.0 40.2

86.6 193.0 90.8 e

90.1 180.0 86.8


74.4 250.0 105.3
89.4 0.0 0.0
93.0 190.0 86.5
94.0 343.0 122.0
57.0 258.0 118.2
96.3 332.0 131.0
122.0 411.0 98.6
0.0 0.0 0.0
124.0 420.0 97.0
144.0 0.0 0.0
0.0 0.0 0.0

99.3 159.0 158.0


113.0 237.0 0.0
124.0 215.0 0.0
148.0 210.0 203.0
Pgina 4 de 12 11/12/2017 20:36:51 Tabla B-1

181.0 233.0 0.0


200.0 228.0 0.0
255.0 239.0 0.0
263.0 239.0 0.0
311.0 238.0 0.0
368.0 248.0 0.0
426.0 254.0 0.0
485.0 259.0 0.0
543.0 265.0 0.0
308.0 284.0 0.0
260.0 312.0 0.0

143.0 338.0 0.0


0.0 0.0 0.0
240.0 410.0 0.0
276.0 413.0 0.0
0.0 0.0 0.0
0.0 0.0 0.0
170.0 404.0 0.0
Tabla B-2.- FUNCIONES PARA LA PREDICCION
DE PROPIEDADES DE TRANSPORTE
DE GASES A BAJA DENSIDAD
u = k
,AB
kT/
o (Para Viscocidad y
kT/AB
(Para Difusividad)
0.30 2.785 2.662
0.35 Conductividad Calorfica)
2.628 2.476
0.40 2.492 2.318
0.45 2.368 2.184
0.50 2.257 2.066
0.55 2.156 1.966
0.60 2.065 1.877
0.65 1.982 1.798
0.70 1.908 1.729
0.75 1.841 1.667
0.80 1.780 1.612
0.85 1.725 1.562
0.90 1.675 1.517
0.95 1.629 1.476
1.00 1.587 1.439
1.05 1.549 1.406
1.10 1.514 1.375
1.15 1.482 1.346
1.20 1.452 1.32
1.25 1.424 1.296
1.30 1.399 1.273
1.35 1.375 1.253
1.40 1.353 1.233
1.45 1.333 1.215
1.50 1.314 1.198
1.55 1.296 1.182
1.60 1.279 1.167
1.65 1.264 1.153
1.70 1.248 1.14
1.75 1.234 1.128
Tabla B-2.- FUNCIONES PARA LA PREDICCION
DE PROPIEDADES DE TRANSPORTE
DE GASES A BAJA DENSIDAD
u = k
,AB
kT/
o (Para Viscocidad y
kT/AB
(Para Difusividad)
1.80 1.221 1.116
1.85 Conductividad Calorfica)
1.209 1.105
1.90 1.197 1.094
1.95 1.186 1.084
2.00 1.175 1.075

2.10 1.156 1.057


2.20 1.138 1.041
2.30 1.122 1.026
2.40 1.107 1.012
2.50 1.093 0.9996
2.60 1.081 0.9878
2.70 1.069 0.977
2.80 1.058 0.9672
2.90 1.048 0.9576
3.00 1.039 0.949
3.10 1.03 0.9406
3.20 1.022 0.9328
3.30 1.014 0.9256
3.40 1.007 0.9186
3.50 0.9999 0.912
3.60 0.9932 0.9058
3.70 0.987 0.8998
3.80 0.9811 0.8942
3.90 0.9755 0.8888
4.00 0.97 0.8836
4.10 0.9649 0.8788
4.20 0.96 0.874
4.30 0.9553 0.8694
4.40 0.9507 0.8652
Tabla B-2.- FUNCIONES PARA LA PREDICCION
DE PROPIEDADES DE TRANSPORTE
DE GASES A BAJA DENSIDAD
u = k
,AB
kT/
o (Para Viscocidad y
kT/AB
(Para Difusividad)
4.50 0.9464 0.861
4.60 Conductividad Calorfica)
0.9422 0.8568
4.70 0.9382 0.853
4.80 0.9343 0.8492
4.90 0.9305 0.8456
5.00 0.9269 0.8422

6.0 0.8963 0.8124


7.0 0.8727 0.7896
8.0 0.8538 0.7712
9.0 0.8379 0.7556
10.0 0.8242 0.7424

20.0 0.7432 0.664


30.0 0.7005 0.6232
40.0 0.6718 0.596
50.0 0.6504 0.5756
60.0 0.6335 0.5596
70.0 0.6194 0.5464
80.0 0.6076 0.5352
90.0 0.5973 0.5256
100.0 0.5882 0.517
Pgina 8 de 12 11/12/2017 20:36:51 Viscocidad de 01 a 05 GASES

Desarrollo de clculos para hallar Viscosidad de una mezcla de Varios Gases

Ingresar datos Generales solamente en las Celdas Amarillas


SUBSTANCIAS
Presion = 1 Atm 1.- CO2 3 M
Temperatura = 310 K 2.- O2 5
3.- N2 6 /K
Redondear = 4 4.-
5.- K

2 KT/
Multiplo
Rango 01 < 0.30 2.00 0.05
Rango 02 < 2.00 5.00 0.1
Rango 03 < 5.00 10.00 1
Rango 04 < 10.00 100.00 10 Viscocodad () (9/cm.seg)

Ecuacin de WILKE

Ui Xi
MEZCLA PM
Nro. GASEOSA
Viscosidad (Fraccin
(g)
(g/cm*s) Molar)
1 CO2 44.0100 1.5380E-04 0.1333
2 O2 32.0000 2.1197E-04 0.0390
Pgina 9 de 12 11/12/2017 20:36:51 Viscocidad de 01 a 05 GASES

3 N2 28.0200 1.8218E-04 0.8280


4 0 0.0000 0.0000E+00
5 0 0.0000 0.0000E+00

U U mezcla
i j Mi/Mj Ui/Uj Mj/Mi Oij Xj*Oij Sumatoria
mezcla p. (g/cm*s)
1 1.000 1.000 1.000 1.000 0.1333
2 1.375 0.726 0.727 0.732 0.0286
1 3 1.571 0.844 0.637 0.731 0.6052 0.767 2.6729302E-05
4 0.000 0.000 0.000 0.000 0.0000
5 0.000 0.000 0.000 0.000 0.0000
1 0.727 1.378 1.375 1.388 0.1850
2 1.000 1.000 1.000 1.000 0.0390
2 3 1.142 1.164 0.876 1.009 0.8351 1.059 0.000007806
4 0.000 0.000 0.000 0.000 0.0000
5 0.000 0.000 0.000 0.000 0.0000
1 0.637 1.185 1.571 1.360 0.1813
2 0.876 0.859 1.142 0.990 0.0386
3 3 1.000 1.000 1.000 1.000 0.8279 1.048 1.4397E-04 1.7851E-04
4 0.000 0.000 0.000 0.000 0.0000
5 0.000 0.000 0.000 0.000 0.0000
1 0.000 0.000 0.000 0.000 0.0000
2 0.000 0.000 0.000 0.000 0.0000
4 3 0.000 0.000 0.000 0.000 0.0000 0.000 0
4 0.000 0.000 0.000 0.000 0.0000
5 0.000 0.000 0.000 0.000 0.0000
1 0.000 0.000 0.000 0.000 0.0000
2 0.000 0.000 0.000 0.000 0.0000
5 3 0.000 0.000 0.000 0.000 0.0000 0.000 0
4 0.000 0.000 0.000 0.000 0.0000
Pgina 10 de512 11/12/2017 20:36:51 0.000 0 Viscocidad de 01 a 05 GASES

5 0.000 0.000 0.000 0.000 0.0000


Pgina 11 de 12 11/12/2017 20:36:51 Viscocidad de 01 a 05 GASES

SUBSTANCIAS
1.-) CO2 2.-) O2 3.-) N2 4.-) 0 5.-) 0
44.01 32.00 28.02 0.00 0.00

3.996 3.433 3.681 0.000 0.000

190.00 113.00 91.50 0.00 0.00

1.6316 2.7434 3.388 0 0

1.60 1.279 2.70 1.069 3.30 1.014 0.00 0 0.00 0


1.6316 1.2695 2.7434 1.0642 3.388 1.0078 0 0 0 0
1.65 1.264 2.80 1.058 3.40 1.007 0.00 0 0.00 0

1.538E-04 2.120E-04 1.822E-04 0.000E+00 0.000E+00


Pgina 12 de 12 11/12/2017 20:36:51 Viscocidad de 01 a 05 GASES