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Catalytic Reforming - Training Material
Uploaded by Jorge Gamarra on Nov 01, 2010
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Cracking (Chemistry)GasolineChemical ProcessesCatalysisChemical Engineering
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Ch.1 BASIC PRINCIPLES ? Table (1.1), RON for some pure hydrocarbons. Another
solution for the low antiknock problem of gasoline was used in 1922 which was the
use of TEL (Tetra Ethyl Lead). TEL increases the octane number greatly when added
to gasoline in small quantities. Pure Hydrocarbons RON Paraffins n-Butane 113 i-
Butane 122 n-Hexane 19 2-Methylpentane 83 2,2-Dimethylbutane 89 2,3-Dimethylbutane
96 n-Heptane 0 2-Methylhexane 41 n-Octane -19 Olefins 1-Pentene 91 1-Octene 29 3-
Octene 73 Naphthenes Methylcyclopentane 107 Ethylcyclopentane 75 1,1-
Dimethylcyclopentane 96 Aromatics Benzene 99 Toluene 124 o-Xylene 120 m-Xylene 145
p-Xylene 146 Oxygenates Methanol 106 Ethanol 99 2-Propanol 90 (MTBE) 117
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CATALYTIC REFORMING ? However, over years, in many countries the amount of added
lead has been decreased gradually by strict regulations in order to pave the way
for completely preventing its use for its harmful effect on man's health and
environment. Nowadays lead-free gasoline is used in most countries around the world
and as a substitute additive for TEL to the gasoline, oxygenates such as alcohols,
MTBE, and TAME are now used to increase the octane number of gasoline. Table(1.2)
shows the Maximum allowable contents of some oxygenates. The ethers may be produced
at the refinery by reacting suitable alcohols such as methanol and ethanol with
branched olefins from the fluid catalytic cracker, such as iso-butene and iso-
pentene, under the influence of acid catalysts. In the mid-1990s, methyl-t-butyl
ether (MTBE) -made by etherification of iso-butene with methanol- became the
predominant oxygenate used to meet reformulation requirements for adding oxygen to
mitigate emissions from gasoline-powered vehicles. Environmental issues involving
MTBE have made it more desirable to dimerize isobutene from the catalytic cracking
unit rather than etherify it. Fortunately, iso-butene dimerization may be achieved
with minimal modifications to existing MTBE plants and process conditions, using
the same acidic catalysts. Where olefin levels are not restricted, the extra
blending octane boost of the di-iso-butylene can be retained. Where olefin levels
are restricted, the di-iso-butylene can be hydrotreated to produce a relatively
pure iso-octane stream that can supplement alkylate for reducing olefins and
aromatics in reformulated gasoline. Oxygenates Maximum, Volume % Methanol Ethanol
Iso-propyl Alcohol Iso-butyl Alcohol Tert- butyl Alcohol Ether (5 or more C atoms)
Other oxygenates 3 5 10 10 7 15 10 Table(1.2), Oxygenates allowed on Gasoline.
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