Conclusion

From the experiments it can be concluded:

a. Transition metal compounds form complexes. It make specific colors, and specific
precipitate depend complex center in compounds.

Question :

1. Write all reaction in experiment I util III, give color changing

Answer :

Firsh experiment I : ion transition metal

a. Reaction with NaOH
CrCl3 + NaOH [Cr(H2 O)3 (OH)3 ] + NaOH [Cr(H2 O)2 (OH)4 ]
Blue dark green dark green (+)

Mn(SO4 ) + NaOH [Mn(H2 O)4 (OH)2 ] + NaOH [Mn(H2 O)3 (OH)3 ]

colorless dark brown (++) dark brown (++)

Fe(NH3 )2 SO4 + NaOH [Fe(H2 O)4 (OH)2 ] + NaOH [Fe(H2 O)3 (OH)3 ]
yellow dark green (++) dark green (+++)

FeCl3 + NaOH [Fe(H2 O)3 (OH)3 ] + NaOH [Fe(H2 O)2 (OH)4 ]

Yellow(-) brown (++) brown (+++)

CoCl2 + NaOH [Co(H2 O)4 (OH)2 ] + NaOH [Co(H2 O)3 (OH)3 ]

Pink tosca tosca (+)

NiCl2 + NaOH [Ni(H2 O)4 (OH)2 ] + NaOH [Ni(H2 O)3 (OH)3 ]

Green(-) green green (+)

CuSO4 + NaOH [Cu(H2 O)4 (OH)2 ] + NaOH [Cu(H2 O)3 (OH)3 ]

Blue (+) tosca tosca++)

ZnCl2 + NaOH [Zn(H2 O)4 (OH)2 ] + NaOH [Zn(H2 O)3 (OH)3 ]

colorless turbid , white turbid (+)
 b. Reaction with amonia
CrCl3 + NH3 [Cr(H2 O)3 (OH)3 ] + NH3 [Cr(H2 O)2 (OH)4 ]
Blue (-) dark green (+) dark green (++)

Mn(S4 ) + NH3 [Mn(H2 O)4 (OH)2 ] + NH3 [Mn(H2O)3 (OH)3 ]

colorless brown (-) dark brown (+)

Fe(NH3 )2 SO4 + NH3 [Fe(H2 O)4 (OH)2 ] + NH3 [Fe(H2 O)3 (OH)3 ]
Yellow dark green (+) dark green (++)

FeCl3 + NH3 [Fe(H2 O)3 (OH)3 ] + NH3 [Fe(H2 O)2 (OH)4 ]

Yellow (-) dark brown (++) dark brown(+++)

CoCl2 + NH3 [Co(H2 O)4 (OH)2 ] + NH3 [Fe(H2 O)3 (OH)3 ]

pink tosca tosca (+)

NiCl2 + NH3 [Ni(H2 O)4 (OH)2 ] + NH3 [Ni(H2 O)3 (OH)3 ]

Green(-) turbid,green (++) green(+++),

CuSO4 + NH3 [Cu(H2 O)4 (OH)2 ] + NH3 [Cu(H2 O)3 (OH)3 ]

Blue(-) blue (-) dark blue (++)

ZnCl2 + NH3 [Zn(H2 O)4 (OH)2 ] + NH3 [Zn(H2 O)3 (OH)3 ]

Colorless white

c. Reaksi dengan NH4CNS

CrCl3 + NH4 CNS [Cr(H2 O)5 (SCN)]+
blue dark blue

Mn(SO)4 + NH4 CNS [Mn(H2 O)5 (SCN)]+

colorless colorless

Fe(NH3 )2 SO4 + NH4 CNS [Fe(H2 O)5 (SCN)]+

yellow reddish brown

FeCl3 + NH4 CNS [Fe(H2 O)5 (SCN)]+

Yellow(-) reddish brown

CoCl2 + NH4 CNS [Co(H2 O)5 (SCN)]+

Pink Pink (+)

NiCl2 + NH4 CNS [Ni(H2 O)5 (SCN)]+

Green (-) dark green (++)
CuSO4 + NH4 CNS [Cu(H2 O)5 (SCN)]+
Blue (+) tosca

ZnCl2 + NH4 CNS [Cl(H2 O)5 (SCN)]+

colorless colorless