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(A) CrO5 and H2O (B) Cr2O3 and H2O (C) CrO2 and H2O (D) CrO and H2O
KI dil H SO
Q.21 Y(g ) CuSO4 2
4 X(Blue colour) , X and Y are
(A) X = I2, Y = [Cu(H2O)4]2+ (B) X = [Cu(H2O)4]2+, Y = I2
+
(C) X = [Cu(H2O)4] , Y = I2 (D) X = [Cu(H2O)5]2+, Y = I2
Q.22 Transition elements are usually characterised by variable oxidation states but Zn does not show this
property because of
(A) completion of np-orbitals (B) completion of (n1)d orbitals
(C) completion of ns-orbitals (D) inert pair effect
Q.23 (NH4)2Cr2O7 (Ammonium dichromate) is used in fire works. The green coloured powder blown in air is
(A) Cr2O3 (B) CrO2 (C) Cr2O4 (D) CrO3
Q.24 The d-block element which is a liquid at room temperature, having high specific heat, less reactivity than
hydrogen and its chloride (MX2) is volatile on heating is
(A) Cu (B) Hg (C) Ce (D) Pm
Q.25 Coinage metals show the properties of
(A) typical elements (B) normal elements
(C) inner-transition elements (D) transition element
Q.26 Iron becomes passive by ..................... due to formation of .....................
(A) dil. HCl, Fe2O3 (B) 80% conc. HNO3, Fe3O4
(C) conc. H2SO4, Fe3O4 (D) conc. HCl, Fe3O4
Q.32
(A) red liquid (B) violet gas (C) greenish yellow gas (D) yellow-brown gas
Q.50 Purple of cassius is:
(A) Pure gold (B) Colliodal solution of gold
(C) Gold (I) hydroxide (D) Gold (III) chloride
Q.51 Amongst the following species, maximum covalent character is exhibited by
(A) FeCl2 (B) ZnCl2 (C) HgCl2 (D) CdCl2
Q.52 Number of moles of SnCl2 required for the reduction of 1 mole of K2Cr2O7 into Cr2O3 is (in acidic medium)
(A) 3 (B) 2 (C) 1 (D) 1/3
Q.53 Amphoteric oxide(s) of Mn is/are
(A) MnO2 (B) Mn3O4 (C) Mn2O7 (D) MnO
Q.54 Pick out the incorrect statement:
(A) MnO 24 is quite strongly oxidizing and stable only in very strong alkalies. In dilute alkali, neutral
solutions, it disproportionates.
(B) In acidic solutions, MnO 4 is reduced to Mn2+ and thus, KMnO4 is widely used as oxidising agent
(C) KMnO4 does not acts as oxidising agent in alkaline medium
(D) KMnO4 is manufactured by the fusion of pyrolusite ore with KOH in presence of air or KNO3,
followed by electrolytic oxidation in alkaline solution.
Q.55 The aqueous solution of CuCrO4 is green because it contains
(A) green Cu2+ ions (B) green CrO42 ions
2+
(C) blue Cu ions and green CrO4 ions 2 (D) blue Cu2+ ions and yellow CrO42 ions
Q.56 Manganese steel is used for making railway tracks because
(A) it is hard with high percentage of Mn (B) it is soft with high percentage of Mn
(C) it is hard with small concentration of manganese with impurities
(D) it is soft with small concentration of manganese with impurities
Q.66 Colourless solutions of the following four salts are placed separately in four different test tubes and a
strip of copper is dipped in each one of these. Which solution will turn blue?
(A) KNO3 (B) AgNO3 (C) Zn(NO3)2 (D) ZnSO4
Q.67 Peacock ore is:
(A) FeS2 (B) CuFeS2 (C) CuCO3.Cu(OH)2 (D) Cu5FeS4
Q.68 925 fine silver means an alloy of:
(A) 7.5 % Ag and 92.5% Cu (B) 92.5 % Ag and 7.5 % Cu
(C) 80% Ag and 20 % Cu (D) 90 % Ag and 10% Cu
Q.69 Iron salt used in blue prints is:
(A) FeC2O4 (B) Fe2(C2O4)3 (C) K4[Fe(CN)6] (D) K3[Fe(CN)6]
Q.70 When acidified KMnO4 is added to hot oxalic acid solution, the decolourization is slow in the beginning,
but becomes very rapid after some time. This is because:
(A) Mn2+ acts as autocatalyst (B) CO2 is formed as the product
(C) Reaction is exothermic (D) MnO 4 catalyses the reaction
Q.73 Assertion : The highest oxidation state of chromium in its compounds is +6.
Reason : Chromium atom has only six electrons in ns and (n1) d orbitals.
Q.74 Assertion : CrO3 reacts with HCl to form chromyl chloride gas.
Reason : Chromyl chloride (CrO2Cl2) has tetrahedral shape.
Q.75 Assertion : Zinc does not show characteristic properties of transition metals.
Reason : In zinc outermost shell is completely filled.
Q.77 Assertion : Equivalent mass of KMnO4 is equal to one-third of its molecular mass when it acts as an
oxidising agent in an alkaline medium.
Reason : Oxidation number of Mn is +7 in KMnO4.