Extraction Techniques

,

--
()
().

(Extraction Filtration)
:




(()
)
;




,




:
(extraction)
(solid phase extraction)

(liquid-liquid extraction)
3


:
,

Soxhlet ()
(Separation funnel)
(Solid Phase Extraction, SPE)
- (Solid Phase MicroExtraction, SPME)
(Ultra Sound Assisted
Extraction, USE)
(Microwave Assisted
Extraction, MAE)

O





,,

. 4


, .



(extraction).
( t ti )

( )

Bchner (
)
)

(
)
7


Soxhlet.
(extraction)

(Separation funnel)

(
( ))

(
(

)) ((liquid-
qu d
liquid extraction)

KD = (Distribution Coefficient)

C2
KD
C 1

dH2O = 1g/mL
d.<dH2O
d.>dH2O

10




: 100 mL (Extractant),
(1)
;
V1 = mL V2 = mL
W0 = g
W1 = g 1
W2 = g 2

W W0 1

1 K C W
2 V 2
W 1 W 0 V 1
D
C 1 1 K V V
D 2 1

V 1

W W1 2
2
2 V1
K C W
2 V 2
W 2 W 1 V 1
W W
D
C K V V
K DV 2 V 1
2 0
1 2 D 2 1

V 1




n Wn = g


V1 n
n W W
K DV 2 V 1
n 0

Wn 0 : V2
n

((..
CH2Cl2)

NaOH 1N

RCOOH + NaOH RCOONa + H2O

pH>7

RCOONa

HCl 1N
RCOONa + HCl RCOOH + NaCl
pH<7
H<7

RCOOH

RCOOH


(Solid Phase Extraction, SPE)

-

(Solid Phase MicroExtraction, SPME)

(Ultra Sound Assisted Extraction, USE)

((Microwave Assisted Extraction, MAE))
14