Rotameter Calibration

Actual
Volume Flow
S No Rotameter Reading (l/hr) Time (s) Rate
(ml) (l/hr)
1 9.9 50 18.1
2 10.0 7.6 50 23.6
3 6.5 50 27.7
4 9.9 50 18.1
5 12.5 7.3 50 24.5
6 4.5 50 40.0
7 9.9 50 18.1
8 15.0 6.5 50 27.7
9 4.1 50 43.9

Table of Constants
Volume of CSTR 2.15 l
Volume of Sample 10 ml
Volume of HCl 20 ml
Normality of Feed NaOH 0.046165 N
Normality of Titration NaOH 0.027449 N
Normality of Feed HCl 0.0258 N
HCLO 5.16E-04 mol
 Observations Table for CSTR
Actual
Burette reading Volume Conv. XA/(1- Flow K_avg
NaOH EtAc HCLO HCLR CA Avg CA k
of NaOH XA)^2 Rates Calculated
S No Temperature (C)
of L/
(L/hr) (L/hr) INITIAL FINAL consume gmol gmol mol/l mol/l NaOH (L/hr) (min) (mol.mi L/(mol.min.)
d (ml) (XA) n)
1 10 10 0 13.5 13.5 5.16E-04 1.45E-04 0.0145
2 10 10 13.5 27.6 14.1 5.16E-04 1.29E-04 0.0129 0.0143 0.691 7.231 18.140 7.111 22.028
3 10 10 27.6 40.8 13.2 5.16E-04 1.54E-04 0.0154
4 12.5 12.5 0 14.1 14.1 5.16E-04 1.29E-04 0.0129
5 60 12.5 12.5 14.1 28 13.9 5.16E-04 1.34E-04 0.0134 0.0131 0.717 8.927 23.642 5.456 35.442 29.066
6 12.5 12.5 28 42.1 14.1 5.16E-04 1.29E-04 0.0129
7 15 15 0 13.7 13.3 5.16E-04 1.51E-04 0.0151
8 15 15 13.7 27.2 13.4 5.16E-04 1.48E-04 0.0148 0.0150 0.675 6.393 27.693 4.658 29.728
9 15 15 27.2 40.8 13.3 5.16E-04 1.51E-04 0.0151
10 10 10 0 12.6 12.6 5.16E-04 1.70E-04 0.0170
11 10 10 12.6 24.9 12.3 5.16E-04 1.78E-04 0.0178 0.0176 0.620 4.280 18.127 7.116 13.029
12 10 10 24.9 37.2 12.3 5.16E-04 1.78E-04 0.0178
13 12.5 12.5 0 13.2 13.2 5.16E-04 1.54E-04 0.0154
14 50 12.5 12.5 13.2 26.3 13.1 5.16E-04 1.56E-04 0.0156 0.0160 0.653 5.433 24.490 5.267 22.342 28.500
15 12.5 12.5 26.4 39 12.6 5.16E-04 1.70E-04 0.0170
16 15 15 0 13.9 13.9 5.16E-04 1.34E-04 0.0134
17 15 15 13.9 27.6 13.7 5.16E-04 1.40E-04 0.0140 0.0141 0.695 7.463 40.000 3.225 50.128
18 15 15 27.6 41 13.4 5.16E-04 1.48E-04 0.0148
19 10 10 0 13.2 13.2 5.16E-04 1.54E-04 0.0154
20 10 10 13.2 26.2 13 5.16E-04 1.59E-04 0.0159 0.0158 0.657 5.593 18.129 7.116 17.026
21 10 10 26.2 39.1 12.9 5.16E-04 1.62E-04 0.0162
22 12.5 12.5 0 12.9 12.9 5.16E-04 1.62E-04 0.0162
23 40 12.5 12.5 12.9 26.1 13.2 5.16E-04 1.54E-04 0.0154 0.0157 0.659 5.675 27.693 4.658 26.391 27.259
24 12.5 12.5 26.1 39.2 13.1 5.16E-04 1.56E-04 0.0156
25 15 15 0 12.9 12.9 5.16E-04 1.62E-04 0.0162
26 15 15 12.9 25.7 12.8 5.16E-04 1.65E-04 0.0165 0.0163 0.647 5.203 43.902 2.938 38.360
27 15 15 25.7 38.6 12.9 5.16E-04 1.62E-04 0.0162
feed naoh 0.050433

titration naoh 0.029788

hcl 0.027405
volume cstr 2.15 L

least counts rotameter 17.5*2 lt/h

rotameter 0.5lph actual 33.06 lt/h
burette 0.1ml
measuring 0.5ml
 Rate constant calculation from graph
Rota Actual
meter k_graph
S No (C) Readi Flow
T
Rate Xa tau Xa/(1- (L/mol.mi
(min) Xa)^2
vs xA/(1-xA)^2 at 60 C
ng n)
(l/hr) 7.500
1 (l/hr)
10.0 18.140 0.691 7.111 7.231 7.000
2
3 6.500
4 6.000

(min.)
5.500 f(x) = 0.1273065472x + 4.7849890486
5 60 12.5 23.642 0.717 5.456 8.927 170.564 R = 0.0172597654
6 5.000
7 4.500
8 15.0 27.693 0.675 4.658 6.393 4.000
6.000 6.500 7.000 7.500 8.000 8.500 9.000 9.500
9
10 xA/(1-xA)^2
11 10.0 18.127 0.620 7.116 4.280
12
13
14 50 12.5 24.490 0.653 5.267 5.433 -18.097
15
16
17 15.0 40.000 0.695 3.225 7.463
18
19
20 10.0 18.129 0.657 7.116 5.593
21
22
23 40 12.5 27.693 0.659 4.658 5.675 3.692
24
25
26 15.0 43.902 0.647 2.938 5.203
27
 vs xA/(1-xA)^2 at 40 C
8.000
7.000
6.000
f(x) = 5.8676183559x - 27.3127901017
(min.)

5.000 R = 0.4961960825
4.000
3.000
2.000
5.100 5.200 5.300 5.400 5.500 5.600 5.700 5.800
xA/(1-xA)^2

vs xA/(1-xA)^2 at 50 C
8.000
7.000
f(x) = - 1.197893923x + 12.0615315852
6.000 R = 0.9833975778
(min.)

5.000
4.000
3.000
2.000
4.000 4.500 5.000 5.500 6.000 6.500 7.000 7.500 8.000
xA/(1-xA)^2
 Activation Energy Calculation
k
S No T (C) T (K) (L/mol.mi 1/T(K-1) ln k Ea (J/mol)
n)
1 40 313.15 27.259 3.19E-03 3.305
2 50 323.15 28.500 3.09E-03 3.350 2792.673
3 60 333.15 29.066 3.00E-03 3.370

ln(k) vs 1/T
3.380
3.370 f(x) = - 335.9476873352x + 4.3818840758
3.360 R = 0.9597019308
3.350
3.340
3.330
ln(k)

3.320
3.310
3.300
3.290
3.280
3.270
2.95E-03 3.00E-03 3.05E-03 3.10E-03 3.15E-03 3.20E-03 3.25E-03
1/T (K^-1)