Grupo

Argandoa - Vargas

Dvila -Moscoso

Reyes Villanueva

Tarazona Vsquez

Urbina

Concentracion de NaOH:
Alicuota de HA:

Concentracin Inicial
0.2
0.4
0.6
0.8
1

Moles antes de adsorcion

0.002
0.004
0.006
0.008
0.01

Y
0.0696
0.1209
 0.165
0.216
0.282

Isoterma de Freundlich
-1.2 -1.1 -1 -0.9 -0.8 -0.7

f(x) = 0.7272340761x - 0.3930000022

R = 0.982855304

Concentracin (t = 0'')
0.084
0.1985
0.325
0.44
0.53

Isoterma de Langmuir para t = 0

140

120 f(x) = 94.9557910078x + 74.8604393785

R = 0.7109781635
100

80

60

40
 120 f(x) = 94.9557910078x + 74.8604393785
R = 0.7109781635
100

80

60

40

20

0
0 0.1 0.2 0.3 0.4

Concentracin Inicial (Co)

0.2
0.4
0.6
0.8
1

Isoterma segn B.E.T para t = 0 ''

700

600 f(x) = - 2289.7616910122x + 1586.7112331902

R = 0.691718416
500

400

300

200

100

0
0.4 0.42 0.44 0.46 0.48 0.5 0
 Gasto NaOH (ml)
ConcentracinCH3COOH Masa de carbn (g)
a 0

0,20 1,0 8.4

0,40 1,0 19.85

0,60 1,0 32.5

0,80 1,0 44

1,00 1,0 53

0.1
10

Concentracin (t = 0'') Concentracin (t = 45') Concentracin (t = 24 h)

0.084 0.0815 0.0805
0.1985 0.188 0.188
0.325 0.3145 0.314
0.44 0.412 0.43
0.53 0.524 0.522

Moles despues de absorcin Moles adsorbidas M adsorbida por M de carbon

0.00084 0.00116 0.0696
0.001985 0.002015 0.1209
0.00325 0.00275 0.165
0.0044 0.0036 0.216
0.0053 0.0047 0.282

log(Y) Concentracin (t = 0'') log( Concetracin)

-1.1573907604 0.084 -1.0757207139
-0.9175736991 0.1985 -0.7022394889
 -0.7825160558 0.325 -0.488116639
-0.6655462488 0.44 -0.3565473235
-0.5497508917 0.53 -0.2757241304

Isoterma de Freundlich para t = 0 ''

0
-1.1 -1 -0.9 -0.8 -0.7 -0.6 -0.5 -0.4 -0.3 -0.2
-0.2

-0.4

-0.6
f(x) = 0.7272340761x - 0.3930000022
R = 0.982855304
-0.8

-1

-1.2

-1.4

log(K) = - 0.393 b = 0.7272

K = 0.40457

Moles adsorbidas (N) Concentracin/N

0.00116 72.4137931034
0.002015 98.5111662531
0.00275 118.1818181818
0.0036 122.2222222222
0.0047 112.7659574468

Isoterma de Langmuir para t = 0''

f(x) = 94.9557910078x + 74.8604393785

R = 0.7109781635
f(x) = 94.9557910078x + 74.8604393785
R = 0.7109781635

0.1 0.2 0.3 0.4 0.5 0.6

Concentracin (t = 0'') (Cf) Moles adsorbidas (N) (Cf)/((N)*(Co-Cf))

0.084 0.00116 624.2568370987
0.1985 0.002015 488.8891625464
0.325 0.00275 429.7520661157
0.44 0.0036 339.5061728395
0.53 0.0047 239.9275690358

Isoterma segn B.E.T para t = 0 ''

f(x) = - 2289.7616910122x + 1586.7112331902

R = 0.691718416

42 0.44 0.46 0.48 0.5 0.52 0.54 0.56

Gasto NaOH Gasto NaOH

a 45 (ml) 24 h (ml)

8.15 8.05

18.8 18.8

31.45 31.4

41.2 43

52.4 52.2

Moles antes de adsorcion Moles despues de absorcin

0.002 0.000815
0.004 0.00188
0.006 0.003145
0.008 0.00412
0.01 0.00524

Y log(Y)
0.0711 -1.1481303993
0.1272 -0.8955128887
0.1713 -0.766242637
0.2328 -0.633017024
0.2856 -0.5442417969

Isoterma de Freundlich para

-1.2 -1.1 -1 -0.9 -0.8 -0.7 -0.6 -

f(x) = 0.7346931579x - 0.3591351989

R = 0.9906459889
 Cf/Co
0.42
0.49625
0.541666667
0.55
0.53
Moles adsorbidas M adsorbida por M de carbon
0.001185 0.0711
0.00212 0.1272
0.002855 0.1713
0.00388 0.2328
0.00476 0.2856

Concentracin (t = 45')log( Concetracin)

0.0815 -1.0888423913
0.188 -0.7258421507
 0.3145 -0.5023793502
0.412 -0.385102784
0.524 -0.280668713

Isoterma de Freundlich para t=45'

0
-1 -0.9 -0.8 -0.7 -0.6 -0.5 -0.4 -0.3 -0.2
-0.2

-0.4

x) = 0.7346931579x - 0.3591351989 -0.6

= 0.9906459889
-0.8

-1

-1.2

-1.4

log(K) = 0.3591 b = 0.7347

K = 0.4374