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  • Génie Des Procédes

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    hamdi
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    chemi

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    chemi

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    1 vues48 pages

    Génie Des Procédes

    Transféré par

    hamdi
    chemi

    Droits d'auteur :

    © All Rights Reserved
    Téléchargez comme PDF ou lisez en ligne sur Scribd
    Signaler comme contenu inapproprié
    sur 48
    Agel Agbl fagall A I jell ay geal 4h MN Ay S55 Age ral ile gataall jibe lt ol yall 2008-2007 Ayal pall Aisa! mh Je DFU Sg QA og EN La aay ts V yotread Ol pew ptt le gabaall Gog! ly sully i qilogll SAB AVN aN Sly Ia 3 aecloll airegere « gizdlaeg Ugisal ya das DD Led Rely Al cll ope Lag Loc ag Lapleg| i aeclotl ode Og=55 ol UG «Lay ant 5 algd GLa! Che Cala Ge ME LLY loz) gl BIGLAM Jes ee AN shes pa Lys oka B dgas co gad pa lye alen pall Lady aeacalgtl ode Rags FU age WAL res Lata Sages a (5 (ipa Austen) Lua gh giSitl : Babe cod itl & peda gall 1 i BS BS ye US ages GE cag Colin Uae Aine A Ginga pa -1 + Mg 36 2 dite gh © © Gane Ge chy cpl MSL) y 5554) KMnO, Mandy A Oe dye 1 Saas AB ya eae G8) y CO BLA GAS pd ioe ce - AN) sas AD Spal le ppp sitall 2D Sa any FeBry syns gf Cal ge Bry psyill elit -2 +E pa paiie pal Se shy la +B Son gles MA) ay 9 JOEY! ge EGS all dois - Si ges 170°C aan bury od F Sl Qu pall £55 — + Aga coletid Gas y De Ee Fs G cls yall due cue - | ipl Aisle ba ob nla) Je Gi pda USL ny F GS all — G Spall 5 yal oe Yetha Polystyrene cy jul! dante yan —3 «Sedat Aten os . Polystyréne ctatsiiul pai Sih — AU cpl Ayia eget cys at) Gal H,N-CH-COOH H,N-CH- COOH H,N-CH- COOH H,N-CH- COOH CH (CHa) CH H Z cit, S cH, O cooH | \ 1 2 3 4 + NYS yall 93a Rage Ge yy GEASS Auays diy yb ge cing) 1 Agel) geal gill pladBAL CYS yal oda Cina -2 Absa) AyihyegSt) Alay 8 pu ob 6162 63 4 Ow asl Gol dle -3 Cot Gilad jul Uplia Salt) Go i gl 4 EU Spall O6 Ugy HES Ae Hy b Ctl -5 2) yp yal + gl) Jerid 298°K Ag all gf Waal (1 + 3/2 O2q—*COxg)_ +2H0q) AH=-173,6kcal.mol AH,’ (209) = -68,4 keal.mol AH’ (COx@) )=-94 keal. mol™ CHOH had CHjOH SSE g Jee als qua! Allvap = 8,4 Keal.mol 4 CHjOH dgitya 58.55) ya oi Lake (2 AD & gids yall Ag $28) Spall phat AIC aga od ( CH3COCI ) dei) asl a CA tS pl Rigua gil y dala) Jel . EUR sles GS ge A GLY) Gnas cya UU ta) ay yl jyaaadl May jb ca) - eA ayy sain gl) B GS) aud CHy CHa - MgBrosyal eA Gated g yaad GS pl Jelly - 2 Cys) CoB capt GS yal iis Qi — | + Gaile) le © byipca Slab C iS yall Ja = © D Spall fe aanid 170°C 5 ya Agus aie H2SO4 tgny AC Gebel g pcaall Sal Os lal! g iy py - 3 etiah Aatea csi +E Spall phe gj Sy D GS pl Bab - (Si joa gia 04) Ayilty Shang ax) ce Sy E Spall ye Ueda a gM eg) py] LULL Ge pH y T= 37°C aie dni Goal) span oad By A cule Ge cute sng) ps6 Sabai oa Ugg any B Ail Lal «A cul Mi dyally agin got ab gil py 3) ULI of (sate ie Sule olny Sty! Abad Aha pH ay a5) dike {Si -1 Sil gh lah 9 5 ly JEU abe AS 15) Chala gag 520) Jelis Gash -2 sca ge ple a pana gi pSall a Le -3 ecopgbilly Oa) Ugg Ge Ayal Laalaal geily quad GUS yal paaalal) plait) - 11 © ye Sled gueaeall (gl -1 2 call LUi) gis bel -2 all ¢ si Lael Apesala SI) nal yy GUS y yall ied 3 anh Cao Chis 52 fal shes Gas - 1 25°C ae olin GURY AH GMb cual - 2 AH? (H20q ) = -285,58 kJ. Mol AH ( COxg) ) = - 393,13 kJ. Molt AH? (CaFiog) 124,61 kJ. Mol” 25°C ac AU Sst MUD ob il Guna! — 3 R=8,314J.mol". K* ay ENN & guca gal 3) Gaal K2CrOy Usage pal Wm Spe Ligne AS sesh 2.1 ag shed ol gpl Lpeaily Ay atl AaiS (A) gas Lisl 1 Mig GAAS gh) 9 DNPH + Je lity Ai 43) jue Oe (B) Sal! ed WSO, Laer syns hy (A) dgastl Maal Say jal Miwall sag) 91 | (A) dps seal ual be 2 (A) Gg dine gil € (B) Spl dag a 3 (©) Saal gid Hy0* 2194 a5a9 od CH3COOH JS Gas a (A) dsaSll etity -I1 etal Joti ste 8) SUEUR Nia Cl jyan a Le 2 goon 1 ¢-0 Ey ) I +NADHH! = 2——————> (4) + NAD" Hy —_ 1,0 2 cooH NEA «a 3) Es 3) (B) +FADH,; ———————> (©) + FAD (OB)A) SHS tl Gre syed ay 5) DIEU Jas I E5,Ex,E1 Gly 38) plaai eh -2 Sly A) oda ithe -3 Sahay) Geany Glu ge! gaan) ee Ey pp 5il tepy GAY) Qe UE se Glee Jelity (IT COOH COOH I t ry “H-NH) ————> 0 He CH; He coon aeny ati Gane ee Es pal tpn Aelia) Gan Qe NE soe Ge Jelits Sh tye Oe dad sD (Urans Aminases) js) 4 Ae gana i Aiton Eg lly Gly 3M) GAS |i) Mata Aaa SN) edeU Gas) 1 ila 5B) oda plead dao -2 ny ) AN Seti ky 200 510 Mays ae CYT ISAS gla lA cual © 2C i) + 3H2(q ———> gj tae AH?359 =-84.6 KJ/mol. (Cp(H2) = 28.8 JK mol". Cp(Cootiae) = 11.3 IK mol", Cp(CrHo) 14.4 JK'mol", aL! gz gall 2d) Guat AGNGM al gla Qh Ly pn Bala ode yada coal st) VY Asawa Ay) Ge Yd patiyel ull yy mm H,SO, Ho + HNO; ———= (A) + 1,0 Fe/ HCl (A) ————= (8) + oO CH3—C ° (B) + o ——~ Y + che CH Jest ta oH AY yaaa Ul dine 9B) 9 (A) oS due spyi -1 CHs-CO-Cl Maly, 89) JoUia yi Jacana ( [O)20 Jal) (asa SleLOy Jlagiu! GSay Ja -2 FAS dle Ayala As pada eR cy al hal iba GuS fe Lsatet Aitcall Aa GLa AG) AAR) Galea! ow Gees JS ge lay Vee bel -1 opin inl ase (/ PS cel Gee ( ged nd ae (a gee cglnl Linas (4 2 AgyS) Gabes$) Gand pHi pd A) Jytell py -2 cat er) rr err (Lys) (Phe) (Glu) 97 58 32 PH cl Gp cay JO le Kika lll Galea ad asSt Ga pH Ol pb gat ls (Glu) 9 (Lys) ca SRA asad) AD Gyan ogllcad Jot sale (Glu) diya gla) Giana igi) ISON oe -E pH=01* pH=3,2* pH= 11 * (He) pied) aaa i gta) clsteall id Spt Guan Sle 3, Aha cig 9 cal Join sh DS coe 2 SA Oy Agia) Ay 3) Gs pall Exothermique Gf ja¥) (lai CLHy — AH) 331.6 kcal/mol. C,HyCh — AH, = -367.1 keal/mol. Enthalpie de formation sds ki - AH)’ (coz) = - 94 Keal/mol. -CoHiCh y CoHy J gh ia¥) Mates Gish -1 sOuS yall Gangs JAI pila @itiaa) -2 sqgltd Jeli IMA 5 yaad Ball qual -3 CoH, + Ch ———+> GHC alll & guia gall Jy) Cap pail FIRBLAD hye coy Oe gfe cag MG pal Ray Masked alisha gt BY AL Sale Gs sayal » yates dal on «CoHsCOOH obs ull yaaa (CoH , CcHs-CHs , CoHs-CH2OH , CH;Cl , HNO; , H2SO4 , KMn0, , H20 , AICL , NaOH , HCl, CH;COOH,..... shyaany Joni Bga g Slyala sd Ge Ae pane — « (CoHsCOOH) Abies 520 jpcaadd cme dia Gu Made ¢ sl AULD 5a) jpn Aybeel il yll Gus St) paw) -2 CH,-OH Api acted inl cian Sern pall 1 Gaya L ine as) i Bilal dle Lie Dad el de Bila) leg sia Sy Oa nal AE gis Bay US pas y cu all AD yy LRN LST Gas) 3 9.15 =pKynz 4 2.21 =pKcoon gid Sale 13) x pall pHi aa) 6 10 sSer-Ala-Gly spy gD JS call y CAN Qo cpl! ag 2 A) Galas! cup byt €.95 Si) y Ser-Ala-Gly aul) DS tine 05) 937 97s gh sid gle Len gst jd py] LULL QNEAD 5 Ja Agus y PHD of 3 Osa ova Je gS SOM i ety ie gi a) Sky DY Gta 4S) -g Niue i 2 ARAM cigaead Sharia CoH cuba) Jot allt coal Ecac = - 808,33kJ.mol". Een =- 415.46 kJ.mol’. +b Ail, sith Hie ais y AHa (12) = 436 kJ.mot". 2448 Sublimation tail AH (Cis) )= 715k J. mol". if ntlual) & 4a gall 294) Gy paitl 30a fate glad] (o& Quest NaNH2 Go 5.016 al yy CsHyBr Git Aine "AY RI laansy (Cutis sal) stp gly 55S) psp gall CS sh! Aa yall JeUiG iY sles AGS ga CB ‘A CAS ll due gia - DT Spall (ple aaaih PCls 4 lala ili Jat) ane -2 DY Sad $825 Jeti Males Gash - ADSI) aaa Gye (DUS) J SIGN cand May yb ¢_ si) -3 2G) cys pall 5 bs a A Aa pact yl) pas A CANN Uae le yan y gia Chay pied aaa Nn 64 0.89 g AY tans + eid pL ga 100mML gg UH) «Ld Hp H.N -CH-COOH c b a | CH; Ate ye a ASA So b Gus NAOH dylan Gina o © SySUil HCI yl cia Alanine Si gly 5839) qual 1 CoA pa ge (Amphotires ) 4ysisisl chs Gant! Gaba: Ayac Stl dal) agua tty Alani HI alan) pau Vike 2 Shaly sealy Ne 3 © pina! Giana Alen Guth ill pall Ayla gle habaied Sage IS sinae le aay He Cod EO Gus gd SD Mall gyal Haut SU Gus i Alanine 5 ype dua -h PK =9.7. pKa =2.3 iby Alanine pHi qual -o O=16 ;N=14; C=12; H=1 ae 12 NEM ye path SA de a Bt a CoH gS My CoH yg g 3A OMEN) 4 JS sia! CDE Gf (-1427,68 k.mol)s (-1322,90 kI.mol"!) igh HzO 9 COp S85 pita g) cate Vth AHY (COD qy = -393,51 kI.-mol 5 AHY,(H20)¢y = -241,82 kJ.-mol™! Call) 3 Cols tg B53) inn Gas SORT y OaMSN) OSS pla Gua -2 sgl Joli Aides hy CaN) aa 9s -3 CHs iy + Hag > CH AH%96K AH rox SEMEN Vim cypMadl ginal sa onal AHY (CH 6 ig 9 AH (CG iy + 100 cm? @ 55 AS dah Ga 27° C aie (HCOOCHs) JBN) A gin Syne Jeli Ae yo ag yi 1 0,02 Magali 4 100 cm? a0 0,02 M Ssh)

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