Académique Documents
Professionnel Documents
Culture Documents
19 It is impractical to provide solutions for all of the systems listed in thetable on page 474; we present
as an example only the solution for thesystem 1-propanol(1)/water(2). Solutions for the other
systems can beobtained by rerunning the following Mathcad program with theappropriate
parameter values substituted for those given. The fileNRTL.mcd reproduces the table of NRTL
parameters on Page 474 andincludes the necessary Antoine coefficients.
B2
Psat2(T) := [A2 (T273.15.K)+C2].kPa
cal 2 4
b12 := 500.40 b21 := = = 0.5081
mol 2
b12 b21
12() = 21() =
RT RT
21() 2 21()21()
[ [
1(1, 2, ) = x22 21() ( 1+221() ) +
(1+221())2
]]
12() 2 21()21()
[ [
2(1, 2, ) = x12 12() ( 2+112() ) +
(1+221())2
]]
Given 1 = 1 1(1, 2, ) 1 ()
1 + 2 = 1
2 = 2 2(1, 2, ) 2 ()
{ 1 } : = (, 1, 2)
2
Given 1 = 1 1(1, 2, ) 1 ()
1 + 2 = 1
2 = 2 2(1, 2, ) 2 ()
{ 1 } : = (, 1, 2)
2
1=0.1 2=11
Guess: = 0.5
1=0.1 2=11
11(1,2,)1 ()
Given 1 = 1 + 2 = 1
22(1,2,)2 ()
2 = 1 + 2 = 1
1 (1 ) + 1 = 1 Eq. (10.15)
1
2
1 : = (1, 2, 1, 2, )
2
()
1 = 0.069 2 = 0.931 1 = 0.352 2 = 0.648 = 0.816
2 = [( 2
2ln(
)
)
2 +273.15 ] 2 = 373.149
1(0,1,T)Psat1 (Tb2)
120 = 120 = 17.578
P
P
121 = 121 = 0.27
2(1,0,T)Psat2 (Tb1)
Since one of these values is >1 and the other is <1, an azeotrope exists.
See Ex. 10.3(e).
Guesses:
2 = 2 2(1, 2, ) 2 () 1 + 2 = 1
1 = 1
1
2
1 : = (1, 2, 1, 2, )
2
( )
= 360.676 1 = 0.4461 1 = 0.4461
228.060
= (239.500)
230.170
(,) : = [ = ] = (65 + 273.15)
( 273.15)+
0 161.88 291.27
Wilson parameters: = { 583.11 0 107.38 }
1448.01 469.55 0
(, , ) =
exp (,
.
) = 1. .3 = 1. .3 = 1. .3
1 = 0.3 2 = 0.4 3 = 1 1 2
0.527
= (0.367) = 117.1 Ans.
0.106
.3 = 3 (3, , ) (3,) = 1
1
2
( ) : = (1, 2, 3, )
3
0.035
= ( 0.19 ) = 69.14 Ans.
0.775
+
P= = 338.15
2
1 = 0.3 2 = 0.4 3 = 1 1 2
Guess: = 0.5 Use x from DEW P and y from BUBL P as initial guess.
Given . 1 = 1 (1, , ) (1,) . 2 = 2 (2, , ) (2,)
. 3 = 3 (2, , ) (2,)
1 (1 ) + 1 = 1 2 (1 ) + 2 = 2
3 (1 ) + 3 = 3
= 1 = 1
1
2
3
1 : = (1, 2, 3, 1, 2, 3, )
2
3
()
0.109 0.109
x= (0.345) y= (0.345) = 0.677 Ans.
0.546 0.546
0 161.88 291.27
Wilson parameters: = { 583.11 0 107.38 }
1448.01 469.55 0
(, , ) =
(.,)
i := 1..3 j := 1..3 p := 1..3
1 = 0.3 2 = 0.4 3 = 1 1 2
1
2
( ) : = (1, 2, 3, )
3
0,536
y= (0.361) = 334.08 Ans.
0.102
(b)DEW T calculation:
1 = 0.3 2 = 0.4 3 = 1 1 2
Guess: 1 = 0.05 2 = 0.2 3 = 1 1 2 =
Given
. 3 = 3 (3, , ) (3,) = 1
1
2
( ) : = (1, 2, 3, )
3
0.043
= (0.204) = 347.4
0.753
Tdew +Tbubl
(c)P,T-flash calculation: T = T = 340.75K
2
1 = 0.3 2 = 0.2 3 = 1 1 2
Guess: = 0.5 Use x from DEW P and y from BUBL P as initial guess.
Given
. 1 = 1 (1, , ) (1,) 1 (1 ) + 1 = 1
. 2 = 2 (2, , ) (2,) 2 (1 ) + 2 = 2
. 3 = 3 (3, , ) (3,) 3 (1 ) + 3 = 3
= 1 = 1
1
2
3
1 : = (1, 2, 3, 1, 2, 3, )
2
3
()
0.125 0.125
= ( 0.17 ) = ( 0.17 ) V = 0.426 Ans.
0.705 0.705