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The Effects of High Alkaline Fly Ash on Strength
Behaviour of a Cohesive Soil
A. Binal
Faculty of Engineering, Department of Geological Engineering, Hacettepe University, Beytepe Campus, 06800 Ankara, Turkey
Copyright 2016 A. Binal. This is an open access article distributed under the Creative Commons Attribution License, which
permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Contemporarily, there are 16 coal-burning thermal power plants currently operating in Turkey. This number is expected to rise to
46 in the future. Annually, about 15 million tons of fly ash are removed from the existing thermal power plants in Turkey, but a
small proportion of it, 2%, is recyclable. Turkeys plants are fired by lignite, producing Class C fly ash containing a high percentage
of lime. Sulfate and alkali levels are also higher in Class C fly ashes. Therefore, fly ash is, commonly, unsuitable as an additive in
cement or concrete in Turkey. In this study, highly alkaline fly ash obtained from the Yenikoy thermal power plants is combined
with soil samples in different proportions (5%, 10%, 15%, 20%, and 25%) and changes in the geomechanical properties of Ankara
clay were investigated. The effect of curing time on the physicomechanical properties of the fly ash mixed soil samples was also
analyzed. The soil classification of Ankara clay changed from CH to MH due to fly ash additives. Free swelling index values showed
a decrease of 92.6%. Direct shear tests on the cohesion value of Ankara clay have shown increases by multiples of 15.85 and 3.01
in internal friction angle values. The California bearing ratio has seen a more drastic increase in value (68.7 times for 25% fly ash
mix).
7m
Figure 1: The soil sampling area.
rise to a soil with improved engineering properties: a more clay, damage to the roads and low-rise structures caused by
granular structure, less plasticity, greater permeability, and differential volume changes of the clay occurs, particularly
above all lower expansion [1522]. Also, the presence of the in the southern part of the city. This damage caused by
OH ions produces an increase of the soil pH up to values the swelling has been deliberately ignored in both design
of approximately twelve. In these conditions, pozzolanic and construction, however, because of limited budgets, poor
reactions take place, when Si and Al which form part of the construction methods, inadequate water drainage, and inef-
sheets of the clay dissolve and combine with the available fective remedial measures [29].
Ca2+ giving rise to cementing compounds such as calcium Finer, reddish-brown clastic of the fluvial-lacustrine
silicate hydrates and calcium aluminate hydrates [18, 21, 23 deposits is referred to as reconsolidate, stiff, and fissured
25]. Ankara clay in engineering, geological, and geotechnical
Akar et al. [3] have studied on short-term leaching studies. Networks of hair cracks and slickensides are often
manner of Fe, Ca, Cu, Co, Cd, Mn, Ni, Pb, Zn, and Cr (VI) present in Ankara clay, and the surfaces of fragments are
from Yenikoy fly ash using TCLP-1311 [26] and ASTM D3987 usually polished and glossy in nature. Undisturbed sampling
[27] tests. According to their results, Ca was found as the most is rather difficult, and specimens tend to fail along the fissures
mobile element while Mn and Fe had the lowest mobility. and irregular surfaces [30].
The dissolution of selected trace elements was observed as This work aims to investigate the possibility of using high
higher for the particles below 38 m size. For the leaching alkaline fly ash from Yenikoy lignite-fired power station to
tests of original fly ash material, the highest solubility values ameliorate the geomechanical properties of Ankara clay. The
were found for Ca, Pb, and Cr (VI), respectively. The results effects of the proportions of the fly ash (FA) and curing
suggested that releases of these trace elements were all lower time on the physical properties and strength development in
than the allowed limits for solid wastes imposed by the EC Ankara clay have been illustrated in laboratory conditions.
Directive [3]. Furthermore, as to the study by Turhan et Scanning electron microscope (SEM) studies were performed
al. [28], the utilization of the examined all fly ash samples to investigate the factors preventing swelling of Ankara clay.
(included Yenikoy fly ash) except Kangal and Soma, in the The outcomes of this work are to create new uses for FA in
road, street, roadbeds, and road pavement does not pose any Turkey as well as build a basic mix design for further studies
significant source of radiation hazard. of strength and durability.
The other material of this study is Ankara clay that
includes a sequence of lacustrine sediments that covers 2. Materials
the surface of the Ankara Valley. These expansive soils are
settled in western, central, and southern parts of Ankara, 2.1. Ankara Clay. Three soil blocks have been supplied from
the capital of Turkey. Due to the expansive nature of this a construction area, from a depth of three meters (Figure 1).
Advances in Materials Science and Engineering 3
Clay Silt Sand Gravel Table 1: The physicomechanical properties and the chemical com-
100 position of AC.
80
Index properties Chemical
composition (%)
Percent finer (%)
Q
4000 Oriented
Smectite
Ethylene-glycol
3000
Intensity
Illite
Kaolinite
2000 S
Q
I/M I FC
1000 K
K C
Q Heated to 550C
0
10 20 30 40 50 60 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32
2 d-spacing
(a) (b)
Figure 3: Typical XRD patterns of AC: (a) bulk (whole) sample and (b) clay fraction.
60
40
number of moulding water contents to establish a rela-
tionship between the dry unit weight and the moulding
water content for the soil. The compaction curve is plotted
20 with the values of the dry unit weight and water content.
The values of the highest dry unit weight and optimum
0 moisture content are found from the compaction curve
0.1 1 10 100 [35]. All CBR tests of samples were realized in optimum
Grain size (m) moisture content value and about at 98% modified proctor
stiffness. Therefore, modified proctor tests were carried out
Figure 4: The grain size of it was determined by using Sympa
Technology Laser Grain Size Analyses System.
to determine optimum moisture content and maximum dry
density of the mixed samples. During sample preparation,
firstly, AC samples were ground and after that screened with
water content is put in five layers into a mould, with each #4 of a sieve which has 4.75 mm of the aperture. Undersize
layer compacted by 56 blows of a 4.5 kg hammer dropped materials were mixed with 5%, 10%, 15%, 20%, and 25% of
from a distance of 45 cm. The resulting dry unit weight is FA by weight at the optimum water content (Table 4). Then
determined. The procedure is repeated for an adequate those mixes were poured into the CBR moulds which have
Advances in Materials Science and Engineering 5
Figure 5: The scanning electron microscope (SEM) views of regular and irregular shaped glass beads of YFA.
800 60 e
FCA
lin
e lin
U- A-
50
600 CH
Intensity (count)
40
A
PI (%)
400
FCa FCA 30
CL
20
A MH
200 10
Q
Q
S A
Q G+H G H
Q A AQ Q A + Ca ML
H
S QCa A+G A+H 0
Ca
0 0 10 20 30 40 50 60 70 80 90 100
5 10 15 20 25 30 35 40 45 50 55 60 65
LL (%)
2
Ankara clay 15% FA
Q: quartz H: hematite 5% FA 20% FA
FCa: free lime Ca: calcite 10% FA 25% FA
A: anhydrite S: sulphide
G: gehlenite Figure 7: Consistency limits of AC and FA mixed soil.
300
250
200
CBR (%)
150
100
50
0
0 5 10 15 20 25 30
Curing time (days)
25% FA 10% FA
20% FA 5% FA Figure 10: The view of 25% FA mixes sample after the CBR test.
15% FA AC
Figure 8: The effects of the curing time and FA content on the CBR 250
values.
200
100
150
c (kPa)
80
Increment ratio
100
60
40 50
20 0
0 5 10 15 20 25
0 FA (%)
0 5 10 15 20 25 30 1 day 28 days
Curing time (days) 7 days
25% FA 10% FA Figure 11: Variation of with FA content and curing time.
20% FA 5% FA
15% FA
35
30
25
20
0
15
10
0
0 5 10 15 20 25
FA (%)
1 day 28 days
7 days
18 c 4 0
15
3
12
Increment ratio
Increment ratio
9 2
6
1
3
0 0
0 5 10 15 20 25 0 5 10 15 20 25
FA (%) FA (%)
1 day 28 days 1 day 28 days
7 days 7 days
Figure 13: The increment ratios of shear strength parameters (-) with FA and curing time.
for an investigation of those soils likely to possess undesirable without any change in the volume of the soils. The final
expansion characteristics. Inferential testing is used to reflect volume in each of the cylinders shall be read out. The level
the potential of the system to swell under different simu- of the soil in the kerosene graduated cylinder shall be read
lated conditions. The actual magnitude of swelling pressures as the original volume of the soil samples. The soil level in
developed depends on the dry density, initial water content, the distilled water cylinder shall be read as the free swell level
surcharge loading, and several other environmental factors. [39].
Swelling tests were carried out to the Indian standard [39]. The free swell index of the soil is calculated as follows:
In this procedure, two 10 g soil specimens of oven dry soil
passing through a 425-micron IS sieve are taken. If highly Free Swell Index (%) = 100, (1)
swelling soils, such as sodium bentonite, the sample size may
be 5 g, alternatively, a cylinder of 250 mL may be used. Each where is the volume of soil specimen read from the
soil specimen shall be poured in each of two glass graduated graduated cylinder containing distilled water and is the
cylinders (100 mL capacity). One cylinder shall be filled with volume of soil specimen read from the graduated cylinder
kerosene oil and the other with distilled water up to a 100 mL containing kerosene.
mark. Then with removal of entrapped air by gentle shaking, The free swell index values of soil samples decreased with
the soils in both the cylinders shall be allowed to settle. the amount of fly ash in the mix (Figure 14). The free swell
Sufficient time which is not less than 24 h shall be allowed value of 25% fly ash mixed soil sample was close to 0%. With
for the sample to attain an equilibrium state of the volume 5% FA mixed soil samples, the swelling ratio decreased by
8 Advances in Materials Science and Engineering
60
Fly ash
50
Free swelling index (%)
40
Clay
30
20
10
0
Figure 16: The SEM view of coated clay with ash pellets.
0 5 10 15 20 25 30
FA (%)
Fly ash
100
Clay
80
Clay
Variation (%)
60
40
Figure 17: The view of ash particles that build the bridge between
20 clay minerals.
0
0 5 10 15 20 25 30 was used to create the regression models. The best fit for
FA (%) estimating cohesion (, kPa) was found as
Figure 15: Free swelling variation versus the amount of FA content. (kPa) = 19.445 + 1.068 + 708.642 FA,
(2)
0 = 10.217 + 0.232 + 69.095 FA,
where is curing time (days) and FA is fly ash (%).
27.4% in value; with 25% FA, it declined by 92.6% (Figure 15). As well, the best model for CBR values was presented in
Clay soils, even with a very low rate of FA, can considerably
reduce their swelling potential. CBR (%) = 37.173 + 2.32 + 5.039 FA, (3)
where is curing time (days) and FA is fly ash (%).
The -test was carried out to test the overall
3.6. Scanning Electron Microscopy Study. After CBR tests,
performance of the regression model (Table 5). Since
scanning electron microscopy (SEM) images of the samples
model (79.776, 50.485) > (0.05,2,15) (3.68) for shear strength
were taken. In the SEM images, the clay surface was perfectly
parameters as well as model (52.921) > (0.05,2,51) (2.79) for
coated with fly ash among the grains. That explains why
CBR or the value is considerably smaller than = 0.05, the
the swelling of the clay was prevented. Ash pellets move
null hypotheses are rejected and as a result of that , , and
between the clay minerals with the water molecules and
CBR related to and FA.
prevent swelling of the clay (Figure 16). Furthermore, FA
The proportion between the regression sum of the square
grains are capable of making bonds among the clay minerals
(SSR ) and the corrected total sum of squares is called the
(Figure 17).
coefficient of determination () and is often used to judge
the adequacy of a regression model [40]. 2 , adj 2
, the root
4. Statistical Evaluation mean square errors, the mean absolute percentage error, and
Akaikes information criterion were used in the evaluation of
Multiple regression analyses were realized to obtain the prediction capacity of MLR models, and these are presented
relationships between shear strength parameters ( and ) in Table 5.
and fly ash content (FA, %) and curing time (, days) as A model with low RMSE (root mean square error), MAPE
well as CBR values and fly ash content. XLSTAT of Addinsoft (mean absolute percentage error), AIC (Akaikes information
Advances in Materials Science and Engineering 9
200 30
150 25
%
95
c (kPa)
0
100 20
%
95
50 15
0 10
0 50 100 150 200 250 10 15 20 25 30 35
0
Pred. (c (kPa)) Pred. ( )
Figure 18: Measured and predicted shear strength (, ) values derived from (2).
criterion), and high 2 and adjusted 2 performance indices Pred. (CBR (%))/CBR (%)
250
was defined, and its prediction capacity was accepted as excel-
lent by several researchers [4144]. By prediction indices,
MLR models have shown good performance for independent 200
variables (Table 6).
Furthermore, measured and predicted shear strength
parameters and CBR values obtained from MLR evaluation at 150
CBR (%)
50
5. Conclusions
By the work reported in this paper, the following conclusions 0
have been drawn: 0 50 100 150 200 250
Pred. (CBR (%))
(1) The liquid and plastic limits of AC were decreased
with fly ash addition. Furthermore, the soil class of AC Figure 19: Measured and predicted CBR values derived from (3).
is changed from CH to MH. AC starts showing
plastic behaviour when increasing the percentages of
FA additives.
(3) SEM views show that FA particles cover the surfaces
(2) The cohesion and internal friction of AC were of clay minerals and constitute an impervious layer.
increased with FA. Furthermore, curing time is very This phenomenon explains why the soil does not swell
useful on the shear parameters. Soil samples with 28 when FA has been added to it. Furthermore, FA grains
days curing time have shown the highest cohesion build bridges between clay minerals. Therefore, the
and friction angle. shear strength (, ) starts to increase with the FA
10 Advances in Materials Science and Engineering
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