Thermodynamics and Its Applications, 3rd edition

Web Page Corrections for the 2nd and 3rd printings

August 6, 1998 - Revision 4

Ch 8

- p255 1 line below Eq. (8-45) where ac is equivalent to the RKEOS a in Eq. (8-43) with Tc
raised to the 2.0 power:

Ch 10
- p395 Eq. (10-12) and below,

note that variables are raised to the N power not 3Nand C = h3N N!

- p398 replace two lines below Eq. (10-29), with lj can be related directly to the pure component
fugacity, fjo (pure). Now the probability of PN(Ei) of finding a system of Nj similar molecules with
energy Ei, can be rewritten; in Eqs. (10-27) - (10-31) replace Ni with Nj, li with lj and mi and mj

- p407 Eq (10-80), insert minus sign in Fij = F

- p408 in the dipole-dipole figure, directional sign of gi and gj should be the same

- p416 Eq (10-96), V extensive not V

- p418 last equation on the page,F(1) should beF(r)

- p424 Eq. (10-129), B should be B

- p427 Eq. (10-133), energy levels k not i ; last line correction not connection

- p438 Eq. (10-164), insert sign on the right hand side

- p440 2 lines above the figure, estimated not estimed

Ch 11

- p467 Eq (11-35), DGEX = DAmix + TDSID

- p471 Eq. (11-48), r2 throughout on RHS

- p473 Eq. (11-52), r2 throughout on RHS

- p479 2 lines below Eq. (11-59), N = rN2

- p480 1 line below Eq. (11-65), (see Problem 15.33)

- p492 Table 11.4 1st entry, misspelling of Acetonitrile

Ch 11 (continued)

- p493 Eq (11-91) in third term on RHS,

Ch 12

-p507 1 line below Eq. (12-9b), g 1.0 as m 0.

-p509, Eq. (12-16) the integral should be multiplied by 2.

-p520, equation below Eq. (12-42), d2z not dz2

- p525 just after Eq. (12-68), in the terms for A = ... insert rs1/2 after 1.8244x106 and replace L
with kg and for B = ... change F 3 to F 2rs, after 5.0292x1011 rs, and replace L with kg
throughout

Ch 13

- p571, Eq. (13-15), both terms in square brackets should be squared

- p572, last line, T 4 should be T 3

- p585 problem 13.4, 4th line, (see Problem 15.38 not 15.40) and add 2 double bonds to the
5-membered ring , > C=C < and N=C N CH3 in the caffeine structural formula (also in Problem
15.38).

Ch 17
- p841, Eq. (17-59), in V(L) equation

- p856, Problem 17.9, 5th line, CO2 5 3/4 H2O(H).