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Original SPE manuscript received for review March 21. 1993. Revised manuscript received
March 11. 1994. Paper accepted for publication Oct. 27.1993. Paper (SPE 25410) first pre-
sented at the 1993 SPE Production Operations Symposium held in Oklahoma City. March
21-23.
.............. (1)
r fa 2:n: h{t ,{rj Thus, the average leakoff rate in the segment will be
rD = ,(rj,fD = Yi' VD = --q-' .................. (5)
0.35
calculate bottomhole temperature
S 0.30
calculate acid flow rate
1 0.25
"c
calculate temperature in the fracture ~ 0.20
]
< 0.15
calculate acid concentration prolile in
the fracture
0.10
where
UoX R; 2v l x
R*=-2v' R* =-UoW
Fig. 3-Flow chart showing the calculation method.
where
(12)
C~i = I,(i = 1,2, ... ,n, + 1)
Then, Eq. 6 can be rewritten in a dimensionless form:
k k
= C D2
(
I _.&)* f'(r)oCov + .&* f(r)oco~
R
O
R
O = _1_L(D*oC
R * Sc o~
O)
e o~
C DI
10~--------------------~--~
~
70 'c
15% HC\
1.0m '1m ,tid
I fraCbJre per
meier fonnatioo
DoIomIle
0.1 oI"_ _~
0.1
Fig. 5-Effect of lithology on acid penetration. Fig. 6-lnfluence of fracture width on acid penetration.
5 ,I ,
oJ~M~D1 t.os
"acid volut:ne =S cu. nVm II
OOOS
0.1
O.2m ImIjD
0.14 10C, Limesloo. ,~
0.08
....... ~ ~
.J
o
0.10 0.15 0.20 0.25 0.30
0.1 1 10
Fracture Frequency (111m) Acid Penetration (m)
Fig. 7-lnfluence of natural fracture density on acid penetration. Fig. 8-Acid penetration for limestone at 40C.
1. We divide the assumed fracture, which stretches from the well- Injection Rate. Acid injection rate is the most important factor af-
bore into the formation, into many small segments. fecting acid penetration (Figs. 4 through 14). The effective acid pe-
2. We calculate BHT. netration will increase significantly as the injection rate increases.
3. We solve Eq. 4 to obtain fluid velocity distribution in the The probable reasons for the increased penetration are that a higher
formation. injection rate can push the acid deeper into the formation in a limited
4. At the time when acid injection is finished, we simultaneously time and will decrease the BHT and the temperature in the fracture,
The acid/rock reaction is low when the formation temperature is low
solve the fracture temperature equation (Eq. 11) and the acid con-
(Fig. 4) or the formation rock is dolomite (Fig. 5). Figs. 4 and 5 show
centration equations (Eqs. 14 and 15) segment by segment, until the
that higher injection rates at lower acid/rock reaction rates will lead
acid is exhausted or does not flow any more. to more acid penetration than in a formation with a higher acid/rock
reaction rate. Because the acid/limestone reaction rate is so fast, the
Results and Discussion influence of injection rate on acid penetration in limestone is not as
Using the calculation method described above, we have simulated large as it is in dolomite. Therefore, to improve the effective acid pe-
many cases of acid penetration in naturally fractured formations, netration, we should inject acid as fast as possible during matrix aci-
where we have considered the influence of the common ion effect, dizing, provided that we keep the treating pressure below fracturing
pressure.
surface temperature, formation temperature, and the heat generated
by the acid/rock reaction. Using the simulation results, we have de-
Acid Concentration. As Fig. 4 shows, higher acid concentrations
veloped a set of graphs (Figs. 4 through 14) that can be used to will improve the acid penetration in a fracture. The amount of acid
choose an optimal acid volume and injection rate for a specific concentration represents the H+ mass transfer rate. For fresh Hel,
formation. These results show that several factors, such as injection the H+ mass transfer rate decreases as the acid concentration in-
rate, acid concentration, lithology, natural fracture width, fracture creases. The acid/rock reaction rate is dramatically affected by the
frequency, formation temperature, and acid volume, will affect acid H+ mass transfer rate. The higher mass transfer rate usually speeds
penetration dramatically. up the acid/rock reaction.
...~ 4 4
g
~ 3 3
~
;
]
<
~
'0
>
2
1 H-~--++/~t- I
oILL~~aV==-3:~g:
:::1:=:I;=---.JI~
Ii bY
0.06 0.08 0.10 0.12 0.14 0.16 0.18 0.20 0.08 0.10 0.12 0.14 0.16 0.18 0.20
Acid Penetration (m) Acid Penetration (m)
Fig. 9-Acid penetration for limestone at 70C. Fig. 10-Acid penetration for limestone at 100C.
t=
4 ....... .... ~~ . g
g
6' 6'
:I: 3
.Q
~ 3 -,,- ............. " -- 1""'" - ,-- .- f- .
~ 3
B
s"
.g
2 i
>
2 1
I
>
-c
'u
<t:
1
o~~~~~--~~--~--~--~
-c
'0
<t:
1 - _.V
~
i II
2 4 6 8 2 4 6 8 2 4 6 8
0.06 0.08 0.10 0.12 0.14 0.16 0.18 0.01 0.1 1 10
Acid Penetration (m) Acid Penetration (m)
Fig. 11-Acid penetration for limestone at 150C. Fig. 12-Acid penetration for dolomite at 40C.
Lithology. The acid/dolomite reaction rate is much slower than the concentration. The acid/rock reaction releases heat that will also af-
acid/limestone reaction rate because the acid/dolomite reaction is fect the acid/rock reaction rate. 3,4,12 In the calculations given here,
controlled by the acid/rock surface reaction rate and the acid/lime- we have considered the effect of the heat generated by the acid/rock
stone reaction is controlled by the H+ mass transfer rate from the reaction on the actual acid penetration distance.
acid to the rock surface. Fig. 5 shows that acid penetration in dolo-
mite is much higher than in limestone. Acid Volume. For a given formation, the volume of acid injected
has little influence on acid penetration (Figs. 8 through 14) mainly
Natural Fracture Width because the acid/carbonate reaction rate is extremely fast. Increas-
ing the acid volume may increase only the etched fracture width, not
As Fig. 6 shows, acid penetration will increase as the natural fracture
the acid penetration. 4 Therefore, there is an optimal acid volume for
width increases. The wider fracture will decrease the temperature of
a specific formation (Figs. 8 through 14). Keep in mind that the vol-
the acid in the fracture and increase the H+ transfer distance, and
ume of acid injected should be increased if the fracture frequency
acid flow resistance is smaller in the wider fracture, so acid can be increases (Fig. 7).
pushed deeper into the formation.
Example
Fracture Frequency. For a given acid volume, the acid penetration
will decrease as the fracture frequency increases (Fig. 7). Increasing To illustrate how to use the graphs given here, consider the follow-
fracture frequency will decrease the fluid velocity in the fractures. ing example. An engineer is trying to design a matrix acidizing in
The lower fluid velocity results in decreased acid penetration. a naturally fractured dolomite with the parameters in Table 1. The
maximum injection rate (m 3/min), without fracturing, will be 14
Formation Temperature. Acid penetration decreases as formation
temperature increases (Fig. 4). Acid/rock reaction rate increases as
temperature increases. In a low-temperature formation, a high acid qrnax = 3.7702 - 05 [ 3 ] ' ......... (16)
concentration gives much longer acid penetration than a low acid f1 In(re/rw) - 4 + s
~L
! q = O.ooolm 11m/min
oJ
r I I !!IIll! I I
0.001 : 0.01
g
4 --,- ~- - , -- -- o.u ....
lt~:
~
3 . . WYY>
~- ~"'''''o ~ on
B ~
J
'-'
~
-- ... e"
"0
>
2 ~
i- 0
~.".
,~
"0
>
2 .............. - _. .... ~ . --- ,... ........ ...... ....
l/
-c
'0
-< ~
1 -, ........ n ....... .... u ...... .....
<t:
1
~
-
2 4 6 8 2 468 2 4 2 4 6 8 2 4 6 8 2 4
0.01 0.1 1 0,01 0.1 1
Acid Penetration (m) Acid Penetration (m)
Fig. 13-Acid penetration for dolomite at 70C. Fig. 14-Acid penetration for dolomite at 100C.
The following recommendations are made for the design and imple- y = variable
mentation of matrix acidizing in naturally fractured carbonate reser- Z' = dimensionless variable
voirs. These suggestions should be useful for designing practical a = escape coefficient
treatment designs. ~ = dimensionless variable
1. Acid injection should be as fast as possible to improve acid pe- 1] = dimensionless variable
netration and to decrease treatment time, within the limitations pro- ~ = viscosity
vided by the maximum allowable surface injection pressure and the v = dimensionless variable
fracturing pressure of the formation. v = kinematic viscosity
2. There is an optimal acid volume for a given formation. Increas- s = dimensionless variable
ing the acid volume may not improve acid penetration. Pj = density of fluid
3. Based on considerations of acid corrosion and effective acid Pm = density of rock
penetration distance, higher-concentration acids should be used in PI = fluid density into a segment
low-temperature formations, while lower-concentration acids P2 = fluid density out of a segment
should be used in high-temperature formations. 1> = porosity
!jf = function
Nomenclature
a = experimental constant Subscripts
A' = dimensionless variable D = dimensionless
b = experimental constant I = fracture system
c = compressibility 2 = matrix system
C = acid concentration
q = specific heat of fluid Acknowledgment
Cm = specific heat of rock My thanks to David Lancaster at S.A. Holditch & Assocs. Inc. for
Co = initial acid concentration his help in editing this manuscript.