ANSWER - SOLUTION Adv 1 PDF

1 AIITS-PT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/15
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ANSWERS, HINTS & SOLUTIONS
PART TEST IV
(Paper-1)
Q. No. PHYSICS CHEMISTRY MATHEMATICS

1. C D A
2. C C D
3. C A C
4. C A A
5. A C B
qualified in JEE (Advanced), 2014.
6. D D B
7. B D A
8. A A A
9. A C C
10. D C C
11. A, D A, B A, B
12. A, B, C B, C, D A, B
13. A, B B, C A, B, D
14. A, B, C, D A, B, C A, C
15. A, B B, D A, B, C
1. 1 5 2
2. 5 1 2
3. 4 4 1
4. 1 2 2
5. 2 0 3
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AIITS-PT-IV-(Ppaer-1)-PCM(S)-IITJEE(Advance)/15
2
Physics PART I
2. Use Lenzs Rule
3. Speed of image = speed of object in all the mirrors
A m
sin
4. Use = 2
A
sin
2
d 2
6. = and P =
dt R
dy
7. For CBF P = 0 = tA(A 1) tB(B 1) +
D
9. VA iR + 15 + (5 103) 103 = VB
Chemistry PART II
SECTION A
2r 2 2r 2
1. PF
2 2r
2 2
8r 4

So packing efficiency = 100 78.54%
4
2. Tf Tf for glucos e Tf for KCl Tf for urea

1.86 1000 10 1.86 1000 1 1.86 1000 5
Tf 2
100 80 74.5 100 100 60
Tf = 3.069
F. Pt = 273 3.069 = 269.93 K
3. ZnNO3 2 2NO2 2H2 O

Zn 4HNO 3
NO3 ion is reduced to NO2 in preference to H3O+ ion.
4. H2O is a weak field ligand and CN is strong, field ligand.
5. 2HClO4 P2 O5
Cl2O7 2HPO3
7. Cu dil HNO3
NO
SnCl2 /HCl
NH2 OH.HCl
HNO2
N2O
X Y Z
9. O O O

F 103 F Cl 110 Cl H 105 H
Because of larger size of Cl atm.
OCl2 have largest bond angle.
2
10. NiCl4 is sp3 hybridized, because Cl is weak field ligand. Hence there is two unpaired
electrons.
15. Number of particles from K4[Fe(CN)6] = 5

Number of particles from FeSO4.(NH4)2SO4.6H2O = 5
Number of particles from KCl.MgCl2.6H2O = 5
SECTION C
1. O O
H O P O P OH
OH OH
2.
O H
H H
4
3.
F F
Xe
F F
1
4. AgNO3 Ag NO2 O2
2
HgNO3 2 Hg 2NO2 O 2
5. In Fe CO 5 , there is no unpaired electron.
Mathematics PART III
2 3 4 3 1 2 3
1. (3 yx ) dx + (x 2y ) dy = 0, x y = y +c
3
1 x
2. f(x)
2
2 2
[x] 1 ({x} 1) ([x] {x})
2

x dy ydx
3. dx Solution is y = x tan (C x)
x2 y2
cos 7 9 cos 7 10 cos 7 11

4. Given determinant = cos 8 9 cos 8 10 cos 8 11
cos 9 9 cos 9 10 cos 9 11
cos 7 sin 8 0 cos 9 sin 9 0
cos 8 sin 8 0 cos 10 sin 10 0 0
cos 9 sin 9 0 cos 11 sin 11 0
sin A sinB sinC tan A tanB tanC

5. Let cos A cosB cos C cos A cosB cos C 1 1 1
cos3 A cos3 B cos3 C cos A cos B cos C
sin(B C)sin(C A).sin(A B) 0
ydx xdy 1 x 2
6. 2 dx sin ydy 0
x2 x
1
d y x d x d( cos y) 0
x
1
y x x cos y c 0
x
n
cos sin cosn sinn
7. We know
sin cos sinn cosn
15
1 3 1 0
Let 3 2

2
I
3
2
1
2 0 1
15
1 3
215 I
3 1
8. X is a skew symmetric matrix of odd order.

det(X) = 0
6
dy 1 dy 2 y x 1 dy dt
9. x 4y x 2 y now let y t
dx 2 y dx x 2 2 y dx dx
dt 2 x
t this is linear differential equation so
dx x 2
2
dx 1 11 x y 1 x2
I.F. e x
2
e2nx
2
2 . dx 2 nx c
solution t y nx x 2c
x x x 2 x 2 2
Given curve passes through (1,(n2)2 )
x2
( n2)2 c c n2 nx x 2 .n2 nowy y(2) 6n2 y(2) (6n2)2
2
1 4 1 1
(1 2) 2
10. Required probability 4 5 7 7
1 4 1 1 49
2(19) 11
4 5 7 7
1 n 1 n 1n 2
3
11. n! n1 1n 2
n 1n 2 n 3
n
n 1n 2 n 1 n 2 n 3 n 4 n 3 n 2 n 1
1 n 1 n 2 n 1 1 n 1 n 2 n 1
2 2
3
n 1 n 2 1 n 2 n 2 n 3 n 1 n 2 0 1 2 n 2
n! 1 n 3 n 3 n 4 0 1 2 n 3
2
n 1 n 2 .2 n 3 n 2

2n n2 4n 5 4
0 1 2 0 1 2 2 1 2
12. A 0 3 0 0 3 0 0 9 0
2
1 1 1 1 1 1 1 1 3
3 1 6
adjA 1
A 1
0 2 0
A 6
3 1 0
Comparing L.H.S and R.H.S., we get a = 1, b = 4, c = 1, d = 12
Alternate method
By Cayley Hamilton theorem, A must satisfy A I 0
3 2 2 5 6 0
A must satisfy the above equation
A 3 2A 2 5A 6I 0
Multiplying by A1
A 2 2A 5I 6A 1
k
13. P(E F) P(E).P(F) xy .. (1)
3
Let P(E) = x and P(F) = y
k
And P(E F) P(E).P(F) (1 P(E))(1 P(F))
6
k
(1 x)(1 y) .. (2)
6
Solving equation 1 and 2, we get 6x 2 x (k + 6) + 2k = 0
As x Q; then D should be perfect square, which is possible for k = 1
2 1 1 2
Therefore we get x or and y = or
3 2 2 3
But given (P(E) P(F)) (1P(F)) > 0 P(E) > P(F)
2 1 2 1
Hence x and y P(E) = and P(F) =
3 2 3 2

bc
14. a c b a b c
2
1 1
ba c c a b 0
2 2
1 1
a c and a b
2 2

1 is and 2 = 120
3
a.a a.b a.c 3 1 1

2
15. a b c b.a b.b b.c 1 3 1 3 9 1 1 3 1 11 3 24 2 2 20
c.a c.b c.c 1 1 3
1 5
Volume of tetrahedron = a b c
6 3

a b b c c a a b b c . c a a b a c b b b c c a

= a b .c a c .c b c .c a b .a a c .a b c .a 2 a b c
a b b c c a
Let d a b

d.c .b d.b .c . c a a b c b 0 c a

2
a b c b c a a b c
SECTION C
1. n(S) = 5 5 5 = 125
n(A) = 514, 541, 523, 532, 413, 431, 422, 312, 321, 211
10 2
Required probability =
125 25
8
6c 2 4c 2 2c 2 3c13c1 4c 2 2c 2 3c 2 3c 2 2 3 90 54 18 6 8
2. p .
6c 2 4c 2 2c 2 90 15
2
3.
d a d d c

4. a.(b c) is maximum then cos = 1.
(S.D.)2 = 2
5. y x 2 y 2 dx x x 2 y 2 dy xdx ydy
xdx ydy
ydx xdy
x2 y2
Integrating both sides, xy x 2 y 2 c , c 2
3
x 2 y 2 xy 2 y 1 x
4

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1 AIITS-PT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/15

ALL INDIA INTEGRATED TEST SERIES

Q. No. PHYSICS CHEMISTRY MATHEMATICS

2. Use Lenzs Rule

3. Speed of image = speed of object in all the mirrors

2. Tf Tf for glucos e Tf for KCl Tf for urea

3. ZnNO3 2 2NO2 2H2 O

4. H2O is a weak field ligand and CN is strong, field ligand.

15. Number of particles from K4[Fe(CN)6] = 5

5. In Fe CO 5 , there is no unpaired electron.

Mathematics PART III

cos 7 9 cos 7 10 cos 7 11

sin A sinB sinC tan A tanB tanC

sin(B C)sin(C A).sin(A B) 0

8. X is a skew symmetric matrix of odd order.

a.a a.b a.c 3 1 1

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