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0.00008
0.00006
0.00004 100
0.00002 80
0 60
0
20 40 Salinity
40 ()
60 20
Temperature
80
(C) 0
100
Revised tables compiled by
Niels Ramsing
and
Jens Gundersen
Di[T,S,P] = the diffusion constant of oxygen at Temperature T (0T40 C)
Content Temp. Sal. Pres. TABLE
and salinity S, (0<S<40) at pressure P, (0<P<1000bar) => cm2 s-1
(C) () (bar)
Calculated from formula:
Diffusion coefficient for O2 0 - 20 0 - 40 1 1 Di[T2,S2,P2]=Di[T1,S1,P1]*(dynvisc[T1,S1,P1]/dynvisc[T2,S2,P2])*(T2/T1)
20 - 40 0 - 40 1 2 Equation from: Li & Gregory, 1974, Geochim. Cosmochim, 38:703-714
0 - 100 0 - 200 1 3 using Di[T1,S1,P1]=difO2 with T1=10C, S1=0 and P1=1bar (see above)
0 - 20 35 0 - 400 4 solO2[T,S] = solubility of oxygen at temperature T (0T40 C)
0 - 20 35 400 - 800 5 and salinity S, (0<S<40) at pressure P = 1 bar => mol kg-1
Solubility of O2 0 - 20 0 - 40 1 6 formula found in Garcia and Gordon. 1992,
20 - 40 0 - 40 1 7
Oxygen solubility in seawater: Better fitting equations,
0 - 100 0 - 200 1 8
Density of seawater 0 - 20 0 - 40 1 9
(calulated for any salinity)
20 - 40 0 - 40 1 10 Limnol. Oceanogr. 37:1307-1312
0 - 100 0 - 200 1 11
Dynamic viscosity of seawater 0 - 20 0 - 40 1 12 Oxygen conversion factors
20 - 40 0 - 40 1 13 0.032 mg/mol
Kinematic viscosity of seawater 0 - 20 0 - 40 1 14 0.02241 ml/mol
20 - 40 0 - 40 1 15 1.428 mg/ml
Schmidt number 0 - 20 0 - 40 1 16
20 - 40 0 - 40 1 17
dens[T,S] = density of seawater at temperature T (0T40)
Cover page: Diffusion coefficient for oxygen at various and salinity S, (0<S<40) at pressure P = 1 bar => g cm-3
temperatures & salinities Equation from:Standard Methods for examination of water and
wastewater 1992, 18 th ed. Edited by A Greenberg et al. p 2-48
diffO2 = Diffusivity of oxygen in distilled water at 10C "2520 C. Density method"
= 1.57*10^-5 cm2 s-1 reprinted from: Millero & Poisson, 1981.
Table from Broeker & Peng, 1974, International one-atmosphere equation of state of seawater,
estimated from Himmelblau, 1964 Deep Sea Res. 28:625
The value at 10 C is used to scale the calculated Di[T,S,P]
dynvisc[T,S,P] = dynamic viscosity of seawater at temperature T (0T40)
To calculate diffusion coefficient for other gasses and salinity S, (0<S<40) at pressure P, (0<P<1000bar)
=> cp = centi poise = 10*^3 Pa s = 10*^-2 g cm-1 s-1
To get diffusivity Formula from: Chemical Oceanography vol. 4, 1975, 2'ed. Edited by
of multiply table values by Riley, Table 25, p 338, developed by Millero, 1974
H2 1.9470 with pressure corrections by Matthus,1972
N2 0.8301 kinvisc[T,S] = kinematic viscosity of water at temperature T (0T40)
He 2.6602 and salinity S, (0<S<40) at pressure P = 1 bar
Ar 0.7573 => cp g-1 cm3 = 10*^-2 cm2 s-1
Rn 0.5825 Calculated from dynamic viscosity:
CO 0.8495 kinvisc[T,S] = dynvisc[T,S]/dens[T,S]
CO2 0.7961
Schmidt number [T,S] = (kinematic viscosity / diffusion coefficient) at Temperature
CH4 0.8495 T, (0T40C) and salinity S, (0<S<40) at pressure P = 1 bar
N2O 1.0049
=> Dimensionless
H2S 0.7573
SO2 0.7476
DATA-TABLE 1 by Niels Ramsing & Jens Gundersen