OBSERVATION SHEET

NAME: …..…………………………
ROLL NO: .…………………………
ENROLMENT NO: ……………..
GROUP NO. : 1
CLASS: M.Sc. (IC)-SEM-III
DATE: 28TH SEPTEMBER, 2017

Feed Raffinate Phase Extract Phase

Volume Volume
S. No. Toluene
Acetic
Water Volume Weight
of
Volume Weight
of
acid NaOH NaOH
(ml) (ml) (ml) (gm) (ml) (gm)
(ml) used used
(ml) (ml)
1 45 5 25 29 28 44 42 37 1.6

2 40 10 25 31 33.5 78 40 34 4.6

3 35 15 25 33.5 39.5 96.5 37.5 30 8

4 30 20 25 35.5 43.5 123 35.5 25.5 10

5 25 25 25 37.25 47.5 146 33.75 20.5 13.6

6 20 30 50 72 78 95 18 16 9.2

7 15 35 50 75 83.5 119 15 12 10.3

8 10 40 50 77.5 89 131 12.5 7.5 12.1

9 5 45 50 90.5 95.5 142 1.5 2.5 13

Calculations:
Volume of sample titrated: 2 ml

Density (g/ml) Toluene Acetic Acid Water

0.8669 1.049 0.9982

For Feed

Wt. Wt.
Weight Wt.
Weight of Weight of fraction fraction
S. No. of acetic fraction
Toluene water of acetic of
acid of Water
acid Toluene
1 5.245 39.011 24.955 0.0758 0.5637 0.3606
2 10.490 34.676 24.955 0.1496 0.4945 0.3559
3 15.735 30.342 24.955 0.2215 0.4272 0.3513
4 20.980 26.007 24.955 0.2916 0.3615 0.3469
5 26.225 21.673 24.955 0.3600 0.2975 0.3425
6 31.470 17.338 49.91 0.3188 0.1756 0.5056
7 36.715 13.004 49.91 0.3685 0.1305 0.5010
8 41.960 8.669 49.91 0.4174 0.0862 0.4964
9 47.205 4.335 49.91 0.4653 0.0427 0.4920

For Raffinate and Extract Phase

Raffinate Phase Extract Phase

S. No. Conc. of acetic Wt. fraction of Conc. of acetic Wt. fraction of
acid(g/ml) Acetic Acid acid(g/ml) Acetic Acid
1 0.1321 0.1368 0.0048 0.005453
2 0.2342 0.2167 0.0138 0.016249
3 0.2897 0.2457 0.0240 0.030025
4 0.3693 0.3014 0.0300 0.0418
5 0.4384 0.3438 0.0408 0.067227
6 0.2852 0.2633 0.0276 0.031076
7 0.3573 0.3209 0.0309 0.038657
8 0.3933 0.3425 0.0363 0.06055
9 0.4264 0.4040 0.0390 0.02342
 From Ternary Diagram
Raffinate Phase Extract Phase
Wt. fraction of Wt. fraction of Wt. fraction of Wt. fraction of
Toluene Water Toluene Water
0.81322 0.0500 0.01596 0.9786
0.7323 0.0510 0.01482 0.9689
0.7054 0.0489 0.01431 0.9557
0.6542 0.0444 0.01514 0.9431
0.5994 0.0568 0.0174 0.9154
0.6899 0.0468 0.01805 0.9509
0.6142 0.0649 0.01514 0.9462
0.5894 0.0681 0.01744 0.9220
0.5241 0.0719 0.1431 0.8335

Selectivity

Sample 1 2.03072011

Sample 2 3.70482968

Sample 3 6.02311003

Sample 4 5.99278407

Sample 5 6.73660047

Sample 6 4.51115542

Sample 7 4.88662965

Sample 8 5.97468178

Sample 9 0.21229295