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Reference Correlation for the Viscosity of Carbon Dioxide1

— Supplementary Material —
Table of Sources of Viscosity Data for Carbon Dioxide
and Bibliography

Arno Laesecke, Chris D. Muzny

Material Measurement Laboratory


Applied Chemicals and Materials Division

325 Broadway
Boulder, CO 80305-3337, U.S.A.

Phone: 1-303-497-3197

E-Mail:Arno.Laesecke@Boulder.NIST.Gov

Date of this version: February 10, 2017

1
Contribution of the National Institute of Standards and Technology. Not subject to Copyright in the U.S.A.
2

Table of Sources of Viscosity Data for Carbon Dioxide

Authors Year Reference Method Uncertainty Temperature range (K) Pressure range (MPa) Number of Notes
Points
Graham 1846 [1] Effusion, Transpiration (Capillary not reported ambient dilute to moderately — Efflux times reported for several gases through glass and copper capillaries
flow) dense gas of various lengths and internal diameters. Precursor experiments of
viscosity measurements.
Kundt, Warburg 1875 [2] Oscillating disk not reported 288.14 dilute gas 1 Careful analysis of entire experiment.
von Obermayer 1876 [3] Capillary flow not reported 252 -514 dilute gas 15 CO2 viscosity data used here: page 466 bottom, page 468 top, page 468
capillary I and capillare D.
Puluj 1876 [4] Oscillating disk not reported 274.48 - 302.22 dilute gas 12 Reports friction data of the disk, not viscosities.
Puluj 1879 [5] Oscillating disk not reported 292.85 atmospheric 3
Warburg, von Babo 1882 [6] Vertical capillary flow driven by 278.15 - 313.49 1.5 - 11.3 61 Very careful work. The authors consider the compressibility of CO2 in the
mercury analysis of viscosity measurements.
Breitenbach 1899 [7] Capillary flow 252.35 - 575.15 atmospheric 5
Thomsen 1911 [8] Oscillating disk not reported 285.15 atmospheric 1 Quotes data from Graham, Puluj, and Breitenbach
Phillips 1912 [9] Transpiration, capillary flow driven 0.40% 293.15 -313.15 0.1 - 12 61
by mercury
Vogel 1914 [10] Oscillating disk not reported 273.1, 195 0.0148, 0.987 2
Lassalle 1921 [11] oil drop method 0.50% 296.15 atmospheric 1
Smith 1922 [12] Capillary flow driven by mercury 0.20% 273.15, 288.15, 373.15 atmospheric 3

Eglin 1923 [13] oil drop method Discussed but not 296.15 atmospheric 1
quantified
Ishida 1923 [14] oil drop method 0.30% 296.15 atmospheric 1
van Dyke 1923 [15] Rotating cylinder 0.05% 296.15 atmospheric 1
Trautz, Zink 1930 [16] Capillary flow not reported 572.15 - 1097.15 atmospheric 12
Trautz, Kurz 1931 [17] Capillary flow not reported 300 - 550 atmospheric 6
Brémond 1933 [18] Capillary flow not reported 292 - 1325 dilute gas 13
Stakelbeck 1933 [19] Falling cylinder not reported 258.15 - 313.15 0.49 - 11.77 181
Schröer, Becker 1935 [20] Falling sphere 0.5 % - 1 % 293.15 0.1 - 10 17
Johnston, McCloskey 1940 [21] Oscillating disk 0.8 % at 198 K to 0.4 % at 198 - 300 atmospheric 10
300 K
Naldrett, Maass 1940 [22] Oscillating disk not reported 304.282 - 305.142 7.3807 - 7.58740 62 In the critical region
Comings, Egly 1941 [23] Transpiration, capillary flow ±2 % below 89 at, ±4 % 313.15 0.1 - 13.44 10
above
Wobser, Müller 1941 [24] Rolling sphere (Höppler) 1 % ascribed; discussed 293.14 - 371.13 dilute gas 5
but not quantified
Comings et al. 1944 [25] Rolling sphere see Comings, Egly (1941) 313.15 0.1 - 13.44 10 Same data as in Comings, Egly (1941) but with one more digit and without
uncertainties.
Vasilesco 1945 [26; 27] Capillary flow 0.07 % - 0.01 % 273 - 1686 dilute gas 27 Radial acceleration correction according to Dean and White applied.
Kiyama, Makita 1951 [28] Rolling sphere 1.5 % 323 - 573 0.1 - 5.88 42
Kiyama, Makita 1952 [29] Rolling sphere not reported 323 - 573 0.1 - 9.9 57 Data supersede those of Kiyama, Makita (1951).
Golubev, Petrov 1953 [30] Capillary flow 1.00% 293.15 - 523.15 0.1 - 80 144
Kompaneetz 1953 [31] Capillary flow 1.00% 301 - 1073 dilute gas 9
Makita 1955 [32] compilation, evaluation 1.00% 323 - 573 0.1 - 9.9 36 Smoothed data in the same range as Kiyama, Makita (1952). No additional
data presented.
Savino 1955 [33] Coiled capillary flow 3.20% 290.4 - 296.2 0.18 - 4.8 39 Radial acceleration according to Dean and White. May be inadequate.
Uchiyama 1955 [34] no original experimental data. Discusses various correlations for the viscosity of gases.
Michels et al. 1957 [35] Transpiration, capillary flow not reported 273.15 - 348.15 0.9 - 209.7 195 Missing compressibility correction in the critical region.
3

Authors Year Reference Method Uncertainty Temperature range (K) Pressure range (MPa) Number of Notes
Points
Novikov 1957 [36] not reported not reported 258.15 - 304.15 Saturated liquid, 13 Source of data not specified. Most likely not measured.
saturated vapor
Kestin, Leidenfrost 1959 [37] Oscillating disk 0.05% 293.15 0.014 - 2.17 9
Savino, Sibbitts 1959 [38] Coiled capillary flow no data Publication of Ph. D. thesis of Savino (1955).
Kennedy, Thodos 1961 [39] compilation, evaluation, No function, only diagrams.
correlation
Kestin, Whitelaw 1963 [40] Oscillating disk 0.50% 297 - 525 0.126 - 6.85 43
Kestin et al. 1964 [41] Oscillating disk not explicitly reported 298.3 - 323.3 3.7 - 11.9 103 Critical region. Critique of the measurements of Michels et al. (1957)
which were not corrected for compressibility effects.
Chakraborti, Gray 1965 [42] Capillary flow 1.00% 298 - 353 dilute gas 3
Kesselman, Chernyshev 1965 [43] No data for CO2. Quoted in Touloukian 1971.
Breetveld et al. 1966 [44] Oscillating disk 0.10% 293, 303 0.101 - 2.34 10 Measurements of binary gas mixtures.
Kestin et al. 1966 [45] Oscillating disk 0.10% 293, 303 0.104 - 2.5 24 Measurements of binary gas mixtures.
DiPippo et al. 1967 [46] Oscillating disk 0.10% 293, 303 0.11 - 2.34 11 Measurements of binary gas mixtures.
Gururaja et al. 1967 [47] Oscillating disk 1.00% 300.7 0.098 1
Weintraub, Corey 1967 [48] correlation (nomogram) not reported no data Only nomogram.
Kestin, Yata 1968 [49] Oscillating disk 0.10% 293.14, 303.13 0.11 - 2.34 8
Pal, Barua 1968 [50] Oscillating disk 0.50% 303.13 - 473.25 < 10 torr 5
Bailey 1970 [51] Capillary flow 0.4 % (precision) 344 - 719 dilute gas 24 Careful work.
Golubev 1970 [52] compilation not reported 163.15 - 1273.15 dilute gas 21
Herreman et al. 1970 [53] Torsionally vibrating crystal 219.3 - 293.5 0.98 - 19.2 111
Maitland, Smith 1970 [54] Capillary flow <1% 292.7 - 1497 dilute gas 13 Relative to nitrogen. Revised with new nitrogen data by Hellmann (2014)
and in this work.
Golubev et al. 1971 [55] Capillary flow ±1.5% 473.1 - 773.1 0 - 49 74
Golubev, Shepeleva 1971 [56] Capillary flow ±1 % 252.8 - 293.8 3.9 - 49 107
Herreman et al. 1971 [57] Torsionally vibrating crystal 5.00% 283.35 - 313.24 0.6 - 124 (calc.) 85 Pressures not reported.
Kestin et al. 1971 [58] Oscillating disk ±0.1 % 296.6 - 302.8 atmospheric 3 Reference values.
Altunin, Sakhabetdinov 1972 [59] compilation, evaluation, 220 - 1300 120 n/a
correlation
Kestin et al. 1972 [60] Oscillating disk ±0.1% at 298.15 K to 298.15 - 973.15 1 atm 8
±0.3% at 973.15 K
Kurin, Golubev 1974 [61] Capillary flow ±2 % 293.15 - 423.15 9.81 - 356 74 Less than 0.1 % impurities. Data below crit. density systematically high.
Strumpf et al. 1974 [62] Torsionally vibrating crystal not reported 304 - 307.65 7.39 - 8.02 20
Timrot, Traktueva 1975 [63] Oscillating disk ±0.7% 294.6 - 447.2 0.1 - 7.82 26
Touloukian 1975 [64] compilation, evaluation, atmospheric Only atmospheric pressure
correlation
Vargaftik 1975 [65] compilation, evaluation

Haepp 1976 [66] Oscillating disk ±0.9% - 1.6% 298 - 473 0.1 - 15 125
Ulybin, Makarushkin 1976 [67] Capillary flow ±1.7% 223.15 - 293.15 6.18 - 54.68 57
Kestin et al. 1977 [68] Oscillating disk 0.1% at room temp., 0.2% 297 - 673 dilute gas 6
at 673 K
Yaws 1977 [69] compilation, evaluation,
correlation
Bruschi, Santini 1979 [70] Vibrating wire not reported no data
Harris et al. 1979 [71] Coiled capillary flow ±1 % 203 - 310 dilute gas 10 Radial acceleration corrected.
Stephan, Lucas 1979 [72] compilation, evaluation ±5 % 310 - 900 0.1 - 100 Based only on the data of Michels et al. (1957) without those between
298.13 K and 313.13 K.
4

Authors Year Reference Method Uncertainty Temperature range (K) Pressure range (MPa) Number of Notes
Points
Kestin et al. 1980 [73] Oscillating disk 0.05 % at 0.1 MPa to 0.3 304.78 0.21 - 7.33 49
% at 7.33 MPa
Bevia et al. 1981 [74] Const. volume capillary flow ±0.4 % 348.5 atmospheric 1 Uncertainty by comparison with literature data for CO2 and O2.
Iwasaki, Takahashi 1981 [75] Oscillating disk ±0.3 % 298.15 - 323.15 0.1 - 14.5 382
Rabe 1981 [76] Const. volume capillary flow 2 - 4% 220 - 300 0.6 - 6.57 5
Bruschi, Torzo 1983 [77] Rotating disk not reported 304.78 no data No data, but correlation
Bruschi et al. 1984 [78] Rotating disk not reported 304.78 critical isotherm 13
Diller, Ball 1985 [79] Torsionally vibrating crystal < ±2 % 220 - 320 ≤ 31.5 96
Vogel, Barkow 1986 [80] All quartz oscillating disk ±0.1 % to 0.2 % or 0.3 % 295.09 - 646.91 4 isochors 40
at high T
Takahashi et al. 1987 [81] Oscillating disk ±2 % 273.10 - 304.09 3.48 - 7.36 32
Trengove, Wakeham 1987 [82] correlation 1.5 % at Tmin, 0.3 % at 200 - 1500  ➝0
298.15 K, 2 % at Tmax
Diller, Ely 1989 [83] Torsionally vibrating crystal ±2 % 293 - 500 1.7 - 59 59
Wang, Cummings 1989 [84] NEMD not reported 313 3 Only three-site model considered here
Berg, Moldover 1990 [85] Torsional oscillator 1.5 % (CO2), 0.8 % (Xe) 304.13 - 334.54 7.38 - 12.7 25 Critical isochor

Vesovic et al. 1990 [86] compilation, evaluation, 200 - 1500 100 n/a
correlation
van der Gulik et al. 1991 [87] Vibrating wire 0.50% 300, 301, 308 6.8 - 450
Hendl et al. 1993 [88] All quartz oscillating disk ±0.15 % at low T to 0.3 % 297 - 685 6 isochors 94
at high T
Hunter et al. 1993 [89] Coiled capillary flow ±0.7 % 213.15 - 353.15 dilute gas 7 Radial acceleration correction?
Sovova, Prochazka 1993 [90] correlation
Pádua et al. 1994 [91] Vibrating wire one of ±0.5 % 260, 280, 300 5.95 - 100 65
Palmer 1994 [92] EMD, 256 and 500 molecules, 0.0057 mPa·s (8.1 %) 290 -3 1
= 798 kg·m
Green-Kubo, transverse-current
autocorrelation function
van der Gulik, El Kharraz 1995 [93] Vibrating wire see publlication in 1997 no data
Vargaftik 1996 [94] compilation, evaluation
Docter et al. 1997 [95] Rotating cylinder viscometer Single 0.6 % - 1.2 % 298.15, 523.15 0.10 - 14.74 8
sinker densimeter
van der Gulik 1997 [96] Vibrating wire ±1 % 220.01 - 308.15 0.56 - 453.20 292 Purity 99.996% stated by manufacturer; contains recalculated data from the
paper published in 1991
Fenghour et al. 1998 [97] compilation, evaluation, 200 - 1500 300 n/a
correlation
Bukowski et al. 1999 [98] ab initio 185 - 2000 ➝0 zero density limit Viscosity from this force field only calculated by Bock et al. (2002).
Docter et al. 1999 [99] Rotating cylinder viscometer Single ±0.08% 298.15 - 523.15 0.10 - 14.74 no data Condensed English version of Docter et al. (1997).
sinker densimeter
Bock et al. 2002 [100] Ab initio calculations, correlation ±0.2 % to 1% 185 - 1500 ➝0 zero density limit —
Mal'tsev et al. 2004 [101] Coiled capillary ±3% 500, 800, 1100 0.3 3 Radial acceleration correction?
Fernández et al. 2005 [102] equilibrium molecular dynamics, not reported 218.9 - 273.7 saturated liquid no data
Green-Kubo, 500 molecules, 2CLJQ

Quiñones-Cisneros, 2006 [103] correlation no data


Deiters
5

Authors Year Reference Method Uncertainty Temperature range (K) Pressure range (MPa) Number of Notes
Points
Nieto-Draghi et al. 2007 [104] equilibrium molecular dynamics, Einstein relation, 300 or 500 328.15 8 - 335 6
molecules

Sih et al. 2007 [105] Falling body ±1 % 298.15 - 313.15 10.9 - 19 20


Estrada-Alexanders, 2008 [106] Greenspan acoustic viscometer ±0.6% 220 - 370 0.195 - 3.146 117
Hurly
Pensado et al. 2008 [107] Vibrating wire ±3% 303.15 - 353.15 10 - 60 62
Abramson 2009 [108] Rolling sphere 5% 308 - 673 480 - 7960 56 For pressures above 500 MPa, uses densities of Giordano et al. (2006) for
Rosenfeld viscosity-entropy correlation.
Liang, Tsai 2010 [109] ab initio molecular dynamics 1.6 % 300 0.1 - 5.07 6
Merker et al. 2010 [110] EMD, 4000 molecules, Green-Kubo 14% to 33% 273, 298, 373 5.3 - 200 18

Heidaryan et al. 2011 [111] Falling sphere ±0.2 % 313.15 - 523.15 7.7 - 81.1 no data Data were not published and not provided by the authors.
Li et al. 2011 [112] compilation
Davani et al. 2012 [113] Rolling sphere not reported, ascribed 309.8 - 388.7 27.6 - 55.2 45
here 3%
Aimoli et al. 2014 [114] equilibrium molecular dynamics, (1.1 - 10.7)% EPM2 273.15 - 573.15 3.5 - 738 60 Various potentials compared.
Green-Kubo, 1024 molecules potential
Hellmann 2014 [115] ab initio 150 - 2000  ➝0 zero density limit 173 Unpublished data to 100 K provided by the author
Raabe 2014 [116] Equilibrium molecular dynamics, 7.60% 273.15 3.5 1
Green-Kubo, 600 molecules
Vogel 2014 [117] All quartz oscillating disk 0.1% at 298.15 K, 0.2% at 295.53 - 685.07 10 isochors 134 Personal communication of corrected values of the measurements of Vogel
other temperatures and Barkow (1986) and Hendl et al. (1993). Published 2016 in IJT.
Locke et al. 2014 [118] Vibrating wire 0.9 - 3.1 303.2 0.5 - 4.5 5
Schäfer et al. 2015 [119] Rotating cylinder viscometer (0.20 % to 0.41) % 253 - 473 < 1.2 54

Zhong et al. 2015 [120] Equilibrium molecular dynamics, transverse-current correlation 223 - 450 10 - 200 50
functions, 300 to 1000 molecules, eventually. 500 molecules

Jiang et al. 2016 [121] Equilibrium molecular dynamics (0.5 - 33) % 273, 323, 373, 423 10 - 200 16
with GROMACS and Green-Kubo,
500 molecules
6

Bibliography to Table of Sources of Viscosity Data for Carbon Dioxide

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631.
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7

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8

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61 Kurin, V. I. and I. F. Golubev (1974). The Viscosity of Argon, Air and Carbon Dioxide
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