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Article history: A hybrid system combining a 2 kW air-blowing proton exchange membrane fuel cell (PEMFC) stack and a
Received 17 April 2010 lead–acid battery pack is developed for a lightweight cruising vehicle. The dynamic performances of this
Received in revised form 4 July 2010 PEMFC system with and without the assistance of the batteries are systematically investigated in a series
Accepted 29 July 2010
of laboratory and road tests. The stack current and voltage have timely dynamic responses to the load
Available online 21 August 2010
variations. Particularly, the current overshoot and voltage undershoot both happen during the step-up
load tests. These phenomena are closely related to the charge double-layer effect and the mass transfer
Keywords:
mechanisms such as the water and gas transport and distribution in the fuel cell. When the external load
Proton exchange membrane fuel cell
Hybrid power system
is beyond the range of the fuel cell system, the battery immediately participates in power output with a
Fuel cell electric vehicle higher transient discharging current especially in the accelerating and climbing processes. The DC–DC
Dynamic performance converter exhibits a satisfying performance in adaptive modulation. It helps rectify the voltage output
Transient response in a rigid manner and prevent the fuel cell system from being overloaded. The dynamic responses of other
operating parameters such as the anodic operating pressure and the inlet and outlet temperatures are
also investigated. The results show that such a hybrid system is able to dynamically satisfy the vehicular
power demand.
Ó 2010 Elsevier Ltd. All rights reserved.
0306-2619/$ - see front matter Ó 2010 Elsevier Ltd. All rights reserved.
doi:10.1016/j.apenergy.2010.07.033
Y. Tang et al. / Applied Energy 88 (2011) 68–76 69
to be a good choice used as an assistant power source due to its inevitably employs more external balance-of-plant (BOP) equip-
advantages in transient discharging ability and energy storage effi- ments and requires more complicated system integration to create
ciency. When the PEMFC is unable to fully satisfy the external load necessary operational conditions. The aim of this work is to vali-
demand, a supplemented power source can produce a transient date the feasibility of a 2 kW PEMFC stack in an ‘‘open” mode to
power output during the accelerating and climbing processes so be the main power in a hybrid system for a lightweight cruising
as to alleviate the sluggish response of the pure fuel cell. On the vehicle. In particular, the dynamic performance of the fuel cell/hy-
other hand, if the PEMFC is able to provide the demanded power brid system is emphatically studied by conducting a series of lab-
by itself, its redundant electricity can be used to recharge the stor- oratory and road tests.
age device. Therefore, a hybrid system combining the PEMFC and
back-up power source appears more competent for electric vehi-
cles. For most of today’s hybrid application, the secondary batteries 2. Experimental
are usually treated as the auxiliary energy storage systems [7–10].
Additionally, the ultra-capacitor is also regarded as a popular part- 2.1. Configuration of the hybrid system
ner to complement the fuel cells [6]. Other attractive alternatives
for energy storage include photovoltaic arrays [11], flywheels In this work, a lightweight electric vehicle (YVK-J08A, Shenzhen
[12] and so forth. Yaveike Tech. Co. Ltd.) for campus cruising application was used as
In previous research work, plenty of achievements were the experimental target, which was modified by replacing the ori-
reported concerning various PEMFC-based transportation applica- ginal pure-battery power system with our self-designed hybrid
tions. Some of them were successfully put into real-life demonstra- system based on the PEMFC technology (see Fig. 1). The framework
tion rather than the laboratory practices or short-term road tests. of the back seat was redesigned to make enough space for the sys-
For example, in China, both the government and research institutes tem installation. The key components of this hybrid system in-
have taken great efforts to develop PEMFC electric vehicles (PEM- cluded a 2 kW air-blowing PEMFC stack, a lead–acid battery
FCEVs) in the past ten years and successfully demonstrated so- pack, a main DC–DC converter and a central controller. Other nec-
called green buses and cars based on PEMFC technology for the essary components for correct system operation could be designed
public services during 2008 Beijing Olympic Games. And a more or commercially available. A schematic diagram of the system con-
extensive PEM-FCEV demonstration can be expected to be imple- figuration was illustrated in Fig. 2.
mented in course of the coming 2010 World Exposition held in Table 1 listed the detailed system parameters of the main com-
Shanghai. ponents in the hybrid electric vehicle. The fuel cell stack was made
Generally speaking, the power level of the fuel cell system de- up of 110 single cells with a 66 V nominal voltage. It could be oper-
pends on the load requirement and energy management strategies. ated without external gas humidification at ambient temperature.
As for the vehicular application, the fuel cell system above 10 kW At the anode, pure hydrogen (>99.95%) was fed into grooved flow
usually involves complex system design and a high cost. Such channels of the fuel cell bipolar plates at a controlled pressure
applications involve various transportation tools such as large- around 0.05–0.06 MPa. Two high-pressurized cylinders made of
scale locomotives [13,14], city buses [15,16] and cars [17]. On aluminum alloy were used for on-board hydrogen storage. A
the other hand, in recent years, lightweight FCEVs (i.e. several-kilo- three-way valve was mounted to joint the two hydrogen feeding
watt class) have shown great prospects due to simpler system inte- lines. The fuel cell anode worked in a dead-end mode. An electron-
gration and lower investment risk, thereby making it more likely to ically controlled purge valve was fixed at the anodic downstream
realize large-scale production and commercialization earlier. Cor- line to periodically drain excessive water diffusing from the cath-
bo and co-workers [8–10] conducted a series of work on the basis ode to the anode through the polymeric membrane. And another
of commercial PEMFC systems for vehicular application. Their solenoid valve was located at the stack inlet to control the hydro-
studies mainly focused on engineering problems and covered dif- gen feeding. While at the cathode, air was supplied through four
ferent power levels for transportation applications. They previ- blowers which also acted as cooling fans to keep the fuel cell stack
ously published a hybrid system based on a 20 kW PEMFC stack at an appropriate temperature. This operating condition could be
and lead–acid batteries for minibus propulsion [8]. At the same identified as a so-called ‘‘open” or semi-integrated mode. Based
time, they also carried out an investigation of a low-power PEMFC on the air-blowing cathode, the produced water cannot be easily
stack around 2.4 kW in a hybrid system for scooter application [9]. expelled from the cathode compartment by unpressurized air flow,
Recently they reported the performance of a 2 kW PEMFC stack thereby improving the fuel cell’s self-humidifying ability. More
coupled with lithium ion batteries combined as an electric energy importantly, the power consumption of the air management sys-
storage system [10]. Jossen et al. [7] also explored the feasibility of tem extremely contributes to high parasitic losses [21]. Therefore,
a hybrid system with combination of lead–acid batteries and PEM- such an ‘‘open” mode is able to not only simplify the system design
FCs for possible application in an electric scooter. The results sug- and integration so as to facilitate easy operation of the fuel cell sys-
gested that the high efficiency of fuel cells at partial load operation tem, but also enhance the system efficiency and economy.
resulted in a good fuel economy for recharging the batteries. Tang As mentioned in the Section 1, power storage elements are nec-
et al. [18] developed a PEMFC boat with a battery set hybridized. essary to assist the fuel cell system. In common circumstances, the
The 2 kW fuel cell stack provided the main power to run the troll- secondary batteries may be suitable choices, among which the
ing motor, while the battery functioned for system starting and lead–acid battery has been characterized by its low cost and
acceleration. They concluded that the PEMFC system showed good acceptable efficiency for the hybrid scheme wherever the cycle life
adaptation to drive a boat. Based on an early project of a 500 W and depth of discharge were not considered the top performance
fuel cell electric bicycle [19], Hwang et al. [20] carried out a preli- criteria [22]. Moreover, as an assistant power source, the lead–acid
minary study on a 5 kW PEMFC system for a light-duty cruising battery has also been widely validated by other research groups
vehicle named MHV. They claimed that the MHV performed satis- [7–9]. In this study, a 48 V battery pack with eight lead–acid bat-
factorily over a hundred-kilometer driving test and would be opti- tery modules connected in series was utilized to cooperate with
mized on a hybrid system aiming at further improvement in the fuel cell system.
configuration and performance. A self-designed DC–DC converter was interconnected between
As reviewed above, most of the published literatures deal with the fuel cell system and the external load (i.e. the motor) in order
the PEMFC system operating thoroughly in a ‘‘close” mode. This to rectify the variable stack voltage to the load required value. This
70 Y. Tang et al. / Applied Energy 88 (2011) 68–76
Fig. 1. The modified electric vehicle with a hybrid system combining the PEMFC stack and lead–acid batteries.
Table 1
System parameters of the hybrid electric vehicle. maximum value that depended on the input voltage range. Thus,
the rotational speed of the cooling fan could be handled automat-
Parameter Value
ically by changing the input voltage according to different power
Electric vehicle
demands, so that the air stoichiometry and stack temperature
Size (m) 3.75 (L) 1.35 (W) 1.88 (H)
Wheelbase (m) 2.58 could be controlled synchronously.
Min. turning radius (m) 4.5 In order to ensure safe and correct power distribution during
Max. speed (km h 1) 30 different stages such as start-up, normal operation and load varia-
Motor voltage (V) 48 tion, a central controller based on the AVR technology was used to
Fuel cell stack coordinate and command all the components through efficient
Number of cells 110 management of the control signals, on–off signals, serial port com-
Nominal voltage (V) 66
Nominal power (kW) 2 (0.6 V/cell)
munication, as well as various operating parameters (e.g. voltage,
Nominal current (A) 30 current, pressure, temperature). A programmed data acquisition
Lead–acid battery pack
(DAQ) unit was employed to facilitate status monitoring and data
Number of batteries 8 collection. The feedback signals and operating parameters could
Nominal voltage of a single battery (V) 6 be transmitted to a Labview-based software interface for real-time
Electric capacity of a single battery (A h) 250 (5 hr) control, and also be downloaded to the personal computer (PC)
Voltage at full charge (V) 53
through the RS232 communication port. Moreover, a remote LCD
DC–DC converter monitor was also fixed on the front instrument panel for the con-
Input voltage (V) 60–120 (adjustable)
venience of observation.
Input under-voltage protection (V) 60 ± 2
Output current (A) 10–100 (adjustable)
Output voltage (V) 5–56 (adjustable) 2.2. Dynamic test of the fuel cell/hybrid system
Voltage stability degree (%) 60.5
Ripple coefficient (%) 61
Response time (s) 0.1 Real-time experiment of the PEMFC-based hybrid system in dy-
namic conditions is of great significance to evaluate the system
performance in both laboratory and road tests. In this study, the
converter also integrated a control unit for battery charging from dynamic performance was the main focus which could reveal tran-
the fuel cell system during idle periods. The charge current in this sient mechanisms and the effects of relevant operating parameters
study was regulated at 10 A. The switch motion between the fuel (e.g. operating pressure and temperature). Before installing the hy-
cell system and the battery pack was realized by a diode which brid power system on the electric vehicle, an in-house bulb-array
could effectively control the power distribution. In addition, a ded- was used as the simulative load in order to preliminarily verify
icated controller for adaptive air flow regulation was developed by the dynamic characteristics of the fuel cell system with and with-
inputting a 5 V, 25 kHz square-wave signal with a changeable duty out assistance from the battery pack. A switch could be easily han-
cycle. The output voltage could be modulated from zero to the dled by the operator to control the battery connection. During the
Y. Tang et al. / Applied Energy 88 (2011) 68–76 71
Fig. 3. Photos of the real road tests: (a) Running on the planar road. (b) Climbing a slope.
72 Y. Tang et al. / Applied Energy 88 (2011) 68–76
Fig. 5. Dynamic responses of the fuel cell stack output and DC–DC output under a Fig. 7. Dynamic responses of the fuel cell stack output and DC–DC output under a
constant simulative load. step-up simulative load.
Fig. 6. Dynamic responses of the fuel cell operating parameters under a constant
simulative load. Fig. 8. Dynamic responses of the fuel cell operating parameters under a step-up
simulative load.
excessively high-pressure operation. Moreover, an increasing step-
up profile of the operating pressure can be observed, indicating
that the hydrogen accumulates inside the fuel cell while the purge
valve periodically repeats ‘‘on–off” motions with a constant cycle.
In addition, the inlet and outlet temperature increases with the in-
crease of current. At the beginning, the difference between the two
temperatures seems smaller. With the reaction going on, the inlet
temperature increases more quickly, because the reaction in the
inlet area is more acute due to abundant reactants, producing more
heat which promotes a higher temperature. Thus, the increasing
rate of the inlet temperature appears higher than the outlet.
Figs. 7 and 8 illustrate the dynamic characteristics of various
parameters under step-up load variations. It is obvious that when
the load is controlled by a regular step-up rule, the stack voltage
correspondingly feeds back in a step-down manner. From 145 s
to 955 s, the DC–DC output voltage does not vary with the increase
of current, although the stack voltage accordingly decreases. This
phenomenon can be attributed to the voltage protective mecha-
nism in the DC–DC converter. In general, during a high-current
Fig. 9. Dynamic responses of the hybrid system under a simulative load.
stage, the stack voltage is forced to be dragged down to a lower le-
vel. To avoid the fuel cell damage caused by long-term operation at
a lower voltage, the DC–DC converter help maintain a steady observed that both the two voltages respond synchronously to the
power output by sacrificing the voltage value, thereby alleviating current variation, showing great sensitivity to the load changes.
the harmful effect of high-current operation. Therefore, after Fig. 8 shows that the hydrogen pressure experiences an increasing
955 s, when the stack current climbs up to 30 A, the DC–DC output process as expected during the step-up load test. The inlet and out-
voltage responds with a prompt drop. A more detailed explanation let temperatures exhibit arc-like trends without any overshoot/
about this adaptive mechanism is specified in Fig. 9. It can be also undershoot behaviors during each stage. This result agrees well
Y. Tang et al. / Applied Energy 88 (2011) 68–76 73
with that reported in our previous study on a commercial PEMFC rehydrate the anode side and accelerate water redistribution. In
system [23]. However, compared with the outlet temperature, the medium-current region (600–700 s) as shown in Fig. 10b, the
the inlet variant increases much faster at each transient turning current overshoot and voltage undershoot phenomena also occur,
point due to more produced heat, as previously mentioned. whereas a small sharp peak in reverse direction simultaneously
Remarkably, the current overshoot and voltage undershoot appears during the transient load change. Moreover, the magni-
both happen when the load transiently increases to a next-step va- tude of the overshoot/undershoot seems to be reduced. Also, both
lue. Fig. 10 shows an amplified view of these interesting behaviors. the stack current and voltage spend a shorter time obtaining re-
As for the overshoot/undershoot phenomena, there may exist two newed steady-state values, compared with Fig. 10a. The reason
contributing factors including the charge double-layer effect and for this result may be explained by the improvement of local
the internal mass transfer mechanism [24]. It is well known that non-uniformity in mass distributions. Under this condition, both
in PEMFCs, a thin layer on or near the interface between the elec- the increased produced water and air stoichiometry contributes
trodes and the electrolyte may act as an electrical capacitor during to the reduced peak of the stack current [24,26]. Another possible
the transient process, producing so-called charge double-layer ef- reason can be explained by the enhanced charge double-layer ef-
fect. Thus, the charges have to take some time to accumulate or fect in the transient process that has to be considered here. It is
dissipate when the current changes. On the other hand, the water more likely to restrict the behavioral extent of the overshoot and
and gas transport also have great influence on the dynamic behav- undershoot. This trend becomes more evident in Fig. 10c which
iors of the current and voltage during transience. It is known that shows that, in the high-current region (900–1000 s), the current
the abrupt load change tends to induce temporary dehydration overshoot does not happen when the load increases. Similarly,
due to electro-osmotic drag on the anode side, and air feeding star- no voltage undershoot appears when the current jumps to a higher
vation on the cathode side [25–27]. It can be seen in Fig. 10a that, level. This result is quite different from the case in the low-current
in the low-current region (300–400 s), the load change tends to re- region (see Fig. 10a). A higher flow rate increases the air stoichiom-
sult in current overshoot and voltage undershoot. When the load etry, which helps obtain a new mass balance by alleviating water
increases, the current firstly reaches a peak value and subse- flooding and oxygen starvation, although a higher discharging cur-
quently drops to a lower value. During this low-current stage, rent promotes more produced water. Thus, the mass transfer and
the membrane wettability is not in a reasonable condition espe- distribution get greatly improved during this stage. In addition,
cially when the fuel cell is operated in a self-humidifying mode, the charge double-layer effect may further become a dominant fac-
because the water produced at the cathode is still limited. Also, tor influencing the dynamic behavior of the current, especially dur-
the low-current operation allows a lower air flow rate. Under this ing the high-current stage. In a word, an integrative influence of
condition, the step-up load may cause critical anode dehydration both the charge double-layer effect and the mass transfer mecha-
and oxygen starvation. In other words, the sudden discharge may nism benefits fast formation of a new steady state. On the contrary,
bring much burden on the water and gas transport, although the the transient spike-like peaks of both the current and voltage can
power demand is still not quite high. It can be inferred that a poor be observed, showing that the load change may suddenly push
water and gas management is more likely to promote the possibil- up the voltage and pull down the current. This is also a different
ity of current overshoot. After overshoot, the current goes down feature, compared with Fig. 10a. Furthermore, it can be seen that,
until reaching a new steady state. This means that a renewed mass when the load increases, the DC–DC output voltage only has a
balance gradually comes into being after a few seconds. Mean- transient fluctuation and then abruptly regains a constant value
while, the voltage is dragged down to a very low value because in the steady state, showing a sensitive and rigid response to the
the higher membrane resistance caused by transient dehydration dynamic load change almost without any delay. This phenomenon
and a lower temperature inevitably leads to a sharp drop of the is determined by its function which helps modulate the ‘‘soft”
voltage, that is voltage undershoot. Subsequently, the voltage in- characteristics of the stack output. To sum up, both the stack and
creases gradually until reaching a relatively steady state. The rea- DC–DC output voltages provide transient responses to the current
son for this performance rejuvenation can be explained by the changes but have different dynamic performances in the subse-
fact that it may take some time for the back-diffusion water to quent time.
Fig. 10. Amplified views of the overshoot and undershoot phenomena during transient processes: (a) low-current region; (b) medium-current region; and (c) high-current
region.
74 Y. Tang et al. / Applied Energy 88 (2011) 68–76
Fig. 11. Dynamic responses of the fuel cell stack output and DC–DC output on stop- Fig. 13. Dynamic responses of the hybrid system on stop-and-go random cycles in
and-go random cycles in the planar road tests. the planar road tests.
Y. Tang et al. / Applied Energy 88 (2011) 68–76 75
Acknowledgements
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