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Phosphorescence is a type of
photoluminescence related to
fluorescence. Unlike fluorescence,
phosphorescent material does not
immediately re-emit the radiation it
absorbs. The slower time scales of the re-
emission are associated with "forbidden"
energy state transitions in quantum
mechanics. As these transitions occur
very slowly in certain materials, absorbed
radiation is re-emitted at a lower intensity
for up to several hours after the original
excitation.
Explanations
Simple
Quantum mechanical
Chemiluminescence
Some examples of glow-in-the-dark
materials do not glow by
phosphorescence. For example, glow
sticks glow due to a chemiluminescent
process which is commonly mistaken for
phosphorescence. In chemiluminescence,
an excited state is created via a chemical
reaction. The light emission tracks the
kinetic progress of the underlying
chemical reaction. The excited state will
then transfer to a dye molecule, also
known as a sensitizer or fluorophor, and
subsequently fluoresce back to the ground
state.
Materials
Common pigments used in
phosphorescent materials include zinc
sulfide and strontium aluminate. Use of
zinc sulfide for safety related products
dates back to the 1930s. However, the
development of strontium aluminate, with
a luminance approximately 10 times
greater than zinc sulfide, has relegated
most zinc sulfide based products to the
novelty category. Strontium aluminate
based pigments are now used in exit
signs, pathway marking, and other safety
related signage.[2]
Phosphorescen
t pigments –
zinc sulfide vs.
strontium
aluminate
left: Zinc sulfide
right: Strontium
aluminate
Pigments in the
dark
Pigments in the
dark after 4 min
Phosphorescent
Phosphorescent pigment
red (calcium sulfide)
Phosphorescent pigment
red in the dark
Phosphorescent pigment
blue (alkaline earth metal
silicate )
Phosphorescent pigment
blue in the dark
See also
Luminous paint
Microsphere
Persistent luminescence
Phosphor
Phosphoroscope
Tritium
References
1. Karl A. Franz, Wolfgang G. Kehr, Alfred
Siggel, Jürgen Wieczoreck, and Waldemar
Adam "Luminescent Materials" in Ullmann's
Encyclopedia of Industrial Chemistry 2002,
Wiley-VCH, Weinheim.
doi:10.1002/14356007.a15_519
2. Zitoun, D.; Bernaud, L.; Manteghetti, A.
Microwave Synthesis of a Long-Lasting
Phosphor. J. Chem. Educ. 2009, 86, 72-
75.doi:10.1021/ed086p72