Qualitative Analysis - 8

8
8 Qualitative Analysis
SECTION – I : STRAIGHT OBJECTIVE TYPE
8.1 Sodium nitroprusside when added to an alkaline solution of sulphide ions produces purple
colouration due to the formation of:
(A) Na[Fe(H2O)5 NOS] (B) Na2[Fe(CN)5 NOS]
(C) Na3Fe(CN)5NOS] (D) Na4[Fe(H2O5NOS)]
8.2 Zinc pieces are added to acidified solution of SO32-. Gas liberated can:
(A) Turn lead acetate paper black (B) Turn lime water milky.
(C) Give both of the above tests (D) Give none of the above tests
8.3 [X] + H2SO4 [Y] a colourless gas with irritating smell.
[Y] + K2Cr2O7 + H2SO4 green solution but a slightly coloured precipitate is not formed. X
& Y are:
(A) SO32-, SO2 (B) Cl-, HCl (C) S2-, H2S (D) CO32-, CO2
8.4 Ammonium salts on heating with slaked lime liberates a colourless gas (X). Identify the
correct statement for gas (X).
(A) (X) turns red litmus blue and produces dense white fumes in contact with dilute HCl.
(B) (X) turns filter paper moistened with mercurous nitrate black and gives intense blue
coloured solution with CuSO4 (aq).
(C) (X) when passed through Nessler’s reagent produces a brown colour precipitate.
(D) All of these.
8.5 A 0.1M solution of a certain cation will form a precipitate with 0.1M solution of all these
anions; OH-, CO32, Cl-, SO42-. Which cation fits this description?
(A) Ba2+ (B) Fe2+ (C) Mg2+ (D) Pb2+
8.6 An aqueous blue coloured solution of a transition metal sulphate reacts with H2S to give a
black precipitate. The black precipitate dissolves in 50% nitric acid forming a blue coloured
solution. The blue solution on treatment with KI in weakly acidic medium turns yellow /
brown and produces a white precipitate.
(A) Co2+ (B) Cu2+ (C) Hg2+ (D) Pb2+
8.7 Which one of the following reagent can be used for differentiating Cu2+ and Bi3+ ?
(A) H2S gas in presence of dil. HCl. (B) NH4OH (excess)
(C) K4[Fe(CN)6] (D) (B) and (C) both
8.8 The ion that cannot be precipitated by both HCl and H2S is
(A) Pb2+ (B) Cu+ (C) Ag+ (D) Sn2+
8.9 Black precipitate of copper sulphide dissolves in:

(A) KCN solution (B) Sodium sulphide solution
(C) Sodium hydroxide (D) Boiling dilute (M) sulphuric acid
8.10 Fe2+ does not give prussian blue colour with K4[Fe(CN)6], but on its reaction with (X), prussian
blue colour appears. (X) can be:
(A) MnO4 -/H+ (B) H2SO4 (C) NH3 (D) All true
8.11 The only cations present in a slightly acidic solution are Fe3+, Zn2+ and Cu2+. The reagent
that when added in excess to this solution would identify the separate Fe3+ in one step is:
Resonance RRBC910PAGE - 1
Where you will be in resonance with IIT-JEE
(A Unit of Resonance Eduventures Pvt. Ldt.)
(A) 2 M HCl (B) 6 M NH3 (C) 6 M NaOH (D) H2S gas
8.12 Fe(OH)3 and Cr(OH)3 precipitates are completely separated by:
(A) Aqueous NH3 (B) HCl (C) NaOH / H2O (D)H2SO4
8.13 To increase significantly the concentration of free Zn2+ ion in a solution of the complex ion
[Zn(NH)3)4]2+
Zn2+ (aq) + 4NH3 (aq) [Zn(NH3)4]2+ (aq)
add to the solution some:
(A) H2O (B) HCl(aq) (C) NH3(aq) (D) NH4Cl (aq)
8.14 A mixture of two white substance was dissolved in water. On passing Cl2 gas through the
solution a deep brown colour is developed. Addition of BaCl2 solution to the original solution
gives a white precipitate. Addition of a large amount of NaOH solution to the original solution
gives a white precipitate, whose suspension in water is used as an ant-acid, the mixture
gives golden yellow colour flame. The mixture contains:
(A) Na+, Mg2+, Br- and SO42- (B) Na+, Ca2+, Br- and SO42-
(C) Na+, Al3+, Br- and SO42- (D) Na+, Zn2+, Br- and SO42
8.15 A mixture containing two salts was treated as follows:
(i) The mixture on heating with MnO2 and concentrated H2SO4 liberates a yellowish green
gas.
(ii) The mixture on boiling with potassium hydroxide liberates a gas which when bubbled
through an alkaline solution of K2[HgI4] gives brown precipitate.
(iii) The mixture on reaction with potassium thiocyanate gives deep red colouration.
The two salts are:
(A) Fe(CH3COO)3 and CH3COONH4 (B) FeCl3 and NH4Cl
(C) HgCl2 and NH4Cl (D) Mg(CH3COO)2 and NH4Cl
8.16 A coloured precipitate is obtained when H2S gas is passed through an aqueous solution of
salt in presence of ammonium hydroxide. The precipitate dissolves in dilute HCl & reacts
with NaOH to give white precipitate which on standing turns into a brown / black precipitate.
The brown / black precipitate on fusion with KNO3 & Na2CO3 gives green coloured compound.
The cation of the salt is:
(A) Co2+ (B) Mg2+ (C) Ni2+ (D) Mn2+
8.17 K4[Fe(CN)6] can be used to detect one or more out of F2+, Fe3+, Zn2+, Cu2+, Ca2+
(A) Fe2+, Fe3+ only (B)Fe3+, Zn2+, Cu2+ only
(C) All but not Ca2+ (D) All
8.18 Intense blue precipitate of Fe4[Fe(CN)6]3 and sodium hydroxide solution when mixed gives:
(A) Soluble prussian salt (B) Reddish-brown precipitate
(C) Deep-red colouration (D) Turnbull’s blue
SECTION – II – MULTIPLE CORRECT ANSWER TYPE
8.19 Which of the following statement(s) is (are) true?

(A) Soluble bicarbonates gives white precipitate with MgCl2 in cold.
(B) Soluble calcium bicarbonates gives white precipitate with dilute ammonium solution.
(C) All bicarbonates are generally soluble in water.
(D) Hg(II) chloride forms a reddish brown precipitate in a solution of sodium carbonate.
8.20 Which of the following statement(s) is (are) correct?
(A) Soluble sulphide gives black precipitate with AgNO3 solution which is soluble in hot
dilute nitric acid.
(B) Soluble sulphide produces a yellow precipitate with a suspension of cadmium carbonate.
(C) Sulphide ions reacts with sodium nitroprusside and gives a purple colouration.
(D) Free H2S gas forms white precipitate with tetrahydroxo plumbate (II) solution.
8.21 Which of the following reagents can be used to distinguish between SO2 and CO2?
(A) Lime Water (B) Zinc nitroprusside paste in water
(C) Potassium iodate and starch (D) Acidified potassium dichromate solution.
8.22 Each of these solution is added to a mixture of aqueous solutions of iodide and chloroform
(CHCl3), separately. Which will give a positive test for iodine when the solutions are vigorously
mixed?
(A) NaCl solution (B) NaBr solution (C) Chlorine water (D) Bromine water
8.23 Which of the following statement(s) is (are) incorrect?

(A) In thiourea test for nitire, a green coloured solution is obtained.
(B) It is not necessary to carry out the chromyl chloride test in a dry test tube.
(C) In PbNO3, the brown ring test can be performed with its water extract
(D) Suspension of CdCO3 gives black ppt. with sodium sulphide solution.
8.24 Which of the following is (are) correctly matched?

(A) [A](OH)4]- (aq) + NH4+ (aq)Slightly heat White precipitate and liberation of ammonia.
(B) Pb2+ (aq) + 2Br- (aq) Red precipitate.
(C) BiI3 (black precipitate) + H2O () Δ Orange precipitate
(D) Ca2+ (aq) + K4 [Fe (CN)6] (aq) White precipitate
(A) Cu2+ salts form soluble complex with excess KCN.
(B) Cu2+ salts form soluble complex with aqueous ammonia.
(C) Cu2+ salts form soluble complex with KI,
(D) A piece of iron or zinc when place in Cu2+ salt solution, precipitates copper.
8.26 The reagents, ammonium chloride and aqueous ammonia will precipitate.
(A)Bi3+ (B) Pb2+ (C) Mg2+ (D) Fe3+ (E) Cu2+
8.27 Which of the following is / are correctly matched?

(A) Fe3+ + C6H4N(NO)ONH4 HCl Reddish brown precipitate
(B) AsO43- + Mg2+ + NH44- White crystalline precipitate
(C) Bi3+ + C9H7ON (5% + H+ + I-) Red precipitate
2+ 2+ -
(D) Hg + Co + 5CN Deep blue crystalline precipitate.

(A) In a mixture of Sr2+ and Ca2+, ammonium sulphate precipitates only Sr2+ as SrSO4 but
CaSO4 dissolves in ammonium sulphate forming a soluble complex.
(B) Barium chromate is insoluble in dilute acetic acid.
(C) Cr(OH)3 is soluble in NaOH and Br2 water while Fe(OH)3 is insoluble.
(D) Cu and Cd separation is based upon the fact that in presence of excess KCN, only Cd
is precipitated as sulphide on passing H2S.
SECTION – III : ASSERTION AND REASON TYPE
8.29 Statement–1 : Baryta water becomes turbid on passing CO2 gas through it but turbidity
becomes clean on passing more CO2 gas.
Statement–2 : Carbonates give white precipitate with silver nitrate solution. The precipitate
becomes yellow or brown if the mixture is boiled.
(A) Statement- 1 is True, Statement- 2 is True; Statement- 2 is a correct explanation for
Statement- 1.
(B) Statement- 1 is True, Statement- 2 is True; Statement- 2 is NOT a correct explanation
for Statement- 1.
(C) Statement- 1 is True, Statement- 2 is False.
(D) Statement- 1 is False, Statement- 2 is True.
8.30 Statement–1 : No yellow precipitate is formed when an excess of a more concentrated
(6M) soluble of KI is added to a solution containing Pb2+ ions.
Statement–2 : Yellow precipitate of Pbl2 does not dissolve in excess of dilute solution of KI.
Statement- 1.
for Statement- 1.
8.31 Statement–1 : A solution of BiCl3 in concentrated HCl when diluted with water gives white
precipitate.
Statement–2 : BiCl3 forms insoluble BiO+Cl when diluted with a large quality of water.
Statement- 1.
for Statement- 1.
8.32 Statement–1 : NH4Cl is added while doing the analysis of IIIrd group radicals to suppress
the ionisation of NH4OH because,.
Statement–2 : With high concentration of OH- ions, basic radicals of other groups are also
get precipitated with III group cations.
Statement- 1.
for Statement- 1.
8.33 Statement–1 : When H2S gas is passed into an aqueous solution of ZnCl2, Zn2+ ions are
completely precipitated as zinc sulphide.
Statement–2 : Zinc sulphide is insoluble in solutions of caustic alkali but dissolves in dilute
HCl.
Statement- 1.
for Statement- 1.
8.34 Statement–1 : White precipitate of zinc phosphate is soluble in ammonia.
Statement–2 : Zinc phosphate forms a soluble complex with ammonia.
Statement- 1.
for Statement- 1.
8.35 Statement–1 : Potassium chromate solution in acetic acid precipitates only Ba2+ as BaCrO4
in group Vth.
Statement–2 : SrCrO4 and CaCrO4 are not precipitated with potassium chromate solution
in acetic acid.
Statement- 1.
for Statement- 1.
8.36 Statement–1 : White precipitate of Mg(OH)2 s insoluble in excess of sodium hydroxide but
readily soluble in solution of ammonium salts.
Statement–2 : Mg()OH)2 is very sparingly soluble in water.
Statement- 1.
for Statement- 1.
8.37 Statement–1 : Addition of ammonium chloride to a solution containing ferric and magnesium
ions is essentials for selective precipitation of ferric hydroxide by aqueous ammonia.
Statement–2 : The function of NH4Cl is to suppress the ionization of NH4OH by common
ion effect and thus prevents the precipitation of Mg(OH)2 because Ksp of Mg(OH)2 is high.
Statement- 1.
for Statement- 1.
8.38 Statement–1 : Reaction of disodium hydrogen phosphate with magnesium sulphate in
presence of ammonium hydroxide gives a white crystalline precipitate.
Statement–2 : Insoluble magnesium ammonium phosphate is formed.
Statement- 1.
for Statement- 1.
SECTION – IV : TRUE AND FALSE TYPE
8.39 S1: Like CO32-, SO32- also gives test with baryta water, Ba(OH)2.
S2: Ag2SO3 is insoluble in dilute HNO3.
S3: Triodide ions (I3-) produced by the reaction of Cu2+ and KI solution are not reduced by
excess of sodium thiosulphate solution.
S4: Black precipitate of Cu(SCN)2 turns into white precipitate when it reacts with saturated
solution of SO2 in water.
(A) F T T F (B) T F F T (C) F T F T (D) T T F T
8.40 S1: The addition of chlorine water dropwise to a solution of a bromide liberates free bromine,
which colours the solution orange red.
S2: Chlorine gas bleaches the filter paper moistened with yellow dyestuff, fluorescein.
S3: Nitrogen gas is evolved when a solution of nitrate is boiled with zinc dust and sodium
hydroxide solution.
(A) T T T (B) T F T (C) T F F (D) T T F
8.41 S1: When copper sulphate is added to K2[HgI4] solution and SO2 is passed into this solution,
white precipitate is obtained.
S2: When copper sulphate solution is boiled with glucose in presence of caustic soda, a
blue precipitate is obtained.
S3: Pure Cu2Cl2 is white, but moist air converts it in to a dark blue material.
(A) T T T (B) T F T (C) F F F (D) F T F
8.42 S1: From solution containing copper (+2) and zinc (+2) ions, copper can be selectively
precipitated using sodium sulphide.
S2: Amongst Ca2+, Al3+, Bi3+ and Mg2+, the NH4Cl and aqueous ammonia will precipitate
only Al3+ as its hydroxide.
S3: Sodium chloride on reaction with conc. H2SO4 in presence of MnO2 liberates a yellowish
green gas.
S4: The formation of brown precipitate on reaction with alkaline K2[HgI4] indicates the
presence of NH4+.
(A) T T T T (B) T F T T (C) F F T T (D) F T F T
8.43 S1: Sr2+ ions in very dilute solution do not give yellow precipitate with CrO42- ions.
S2: Ca2+ ions give yellow precipitate in presence of ammonia with potassium ferrocyanide
solution.
S3: Mg2+ ions in solution gives gelatinous white precipitate of magnesium hydroxide with
ammonia solution.
S4: HgS dissolves in both sodium sulphide solution and aquaregia.
(A) F T F F (B) T T F F (C) T F T T (D) F F T T
8.44 S1: Ammonium chloride on heating with an aqueous solution of K2Cr2O7 and concentrated
H2SO4 produces deep red vapours.
S2: Barium nitrate dissolved in water responds to brown ring test.
S3: Deep red solution of ferric acetate on boiling with water turns to a brownish red solution.
S4: NaNO2 soution acidified with acetic acid produces blue colour with a starch paste
contaminated with iodide ions.
(A) T T T F (B) F F F T (C) T T F F (D) F F T T
SECTION – V : COMPREHENSION TYPE

Comprehension # 1
Following flow chart describes the scheme of classifications of anions on the basis of the
nature of the products or nature of reaction with chemical reagents and acids.
Group – A Group - B
Evolve the volatile Depend upon the
products with acids reactions in solutions.
(HCl or H2SO4)
Group – B1 Group – B2
Give precipitation Give oxidation-reduction
Group – A1 Group – A2 reaction, e.g. reaction in solution
Evolve gases or acid vapours Evolve gases with sulphate, phosphate, etc manganate,
chromate etc.
with dilute HCl or H2SO4, e.g. Evolve gases with
carbonate, sulphide, sulphate, HCl or H2SO4, e.g.
nitrite, acetate, etc halides nitrates. etc.
8.45 A salt on reaction with dil. H2SO4 produces a colourless gas which turns lime water milky
and an acidified orange coloured potassium dichromate solution green. The salt may be
(A) A carbonate (B) A sulphite (C) A sulphide (D) Acetate.
8.46 A solution of a salt in concentrated H2SO4 turns white paste of starch containing potassium
iodide blue. the salt may be a:
(A) Chloride (B) Carbonate (C) Bromide (D) Acetate
8.47 Which of the following statements is incorrect?
(A) Metal iodide with excess chlorine water forms colourless iodic acid.
(B) Nitrates on gentle warming with aluminium powder and sodium hydroxide produces
ammonia gas.
(C) Mercury nitrate solution produces yellow precipitate of basic mercury (II) sulphate with
sodium sulphate solution.
(D) A deep red solution of complex ion [Fe3(OH)2(CH3COO)6]+ on boiling with water produces
a greenish-yellow precipitate.
Comprehension # 2
For the purpose of systematic qualitative analysis, cations are classified into various groups
on the basis of their behaviour against some reagents. The group regents used for the
classification of most common cations are hydrochloric acid, hydrogen ammonium hydroxide,
and ammonium carbonate. Classification is based on whether a cation reacts with these
reagents by the formation of precipitates or not.
8.48 Which one among the following pairs of ions cannot be separated by H2S in presence of
dilute hydrochloric acid?
(A) Bi3+, Cd2+ (B) Al3+, Hg2+ (C) Zn2+, Cu2+ (D) Ni2+, Cu2+
8.49 An aqueous solution contains Hg2+, Hg22+, Pb2+ and Cd2+. The addition of 2 M HCl will
precipitate:
(A) 2M HCl (B) 6M NH3 (C) 6M NaOH (D) H2S gas
8.50. An aqueous solution which is slightly acidic contains cations Fe3+, Zn2+ and Cu2+. The reagent
that when added in ecess to this solution would identify the separate Fe3+ ion in one step is:
Comprehension # 3
The reagents like silver nitrate, potassium ferrocyanide, potassium thiocyanate, potassium
iodide, potassium chromate. Nessler’s reagent, etc, find extensive and very important
applications in qualitative analysis because these reagents form different types of products
with different cations. For example potassium iodide forms yellow precipitate with Pb2+ but
it forms red precipitate with Hg2+. Hence, these reagents are widely used in the qualitative
analysis of inorganic salts:
8.51 Which of the following is not correctly matched?
(A) [A(OH)4]- (aq) + NH4+ (aq) Slightly heat White precipitate and liberation of ammonia
(B) Pb2+ (aq) + 2Br- (aq) Yellow precipitate
(C) BiI3 (black precipitate) + H2O () Δ Orange precipitate
2+
(D) Ca (aq) + K4 [Fe (CN)6] (aq) White precipitate.
8.52 Which of the following cations (i.e. basic radical) forms coloured (not white) precipitates
with aqueous solution of potassium iodide but precipitate does not dissolve in excess of
reagent?
(A) Hg2+ (B) Hg22+ (C) Bi3+ (D) Cu2+
8.53 Which of the following hydroxide does not dissolve in ammonia solution but dissolves in
sodium hydroxide?
(A) Zn(OH)2 (B) Cd(OH)3 (C) Cu(OH)2 (D) Al(OH)3
Comprehension # 4
In qualitative analysis, IIIrd group includes Fe3+, Al3+ and Cr3+. The group reagent is ammonium
hydroxide in presence of ammonium chloride. NH4Cl added to suppress the ionisation of
NH4OH so that only the IIIrd group radicals are precipitated as their insoluble hydroxide and
not the IVth and Vth group radicals as the solubility products of their hydroxides are much
higher. Before adding group reagent to the filterate of IInd group, one drop of concentrated
HNO3 (oxidising agent) is added and the content is boiled for 2-3 minutes and then cool
because the solubility product of Fe(OH)2 is very high as compared to Fe(OH)3.
When a light bluish green crystalline compound containing cations of IIIrd group and zero
group is analysed, it responds to following tests / reactions.
(a) Its aqueous solution gives a reddish brown precipitate with alkaline solution of potassium
tetraiodomercurate (II)
(b) Its aqueous solution after boiling with conc. HNO3 gives a reddish brown precipitate
with sodium hydroxide.
(c) Solution of reddish brown precipitate in dil. HCl gives blood red colouration with
ammonium sulphocyanide and Prussian blue with potassium ferrocyanide.
(d) Its very dilute solution gives white precipitate with (CH3COO)2 Pb solution and white
precipitate is only soluble in hot ammonium acetate.
8.54 Why one ml conc. HNO3 is added to IInd group filterate before proceeding for IIIrd group
radicals?
(A) Because it oxidises the dissolved H2S to colloidal sulphur.
(B) Because it oxidizes Fe2+ to Fe3+ so that Fe3+ can be completely precipitated as its
hydroxide.
(C) Because precipitation of cations belonging to IIIrd group by group reagent takes place
only in presence of conc. HNO3.
(D) None of these.
8.55 Identify the correct statement:
(A) NH4Cl is added along with NH4OH so that only IIIrd group cations can be precipitated as
their hydroxides.
(B) In pace of NH4Cl, (NH4)2 SO4 can not be used as barium (vth group radical) will also be
precipitated as BaSO4 along with Al+3, Fe+3 & Cr+3.
(C) The metals of this group are not precipitated by the group reagents for 1st and 2nd, but
are all precipitate, in the presence of ammonium chloride, by hydrogen sulphide from
their solutions made alkaline with ammonium solutions.
(D) All of these.
8.56 The reddish brown precipitate formed in (a) reaction is of:

(A) Mercury amido iodide (B) Mercury iodide
(C) Oxydimercuric ammonium iodide (D) Mercury amido iodide and mercury
8.57 Aqueous solution of light greenish crystalline compound reacts with potassium ferrocyanide
to give a deep blue coloured solution or precipitate. Its chemical formula is:
(A) Fe Fe[Fe(CN)6] (B) Fe4[Fe(CN)6]3 (C) Fe3[Fe(CN)6]2 (D) None of these
Comprehension # 5
A black coloured (A) on reaction with dil. H2SO4 gives a gas (B) which on passing in a
solution of an acid (C) gives a white turbidity (D). Gas (B) when passed in an acidified
solution of a compound (E) gives a black precipitate (F) which is soluble in hot concentrated
(C). After boiling this solution when excess of ammonia solution is added, a blue coloured
compound (G) is formed. To this solution of (E), on addition of acetic acid and aqueous
potassium ferrocyanide, a chocolate brown precipitate (H) is formed. On addition of an
aqueous solution of BaCl2 to an aqueous solution of (E) white precipitate insoluble in HNO3
is obtained.
8.58 Black coloured compound (A) is:
(A) PbS (B) CuS (C) Ags (D) All of these.
8.59 The gas (B) on passing through an acid (C) gives a white turbidity (D) because:
(A) Gas (B) acts as an oxidising agent (B) Gas (B) acts as an reducing agent
(C) Acid (C) acts as an oxidising agent (D) (B) and (C) both
8.60 To which of the following property, the compound (E) will respond?
(A) It gives white precipitate with (CH3COO)2 Pb solution soluble in ammonium acetate.
(B) It gives dirty white precipitate with KI.
(C) Its hydrated salt effloresces.
(D) All of these.
8.61 When a piece of iron or zinc id added to the solution of compound (F) in hot concentrated
(C) acid:
(A) A reddish brown precipitate is formed. (B) A white precipitate is formed.
(C) A black precipitate is formed. (D) None of these.
Comprehension # 6
A chemist opened a cupboard and found four bottles containing water solutions, each of
which had lost its label. Bottles 1, 2 , 3 contained colourless solutions, while bottle 4 contained
a blue solution. The labels from the bottles were lying scattered on the floor of the cupboard.
They were:
Copper (II) sulphate, hydrochloric acid
Lead nitrate, sodium carbonate
By mixing samples of the contents of the bottles, in pairs, the chemist made the following
observations:
Bottle 1 + Bottle 2 White precipitate is formed.
Bottle 2 + Bottle 3 olourless and odourless gas is evolved.
Bottle 2 + Bottle 4 No visible reaction is observed.
Bottle 3 + Bottle 4 Blue precipitate is formed.
With the help of the above observations answer the following questions.
8.62 Bottle 3 contains:
(A) Copper (II) sulphate (B) Hydrochloric acid
(C) Lead nitrate (D) Sodium carbonate.
8.63 Which of the following statements is correct for salts contained in bottle 1 and 4?
(A) Bottle 4 gives white precipitate with excess of KI solution.
(B) Bottle 4 gives white precipitate with excess of K4[Fe(CN)6] solution.
(C) Bottle 1 and 4 both gives precipitate with excess of NaOH solution.
(D) Bottle 1 gives white precipitate with concentrated HCl solution.
8.64 Which of he following bottles develops intensive deep blue colour with aqueous ammonia?
(A) Bottle 1 (B) Bottle 2 (C) Bottle 3 (D) Bottle 4
8.65 Which of the following will give white precipitate with bottle 1?
(A) Bottle 2 (B) Bottle 3 (C) Bottle 4 (D) All of these
SECTION – VI : MATRIX – MATCH TYPE

8.66 There are certain chemical reagents which are used in the qualitative analysis of specific
acid i.e anionic radicals. Match the reagent listed in column (I) with acid radicals listed in
column (II).
Column I Column II
(A) Silver nitrate solution (p) Co32-
(B) Barium chloride solution (q) CO32-
(C) Lead nitrate solution (r) S2-
(D) Acidified potassium permanganate solution (t) NO2-
8.67 Column (I) contains some reagents which when taken in excess produce precipitate with
radical (s) given in column (II). Accordingly match the column (I) with column (II)
Column I Column II
(Reagent) (Radical)
(A) KCN (aq) (p) Pb+2
(B) NaOH (aq) (q) Ag+
(C) KI (aq) (r) Hg22+
(D) K2CrO4 (aq) (t) Cu2+
8.68 Match the reactions listed in column (I) with the colour of the precipitate(s) listed in column
(II).
Column I Column II
allow to
s tan d for
(A) Cu2+ (aq.) + 2SCN (aq) 
Sometime
 (p) Brown
H+
(B) Hot Bi3+ (aq.) + C6H3 (OH3)  (q) Brownish - red

(C) Ag+ (aq.) AsO43- (aq.)  (r) Yellow
(D) Mn2+ (aq.) + 2OH- (aq.)  air
 (s) White
8.69 Match the particulars given in column (I) with the appropriate chemical reagents given in
column (II)
Column I Column II
(A) Fe3+, Zn2+ & Cu2+ can be separated by (p) KI solution
(B) PbS, CuS and CdS dissolve in (q) Alkaline Na2SnO2 solution
2+
(C) Pb gives yellow precipitate with (r) 50% HNO3
(D) [Ag(NH3)2Cl gives black precipitate with (s) K2CrO4 solution
(t) Aqueous NH3
8.70 Match the colour of precipitates listed in column (I) with the reagent(s) listed in column (II).
Column I Column II
3+
(A) Bi gives black precipitate with (p) Saturated solution of H2S in water.
(B) Cu2+ gives black precipitate with (q) Potassium thiocyanate solution
2+
(C) Zn gives black precipitate with (r) Potassium iodide solution
+
(D) Ag gives black precipitate with (s) Potassium ferrocyanide solution
8.71 Match the salts listed in column (I) with the colour of the precipitate and reagent (s) listed in
column (II).
Column I Column II
(A) FeSO4 (p) Green precipitate with NaOH.
(B) Bi(NO3)3 (q) White precipitate with Ph(NO3)2.
(C) Ni(NO3)2 (r) Yellow precipitate with NH4NO2 and CH3COOH on warming
(D) CoCl2 (s) Black precipitate with H2SSodium peroxide
8.72 Match the precipitates listed in of the compounds listed in (I) with the solvent(s) listed in
column (II).
Column I Column II
(E) Zn(OH)2 precipitate dissolves in (p) Potassium cyanide
(F) Cr(OH)3 precipitate dissolves in (q) Ammonia
(G) AgCl precipitate dissolves in (r) Sodium hydroxide
(H) CuS precipitate dissolves in (s) Sodium peroxide
SECTION – VII : SUBJECTIVE ANSWER TYPE
SHORT SUBJECTIVE :
8.73 An alcoholic solution of dimethylglyxime is added to an aqueous solution of nickel (II) chloride.
Slow addition of ammonium hydroxide led to the precipitation of a bright-red coloured metal
complex. Find out the number of hydrogen bonds present in the structure of the complex.
8.74 Fe2+(aq) + NO3- (aq) + H2SO4 (conc.) Brown ring
The brown ring is due to the formation of complex, [Fe(H2O)5NO]SO4. What is the oxidation
state of iron in the complex?
8.75 CrO42- + 2H+ + 2H2O2 CrO5 + 3H2O
How many peroxide linkages are found in the structure of CrO5?
CrO42- + 2H+ + 2H2O2 CrO5 + 3H2O
8.76 An aqueous solution of contains Hg2+, Hg22+, Pb2+ and Cd2+. Out of these, how many ions
will produce white precipitate with dilute HCl?
8.77 A solution of Hg2+ ion on treatment with a solution of cobalt (II) thiocyanate gives rise to a
deep blue crystalline precipitate. The coordination number of mercury in the deep blue
coloured compound is:
LONG SUBJECTIVE :
8.78 A mixture of two inorganic salts gives following chemical reactivity:
(i) Mixture on reaction with dil. H2SO4 produces a colourless suffocating gas which turns
acidified potassium dichromate solution green.
(ii) Mixture on reaction with dil. H2SO4 gives reddish brown gas and on adding paper pellets
the evolution of reddish brown vapours becomes brisk.
(iii) Original solution of mixture gives white precipitate with dil. HCl which is soluble in
ammonium hydroxide forming a soluble complex. The soluble complex gives white
precipitate with HNO3 and yellow precipitate with KI solution.
(iv) The filterate obtained after separating the white precipitate also gives white precipitate
with H2S in presence of NH4OH & NH4Cl. The solution of white precipitate in dil. HCl
again gives white precipitate with excess of potassium ferrocyanide solution. Identify
the cations and anions present in the mixture.
8.79 A mixture consists (A) (yellow solid) and (B) (colourless solid).
(i) Mixture gives lilac colour in flame.
(ii) Mixture gives black precipitate on passing H2S which is soluble only in aquaregia.
(iii) Black precipitate soluble in aqua-regia, on adding SnCl2 gives grayish black precipitate.
(iv) The salt solution with NH4OH gives a brown precipitate.
(v) The sodium extract gives bright yellow precipitate with AgNO3, very slightly soluble in
concentrated ammonia.
Identify the cation and anion present in (A) and (B)?

Qualitative Analysis - 8

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Qualitative Analysis - 8

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8

8.9 Black precipitate of copper sulphide dissolves in:

SECTION – II – MULTIPLE CORRECT ANSWER TYPE

8.19 Which of the following statement(s) is (are) true?

8.23 Which of the following statement(s) is (are) incorrect?

8.24 Which of the following is (are) correctly matched?

8.27 Which of the following is / are correctly matched?

8.28 Which of the following statement(s) is (are) true?

SECTION – V : COMPREHENSION TYPE

8.56 The reddish brown precipitate formed in (a) reaction is of:

SECTION – VI : MATRIX – MATCH TYPE

(B) Hot Bi3+ (aq.) + C6H3 (OH3)  (q) Brownish - red

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