39.

Which of the following represents correctly the changes in thermodynamic properties during the
formation of 1 mol of an ideal binary solution :

+ Gmix + Gmix
TSmix Hmix
J mol–1 0 J mol–1 0
– Hmix – TSmix

(A) mole fraction (B) mole fraction

+ TSmix + TSmix
–1 Hmix –1 Gmix
J mol 0 J mol 0
– Gmix – Hmix

(C) mole fraction (D) mole fraction

40. FeCl3 on reaction with K4[Fe(CN)6] in aqueous solution gives blue colour.
These are separated by a semipermeable membrane AB as shown. Due
to osmosis there is :
(A) blue colour formation in side X.
(B) blue colour formation in side Y.
(C) blue colour formation in both of the sides X and Y.
(D) no blue colour formation.
0.1M 0.01M
K4Fe(CN)6 FeCl3

Side X Side Y

SPM
34. Dry air was passed successively through a solution of 5 g of a solute in 180 g of water and then through
pure water. The loss in weight of solution was 2.5 g and that of pure solvent 0.04 g. The molecular weight
of the solute is :
(A) 31.25 (B) 3.125 (C) 312.5 (D) None of these
32. The vapour pressure of pure benzene at 50°C is 268 torr. How many mol of non-volatile solute per mol of
benzene is required to prepare a solution of benzene having a vapour pressure of 167 torr at 50°C:
(A) 0.377 (B) 0.605 (C) 0.623 (D) 0.395
29. The freezing point of an aqueous solution of a non-electrolyte is –0.14°C. The molarity of this solution is
[Kf (H2O) = 1.86 K kg mol–1] :
(A) 1.86 m (B) 1.00 m (C) 0.15 m (D) 0.075 m
23. An azeotropic solution of two liquids has a boiling point lower than either of them when it :
(A) shows negative deviation from Raoult's law (B) shows no deviation from Raoult's law (C) shows p
22. In cold countries, ethylene glycol is added to water in the radiators of cars during winters. It results in :
(A) reducing viscosity (B) reducing specific heat
(C) reducing freezing point (D) reducing boiling point
17. An aqueous solution of NaCl freezes at –0.186°C. Given that kg mol–1 and kg mol–1, the elevation in
boiling point of this solution is :
(A) 0.0585 K (B) 0.0512 K (C) 1.864 K (D) 0.0265 K
14. A 0.2 molal aqueous solution of a weak acid HX is 20% ionized. The freezing point of the solutions is (k f
= 1.86 K kg mole–1 for water) :
(A) –0.45°C (B) –0.9°C (C) –0.31°C (D) –0.53°C
10. Which one of the following aqueous solution has the highest freezing point at 1 atm :
(A) 0.1 M urea (B) 0.1 M acetic acid (C) 0.1 M NaCl (D) 0.1 M BaCl2
7. The Van't Hoff factor 0.1 M La (NO3)3 solution is found to be 2.74 the percentage dissociation of the salt
is :
(A) 85 % (B) 58 % (C) 65.8% (D) 56.8%
1. When 0.6 g of urea dissolved in 100 g of water, the water will boil at (K b for water = 0.52 kJ. mol–1 and
normal boiling point of water = 100°C) :
(A) 373.052 K (B) 273.52 K (C) 372.48 K (D) 273.052 K
8. Maximum freezing point will be for 1 molal solution of (assuming equal ionisation in each case) :
(A) [Fe(H2O)6 Cl3] (B) [Fe(H2O)5Cl] Cl2.H2O (C) [Fe(H2O)4Cl2]Cl.2H2O (D)
[Fe(H2O)3Cl3].3H2O
8. In which case van't Hoff factor is maximum
a) KCl, 50% ionised
K 2 SO4 , 40% ionised
b)
c)
FeCl3 , 30% ionised d) SnCl4 , 20% ionised
30. What is the molarity of ethanol in a solution of 23% and 77% by weight?
a) 6.49 b) 3.25 c) 9.75 d) 4.65
38. The expression relating molarity (M) and molarity (m) of a solution is

m
M
m
M   MM 2   MM 2
m m
a)
  MM 2 b)
  MM 2 c) M d) M
60. The molecular weight of benzoic acid in benzene as determined by depression in freezing point
method corresponds to
a) ionization of benzoic acid b) dimerization of benzoic acid
c) trimerization of benzoic acid d) solvation of benzoic acid
0
70. The vapour pressure of pure liquid is 70 Torr at 27 C. The vapour pressure of a solution of this
liquid and another liquid(mole fraction 0.2) is 84 Torr at 270C. The vapour pressure of pure liquid
B at 270C is
a) 140 Torr b) 280 Torr c) 160 Torr d) 200 Torr
30. The amount of ice that will separate out on cooling the solution containing 50g of ethylene glycol
(CH2OH)2 in 200 g of water at -9.30C is (Kf for water = 1.86 kcal mol-1)
1) 276 g 2) 188 g 3) 138 g 4) 250 g
25. Two solutions of glucose have osmotic pressurses 1.5 and 2.5 atm. 1L of first is mixed with 2L of
second solution, the osmotic pressure of the resultant solution is
1) 0.65 2) 6.5 3) 65 4) 650
-1
1. The density (in g mL ) of a 3.6M sulphuric and solution that is 29% H2SO4 by mass will be

(AIEEE 2007)
1) 1.88 2) 1.22 3) 1.45 4) 1.64
10. The weight of KMnO4 that can oxidise 100 ml of. 0.2M oxalic acid in acidic medium is [MW of
KMnO4 = 158]
1) 1.58 g. 2) 1.264 g. 3) 12.64 g. 4) 15.8 g.
114. Two elements A and B form compounds having molecular formula AB2 and AB4. When dissolved in
20gm of benzene 1gm of AB2 lowers the freezing point by 2.3K, where as 1gm at AB4 lowers it by
1.3K, then atomic masses of A & B respectively. (Kf for benzene = 5.12 K.m–1)
1) 64.4, 128.2 2) 25.5, 42.6 3) 28.4, 64.9 4) 101.3, 186.5
86. At certain temperature, the solution of benzene in toulene exihibits the vapour pressure (in m bar)
representes as P = 150x +65, where 'x' is mole fraction of benzene, the vepour pressure of pure
benzene is
1) 150 m bar 2) 65 m bar 3) 90m bar 4) 215 m bar
79. In a mixture of A and B, components show negative deviation when (AIEEE-
2002)
1) A - B interaction is stonger than A-A and B - B interaction
2) A - B interaction is weaker than A - A and B - B interaction

3)
Vmix  0 , Smix  0 4)
Vmix  0 ,
Smix  0
57. Which of the following statement is correct about Henry’s law
1) It is applicable only when pressure is high
2) It is applicable only when temperature is very high
3) It is applicable only when gas reacts with the solvent
4) KH (Henry’s constant) is a function of the nature of the gas
62. The quantity of CO2 in 500ml of soda water when packed under 2.5 atm CO2 pressure at 298 k is
(Henry's law constant 1.67 x 108 pa at 298 k)
1) 0.64 gm 2) 1.86 gm 3) 6.4 gm 4) 18.6gm

47. The maximum allowable level of Nitrates in drinking water as set by U.S. is 45mg
NO3 ions per
dm3, the level in ppm is
1) 15 2) 30 3) 45 4) 60
44. The mole fraction of solvent in 0.1 molal aqueous solution is
1) 0.9982 2) 0.0017 3) 0.017 4) 0.17
24. 100 ml of 0.1N FeSO4 solution will be completely oxidised by ‘x’ gms of K2Cr2O7 in acidic
medium (Mol.wt = 294). The value of ‘x’ is
1) 4.9 2) 2.94 3) 0.49 4) 1.47