If you’ve ever been to the petrol kiosk, you’ll probably
recall seeing several choices of petrol you can pump –
usually 92, 95 or 98. I recall asking my mother about the number and my mom just told me that the higher the number, the better it is, the more you have to pay. What do those numbers mean and why does diesel not have them? To understand the numbers well, I need to first tell you a little more about the petrol engine. Both the petrol and diesel engines are internal combustion engines, which mean that the source of energy is combusted within the engine itself instead of externally (think steam engine, where coal is the source of energy to heat up steam in the engine, providing power). However, one important difference between petrol and diesel engines is that petrol requires a spark plug to ignite the air-petrol mixture at specific times whereas a diesel does not as it would self-combust at the right time when compressed, due to the mechanics of the engines which I shall not go into. The problem arises in the petrol engine when the compressed air-petrol mixture ignites by itself prematurely before the spark plug ignites it at the right time, causing it to explode/detonate in the combustion chamber (Taylor, 1985). This produces a knocking sound in the engine, thus this problem is called engine knocking. Knocking damages the engine because it causes a rapid pressure rise in the combustion chamber and deposits undesirable compounds in the engine, affecting the engine performance.
Photo taken from knocking-of-engines.blogspot.com
Petrol contains a mix of octane (hydrocarbons with 8 carbon atoms) and heptane (7 carbon atoms). The numbers 92, 95 and 98 refer to the octane rating of the petrol, or, the amount of octane there is in the petrol. The higher the octane rating, the less likely knocking will occur, because octane burns slower since it has longer- chained hydrocarbon and is more resistant to igniting prematurely. If you wanna find out more about the mechanics of the petrol engine, check out this video which explains it in relation to engine knocking pretty well: https://www.youtube.com/watch?v=8VWEwEveGT Q Also, just a fun fact to add on, in places that are higher altitude, where the air is thinner, gas stations tend to sell lower-octane rating petrol as ‘regular’ petrol because the petrol is less-likely to knock since there is less air for the petrol to auto-ignite before the spark plug ignites it (AAA, 2007). For example in Colorado which is about 1500m above sea level, ‘regular’ petrol has a rating of 85 whereas at most other US states, the lowest rating available is 87. In Singapore, the ‘regular’ rating is 92, which could be due to Singapore’s low-lying position as an island. The reason why I would likely to talk about octane rating is because in my following post, I would tell you guys about about why is leaded petrol being used in the past (yup it’s got to do with knocking) and the environmental consequences of leaded petrol. Stay tuned! Sources: AAA Colorado (2007) Gasoline octane levels in Colorado. EnCompass Online. 81(2). Retrieved 2014, October 12 from http://www.aaa.com/aaa/006/EnCompass/2007/mar/ mar_AutoTalk.htm Taylor, C.F. (1985) Internal Combustion Engine in Theory and Practice (2nd Ed.) Cambridge, MA: Massachusetts Institute of Technology Press
Have you heard of leaded petrol? In the 1970s, it was
widespread and almost all petrol used throughout the world was leaded petrol (Landrigan, 2002). Thankfully, nowadays it serves only as a reminder of a success of humankind in taking concrete steps to the environment. A quick recap on where I left off from last week, high octane ratings help to prevent engine knocking in high performance petrol engines, which is basically a mechanical difficulty car drivers would not wish to encounter. For more details do read my previous blog post on the numbers 92, 95 and 98 in the petrol kiosks which don’t seem to mean anything (to most people anyway)!
Tetraethyllead, or TEL, is a compound containing lead.
Starting in the 1920s, TEL was added to petrol as an additive due to its effective anti-knock properties, which allowed increased engine performance (Landrigan, 2002). However, there was a problem. The use of leaded petrol contributed to increased lead levels in the atmosphere, with the levels detected around the world increasing. The amount of lead in snow deposited on Greenland has risen sharply, being ~200 times higher in the mid 1960s than ancient times (Boutron et al., 1991).
Blood lead level also increased with that, as atmospheric
lead could enter the blood stream via inhalation (Schuhmacher et al., 1996). Lead is highly toxic to humans, affecting multiple organ systems even at low levels previously considered safe, as shown through epidemiological studies (Landrigan, 2002).
Lead enters the blood stream via inhalation or ingestion
and ingestion. A potent neurotoxin, high levels of exposure can lead to damage to almost all organs and systems, especially the nervous system, whereas low levels of exposure can affect psychological and neurobehavioural functions, and these are particularly pronounced in young children (Tong et al., 2000). Preschool lead exposure has even been linked to violent crimes due to its effect on mental functions (Needleman, 2004).
As health concerns and other issues such as evidence of
lead damaging catalytic converters of vehicles, which remove other toxic pollutants from exhaust, started surfacing and gaining public attention, governments around the world started phasing out leaded petrol in the 1990s, many eventually implementing a total ban by the late 1990s and early 2000s (Landrigan, 2002). This gradual phasing out of leaded petrol led to a decrease in mean blood lead level in the US and countries around the world, as seen from percentage of children with elevated blood lead levels falling significantly since 1997, a year after leaded petrol was banned (CDC, 2014). Anthropogenic lead levels found in snowfall in Greenland has since decreased also (Boutron et al., 1991), and some have even attributed decrease in violent crime rates in numerous countries in North America and Europe to the banning of leaded petrol since there was a correlation (Nevin, 2007).
Plans to protect air and water, wilderness and wildlife are
in fact plans to protect man. – Stewart Udall, American politician
Thanks to the phasing out of leaded petrol in the 1990s,
TEL in petrol has become a thing of the past, helping to reduce human exposure to atmospheric lead, improving the health of people worldwide. References:
M.A. & Delmas, R.J. (1991). Decrease in anthropogenic lead, cadmium and zinc in Greenland snows since the late 1960s. Letters to Nature. 353 (1996): 153-156
CDC (2014). National Surveillance Data (1997-2012).
Retrieved 2014, October 15 from http://www.cdc.gov/nceh/lead/data/national.htm Landrigan, P.J. (2002). The worldwide problem of lead in petrol. Bulletin of the World Health Organisation. 80(10)
Needleman, H. (2004). Lead poisoing. Annu. Rev. Med.
55, 209-222
Nevin, R. (2007). Understanding international crime
trends: the legacy of preschool lead exposure. Environmental research, 104(3), 315-336. Schuhmacher, M., Belles, M., Rico, A., Domigo, J.L. & Corbella, J. (1996) Impact of reduction of lead in gasoline on the hair and blood lead levels in the population of Tarragona Province, Spain, 1990-1995. The Science of the Total Environment 184:203-209