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INDIA
Sec: Sr.IIT-IZ-CO-SPARK Date: 23-05-15
Time: 9:00 AM to 12:00Noon WTM-7 Max.Marks: 360
IMPORTANT INSTRUCTIONS:
1. Immediately fill in the particulars on this page of the Test Booklet with Blue/Black Ball Point Pen. Use
of pencil is strictly prohibited.
2. The test is of 3 hours duration.
3. The Test Booklet consists of 90 questions. The maximum marks are 360.
4. There are three parts in the question paper A, B, C consisting of Chemistry, Physics, and
Mathematics having 30 questions in each part of equal weightage. Each question is allotted 4 (four)
marks for correct response.
5. Candidates will be awarded marks as stated above in instruction No. 4 for correct response of each
question. (1/4) (one fourth) marks will be deducted for indicating incorrect response of each question.
No deduction from the total score will be made if no response is indicated for an item in the answer
sheet.
6. There is only one correct response for each question. Filling up more than one response in any question
will be treated as wrong response and marks for wrong response will be deducted accordingly as
per instruction 5 above
Chemistry:
Compounds of Fe, Cu, Ag, Zn, Hg, QUALITATIVE ANALYSIS: Introduction, action of
heat, flame test, borax bead test, micro cosmic bead test, charcoal test,
Physics:
L-R circuits, L-C Oscillations with D-C source and eddy currents,AC: Definition of Mean
and RMS values, AC measuring devices, simple circuit involving AC source across only
resistor, only capacitor, only inductance (100%)
Mathematics:
Complete combinations,Problems on nCr,Division of different things into groups,number of
integral divisors (Avoid number of integral solutions,derangement)
Narayana IIT Academy 23-05-15_ Sr.IIT-IZ-CO-SPARK _JEE-MAIN_WTM-7_Q’Paper
CHEMISTRY
1. Anhydrous ferric chloride can be prepared
1) By passing dry chlorine gas over heated iron powder
2) By the dehydration of FeCl3.6H 2O with thionyl chloride
3) By treating the FeCl3.6H2O with 2,2-dimethoxy propane
4) By all the above three methods
2. Regarding copper (II) chloride the wrong statement is
1) It has layered lattice structure
2) The coordination number of copper in copper (II) chloride is six
3) All Cu-Cl bond lengths around copper in solid CuCl2 are equal
4) Copper (II) chloride is predominantly covalent
3. The false statement among the following is
1) Zinc oxide can be used as white pigment
2) By mixing syrupy zinc chloride solution with zinc oxide sets into hard mass
3) Burning of zinc in air gives philosopher’s wool
4) From solution zinc chloride crystallizes as ZnCl2.6H2O
4. In the flame test, the salt is mixed with conc. HCl. The function of acid is
1) to make a paste of the salt 2) to convert salt into volatile chloride
3) to make hydrated salt 4) to convert into non – volatile chloride
5. The salt which gives SO 2 and oxygen gases on heating is
1) CuSO 4 at 750 2) FeSO 4 .7H 2 O at 300C
3) Fe2 SO 4 on heating 4) ZnSO 4
space for rough work Page 2
Narayana IIT Academy 23-05-15_ Sr.IIT-IZ-CO-SPARK _JEE-MAIN_WTM-7_Q’Paper
6. Which is not correct about borax bead test?
1) NaBO2 and B2O3 is the composition of initial glassy bead formed on heating borax
2) coloured salt samples give positive test
3) borax swells due to loss of water of crystallization
4) to detect copper metal this test is used
7. The metal which cannot be identified in flame test is
1) Mg 2 2) Li 3) Ba 2 4) K
8. In the micro cosmic salt bead test with copper salt, the coloured product formed is
1) Cu BO 2 2 2) NaCuPO4 3) NaPO3 4) Cu 3 PO 4 2
9. The formula of Thenard blue is
1) CoMgO2 2) CoZnO2 3) Co AlO2 2 4) Co BO2 2
10. Which of the following forms precipitate by adding ammonia but do not dissolve in
excess of ammonia
1) AgNO3 2) CuSO 4 3) ZnSO4 4) Fe2(SO4)3
11. The salt which gives only oxygen gas on heating is
1) LiNO3 2) BaNO3 3) KNO3 4) Pb NO3 2
12. Which of the following form white or nearly white precipitate with K4[Fe(CN)6]
1) ZnSO4 2) FeSO4 3) AgNO3 4) All
13. The metal salt which gives red bead in charcoal cavity test is
1) SnCl2 2) CuSO 4 3) FeSO4 4) PbSO4
21. Which of the following does not give borax bead test?
1) Cu 2 2) Pb2 3) Cu 2 4) Mn 2
22. A reddish – pink substance on heating gives off a vapour which condences on the
sides of the test tube and the substance turns blue. If on cooling water is added to the
residue it turns to its original colour. The substance is
23. Which of the following gives blue bead in borax bead test:
1) Cr 2 2) Co2 3) Ni 2 4) Cd 2
25. A minute quantity of cupric salt when heated on borax bead in reducing flame on
Bunsen burner, the colour of bead after cooling will be
are
29. Which salt on heating does not give brown coloured gas?
30. Which of the following metal nitrate produces gaseous product contains 4 bonds and
3 bonds, when reacts with KCN?
1) Cu NO3 2 2) AgNO3 3) Cd NO3 2 4) Pb NO3 2
containing an ideal ac ammeter and a capacitor of capacitance 2F . The reading of the
ammeter will be
1) 10mA 2) 10 2 mA 3) 40 mA 4) 40 2 mA
32. In the circuit shown the cell is ideal. The coil has an inductance of 4H and zero
resistance. F is a fuse of zero resistance and will blow when the current through it
2R
R
L
2R
2E 5E E 3E
1) 2) 3) 4)
5R 11R 2R 8R
34. The current drawn by the cell in the above network a long time after the key is closed is
4E 5E 2E 3E
1) 2) 3) 4)
3R 8R 5R 5R
35. In the circuit shown in fig, switch S is shifted to position 2 from position 1 at t = 0,
having been in position 1 for a long time. The current in the circuit just after shifting of
switch will be (battery and both the inductors are ideal)
4E 5E 5E 5E
1) 2) 3) 4)
5R 4R 9R 9R
i12 i 22 | i1 i 2 | | i1 | | i 2 | i12 i 22
1) 2) 3) 4)
2 2 2 2
XC XC
1) n 2) n
XC XC
3) n 4) n
I V
t
IL IL
1) t 2) t
IL IL
3) t 4) t
L R
S
E
eEL R2 EL eEL
1) 2) 3) 4)
R 2 eEL eR 2 R2
42. The network shown in figure is part of a complete circuit. At a certain instant, the
current is 6A and is decreasing at the rate of 103 A / s . Then VA VB is
A 1 7mH B
12V
1) 13 V 2) 15 V 3) 25 V 4) 11 V
t0 t0 t0
1) t0ln 2) 3) 4)
ln 1
46. A simple LR circuit is connected to a battery at time t = 0. The energy stored in the
inductor reaches half its maximum value at time
R 2 L 2 1 L 2 R 2 1
1) In 2) In 3) In 4) In
L 2 1 R 2 R 2 1 L 2
10
0
t
10
10
1) 5V 2) 10 V 3) V 4) 6.37 V
2
48. Two inductors L1 and L 2 are connected in parallel and a time varying current i flows as
i1
shown. The ratio of currents at a given time t is
i2
L1
i1
i i
i2 L2
1
2
L 2 L L L2
1) 2 2) 1 3) 1 4)
L1 L2 L2 L1
R1 L
S
E
E E E R1 R 2 E
1) 2) 3) 4)
R1 R 2 R 1e R 1R 2 e R1 R 2 e
50. In the circuit shown, the steady state currents i1 and i 2 in the coils after the switch S is
closed are
i1 L1
i2 L2
S
E R
20V
R2
R1
1) 1 2)
R1 R 2 3)
R 1R 2
4)
R1 R 2
2
R 1R 2 R1 R 2 R2
this rate to remain constant at this value, the current will reduce to zero in a time
interval of
1
1) e 2) 3) 4) i0 1
ei 0 e
54. In the circuit of fig (1) and (2) are ammeters. Just after key K is pressed to complete
the circuit, the reading is
1) 25 Hz 2) 2000 Hz 3) 100 Hz 4) 50 Hz
A
B
E
L
s2
s1
CE CE
1) 2) CE 3) 4) 2CE
2 4
1 C C C
1) zero 2) E 3) E 4) 2E
2 L L L
60. After switch S2 is closed and S1 is opened, the maximum current through the inductor is
5C C C 3C
1) E 2) E 3) E 4) E
4L 2L L 2L
62. If n Cr denotes the number of combinations of n things taken r things at a time, then the
expression n Cr 1 n C r 1 2 n C r is
n 2 n 1
1) C r 1 2) Cr 3) n 1 C r 1 4) n2
Cr
63. The number of 6 digit numbers that can be made with the digits 1, 2, 3 and 4 and
having exactly two pairs of digits, is
1) 480 2) 540 3) 1080 4) 1240
10
64. The value of 40 C31 40 r C10 r is equal to
r 1
1) 64 2) 150 3) 56 4) 72
n n
1 r
66. If a n n then n
equal to
r 0 Cr r 0 Cr
n 1 1
1) a0 2) n.a n 3) n.a n 4) a n 1
2
75. The number of ways in which 900 can be resolved as a product of two factors is
1) 13 2) 14 3) 28 4) 30
76. A is a set containing n elements. A subset P of A is chosen. The set A is reconstructed
1) 2n 2) 22n 3) 3n 4) 32n
77. The number of ways in which a mixed double game can be arranged from amongst 9
married couples if no husband and wife play in the same game is
1) 1512 2) 3024 3) 9! 4) 216
78. A box contains 5 pairs of shoes. If 4 shoes are selected, then the number of ways in
which exactly one pair shoes obtained is
1) 120 2) 140 3) 160 4) 180
n 1
79. The value of n
Cr / n Cr n C r 1 equals
r 0
women and six men, if Mr. A refuses to serve on the committee if Mr. B is a member
and Mr. B can only serve, if Miss C is the member of the committee is
87. The number of ways to give 16 different things to three persons A, B, C so that B gets
16! 16!
1) 2) 4!5!7! 3) 4) None of these
4!5!7! 3!5!8!
88. Let A x1 , x 2 , x 3 ,..., x 7 , B y1 , y 2 , y 3 . The total number of functions f : A B that are
onto and there are exactly three element x in A such that f(x) = y2 is equal to
89. A man has three friends. The number of ways he can invite one friend everyday for
dinner on six successive nights so that no friend is invited more than three times is
90. The number of ways in which 8 non identical apples can be distributed among 3 boys
such that every boy should get at least 1 apple and at most 4 apples is