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Desalination
journal homepage: www.elsevier.com/locate/desal
A R T I C L E I N F O A B S T R A C T
Keywords: The integration of Multi Effect Desalination (MED) unit with and without Thermal Vapor Compression (TVC)
MED system into the Linear Fresnel Rankine Cycle (LFRC) was investigated for different seawater temperatures when
RO it is located at the regions with different solar radiation levels. A comparison was made between the fresh water
Linear Fresnel costs of the dual purpose LFRC/MED (or LFRC/MED/TVC) plants and the case when the MED and MED/TVC
Dual purpose plants
systems use direct steam of the LF solar field to produce fresh water (LF/MED & LF/MED/TVC). The water
Exergo-economic analysis
production costs of the described dual purpose plants were compared with that of the LFRC/Reverse Osmosis
Fuel price
(RO) plant (LFRC/RO). An exergo-economic analysis was performed to determine the water unit costs of the
plants. The results show that the fresh water costs of the LF/MED and LF/MED/TVC configurations are higher
than that of the dual purpose plants. Also, it was shown that the fresh water cost is more affected by solar
radiation level rather than seawater temperature of a region. It was also found that at fuel prices of 0.23$/m3,
the water production costs of fuel based dual purpose plants would be equal to that of the plants with solar
thermal source.
1. Introduction plants to reduce the fossil fuel consumptions in Iran. MED and RO
technologies are two major desalination technologies that are used in
Most of the power plants that are located next to the sea use Once- Iran. Please refer to [2] to find the water desalination technologies and
Through (OT) cooling method by running a large amount of water capacities that have been installed in Iran until 2014. Among all de-
through the condenser in a single pass and discharging it back into the salination plants in Iran, Qeshm water-power cogenerating is the only
sea. In these cases, the efficiency of the plants is depended on the sea dual purpose plant that utilizes the waste heat of a gas turbine to
water temperature. The integrating of the Multi Effect Desalination produce the fresh water in a MED system with water production rate of
(MED) unit to the steam power plants are one of the alternatives to 18,000 m3/day.
produce water and electricity. The water production rate and efficiency Several research works have been conducted on MED and MED/TVC
of dual purpose (electricity/water) plants are highly depended on the performances under different operational conditions [3–11]. The in-
seawater temperature. The higher seawater temperatures results in tegration of MED and MED/TVC units with solar Rankine cycles (SRC)
higher required heat transfer areas of the MED desalination unit to plants was investigated by Fiorenza et al. [12]. In that research, MED
produce specific amount of fresh water [1]. More than half of Iran's and RO desalination systems with different capacities were considered
international border of 4430 km is coastline, including 740 km along to be powered by Photovoltaic panels and solar thermal power plants,
the Caspian Sea in the north and 1700 km along the Persian Gulf and respectively. The water production costs of the PV/RO and SRC/MED
adjacent Gulf of Oman in the south (Fig. 1). Iran has started to decrease plants were determined as 2.05$/m3 and 2$/m3, respectively. The ap-
the fuel price subsidy and therefor the application of renewable energy plication of SRC/MED and SRC/RO plants for the Persian Gulf,
technologies have been received great attention during the recent years Mediterranean Sea and Red sea were investigated by Fichtner and DLR
by Iran government. Due attention to high annual Direct Normal Irra- [13]. The water and electricity costs of two dual purpose plants were
diance (DNI), especially in south of Iran, solar energy appears as the found to range from 1.8$/m3 to 2.1$/m3 and 0.21$/kWh to 0.24$/
most appropriate technology to be used as thermal source of the power kWh, respectively. Sharaf et al. [14] investigated two techniques for
⁎
Corresponding author at: P.O. Box 76175-133, Iran.
E-mail address: ameri_mm@mail.uk.ac.ir (M. Ameri).
http://dx.doi.org/10.1016/j.desal.2017.10.008
Received 14 July 2017; Received in revised form 2 October 2017; Accepted 4 October 2017
0011-9164/ © 2017 Elsevier B.V. All rights reserved.
I.B. Askari et al. Desalination 425 (2018) 37–67
desalination. In one technic the direct steam of the solar field was used plant is approximately 10% and 25% lower than that of the PTC/MED
to feed a MED/TVC unit. In another technique the electricity generated plant. Also, it was shown that because of the higher thermal efficiency
from the SRC plant was considered to be used as the power source of an of the PTC solar field as compared to the LF, the electricity and water
MED unit with Mechanical Vapor Compression (MVC) system. The production costs of both plants would be equal, if the capital cost of the
water production costs of the first and second techniques were found to PTC solar field would be decreased to 66% of its first cost assumption
be as 1.5$/m3 and 2.1$/m3, respectively. The integration of MED and (420$/m2). In another research, the authors of the present paper in-
RO units with SRC plants was investigated by Iaquaniello et al. [15]. vestigated the application of the LF solar field direct steam as the heat
The authors considered a case in which the low pressure output steam source of the MED/TVC [21]. The results of that paper shown that the
of the plant is used as thermal source of the MED unit. Also, the RO unit water production costs of the LF/MED/TVC system varies between
was assumed to be fed by the electricity generated from the SRC plant. 1.63$/m3 to 3.03$/m3 for the cases with no Thermal Storage System
That research has shown that increasing the lifetime of the described (TES) and 15 h of TES, respectively. The energy and exergy analysis of a
systems from 20 years to 30 years would result in decreasing the water polygeneration system was performed by one of the authors of the
production cost by about 8.8%. Moser et al. [16] investigated two de- present paper (Calise et al. [22]). The described system includes Con-
salination systems of RO and MED/RO powered by the fuel based and centrated Photovoltaic Thermal (CPT), biogas heater, absorption chiller
solar based steam plants. Different fuel price scenarios were used in the and an MED unit. An exergo-economic analysis was used in that work to
economical calculations of that research. The results of that study determine the fresh water, electricity, heating and cooling costs of the
shown that the water production cost of the RO and RO/MED systems so-called system. In another research by Calise et al. [23], a poly-
with fuel based steam power plants would be 0.85$/m3 and 0.80$/ generation system comprising geothermal well, PTC, Organic Rankine
m3,respectively. However, for the solar based power plants the water Cycle (ORC), MED and absorption chiller was investigated to determine
production cost were determined to be 1.22$/m3 and 1.1$/m3 for RO the water, electricity, cooling and heating energy costs of the system.
and RO/MED systems, respectively. Different combinations of the RO, An exergo economic model was used in that research work to determine
MED and MED/TVC systems with SRCs were investigated by Palenzuela the production costs of different products of the system. In that work,
et al. [17]. In that research, the SRCs were assumed to cool down by the cumulative exergy analysis of the plant for two periods during the
three cooling methods of dry, wet and once through. The results of that cold and hot seasons was applied instead of the instantaneous exergy
work shown that only for high salinities of seawater and high cooling analysis.
temperatures of the SRC condenser, the SRC/MED has lower water As it can be seed from the literature review, there are valuable re-
production costs as compared to the SRC/RO plant. The integration of a search works that address the integration of MED and RO systems with
MED/TVC unit with SRC plant was studied by Delgado et al. [18]. The SRC plants. However, to the best of our knowledge, the water pro-
output steam of high pressure and low pressure steam turbines duction costs of dual purpose SRC/MED, SRC/MED/TVC and SRC/RO
(4540 kPa and 362 kPa, respectively) of SRC plant were considered to plants have not been reported to be compared with that of the MED and
be used as the motive steam of the MED/TVC unit. The fresh water MED/TVC plants feed by direct steam of the solar field. Also, the de-
production rate of 10,000 m3/day with sweater temperature of 26 °C tailed investigation on the integration of MED/TVC unit into the SRC
was considered in that research. The integration of the MED/TVC unit plants has not been vastly investigated. Only in two references of
with different water production rates into a fuel based steam Rankine [18,19] the detailed analysis of SRC/MED/TVC plants were reported.
cycle was studied by Tamburini et al. [19]. The steam extracted from As it has been shown in [18], the described plant was considered at a
the steam turbines of the plant at different suction pressures were specific seawater temperature and for a specific water production rate.
considered to feed the MED/TVC unit. The results of that study revealed Also in [19], a fuel based Rankine cycle was considered and the GOR of
that the efficiency of the plant (38%) would be decreased to 21% when the MED/TVC plant was assumed to be constant for a specific seawater
the high pressure steam of the 4880 kPa is extracted from the high temperature. However, the seawater temperature has an important ef-
pressure turbine of the plant to produce 36,000 m3/day of fresh water fect on the GOR of the MED/TVC plant and consequently on the water
in the MED/TVC unit. A comparison between the Parabolic Trough production cost of the plant. In the present paper, three different sea-
Collector (PTC) base and LF base dual purpose SRC plants was con- water temperatures corresponding to the Mediterranean Sea, North
ducted by the authors of the present study [20]. The results of that work Australia coastlines and Persian Gulf seawater temperatures were
shown that the water and electricity production costs of the LF/MED considered in the calculations of the MED and MED/TVC plants. No
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I.B. Askari et al. Desalination 425 (2018) 37–67
considerable exergo-economic analysis on the SRC/MED, SRC/MED/ temperature of 26 °C and the results are useful for the regions located in
TVC and SRC/RO plants has been reported in the literature. Only, in the Mediterranean Sea. In another research conducted by Catrini et al.
reference [24] the authors performed a detailed exergo-economic [25], an exergo-economic analysis was performed to determine the
analysis on the SRC/MED and SRC/RO plants. However, the water electricity and water production costs of a fuel based Rankine cycle
production costs of that research were obtained for the seawater integrated with MED/TVC unit. In that research also the Mediterranean
39
I.B. Askari et al. Desalination 425 (2018) 37–67
seawater temperature was assumed as the operational conditions of the energy and exergy balances as well as the exergy efficiencies for each
MED/TVC plant. In the present paper, an exergo-economic analysis was component are presented in Table A1 (Appendix A). Also, for the MED
performed to determine the water production costs of the dual purpose unit, the governing equations of energy balance, exergy balance and
LFRC/MED, LFRC/MED/TVC, LFRC/RO and single purpose LF/MED exergy efficiency are shown in Table A2.
and LF/MED/TVC configurations. The unit costs of the electricity and
water for dual purpose plant and also the water production costs of one 2.1. Configuration A (LFRC/RO)
purpose plants were compared with each other for the plants located at
regions having different solar Direct Normal Radiation (DNI) levels and As it can be seen from Fig. 2, the resulting steam at temperature of
three different seawater temperatures of 26 °C, 31 °C and 36 °C. The 373 °C and pressure of 100 bar is introduced into the high pressure
water production costs of the described plants were determined for turbine and after two stages expansion, the output steam is flowed
three different capital costs of the MED unit. Also, the calculations of through the regenerator. The hot steam leaves the regenerator at high
the exergo-economic analysis were conducted for the plants with nat- temperature of 373.4 °C and it is flowed through the second turbine to
ural gas boiler heat source, and the water production costs of the plants be expanded into lower pressures. The low pressure steam turbine of
were determined under different fuel price scenarios. the plant has four extractions that are required to be used in three low
pressure Feed Water Heaters (FWHs) and deaerator. The final extrac-
2. System description tion pressure from the low pressure steam turbine is determined de-
pended on the seawater temperature and assuming the temperature
A regenerative 50 MWe SRC plant was selected based on the current difference of 8 °C between the seawater and once through cooling
commercial SRC plants like Andasol-1, in Spain [26]. The input and condenser.
output temperatures of the plant were considered as 373 °C and 256 °C,
respectively. Five main configurations of LFRC/RO (A), LFRC/MED 2.2. Configuration B1 (LFRC/MED)
(B1), LFRC/MED/TVC (C1 & D1), LF/MED/TVC (C2 & D2) and LF/MED
(B2) were considered as it is shown in Figs. 2 to 6. In the case of LFRC/ A process flow diagram of configuration B1 is shown in Fig. 3. This
MED/TVC, the heating steam was considered to be supplied by ex- configuration is similar to configuration A but with the difference that
tracting the steam from the high and low pressure turbines at two four extractions are taken from the low pressure turbine unlike the
different pressures of 4540 kPa (C2) and 362 kPa (D2), respectively. As typical five that are used in configurations A. The low temperature MED
it is shown in Figs. 2 to 4, the SRC plant comprises of six regenerative unit is replaced by condenser of the plant to be fed by the steam from
heat feeders (five numbers in the case of LFRC/MED) to preheat the the low pressure turbine outlet. In this case, the exhaust steam is con-
water before entering the solar field. The Direct Steam (DS) generated sidered to be extracted at a slightly higher pressure than the condenser
in the Linear Fresnel (LF) solar field was assumed to be used as the pressure of configurations A, as it must feed the MED unit at 70 °C
working fluid of the plant. The solar field with no Thermal Storage (31.2 kPa). It is necessary to mention that, the steam with 67.5 °C is
System (TES) was considered providing a solar share of nearly 20.50% flowed into the first effects of the MED unit considering the temperature
for all configurations. The other part of the plants heating requirements drop of 2.80 °C at each effect.
were considered to be supplied on natural gas boiler (NGB) back up.
Since, the governing equations in thermodynamic modeling of dual 2.3. Configurations C1 and D1 (LFRC/MED/TVC)
purpose configurations (A, B1, C1 and D1) are same with the exceptions
of RO and MED components, only for configuration A (LFRC/RO), the It can be observed from Fig. 4 (dashed lines to TVC) that two
40
I.B. Askari et al. Desalination 425 (2018) 37–67
possible steam extraction options (indicated as t8a and t4a) are as- totally six closed type feed water heaters are included in the SRC; one of
sumed as alternatives to supply the motive steam to the TVC system of which has drains pumped forward and the others comprise drains
the MED unit. These steam extractions (t8a and t4a) are respectively cascaded backward flows. Also, the plant has a direct-contact feed
assumed to be positioned at pressures of 4540 kPa and 362 kPa. The water heater, which serves as a deaerator. The steam with 67.5 °C is
amount of motive steam extracted to drive the TVC system may change flowed into the first effects of the MED unit and the output steam from
depending on the required fresh water that is considered in the calcu- the MED/TVC, which is sub-cooled water at 67.5 °C, is pumped and
lations. As it is clear from Fig. 4, similar to the case of configuration A, returned back into a mixing chamber. To have the same evaporative
41
I.B. Askari et al. Desalination 425 (2018) 37–67
effect areas for the MED/TVC and MED units, the temperature differ- configurations do not need the power block and their LF solar fields are
ences between the effects was considered to be constant and approxi- smaller than the dual purpose plants solar fields. For configuration B2,
mately equal as 2.80 °C for both cases of MED (B1) and MED/TVC the output steam of the LF field at the temperature of 70 °C and pressure
(C1 & D1) units. of 31.2 kPa is introduced into the MED first effect. Also, for the LF/
MED/TVC configurations (C2 & D2), the output steam from the LF solar
2.4. Configuration B2 (LF/MED), C2 and D2 (LF/MED/TVC) field at two high pressure/temperature scenarios of 362 kPa/140.5 °C
and 4540 kPa/259 °C are introduced into the TVC unit. The high
The MED and MED/TVC plants were considered to fed by the direct pressure motive steams (362 kPa and 4540 kPa) are flowed throw the
steam of the LF solar field. These cases are single purpose plants with TVC systems and their temperatures and pressures are decreased into
the only product of fresh water. Unlike the dual purpose plants, these the lower values of 70 °C and 31 bar.
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I.B. Askari et al. Desalination 425 (2018) 37–67
43
I.B. Askari et al. Desalination 425 (2018) 37–67
investigated and reported in the literature [1,6,9]. Also, the MED/TVC Table 1
unit with the TVC location at the last effect has been reported by many The main input data that are used in thermodynamic modeling of SRC plant.
researchers [1,3,4,5,8,10,11]. Therefore, only the formulations of the
Component Reference [28] Model
MED/TVC changing the TVC locations on the effects are shown in this
paper (Appendix A, Table A3). For both MED and MED/TVC systems, Turbine
the governing equations of mass and energy balances for each compo- High pressure turbine inlet 370 373
temperature (C)
nent of the system have been applied in the METLAB computer code.
High pressure turbine inlet pressure 9000 10,000
Since such balances are trivial and may be easily formulated, describing (kPa)
the model in details is not necessary. The same temperature difference High pressure turbine efficiency 85.5 85.5
of approximately 2.8 °C was set in the calculations applying the con- (%)
straints of entrainment and compression ratios (Eqs. (a80) and (a82), Low pressure turbine efficiency (%) 89.5 89.5
Appendix A) of Ra ≤ 4 and 1.8 ≤ Cr ≤, respectively [1]. Also, for each Extraction point pressures
location, depending on the seawater salinity (Xbn, Eq. (a63), Appendix), Extraction t8 (kPa) 4540 4540
Extraction t6 (kPa) 2060 2060
the allowable resultant salt concentration was set as a constant value. In
Extraction t5 (kPa) 875 875
the case of MED/TVC system, for each number of effects, by applying Extraction t4 (kPa) 362 362
the mass and energy balance equations for each component of the Extraction t3 (kPa) 122.4 122.4
system (Table A3), the calculations were made to determine the amount Extraction t2 (kPa) 34.6 34.6
of distillate changing the location of TVC unit from the last effect to the Pressure drop
middle effects. Please refer to [1,3–11] to find the detailed thermo- Extraction t8 (%) 2.5 3
dynamic modeling of MED and MED/TVC systems. The calculations of Extraction t6 (%) 3 3
Extraction t5 (%) 4.5 3
this part of the study were conducted to determine the proper sizes of
Extraction t4 (%) 3 3
the MED and MED/TVC systems when they are located in the regions Extraction t3 (%) 3 3
with three different sea water temperatures of 26 °C, 31 °C and 36 °C. Extraction t2 (%) 3.5 3
The maximum numbers of effects for both desalination systems was Reheating line (%) 11.5 11.5
considered as 12 numbers and for the regions with higher seawater Condenser pump P1
temperatures, the calculations were done to find the lower number of Isentropic efficiency 75 73.5
effects in order to keep constant the temperature differences between Electro-mechanical efficiency 98 –
the effects. The temperature difference between effects has a direct Feed water pump P2
impact on the size of the evaporator areas. For both MED and MED/TVC Isentropic efficiency 78 76.4
Electro-mechanical efficiency 98 –
units, the ratio between the distillate water and seawater mas flow rate
were determined to calculate the pumping power that is required to Low/high pressure closed feed water heaters
Terminal temperature difference 1.5 1.5
transfer the seawater to the plants. The GOR of the plants were de-
(C)
termined for different numbers of effects and different seawater tem- Drain cooling approach (C) 5.5 5.5
peratures. As it was formerly mentioned in the assumptions of the de-
Condenser
salination units, the maximum yearly seawater temperature was used in Condensing pressure (bar) 0.08 0.08
the calculations. Steam generator thermal efficiency 98 Direct steam generated
(%) from LF
3.2. LF solar field and dual purpose plants Total pressure drop (water side) 450 Direct steam generated
(kPa) from LF
Thermal efficiency (%) 38.21 38.98
System Adviser Model (SAM), a software developed by NREL, was
used to calculate the output thermal power of the LF solar fields [27].
For each region of the study, the hourly solar radiation data, tem- The LF solar field comprises of different numbers of Loops with a
perature data, wind speed data, latitude and longitude of that region total area of 6676.8 m2 for each loop. The specifications of the LF solar
are input into the SAM. The other parameters such as input temperature field are shown in Table 2. The total land area in Table 2, is sum of the
of the Heat Transfer Fluid (HTF) at the inlet of the solar field, the solar field required land area and the non-solar field land area which is
aperture area and operating pressure of the solar field are input into the considered for the distances between each loops of the mirrors and also
software to calculate the output temperature of the steam generated by other facilities such as power block and so forth. The total solar field
solar field [20,21]. The thermodynamic modeling of the plants was required land area is determined by multiplying the LF aperture areas
developed in EES (Engineering Equation Solver). The net electricity by non-solar field multiplier, which was considered as 1.4 in the present
generation of all plants was considered as 50 MWe, and the thermo- work [27].
dynamic property of the plant model was set based on the SRC plant
that has been reported in [28] with the exception of the plant top 3.3. Energy and exergy model
pressure which was considered as 10,000 kPa (Table 1). Since the
thermodynamic modeling formulations of the plant is trivial and rather In order to investigate the thermodynamic behavior of the plants,
than standard, describing the model in details is not necessary. As it can and to determine the amount of thermal energy that is wasted in each
be seen from Table 1, there are six steam extraction from two steam
turbines of the plant two of which were chosen as the high and low Table 2
pressures (4540 kPa and 362 kPa) to be used as the motive steam of the Geometrical and optical parameters of LF solar fields.
MED/TVC system in the calculations of the present study. The outputs
Design parameter LF solar field
of SAM and EES, which are the required thermal loads of the plants,
mass flow rates of Rankine cycles and solar fields, gross and net elec- Alignment North–South
trical works of the plants as well as water production rates, were used in Reflective aperture area (m2) 513.6
MATLAB to calculate the required aperture areas of the LF solar field Length of collector module (m) 44.8
Focal length (m) 7
providing the solar share of 20.5% for the all plants and based on a
Solar field area (m2) 1× (total aperture area (m2))
simple optimization method that has been presented in the previous Total land area (m2) 1.4× solar field area (m2)
work of the authors [20].
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I.B. Askari et al. Desalination 425 (2018) 37–67
component of the plants, the respective calculations were performed for Ẇnet = ẆGross − ẆPumps − Ẇdes (6)
the inlet and outlet enthalpies, exergies, mass flow rates, pressures and
temperatures. Exergy destructions were calculated to determine the WPumps is the required powers of the condenser, feedwater, on-
plant irreversibilities. For each component of the plants, the mass, en- cethough cooling and sewater intake pumps. Wdes is the required power
ergy and exergy balances were applied based on the inlet and outlet that is consumed in MED, MED/TVC or RO desalination plants. Ė fresh is
thermodynamic properties. The calculations were developed in EES the chemical exergy flow associated with the produced fresh water that
making the following assumptions: was calculated based on the minimum theoretical work of separation
required in any reversible desalination process using the following
• Solar field supplies only 20.5% of the plants required annual Ė fresh = ṄFresh × ∅ × Ru × T0 × X s,feed (7)
thermal loads.
• Because the NGB is used as the backup system, the inlet and outlet where, ṄFresh is the molar flow rate of product freshwater that is defined
as follows:
temperatures of the plants are constant.
• The changes in the kinetic and gravitational terms in the energy and ṄFresh =
ṁ fresh
=
ṁ 15
exergy balances are negligible. MMwater MMwater (8)
• The turbines and pumps efficiencies and the pressure losses in heat ∅ in Eq. (7) represents the dissociation factor of salts (equal to 2 for
exchangers and the pipelines were applied according to the speci-
fications that are shown in Table 1. sodium chloride), Ru is the universal constant of gases, and Xs, feed is the
• The MED or MED/TVC units were considered as a component with molar fraction of the dissolved salts that was calculated using the fol-
lowing formulation:
specific inlet and outlet flow rates.
• The reference (dead) state temperature was considered to be 2 °C X s,feed = (TDSSeawater × MMwater )/(MMNACL ) (9)
greater than the seawater temperature.
• The once through cooling temperature was considered to be 8 °C where, TDSSeawater is the salinity of seawater in terms of milligram salt
per each liter of water that differs for different seawaters across the
greater than the seawater temperature.
• For SRC/RO and SRC/MED/TVC plants that include once through world (0.035 g/L to 0.048 g/L). MMwater and MMNACL are the molecular
mass of water and salt that are equal to 18 kg/kmol and 58.5 kg/kmol,
cooling condenser, the specific water flow rate of 87 m3/MWh was
considered to exhaust the vapor extracted from the steam turbine respectively. For the seawaters with the salinities of 0.038 g/L
[29]. (38,000 ppm) and 0.07 g/L (70,000 ppm), Xs, feed (Eq. (7)) is obtained
• For all cases, the desalination plants (MED, MED/TVC and RO) were as 0.01160 and 0.02154, respectively.
considered to be near the sea with the maximum distance of 2.5 km.
4. Exergo-economic model
For all components of the plants, the majority of components doesn't
involve the chemical exergy considering that the working fluid of the Exergo-economics is usually used for systems with steady or quasi-
plants dose not undergone any change in the chemical compositions. steady operating conditions. The following formulation of cost balances
However, in the desalination units some important chemical processes was used in the present study:
occur, and chemical exergy must be taken into account in exergy bal-
∑ c i ∙Eẋi + Ż unit = ∑ c j∙Eẋj
ances [23]. The physical exergy of each state point can be calculated i ∈ {inlet} j ∈ {outlet} (10)
using following equation:
where, Eẋi and Eẋj are the inlet and outlet exergy powers of the stream
Eẋ = ṁ ∙ [(h − h o) − T0 ∙ (s − s 0)] (1) at inlet and outlet of a component, respectively, which are expressed in
For each component of the plant, the equation of the exergy de- kWex or kJex . ci and cj are the exergetic unit cost ($/kWh) at the inlet and
h
struction rate, Ėd , can be expressed as: outlet of a component, respectively. This approach inherently assumes
that instantaneous or average hourly exergy flows maintains constant
Ėd = ∑ Exin − ∑ Eẋ out − Ẇ (2) throughout the operating period, and has been proven reliable for ap-
plication in large power plants. Ż unit is the cost rate of the capital in-
where, Exin and Exout refere to the input and output exergy of a com- vestment and the operation and maintenance (ŻO & M) of each compo-
ponent, respectively. nent which is calculated as follows:
The following equations were used to determine the energy and
j=N
exergy efficiency of the plants at the hours with maximum solar ra-
Ż unit = ŻCapital,unit + ∑ ŻO & M, unit
diation level for each location:
j=1 (11)
Ẇ
ηI = net where, N is the life time of the project. Ż unit can be calculated as the
Q̇s (3) levelized cost divided per the number of hours of annual operation by
applying the Capital Recovery Factor (CRF) as follows:
Ẇnet + Ė fresh
ηII =
Ėin,SF (4) ŻCapital,unit ∙CRF + ŻO & M,
Ż unit =
unit
⎛$⎞
8760 ⎝h⎠ (12)
where, Ėin,SF is the inlet exergy to the system that is the function of the
sun's outer surface temperature (Ts = 5800 K) and defined as follows i. (1 + i) N
[30]: CRF(i, N) =
(1 + i) N − 1 (13)
4
4 T T
Ein,SF = Afield ∙DNI × ⎛⎜1 − ⎛ 0 ⎞ + ⎛ 0 ⎞ ⎞⎟
⎜ ⎟ ⎜ ⎟
where, i and N are the real interest rate (6%) and life time of the project
⎝ 3 ⎝ Ts ⎠ ⎝ Ts ⎠ ⎠ (5) (25 years), respectively. Eq. (10) can be written in terms of cumulative
exergy flows over a yearly period as follows:
where, DNI is Direct Normal Irradiance, and Afield is the LF apperture
area. Ẇnet is the total net power of the plant that is obtained by sub- ∫period Ci ∙Ei + ∫period Ż unit = ∫period Cj∙Ej̇ (14)
tracting the parasitic powers from total gross power generated by the
plants using the following equation: Considering the application of NGB back up system, the inlet and
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I.B. Askari et al. Desalination 425 (2018) 37–67
Table 3 Z͠ unit = 8760 × Ż unit = ŻCapital,unit ∙CRF + ŻO & M, unit (16)
Different cost parameters of the Linear Fresnel solar field, MED desalination unit
[13,27,33,34]. As mentioned formerly, the solar fields were considered to supply
20.5% of total annual thermal requirements of the plants during the
MED or MED/TVC
year hours. Therefore, the exergy costs of the inlet and outlet stream
Direct costs (DC)
Main investment ($/m3/day) 1240 to 1800 should be calculated based on solar and NGB thermal sources. It is
Post-treatment plant ($/m3) 120 evident that the exergy costs corresponding to the solar thermal source
Open sea water intakes ($/m3) 313 is high as compared to the fuel base thermal source. The following
Drinking water storage and pumping 100
equations were used to determine the solar field and NGB inlet and
($/m3)
Indirect costs (IC)
outlet exergy costs, respectively, for the hours with pick solar radiation
Freight & insurance rate during 5.00% DC and for night hours when the NGB supplies the thermal loads of the
construction plants:
Owner's cost rate 10.00% of direct material and
labor cost solarshare × 8760 × Csin ∙Ein + Z͠ LF = solarshare × 8760 × CSout ∙Eout (17)
Contingency rate 10.00% of DC
Construction overhead (interest during 12.24% of DC f
NGBshare × 8760 × Cin ∙Ein + Z͠ NGB = NGBshare × 8760 × Cout
f
∙Eout
construction)
Operation costs (OC) (18)
Electricity costs ($/m3) Depending on electricity cost
where, solarshare and NGBshare are the percentage of solar share and
(assuming: 1.55 kWh/m3)
Spare parts replacement 1.5% of total DC NGB share which were considered as 20.5% and 79.5%, respectively, in
Chemical cost of product water ($/m3) 0.04 the present work. Also, Couts and Coutf are the exergy unit costs of the
Insurance 0.5% of total DC solar field and NGB outlet streams, respectively. The main aim of the
Natural Gas auxiliary boiler costs ($/m3) 0.02 to 0.8 present work is to determine and compare the exergy costs of the
Labor cost of product water ($/m3) 0.025
electricity and fresh water streams for the plants with solar field
RO thermal source. However, at the final part of this research, the afore-
Direct costs (DC)
mentioned costs were calculated for the plants with fuel based thermal
Main investment ($/m3/day) 900
Pretreatment plant ($/m3) 250 source. The initial capital costs, operation & maintenance costs and
Post-treatment plant ($/m3) 120 other relevant costs, which were used n the calculations of the present
Open sea water intakes ($/m3) 313 paper, are shown in Table 3.
Drinking water storage and pumping 100
($/m3)
Wastewater collection & treatment 50 5. Results and discussions
($/m3)
Indirect costs (IC) At the first part, the thermodynamic modeling of MED and MED/
Freight & insurance rate during 5.00% DC
TVC systems was conducted. Then, the results were used in the ther-
construction
Owner's cost rate 10.00% of direct material and modynamic modeling of the whole plants; which were done using the
labor cost calculations of EES program. The output results of EES were input in
Contingency rate 10.00% of DC MATLAB to calculate the required solar field area supplying 20.5% of
Construction overhead (interest during 12.24% of DC total annual thermal load of each plant that were assumed to be located
construction)
at the specific locations of the study.
Operation costs (OC)
Electricity costs ($/m3) Depending on electricity cost
(assuming: 3.5 kWh/m3 to 5.1. MED and MED/TVC thermodynamic modeling results
5.5 kWh/m3)
Spare parts replacement 1.5% of total DC
Chemical cost of product water ($/m3) 0.04
In order to have a proper comparison between the plants with MED
Insurance 0.5% of total DC and MED/TVC units, the evaporator surface areas of these units should
Natural gas auxiliary boiler costs ($/m3) 0.02 to 0.8 be same in the technical and exergo-economical calculations of the
Labor cost of product water ($/m3) 0.05 plants. The surface areas of the MED and MED/TVC units play an im-
Solar field, NGB and power block portant role in the unit costs of the water as it was mentioned formerly.
Direct costs (DC) Two programs were developed in MATLAB to determine the GOR of
Site improvement ($/m2) 20
MED and MED/TVC units when it is located in the regions with three
Solar filed ($/m2) 108, 144 and 180
HTF system ($/m2) 35
different seawater temperatures (26 °C, 31 °C and 36 °C). In order to
Thermal Storage System ($/kWht) 77 insure the accuracy of the MED unit thermodynamic model, the results
Contingency rate 10.00% total DC were compared with that reported in [35]. The input parameters that
Power block (PB) ($/kWh) 1540 were used in the calculations of the model are shown in Table 4. The
NGB (million $/MWht) 0.12
main outputs of the model are GOR, evaporative specific areas of the
Indirect costs (ID)
Design and construction 15% of total DC effects, condenser surface area and the specific cooling water flow rate
Land cost ($/m2) 10 (SMcw). The results from the validation are shown in Table 5. It is ne-
Insurance 1% of total DC cessary to mention that in order to match the performance parameters
of the present model with that is presented in reference [35], the total
heat transfer areas of the effects, condenser and preheaters were set as
outlet exergy of the components are constant during the year hour
constant in the model. As it can be seen from Table 5, there is a good
(8760 h). Therefore, the above equation can be written as follows:
agreement between the results of the present model and Darwish et al.
model [35]. It is important to note that in Darwish et al. model [35], the
8760 × Ci ∙Ei + Z͠ unit = 8760 × Cj ∙Ej (15)
specific surface area of the MED unit (SA) was calculated as 184 m2/kg/
s of D excluding the condenser heat transfer area. The present model
where, Z͠ unit is the yearly cost rate of the capital investment and the
operation & maintenance. Z͠ unit is obtained from the following equation results shown that considering the condenser heat transfer area, the SA
by using Eq. (12): would be obtained as 233 m2/kg/s of D.
Table 6 shows the results of the thermodynamic modeling of MED
46
I.B. Askari et al. Desalination 425 (2018) 37–67
Table 4 temperatures. In Table 6, the specific cooling water flow rate (SMcw) is
Input data in the MED system thermodynamic model [35]. the ratio between the distillate and intake seawater mass flow rates. We
used this ratio in the calculations of the seawater pumping power. It is
Design parameters Values
necessary to mention that SMcw ratio is different from the ratio between
Effects specific heat (Cp) (kJ/kg) 4 the distillate and feed water mass flow rates; which is approximately
Distillate (kg/s) 94.39 equal to 0.35 for the MED desalination process.
BPE (°C) 1
Similar calculations were conducted to determine the performance
Latent heat of the vapor inside the effects (λ) (kJ/kg) 2333
Seawater cooling temperature (TSW) (°C) 26 parameters of MED/TVC unit based on the formulations that are shown
Condenser temperature (°C) 35 in Appendix A, Table A3. The thermodynamic modeling of the MED/
Seawater salinity (ppm) 45,978 TVC unit has been vastly investigated in the previous literature. How-
Resultant brine salinity (ppm) 72,000 ever, with the exception of the research works that have been reported
Heating steam (kg/s) 72.8
in [11,18], most of the previous works are related to the MED/TVC
Heating steam temperature (Tc) (°C) 70
First effect Brine temperature (Tb) (°C) 65 systems with the TVC unit located after the last effect of the MED
Total heat transfer coefficients of the effects, preheaters and condenser 3 system. The parametric study of MED/TVC units reported in [18] has
(U) (kW/m2 °C) been conducted for seawater temperature/salinity of 26 °C/38,000 ppm
Numbers of effects (n) 6
and for MED/TVC motive steam pressures of 362 kPa, 875 kPa,
2060 kPa and 4540 kPa. In the present work, similar modeling was
conducted for two different heating steam pressures of 362 kPa and
Table 5
Comparison between the results obtained from the present model and Darwish et al. 4540 kPa and for three seawater temperatures/salinity of 26 °C/
model [35]. 38,000 ppm, 31 °C/35,000 ppm and 36 °C/46,000 ppm. The low and
high motive steam pressures of 362 kPa and 4540 kPa can be extracted
Results Present work Darwish et al. [35] from the low pressure and high pressure steam turbines of the SRC plant
Feed water mass flow rate (kg/s) 1107 1090 as it was formerly shown in Table 1. For the first, the model results were
GOR 5.46 5.40 compared with the results reported in [18]. The validation results and
Specific cooling water flow rate (SMcw) 8.22 7.78 design parameters that were used in the modeling of the MED/TVC are
SA (m2/(kg/s of distillate)) 191 184 shown in Table 7. As it can be seen from Table 7, the results are in a
Condenser heat transfer area (m2) 9827 9448
good agreement with the results that have been presented in reference
[18].
Table 6 The same assumptions were made for thermodynamic modeling of
MED system specifications for different seawater temperatures. MED/TVC desalination plant as in the case of MED unit. Three different
seawater cooling temperatures were considered with different numbers
Location Persian Gulf Indian Mediterranean sea of effects for MED/TVC unit. Table 8 shows the results of thermo-
Ocean
dynamic modeling of MED/TVC unit with motive steam pressure of
Seawater salinity (ppm) 46,000 35,000 38,000 4540 kPa and for three different seawater temperatures and salinities.
Resultant brine salinity (ppm) 72,000 63,000 66,000 As it can be seen from Table 8, the specific heat transfer areas (SA) of
Numbers of effects (n) 10 11 12 the systems are approximately equal to that are obtained for the MED
GOR 8.50 9.41 9.78
units (Table 6). The comparison between the GORs of MED and MED/
Heating steam flow rate (kg/s) 8.01 7.22 6.95
Heating steam temperature (Ts) 70 70 70 TVC units shows that the GORs of MED/TVC units are nearly 55% more
(°C) than that of MED unit. Also, as it can be seen in Tables 6 and 8, the total
Effects temperature difference 2.86 2.83 2.83 heat transfer areas of the MED and MED/TVC units are obtained as
(°C)
nearly equal to 35,400 m2 by multiplying the specific areas of the ef-
Seawater cooling temperature 35.9 30.9 25.9
(TSW) (°C)
fects (SA) by distillate mass flow rates. Table 6 shows that the specific
Last effect temperature T(n) (°C) 41.65 39.15 36.36 cooling water flow rate (SMcw) of MED units are lower than that of
Condenser temperature 3.76 6.25 8.46 MED/TVC units, which means for a specific distillate mass flow rate,
difference for Mc (°C) the MED units required more seawater intake flow rates than the MED/
First effect temperature T(1) 67.5 67.5 67.5
TVC units. Also, as it is shown in Tables 6 and 8, the motive steam flow
(°C)
Distillate (kg/s) 59.46 65.91 70.54 rates of the MED/TVC units are approximately 55% lower than the
SA (m2/(kg/s of distillate)) 520.43 520.75 520.90 heating steam flow rates of the MED units. The results of this part of the
Specific cooling water flow rate 0.070 0.127 0.189
(SMcw)
Table 7
Mathematical model predictions against of Trapani desalination unit.
system that were derived from the MATLAB program. The seawater
Variable Reference [18] Model
temperature/salinity of Mediterranean sea, north Australia (Indian
Ocean) and Persian Gulf were considered as, respectively, 26 °C Number of effect 12 12
(38,000 ppm), 31 °C (35,000 ppm) and 36 °C (46,000 ppm) in the pre- Optimum effect for TVC location 11 11
sent study. As it can be seen from Table 6, for the effect temperature Seawater salinity (ppm) 40,000 40,000
differences of approximately 2.8 °C, the specific area (SA) of MED plant Seawater concentration at output (ppm) 65,900 65,900
Motive pressure Ps, kPa 4540 4540
is obtained as constant for two different seawater cooling temperatures. Seawater cooling temperature (TSW) (°C) 25.9 25.9
In the calculations of the LFRC/MED plant, the MED unit was assumed Motive steam temperature (TMS) (°C) 70 70
to have a same SA for different seawater temperatures. As it can be seen Top brine temperature (T1) (°C) – 67.5
from Table 6, the MED plants for three regions should have different Minimum brine temperature (Tn) (°C) 37 37
Feed sea water temperature to nth effect (Tf) (°C) 35 35
numbers of effects to keep constant their evaporative surface areas. For
Feed sea water temperature to 1st effect (Tf1) (°C) 60 60
the regions with lower seawater temperatures, the required heating Temperature drop per effect (ΔT) 2.7–2.8 2.77
steam flow rate is lower, the numbers of effects are higher and conse- GOR 14.66 15.00
quently the GORs are higher than the locations with higher seawater SA (m2/(kg/s of distillate)) 523.46 520.52
47
I.B. Askari et al. Desalination 425 (2018) 37–67
The higher GOR of the MED/TVC plant results in lower required intake 14 520
seawater mass flow rate to produce each unit of fresh water as com-
13.5
GOR
pared to the MED unit. This is why the ratio of distillate to cooling
510
seawater mass flow rate (SMcw) for the MED/TVC units are higher than
13
that for the MED units. Table 9 also shows that the percentage differ-
ence between the GOR of MED/TVC and MED units are varied de- 12.5 500
pending on the seawater temperature and suction pressure. For in- Pm=4540kPa, SA
stance, the GOR of the MED/TVC system with suction pressure of 12 Pm=362kPa, SA
362 kPa is higher than that of the MED system by about 41.88%, 490
Pm=4540kPa, GOR
37.83% and 36.90% for sweater cooling temperatures of 36 °C, 31 °C 11.5 Pm=362kPa, GOR
and 26 °C, respectively. These percentages are higher than the men-
11 480
tioned values for the suction pressure of 4540 kPa; about 61.22%, 5 6 7 8 9 10 11 12
55.31% and 53.61% for sweater cooling temperatures of 36 °C, 31 °C Thermocompresor Location
and 26 °C, respectively. Parts of the results (Table 9) such as GOR, SMcw,
Fig. 9. GOR and SA for sea water cooling temperature of 26 °C.
seawater cooling temperature and suction pressures were used in the
48
I.B. Askari et al. Desalination 425 (2018) 37–67
15.5 540 40
15 38
530 36
14.5
34
SA(m2/kg/s of D)
32
13.5
GOR
30
510
13 28
26
12.5 500
Conf#A(3.5 kWh/m )
3
Pm=4540kPa, SA 24 3
Conf#A(5.5 kWh/m )
12 Pm=362kPa, SA Conf#B1(1.5 kWh/m )
3
22
Pm=4540kPa, GOR 490 Conf#B1(2.5 kWh/m3)
11.5 Pm=362kPa, GOR 20 Conf#C1(362 kPa, 1.5kWh/m3)
3
Conf#C1(362 kPa, 2.5kWh/m )
3
11 480 18 Conf#D1(4540 kPa, 1.5kWh/m )
5 6 7 8 9 10 11 3
Conf#D1(4540 kPa, 2.5kWh/m )
16
Thermocompresor Location 10000 20000 30000 40000 50000
3
Fig. 10. GOR and SA for sea water cooling temperature of 31 °C. Fresh water rate (m /day)
Fig. 12. Once through cooling temperature 34 °C (TSW = 26 °C).
15.5 540
Pm=4540kPa, SA
15 40
Pm=362kPa, SA
Pm=4540kPa, GOR 530 38
14.5 Pm=362kPa, GOR
36
SA(m /kg/s of D)
14 520
34
Energy efficiency (%)
13.5
GOR
32
510
13 30
2
28
12.5 500
26
12 Conf#A(3.5 kWh/m )
3
490 24 3
Conf#A(5.5 kWh/m )
3
11.5 22 Conf#B1(1.5 kWh/m )
3
Conf#B1(2.5 kWh/m )
11 480 20 Conf#C1(362 kPa, 1.5kWh/m3)
5 6 7 8 9 10 3
Conf#C1(362 kPa, 2.5kWh/m )
3
Thermocompresor Location 18 Conf#D1(4540 kPa, 1.5kWh/m )
3
Conf#D1(4540 kPa, 2.5kWh/m )
Fig. 11. GOR and SA for sea water cooling temperature of 36 °C. 16
10000 20000 30000 40000 50000
3
Fresh water rate (m /day)
(30.78%). By increasing the electricity consumptions of MED unit from
1.5 kWh/m3 to 2.5 kWh/m3, the electricity efficiency of configuration Fig. 13. Once through cooling temperature 44 °C (TSW = 36 °C).
B1 would be decreased by about 2.2%. Configuration A with RO de-
salination unit has the highest electrical efficiency among four plants extracted steam of the plants at high pressure of 4540 kPa, has the
even with the electricity consumptions of 5.5 kWh/m3 in RO unit. Also, lowest electrical efficiency among four configurations. The results of
as it is clear from Figs. 12 and 13, configurations D1, which uses the Figs. 12 and 13 show that for the constant electricity generation rate of
Table 9
The specifications of the MED and MED/TVC systems for different seawater cooling temperatures.
Desalination Suction GOR TVC Number Effects Seawater Last effect Condenser First effect SA (m2/(kg/ Specific
system pressure location of effects temperature cooling temperature temperature temperature s of cooling
(kPa) difference °C temperature (°C) difference for (°C) distillate)) water flow
(°C) (°C) rate (SMcw)
49
I.B. Askari et al. Desalination 425 (2018) 37–67
50 MWe, configurations C1 and D1 with water production rates of Direct Normal Irradiance (DNI) of respectively 2700 kWh/m2 and
27,000 m3/day and 21,000 m3/day, respectively, have the same elec- 1990 kWh/m2. For configurations A, C1 and D1 the condenser cooling
trical efficiency of approximately 30.5% as configuration B1 with water temperature were considered to be 8 °C more than the seawater tem-
production rate of 40,970 m3/day for sweater temperature of 26 °C. peratures for all locations. Please refer to reference [37] to obtain the
Also, for seawater temperature of 36 °C, the electrical efficiency of seawater temperature of any location around the world.
configurations C1 and D1 with water production rates of 22,000 m3/ The required aperture areas of the LF solar field can be calculated by
day and 16,000 m3/day, respectively, are equal to that of configuration using the solar radiation data of a specific location, mass flow rate and
B1 with fresh water production rate of 34,660 m3/day. required thermal energy of the plants. The calculations were done for
The results of Figs. 12 and 13 show that the electrical efficiency of solar share of 20.5% as it was mentioned formerly. Fig. 16 shows the
configuration A is higher than that of configuration B1 with MED unit. percentages of solar share and defocused fraction for the LF solar fields
In some cases where the once through cooling temperature of LFRC/RO of configurations A, B1, C1 and D1 located in Kish Island with seawater
plant is high, the electrical efficiency of configuration A would be de- temperature of 36 °C and total annual DNI of 2300 kWh/m2. The total
creased to a value close to that of configuration B1. The variations in annual defocused thermal energy is defined as the total annual solar
electrical efficiency of configurations A and B1 versus the fresh water thermal energy that is wasted by defocusing the solar field mirrors to
production rate of these two dual purpose plants are shown in Figs. 14 prevent the overheating of the plant. The defocused fraction was de-
and 15 for the once through cooling temperatures of 52 °C and 57 °C, fined as the ratio of total annual defocused solar thermal energy to the
respectively, in the condenser of configuration A. The cooling tem- total annual required thermal energy of the plant [21]. The LF solar
peratures of 52 °C to 57 °C are commonly used in the conventional field comprises of different numbers of loops with aperture area of
steam plants that are operating within the Persian Gulf. As it is shown 6676.8 m2 for each loop. As it can be seen from Fig. 16, depending on
in Figs. 14 and 15, for higher cooling temperatures of LFRC/RO plant the thermal energy needs of each plant, the solar field with specific
and for electricity consumptions of 5.5 kWh/m3 in RO unit, the elec- number of loops satisfies the total annual solar share of 20.5%. For
trical efficiency of configuration A is equal to that of configuration B1 instance, for configuration A with lowest required thermal energy
with the MED unit. It can be concluded that only in the specific con- (148.60 MWht, Table 10), the LF solar field with 41 numbers of loops
ditions when the once through cooling temperatures are high and the supplies 20.5% of total annual required thermal energy of the plant.
electricity consumptions of RO unit is high as the result of high salinity Configuration D1 with highest thermal energy needs requires larger
of seawater, the electrical efficiency of the LFRC/RO and LFRC/MED aperture areas of LF solar field (63 loops) to supply 20.5% of total
plants approach to a same value. For the other cases, configuration A annual thermal load of this plant. Similar calculations were performed
with RO unit has higher electrical efficiency than configuration B1 with to determine the LF solar field numbers of loops supplying 20.5% of the
MED unit. total annual thermal needs of the plants when they are located in Port-
Hedland and de Almeria with different seawater temperatures and solar
5.3. Exergy analysis of dual purpose plants DNI levels. The results of the calculations are shown in Table 12. The
reference plant in Table 12 is the LFRC plant without desalination units.
Based on the obtained results of the previous parts of the present As it is clear from Table 12, the required aperture areas of the LF solar
study, configuration A has always higher electrical efficiencies as fields in the reference plants are lower than that of the dual purpose
compared to the other plants. However, the highest electrical effi- plants due to lower required thermal energy needs and mass flow rate
ciencies of a dual purpose plant cannot guarantee its lowest fresh water of the reference plants. It is evident that the locations with higher solar
production costs. In this part of the study, an exergy analysis was made radiation levels require lower aperture areas of the LF solar field as it is
to obtain the inlet and outlet exergy flow rates as well as the exergy shown in Table 12. For Port-Hedland, the required LF numbers of loops
destruction rates of each component of the study plants. The exergy is approximately 22% and 32% lower than that for the Kish Island and
flow rates were used in the exergo-economic analysis to determine the de Almeria, respectively. The increasing in the electricity consumptions
electricity and fresh water unit of costs that are produced by each plant. of RO unit from 3.5 kWh/m2 to 5.5 kWh/m2 increases the required
Firstly, the thermal loads and mass flow rates of all plants were cal- numbers of LF solar field by about 5.8% and 7.4% for the Port-Hedland
culated using the EES calculations. Table 10 shows the mass flow rates,
temperatures and pressures of Configurations A, B1, C1 and D1 (Figs. 2
to 4) for seawater temperatures of 26 °C and 36 °C and fresh water flow 40
rates of 40,970 m3/day and 34,660 m3/day, respectively. As can be 38
seen from Table 10, because of the higher electricity consumption in the
RO unit, the total electricity generation of configuration A is higher 36
than that of the other plants. However, the higher electrical efficiency 34
Energy efficiency (%)
of configuration A implies the lower mass flow rates for the plant and its
LF solar field. Configuration B1 with electrical efficiency of higher than 32
C1 and D1 has lower required thermal energy and lower mass flow rates 30
for its Rankine cycle and LF solar field as compared to C1 and D1. The
28
highest required thermal energy and mass flow rate are related to
configuration D1 with lowest electrical efficiency among the other 26
3
configurations. Conf#A(3.5 kWh/m )
24 3
Conf#A(5.5 kWh/m )
Three locations with three different seawater temperatures and 3
22 Conf#B1(1.5 kWh/m )
different total annual solar radiation levels were chosen to obtain the
Conf#B1(2.5 kWh/m3)
electricity and water production costs of the plants operating at dif-
20
ferent weather conditions around the world. The specifications of the
study locations are shown in Table 11. As it is shown in Table 11, the 18
seawater temperatures of the study areas are as equal as 26 °C, 31 °C 16
and 36 °C, respectively, for de Almeria in Mediterranean Sea, Port- 10000 20000 30000 40000 50000
Hedland in north Australia (Indian Ocean) and Kish Island in Persian 3
Fresh water rate (m /day)
Gulf. The solar radiation levels of three locations are different so that
Fig. 14. Once through cooling temperature of 52 °C for configuration A-TSW = 36 °C.
Port-Hedland and de Almeria has the highest and lowest total annual
50
I.B. Askari et al. Desalination 425 (2018) 37–67
40 Table 11
The specifications of three locations around the world that were used in the calculations
38 of present work.
36 Location DNI (kWh/m2/ TSW (°C) Condenser cooling temperature
34 day) (°C)
Energy efficiency (%)
28
26 30 60
Solar Share(%)
Def, Conf#D1 40
18 Ssh, Conf#D1
16
10000 20000 30000 40000 50000 20 30
3
Fresh water rate (m /day)
Fig. 15. Once through cooling temperature of 57 °C for configuration A-TSW = 36 °C. 20
15
and Kish Island (or de Almeria), respectively. As it can be seen from 10
Table 12, the required solar field aperture area for the Port-Hedland
reference plant is approximately 23% and 63% lower than that for the
Kish Island and de Almeria, respectively. In the other words, the in- 10 0
creasing of the total annual solar radiation levels by about 17.40% 30 35 40 45 50 55 60 65 70
(from 2300 kWh/m2 to 2700 kWh/m2) and 35.13% (from 1990 kWh/ LF solar field number of loops
m2 to 2700 kWh/m2) results in decreasing the required LF solar field Fig. 16. The variations of solar share and defocused fraction versus the solar field re-
area of the reference plant by about 23% and 63%, respectively. quired number of loops-, TSW = 36 °C, DNI = 2300 kWh/m2/year.
The calculations of exergy analysis were performed by using the
computer code that was developed in EES. Table 13 shows the ther- destructions in each component to the total exergy destruction of the
modynamic specifications of the inlet and outlet streams for each
plant, are shown in Fig. 18a to d. As can be seen from Figs. 17 and 18,
component in configuration A and for seawater temperature of 26 °C. the highest percentage of exergy destruction is caused by the LF solar
Based on Table 13, the mass flow rate of the plant is equal to 62.2 kg/s
field. Based on Fig. 17, the highest exergy destructions are occurred
which is different from the solar field mass flow rate of this plant
respectively in MED/TVC units of configurations D1 and D2, high
(77.13 kg/s, Table 10). Part of the solar field mass flow rate is not pressure turbine of configuration D1, Reheat turbine and MED unit of
flowed into the power plant and that is used to increase the temperature
configuration B1. Fig. 18a shows that for configuration A, the reheat
of the output stream from the high pressure turbine (point 2, Fig. 2) in turbine has the highest percentage of exergy destruction after solar field
the re-heater of the plant.
and for high pressure turbine and condenser of the plant, the percen-
The main exergy destructions corresponding to the components of tage of exergy destruction is low; nearly 1%. The MED and MED/TVC
configurations A, B1, C1 and D1 are shown in Fig. 17 for seawater
units in configurations B1, C1 and D1 have the percentages of 5%, 7%
temperature of 26 °C. Also, the percentages of exergy destructions in and 8%, respectively, which are high as compared to the percentage of
main components of the plants, which are defined as the ratio of exergy
exergy destruction in the condenser of configuration A (1%). The
Table 10
The specifications of dual purpose plants for two cooling seawaters of 26 °C and 36 °C.
Conf. Desalination electricity Seawater cooling Condenser temperature LF mass flow LFRC thermal load Gross electricity Fresh water flow
consumption (kWh/m3) temperature (°C) (°C) rate (kg/s) (MWhth) (MWh) rate (m3/day)
51
I.B. Askari et al. Desalination 425 (2018) 37–67
Port Hedland, TSW = 31 °C, DNI = 2700 kWh/m2/year 5.4. Exergo-economic analysis results
Numbers of 34 36 41 47 51 30
loops
In order to determine the electricity generation and water produc-
Kish, TSW = 36 °C, DNI = 2300 kWh/m2/year tion costs of the dual purpose plants and also the fresh water production
Numbers of 42 44 50 57 63 37
loops
costs of the single purpose plants, an exergo-economic analysis was
performed in this part of the study applying Eqs. (1) to (18). The
de Almeria, TSW = 26 °C, DNI = 1990 kWh/m2/year
electricity generation costs of the plants were calculated based on both
Numbers of 54 58 66 75 83 49
loops gross electricity (excluding electricity consumption in desalination
units) and net electricity rates. The electricity generation costs of the
a
LFRC plant without desalination unit. plants based on the gross electricity rate are slightly lower than that
based on the net electricity rates. The gross electricity unit of cost was
Table 13 used in the calculations of fresh water unit of cost considering different
The thermodynamic specifications of each state point of configuration A shown in Fig. 2. electricity consumption rates in the desalination units. The capital,
operating and maintenance costs of the plants were set based on the
Stream number T (°C) P (kPa) h (kJ/kg) S (kJ/kg ∙ K) ṁ (kg/s)
cost data that are shown in Table 3. The total exergy of the plants were
1 373.0 10,000 3008.0 6.07 62.20 calculated using Eq. (4) and based on solar thermal energy of the LF
t8 273.9 4540 2856.0 6.12 6.79 solar fields at the hour of maximum solar radiation level in a sunny day
d8 219.4 4540 941.4 2.50 6.79
of the year for three regions of the study. The LF solar thermal energy is
t6 213.9 2060 2703.0 6.13 3.67
d6 190.4 2060 809.8 2.24 10.46 capable of supplying 100% of required thermal load of the plants at the
2 213.9 2060 2703.0 6.13 51.57 hour of peak solar radiation level. The diagram blocks of exergy flows
3 373.4 1818 3192.0 7.08 51.57 between different components of configurations A, B1, C1, D1, D2, C2
t5 282.8 875 3017.0 7.12 3.49 and B2 are shown in Figs. 19 to 22. As can be seen from Figs. 19 to 21,
t4 188.9 362.7 2839.0 7.12 3.01
d4 110.9 362.7 465.2 1.42 3.01
LF solar field, power block, RO, MED and MED/TVC units were con-
t3 105.4 122.4 2659.0 7.22 2.69 sidered as a system with inlet and outlet exergy streams in kWhex. For
d3 77.94 122.4 326.3 1.05 5.70 configuration A, WRO is the only exergy stream that is flowed into the
t2 72.44 34.6 2481.0 7.28 2.96 RO unit from the LFRC. However, for configurations B1 and C1 (or D1),
d2 39.19 34.6 164.1 0.56 8.66
two exergy streams of WMED and E4 (Et4c and Et8c for configurations C1
4 33.90 5.3 2275.0 7.43 39.60
5 33.90 5.3 142.0 0.47 39.60 and D1, respectively) are flowed into the MED and MED/TVC units of
6 34.10 5.3 146.8 0.49 48.26 configurations B1 and C1 (or D1). Each exergy stream has a specific cost
7 34.83 1000 146.8 0.48 48.26 in $/kWhex that is determined by solving a set of equations. The exergy
8 140.10 1000 589.9 1.74 48.26 stream unit of costs is mainly related to the capital costs of components
9 179.90 1000 763.0 2.14 62.20
of the plants. Table 14 shows the exergy balance equations of the plants
10 149.90 10,460 790.0 2.17 62.20
11 258.10 10,460 1125.0 2.86 62.20 that were used to calculate the unit cost of each inlet or outlet stream
into or from the components of the study plants. The exergo-economic
model consists of a series of cost balances, one for each component, and
extraction of the steam at the temperature of 70 °C in configuration B1 a number of auxiliary equations for each component associated with
causes to increase the exergy destructions of the Reheat steam turbine multiple exiting exergy flows. As can be seen from Table 14, the exergy
of this plant. As can be seen from Fig. 18b, the Reheat turbine of con- balance equations are written based on Eqs. (10) to (18) so that each
figuration B1 has the percentage destruction of 8% which is twofold of parameter represents the total annualized cost of a component (Z͠LF ,
that for configurations C1 and D1 (4%). In configuration D1, the ex- Z͠RO , Z͠MED , Z͠PB ) or total annualized cost of the inlet or outlet exergy
traction of the steam from the high pressure turbine of the plant results streams into or from a component. For instance, the total annual cost of
in high exergy destruction in this component; so that the percentage of the outlet exergy stream from the solar field is calculated by multi-
exergy destruction in this component (7%) is nearly same as that in plying the total annual number of hours with solar thermal energy by
hourly cost of the outlet exergy stream from the solar field as
52
I.B. Askari et al. Desalination 425 (2018) 37–67
18-a-Configuration A 18-b-Configuration B1
18-c-Configuration C1 18-d-Configuration D1
(solarshare × 8760 × C1s ∙ E1). C1s is the cost of outlet exergy stream lower input exergy in the solar field and consequently higher exergy
($/kWhex) from the solar field that is determined based on the LF solar efficiencies. Extracting the high pressure steam of 4540 kPa from the
field capital cost. E1 is the hourly exergy of solar field outlet stream in high pressure steam turbine of configuration D1 results in an exergy
kWhex. As can be seen from Table 14, the seawater intake costs were set efficiency of 14% for this configuration which is nearly 50% lower than
as zero due to the free source of energy and water. Also, the exergy cost that of 21% for configuration A with the RO unit. The electricity unit
of the wasted streams such as wasted brine or outlet cooling seawater cost of configuration A is the lowest value among four plants. As it was
from the condenser of MED or MED/TVC unit (point 14 in configura- expected, the electricity unit costs calculated based on the gross elec-
tions B1, C1 and D1 also point 5 in configurations D2, C2 and B2) were tricity generation rate are approximately 7.8% lower than that are
assumed to be zero. For configurations A, C1 and D1, the unit cost of calculated based on the net electricity generation rate. The electricity
input and output exergy streams of the condenser unit were assumed to unit costs that were obtained based on gross electricity generation rate
be wasted with the exergy flow cost of zero. were used in the calculations of the fresh water unit costs of the plants.
Fig. 23 shows the exergy efficiency, the gross and net electricity The capital cost of MED and MED/TVC units plays an important role
generation unit costs of dual purpose plants assuming net electricity in the calculations of fresh water unit of costs. According to the results
generation rate of 50 MWe and water production rate of 34,660 m3/day of former sections, assuming constant evaporative areas for the MED or
for Persian Gulf with solar radiation level of 2300 kWh/m2/year and MED/TVC effects, the lower seawater temperatures entails higher fresh
seawater temperature of 36 °C. As can be seen in Fig. 23, the electricity water flow rates. Therefore, the capital cost of MED or MED/TVC units
unit cost is defined in terms of cost of electricity (COE) ($/kWh). The can be different for the locations with different seawater temperatures.
exergy efficiencies of the plants were calculated based on the peak solar Assuming the capital costs of 1240$/m3/day for the MED (or MED/
radiation level in a sunny day of summer in the Persian Gulf (ap- TVC) system located in a region with seawater temperature of 26 °C and
proximately 960 W/m2). However, the unit cost of electricity was de- distillate flow rate of 40,970 m3/day (50.8M$/day), for a location with
termined based on the total annual thermal energy of the plants that is seawater temperatures of 31 °C and 36 °C with distillate flow rates of
supplied by the solar field; assuming the solar share of 20.5% and using respectively equal to 38,100 m3/day and 34,660 m3/day, the capital
the equations that are shown in Table 14. Fig. 23 shows that config- cost of MED unit would be obtained as equal to 1333$/m3/day and
urations A and D1 have the highest and lowest exergy efficiencies, re- 1465$/m3/day, respectively. In the other words, with the specific in-
spectively, among four dual purpose plants. The higher electrical effi- vestment of 50.8M$/day, the capital cost of an MED unit located in the
ciency implies the lower aperture area and the lower mass flow rates of places with different seawater temperatures and consequently different
the solar field as it was explained formerly in the explanations of distillate flow rates is obtained as different values. Besides the seawater
Table 10. Therefore, considering the same electricity generation and temperature, the total annual DNI of a location has an important effect
water production rates, the plants with smaller solar fields has the on the electricity or fresh water unit cost of the plants. Based on
53
I.B. Askari et al. Desalination 425 (2018) 37–67
Table 11, the locations with higher solar radiation level are not ne- and 5.5 kWh/m3
cessarily that with the higher seawater temperatures due to the factors • Configuration B1 with MED electricity consumption of 1.5 kWh/m3
such as humidity of a region, shore wind speeds and so forth. That is and 2.5 kWh/m3
why the seawater temperature of a region like Port-Hedland with • Configuration C1 with MED/TVC having the motive steam pressure
higher DNI level is lower than that of the Kish Island in Persian Gulf of 362 kPa and electricity consumption of 1.5 kWh/m3 and
with DNI level of lower than Port Hedland. The calculation of the 2.5 kWh/m3
electricity and fresh water unit of costs were done for three locations • Configuration D1 with MED/TVC having the motive steam pressure
(Table 11) considering different distillate flow rates and capital costs of of 4540 kPa and electricity consumption of 1.5 kWh/m3 and
the MED unit for the plants comprising the MED system. 2.5 kWh/m3
The low seawater temperature in the Mediterranean coastal regions • Configuration D2 with MED/TVC having the motive steam pressure
is an advantage for water productions using the MED or MED/TVC of 4540 kPa and electricity consumption of 1.5 kWh/m3 and
plants. However, the low DNI level on one hand and the high fuel prices 2.5 kWh/m3
on the other hand are two disadvantages of MED technologies in that • Configuration C2 with MED/TVC having the motive steam pressure
region. For the Persian Gulf, the high seawater temperature and high of 362 kPa and electricity consumption of 1.5 kWh/m3 and
solar radiation level are respectively the advantage and disadvantage of 2.5 kWh/m3
solar based MED technologies within this region. However, with the • Configuration B2 with MED electricity consumption of 1.5 kWh/m3
low fuel price of 0.02$/m3 (natural gas), the application of solar and 2.5 kWh/m3.
thermal energy as the thermal source of the desalination plants is not
still economically justified for the Persian Gulf region. Port-Hedland The inlet and outlet exergy streams of the main components of the
located in north Australia, which has high solar radiation level and systems were calculated in terms of kWhex based on Figs. 19 to 22. The
moderate seawater temperature, can be a suitable place for seawater unit cost of electricity (COE) and fresh water (COW) were determined
distillation using solar thermal source. In the present work, the exergo- for dual purpose configurations. Also, the COW of LF/MED (B2) and
economic analysis of totally 8 configurations were done in order to LF/MED/TVC (C2 and D2) systems were compared to that of dual
determine the electricity or fresh water unit of costs assuming that the purpose configurations (B1, C1 and D1). For all configurations COW
plants are located at three different regions around the world were determined based on $/kWhex and $/m3 of produced fresh water.
(Table 11): For two configurations of D1 and D2, the results of exergo-economic
analysis are shown in Tables 15 and 16, respectively, for the case
• The reference plant of configuration A without desalination unit. when the plants are located in Port-Hedland with DNI of 2700 kWh/m2
• Configuration A with RO electricity consumption of 3.5 kWh/m 3
and seawater temperature of 31 °C. It is necessary to mention that all
54
I.B. Askari et al. Desalination 425 (2018) 37–67
the annual exergy streams (kWh/year) were determined by applying MED/TVC desalination unit is obtained as 0.034$/kWhex as it is shown
the solar share of 20.50%. For instance, considering the net electricity in Table 15. As it is clear from Table 15, the exergy efficiency of re-
generation rate of 50 MWe, the total annual electricity that is ference and dual purpose plants (D1), which were obtained for Port-
generated by solar thermal source is equal to 89.78 GWh Hedland at a typical hour with maximum solar radiation level, are
(50 MWe × 8760 × 0.205). As can be seen from Table 15, assuming equal to 29.07% and 17.12%, respectively. The exergy efficiency dif-
same electricity generation rate of 53.55 MWe for both reference and ference is occurred due to decreasing of the dual purpose plant (D1)
dual purpose plants (Conf#D1 in Table 10), because the reference plant electricity generation rate which is caused by integration of MED/TVC
of D1 (without desalination unit) requires lower thermal energy than unit into the plant. In fact, part of the steam in the high pressure steam
dual purpose plant of D1, the aperture area of the LF solar field and turbine of the dual purpose plant is not used to produce the electricity
consequently its capital cost for the reference plant is lower than those and it is extracted to be used as the motive steam of the MED/TVC unit.
for the dual purpose plant. That is way the solar field annualized costs Table 15 also shows that the fresh water exergy unit of cost is equal to
in the case of reference plant is approximately 58% lower than that in 1.84$/kWhex for configuration D1. Considering the total annual che-
the case of dual purpose plant as it is shown in Table 15. It can be also mical exergy of the fresh water that is produced by solar field
seen from Table 15 that the COE of reference plant (0.1405$/kWh) is (2.66 × 106 kWhex/year), the total annual exergy cost of the fresh
approximately 13% lower than that of the dual purpose plant (0.1589$/ water is obtained as equal to 4.89 × 106$/year (1.84$/
kWh). The difference between the COE of dual purpose and reference kWhex × 2.66 × 106 kWhex/year). Finally, the unit cost of fresh water
plants were used to determine the thermal energy cost that is used in (1.71$/m3 in Table 15) is obtained by dividing the total annual exergy
the MED/TVC desalination unit as follows: cost of the fresh water by total annual fresh water that is produced by
LF solar field thermal source which is equal to 2.85 × 106 m3/year
(LCOED1 − LCOERef,D1) × WGross = Cst4c ∙Et4c − Cst4e ∙Et4e (19)
(38,100 m3/day × 365 × 0.205). Table 16 shows that the unit cost of
where, WGross is the total electrical work (53.55 MWe) including the exergy stream that is entered (or exit) into (or from) the MED/TVC unit
required electricity that is consumed in the desalination unit and the of configuration D2 (0.053$/kWhex) is approximately 57% higher than
condenser pump of dual purpose plant (3.7 MWe). Also, Ct4cs and Ct4es that of configuration D1 (0.034$/kWhex, in Table 15). That is why the
are respectively the costs of inlet and outlet exergy streams into or from fresh water unit of cost for configuration D1 (dual purpose plant) is
the MED/TVC desalination unit as it is shown in Fig. 21. Based on Eq. lower than that for configuration D2 (2.06$/m3). In contrast to con-
(19), the total annual electricity cost that is induced into the plant due figuration D1, which has two products of electricity and fresh water
to integration of the desalination unit is obtained as 9.24 × 106$/year. with total hourly exergy value of 55.03 MWex (53.55 MWe
Therefore, the cost of inlet and outlet exergy streams into or from the + 1.48 MWex), the only product of configuration D2 is fresh water with
55
I.B. Askari et al. Desalination 425 (2018) 37–67
a low hourly exergy value of 1.48 MWex. Therefore, applying Eq. (4), MED/TVC units. However, for configuration B2 (LF/MED), the solar
the exergy efficiency of dual purpose plant (D1) is obtained con- field required aperture area is higher than that of configurations C2 and
siderably higher than that of configuration D2 with the exergy effi- D2 because the lower GOR of MED unit as compared to the GOR of
ciency of 1.37% as it is shown in Table 16. MED/TVC units in configurations C2 and D2 (LF/MED/TVC). There-
The exergy efficiency of all configurations and the reference plants, fore, the exergy efficiency of configuration B2 would be obtained lower
which were calculated using Eq. (4), are shown in Fig. 24 for three than that of configurations C2 and D2.
locations of the study at the hour of maximum radiation level. As it is The fresh water unit costs that are obtained assuming the applica-
clear from Fig. 24, the reference plants have the higher exergy effi- tion of different configurations within three locations of the study are
ciencies as compared to dual purpose plants for three locations of the shown in Fig. 25; considering the electricity consumptions of 1.5 kWh/
study. The locations with higher solar radiation level have higher ex- m3 for MED and MED/TVC units as well as 3.5 kWh/m3 and 5.5 kWh/
ergy efficiencies; so that the maximum and minimum exergy effi- m3 for RO desalination unit. Generally, Port-Hedland and de-Almeria
ciencies are related to the Port-Hedland and De-Almeria, respectively. with the maximum and minimum DNI levels, respectively, have the
The lower DNI level the higher required aperture area in the solar field minimum and maximum fresh water units of costs for all configura-
and consequently the lower exergy efficiency based on Eq. (4). For tions. The advantage of low seawater temperature in Mediterranean Sea
three locations of the study, configuration D1 with moving steam (de-Almeria), which causes to have higher GORs in the MED and MED/
pressure of 4540 kPa in the MED/TVC unit has the minimum exergy TVC units, cannot compensate the disadvantage of lower solar radiation
efficiency among the dual purpose plants. Fig. 24 also shows that be- level at this region. Therefore, the high solar radiation levels of Port-
cause the low exergy of produced fresh water, the exergy efficiency of Hedland and Persian Gulf results in lower fresh water productions costs
configurations B2, C2 and D2 are lower than that of the dual purpose of all configurations as compared to the case when the systems are
plants. In configuration B1, part of the thermal energy that is used in located at Mediterranean Sea with lower DNI level. As it is shown in
the desalination process is cost free because the first low of thermo- Fig. 25, with the exception of Port-Hedland region, the COW of con-
dynamic that implies part of the thermal energy is wasted due to figurations with MED or MED/TVC units are lower than that of the dual
cooling up the plant. Therefore, the thermal energy costs of the desa- purpose configuration of A with RO desalination unit. In fact, the higher
lination process in configuration B1 is lower than that of in config- electricity efficiency of configuration A implies the lower required
urations C1 and C2. Therefore, configuration B1 with MED unit has thermal energy and consequently lower solar field aperture area for this
higher exergy efficiency as compared to configurations C1 and D1 with configuration as compared to other dual purpose plants. Therefore, the
56
I.B. Askari et al. Desalination 425 (2018) 37–67
water production cost of configuration A is low as compared to that of and Fig. 20) are tabulated in Table 17 for three locations of the study.
configurationsB1, C1 and D1. Fig. 25 shows that unlike two other re- As it can be seen from Table 17, the highest and lowest unit costs of
gions of the study, for Port-Hedland the COW of configuration A is exergy streams are related to De-Almeria with lowest DNI level and
higher than that of configuration B1. In order to illustrate the reason, Port-Hedland with highest DNI, respectively. The lower unit cost of
the unit cost of exergy streams that are exit from the LF solar field and exergy stream that is entered into the MED unit results in the lower
entered into the MED unit of configuration B1 (C1s and C4s, Table 14 water production cost. It can be concluded that even if the electricity
Table 14
The exergy balance equations that were used in the calculations of exergy stream unit of costs.
57
I.B. Askari et al. Desalination 425 (2018) 37–67
0.4 26 4
2 o 3
DNI=2700kWh/m /yr, TSW=31 C, D=38100m /day
Exergy Efficiency 24 3.5
0.35 2 o
DNI=2300kWh/m /yr, TSW=36 C, D=34660m /day
3
LCOE (WNet)
2 o 3
LCOE (WGross) DNI=1990kWh/m /yr, TSW=26 C, D=40970m /day
22 3
0.3
3
5.5kWh/m
20 2.5
COW($/m3)
3.5kWh/m3
COE ($/kWh)
0.25
18 2
0.2
16 1.5
0.15
14 1
0.1 0.5
12
0.05 10 0
0 A A B1 C1 D1 D2 C2 B2
Plant
0 8
A B1 C1 D1
Fig. 25. Water unit cost of the plants for three locations of the study.
Plant
Fig. 23. Exergy efficiency and electricity unit costs of the plants for Persian Gulf. efficiency of configuration A with RO unit would be higher than that of
configuration B1 with MED unit, the high radiation level at a region can
be reduces the thermal energy costs and consequently water production
cost of configuration B1 to the values lower than that of configuration
A. Fig. 25 also shows that the COW of configurations B2, C2 and D2 are
40 higher than that of dual purpose configurations. In fact, the application
2 o
DNI=2700kWh/m /yr, TSW=31 C, D=38100m /day
3
of solar field as the thermal source of MED or MED/TVC units to pro-
35 2 o
DNI=2300kWh/m /yr, TSW=36 C, D=34660m /day
3
duce only fresh water results in high COW values because of the high
2 o 3
30
DNI=1990kWh/m /yr, TSW=26 C, D=40970m /day exergy value of solar thermal source and low exergy value of produced
Exergy efficiency(%)
fresh water.
25 Fig. 26 shows the unit cost of electricity generation for dual purpose
plants as well as the unit electricity costs of the reference plants that are
20 used in the calculations of COW of configurations B2, C2 and D2 when
they are located at three regions of the study. For configurations B2, C2
15
and D2, it was assumed that the electricity, which is generated by the
10 reference plant (configuration A without RO desalination unit) at the
condenser cooling temperature of 8 °C higher than the seawater tem-
5 perature, is used in the MED and MED/TVC units. As it is clear from
Fig. 26, the electricity generation cost of reference plants that are used
0 in the COW of configurations B2, C2 and D2 are lower than that of dual
Ref. A B1 C1 D1 D2 C2 B2
Table 15
The results of exergo-economic analysis of Conf#D1, DNI = 2700 kWh/m2/year, TSW = 31 °C (port-Hedland).
58
I.B. Askari et al. Desalination 425 (2018) 37–67
Table 16
The results of exergo-economic analysis of Conf#D2, DNI = 2700 kWh/m2/year, TSW = 31 °C (port-Hedland).
E (kW/ cs ($/kWh)
year)
Costs Conf#D2
Table 17 0.75
The unit cost of exergy streams that are entered into the MED or exited from solar field of 0.7 2 o
DNI=2700kWh/m /yr, TSW=31 C, D=38100m /day
3
Conf#B1.
Solar field apperture area(km ) 0.65 2 o 3
DNI=2300kWh/m /yr, TSW=36 C, D=34660m /day
2
0.6 2 o 3
DNI=1990kWh/m /yr, TSW=26 C, D=40970m /day
Location The unit cost of exergy stream The unit cost of exergy stream 0.55
that is entered into the MED that is exited from the solar 0.5
unit (C4s) ($/kWhex) field (C1s) ($/kWhex)
5.5kWh/m3
3.5kWh/m3
0.45
Port-Hedland 0.027 0.043 0.4
Kish Island 0.044 0.054 0.35
De_Almeria 0.056 0.069 0.3
0.25
0.2
0.15
0.35 0.1
2 o
DNI=2700kWh/m /yr, TSW=31 C, D=38100m /day
3 0.05
0.3 2 o 3 0
DNI=2300kWh/m /yr, TSW=36 C, D=34660m /day 0 A A B1 C1 D1 D2 C2 B2
DNI=1990kWh/m2/yr, TSW=26oC, D=40970m /day
3
Plant
0.25
3
5.5kWh/m3
3.5kWh/m
Ref. cycle LCOEs unsed in Fig. 27. Required solar field aperture areas for different configurations located at three
COE($/kWh)
0.15
configuration A should be higher than that of configuration B1 as it is
0.1 shown in Table 10. The higher electricity generations rate of config-
uration A (5.5 kWh/m3) causes to increase the capital cost of Rankine
0.05 cycle (power block) of that plant to the higher values than that of
configuration B1. In consequence, in despite of lower capital cost of
0
0 A A B1 C1 D1 D2 C2 B2 solar field for configuration A as compared to configuration B1, the sum
Plant of solar field and Rankine cycle capital costs for the configuration A
(5.5 kWh/m3) would be obtained higher than that for configuration B1.
Fig. 26. Water unit cost of the plants for three locations of the study.
That is why the COE of configuration B1 is obtained as lower than that
of configuration A with electricity consumption of 5.5 kWh/m3 in RO
unit. It is worth to mention that the decreasing of Rankine cycle capital
cost may changes the results. Also, these results can be different for the
locations of the study. Since the electrical efficiency of configuration A configurations with PTC solar field due to the higher capital cost of PTC
(5.5 kWh/m3) is higher than that of configuration B1, the required solar field as compared to the LF solar field. In such a case, the sum of
aperture area and consequently capital cost of solar field for config- capital costs of the solar field and Rankine cycle of the plant with lower
uration A (5.5 kWh/m3) is lower than that for configuration B1. How- solar field aperture area can be lower than that of the plant with higher
ever, because of higher electricity consumption of RO unit in config- solar field aperture area.
uration A (5.5 kWh/m3), in order to obtain a constant net electricity For three locations of the study with different DNI level, the re-
generation rate of 50 MWe, the electricity generation rate of quired aperture areas of solar fields were calculated for all
59
I.B. Askari et al. Desalination 425 (2018) 37–67
0.25 4.5
COW($/m3)
0.15
2.5
0.125
3.5kWh/m3
2
0.1
0.075 1.5
0.05 1
0.025 0.5
0
Ref A B1 C1 D1 0
B1 C1 D1 D2 C2 B2
Plant
Plant
Fig. 28. The effect of solar field capital cost on the COE of dual purpose plants for Persian
Gulf. Fig. 30. The effect of solar field capital cost on the COW of dual purpose plants for
Persian Gulf-MED capital cost = 1465$/m3/day.
4.5 (Mediterranean Sea) with DNI levels of respectively 17% and 35%
2 lower than that of Port-Hedland in Australia, the required solar field
LF Capital cost=180$/m aperture areas of dual purpose configurations (B1, C1 and D1) are 21%
4
LF Capital cost=144$/m2 and 62% higher than that of dual purpose configurations located in
2
3.5 LF Capital cost=108$/m Port-Hedland region, respectively.
3 5.4.1. The effect of solar field and MED capital costs on COW and COE of
COW($/m )
2.5 It has been shown by the authors of the present study [20] that the
COW of the systems with solar field thermal source is highly sensitive to
2 the capital cost of solar field. In this part, the COWs of all configurations
of the study were calculated for three different scenarios of solar field
1.5 capital cost when they are located in Persian Gulf region with seawater
temperature of 31 °C and DNI level of 2300 kWh/m2/year. Fig. 28
shows the effect of decreasing capital cost of LF solar field on the COE of
3
1
3.5kWh/m
reference and dual purpose plants for Persian Gulf region. The results of
0.5 Fig. 28 reveal that the decreasing of solar field capital cost to 80% and
60% of its first cost assumption (180$/m2) results in decreasing the
0 COE of the study configurations by about 8.16% and 16.17%, respec-
A B1 C1 D1 D2 C2 B2 tively. The percentage decrease in COE of dual purpose configurations
Plant is low as compared to the percentage decrease in capital cost of the LF
solar field. The reason is that the solar field capital cost is one of the
Fig. 29. The effect of solar field capital cost on the COW of dual purpose plants for
parameters that affect the COE of the plants, and COE is depended on
Persian Gulf-MED capital cost = 1465$/m3/day.
the other cost parameters such as capital cost of Rankine cycle and so
forth. Generally, it can be concluded that each 10% decrease in solar
configurations (Fig. 27). As it was mentioned formerly, it was assumed field capital cost results in 4% decrease in the COE of dual purpose
that the solar fields supply 20.50% of total annual required thermal plants when they are located in Persian Gulf.
energy of the plants. It is evident that the locations with high solar Similar calculations were done to determine the effect of solar field
radiation level are those with low required aperture areas in the solar capital cost on COW of dual purpose and single purpose configurations
field of the plants. The results of Fig. 27 show that for all three locations when they are located in Persian Gulf region. As can be seen from
of the study the solar field required aperture area of configurations B2, Fig. 29, by decreasing of the solar field capital cost to 60% of its first
C2 and D2 are approximately equal to 65%, 46% and 38% of the solar cost assumption, the COW of configurations A, B1, C1, D1, D2, C2 and
field aperture areas of configurations B1, C1 and D1, respectively. In B2 would be decreased by about 5.06%, 9.42%, 14.67%, 18.93%,
fact, the low GOR of MED unit in configuration B2 causes to increase 21.47%, 22.10% and 24.55%, respectively. As it is clear, configurations
the required solar field aperture area of this configuration as compared A (LFRC/RO) and B2 (LF/MED) with, respectively, maximum and
to configurations C2 and D2 with higher GORs in MED/TVC units. minimum exergy efficiencies have the minimum and maximum per-
Fig. 27 also shows that for the Kish Island (Persian Gulf) and de-Almeria centages decrease among the other configurations, respectively.
60
I.B. Askari et al. Desalination 425 (2018) 37–67
7 7
D1-NGB heat source B2-NGB heat source
6 D1-Solar heat source 6 B2-Solar heat source
C1-NGB heat source C2-NGB heat source
C1-Solar heat source C2-Solar heat source
5 B1-NGB heat source 5 D2-NGB heat source
B1-Solar heat source D2-Solar heat source
COW($/m )
COW($/m )
3
3
4 4
3 3
2 2
1 1
0 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
3 3
Natural gas price ($/m ) Natural gas price ($/m )
Fig. 31. The effect of fuel price on COW of dual purpose plants for Persian Gulf-MED Fig. 32. The effect of fuel price on COW of single purpose plants for Persian Gulf-MED
capital cost = 1465$/m3/day. capital cost = 1465$/m3/day.
Because of the low GOR and exergy efficiency of configuration B2, the source and solar field thermal source, the COWs of the plants with solar
sensitivity of COW of this configuration to the capital cost of solar field field thermal sources are also shown in Figs. 31 and 32. As can be seen
is higher than that of the other configurations. For dual purpose con- from Fig. 31, because of the low natural gas fuel price in Persian Gulf
figurations with high electrical efficiency and consequently low re- (0.02$/m3), the COW of fuel based plants are considerably lower than
quired thermal energy, the COW is less sensitive to the solar field ca- that of the solar based plants. Fig. 31 also shows that assuming the
pital cost. constant cost parameters at the fuel price of approximately equal to
The other effective cost parameter that can affect the COWs of the 0.23$/m3, the COW of the fuel based and solar based plants would be
study configurations is capital cost of the MED and MED/TVC units. equal to a same value. In the other words, for fuel price of 0.23$/m3,
Fig. 30 shows the effect of decreasing the capital cost of MED unit on the total electricity and thermal costs of the fuel based plants would be
COW of configurations with MED or MED/TVC units for Persian Gulf equal to that of the solar based plants with LF solar field capital cost of
region. As can be seen from Fig. 30, the capital cost of MED unit was 180$/m2. Also, as can be seen from Fig. 31, the slop of COW chart for
considered in three scenarios of 1800$/m3/day, 1465$/m3/day (first
cost assumptions for Persian Gulf in the calculations of present study) 4
and 1333$/m3/day. As it is shown in Fig. 30, by decreasing the capital
MED electrcicty need (2.5kWh/m3)
cost of MED from 1800$/m3/day to 1465$/m3/day and 1333$/m3/day 3.5 MED electrcicty need (1.5kWh/m3)
(23% and 35% decrease, respectively), the COW of configuration B1
would be decreased by about 4.51% and 7.78%, respectively. Also, for
3
configuration B2, 2.98% and 5.08% of decrease would be obtained by
decreasing the capital cost of MED unit from 1800$/m3/day to 1465$/
m3/day and 1333$/m3/day, respectively. In fact, due to high cost of 2.5
COW($/m3)
exergy stream that is flowed into the MED unit of configuration B2,
which causes this configuration has the minimum exergy efficiency and 2
maximum COW among all configurations, the COW of configuration B2
is more affected by the thermal energy cost rather than the capital cost
1.5
of MED unit. That is why the COW of configuration B1 has the low
decrease of 5.08% by decreasing the MED capital cost by about 35%.
Since nearly 79.5% of total annual required thermal loads of the 1
study plants were assumed to be supplied by natural gas boiler (NGB),
the fuel cost has an important role on the COWs of the study config- 0.5
urations with fuel thermal source. The COWs of the plants, which were
presented in former sections, were calculated based on the solar field 0
thermal source capital and other costs. In this part of the study, the B1 C1 D1 D2 C2 B2
effect of fuel cost on the COWs of configurations with MED or MED/
Plant
TVC unit were determined for dual purpose and single purpose con-
Fig. 33. The effect of MED electricity consumption on COW of plants for Persian Gulf-
figurations, respectively, as shown in Figs. 31 and 32. Also, in order to
MED capital cost = 1465$/m3/day.
make a comparison between the COWs of the plants with NGB thermal
61
I.B. Askari et al. Desalination 425 (2018) 37–67
the plants with low exergy efficiencies is steeper than that with high following results were derived from the present work:
exergy efficiency. The low exergy efficiency means that a plant requires
high amount of thermal energy and fuel to produce a specific amount of • At a same surface area for MED and MED/TVC evaporators and
electricity and water. Therefore, the sensitivity of COWs of plants with considering the net electricity generation rate of 50 MWe, the water
low exergy efficiencies to the fuel price is more than that with high production rate of dual purpose plants for the locations with sea-
exergy efficiency. It is evident that at lower COWs for the solar based water temperatures of 26 °C, 31 °C and 36 °C are obtained as
plants, the COW of fuel based plants is equal to that of the solar based 40,970 m3/day, 38,100 m3/day and 34,460 m3/day, respectively.
plants at lower fuel prices and vice versa. That is why for single purpose • The integration of RO unit into the solar Rankine cycle (LFRC/RO)
configurations of B2, C2 and D2 with higher COWs than dual purpose entails the higher electrical efficiency as compared to the dual
plants, the COW of the systems with solar and fuel thermal sources are purpose plants with MED or MED/TVC units. Only in the specific
equal at higher fuel prices as it is clear in Fig. 32. Based on Fig. 32 for conditions when the once through cooling temperatures of LFRC/RO
configurations of B2, C2 and D2, the COWs of configurations with solar plant are high and the electricity consumptions of RO unit is high as
based and fuel based thermal sources would be equal at the fuel price of the result of high salinity of seawater, the electrical efficiency of the
approximately 0.31$/m3; which is approximately 35% higher than that LFRC/RO and LFRC/MED plants approach to a same value.
value that is obtained for dual purpose plants as it is shown in Fig. 31 • The results of exergy analysis show that for dual purpose plants, the
(0.23$/m3). A comparison between Figs. 31 and 32 shows that the LF solar field causes the highest percentage of exergy destruction
slope of COW chart for dual purpose configurations in Fig. 31 is lower among the other components of the plants. The portion of exergy
than that for single purpose configurations in Fig. 32. This shows that destruction for condenser of LFRC/RO plant was obtained as < 1%.
for configurations B2, C2 and D2, the sensitivity of COW to the fuel However, for LFRC/MED and LFRC/MED/TVC the percentages of
price is higher than that for dual purpose plants of B1, C1 and D1. In exergy destructions of MED and MED/TVC units were determined as
fact, the low exergy efficiency of single purpose configurations causes 5% and 7%, respectively. Because of the steam extraction at high
to increase the sensitivity of their COWs to the fuel cost. temperature of 70 °C in configuration LFRC/MED, the percentage of
The effect of increasing the electricity consumptions of MED or exergy destruction for the reheat steam turbine of this plant was
MED/TVC units on the COWs of dual purpose and single purpose obtained as 8% which is twofold of that of the LFRC/MED/TVC
configurations are shown in Fig. 33. As it is shown in Fig. 33, the in- plants.
creasing of electricity consumption from 1.5 kWh/m3 to 2.5 kWh/m3 • Because the low exergy value of fresh water as compared to the
would result in increasing the COWs of configurations B1, C1 and D1 by electricity, the exergy efficiency of single purpose configuration is
about 11.72%, 11.04% and 9.53%, respectively. Also, the results of considerably low as compared to that of dual purpose plants with
Fig. 33 show that for configurations B2, C2 and D2, respectively, two products of electricity and fresh water. Consequently, the unit
3.86%, 4.75% and 5.07% increase in the COWs of these plants would be costs of fresh water for single purpose systems are higher than that
obtained if the electricity consumption of desalination units is increased for the dual purpose plants.
from 1.5 kWh/m3 to 2.5 kWh/m3. The lower percentages increase in • At the regions with high solar radiation levels (2700 kWh/m2/year),
COWs of single purpose plants as compared to dual purpose plants is the sum of solar field and Rankine cycle capital costs for the LFRC/
because of the higher thermal energy costs that are used in the desa- MED plant is obtained as lower than that for the LFRC/RO plant
lination units of single purpose plants. In fact, the thermal energy costs with electricity consumption of 5.5 kWh/m3 of fresh water in RO
and electricity costs are two factors that affect the COWs of desalination unit. Therefore, the unit cost of fresh water for LFRC/MED plant is
plants. Therefore, the higher thermal energy costs of desalination pro- lower than that for LFRC/RO plant. Also, the high solar radiation
cess decrease the impact of electricity costs in the COW of plant. That is level results in low thermal energy costs that is required in the MED
why in single purpose configurations with high thermal energy costs of unit of LFRC/MED plant, and in consequence, the electricity unit
desalination process, the COWs of the systems are less sensitive to the cost of this configuration is obtained as lower than that of LFRC/RO
electricity consumption of the MED units as compared to dual purpose plant for the regions with high solar radiation levels.
plants. • The effect of seawater temperature on the unit cost of fresh water is
lower than that of the solar DNI level. Therefore, the locations with
6. Conclusion higher solar radiation levels are those with lower unit costs of fresh
water for the considered configurations.
In the present paper, the energy and exergy analysis of different • For dual purpose and single purpose configurations that are used in
desalination technologies were performed. The effect of integration of Persian Gulf, when the fuel cost is increased from 0.02$/m3 to
RO, MED and MED/TVC desalination units into the solar Rankine cycles 0.23$/m3 and 0.31$/m3, respectively, the COW of plants with fuel
on the unit costs of water (COW) and electricity (COE) of dual purpose based or solar based thermal sources is equal. Otherwise, the COWs
plants were considered. The COWs for dual purpose plants (LFRC/RO, of the fuel based plants are considerably lower than that of the solar
LFRC/MED and LFRC/MED/TVC) were compared with that for the based plants.
single purpose configurations (LF/MED, LF/MED/TVC). The GORs of • For single purpose configurations, because of the high thermal en-
MED and MED/TVC desalination units were determined for the loca- ergy costs, the COW of these configurations are less sensitive to the
tions with different seawater temperatures. Also, the effect of solar DNI capital cost of MED unit and electricity consumption rate of desa-
level on the COWs of all configurations was determined considering lination process as compared to the dual purpose plants. The in-
three different DNI levels for three locations in the calculations of the creasing of MED electricity consumption from 1.5 kWh/m3 to
study. Finally, the effect of fuel price on the COWs of different con- 2.5 kWh/m3 results in increasing the COW of dual purpose plant of
figurations was determined when they are located in Persian Gulf re- LFRC/MED by about 11.72%. However for single purpose config-
gion. All dual purpose plants were considered to have a constant net uration of LF/MED, only 5.07% increase in the COW would be ob-
electricity rate of 50 MWe and for different water production rates tained by increasing the MED electricity consumption from
depending on the seawater temperatures of the study regions. The 1.5 kWh/m3 to 2.5 kWh/m3.
62
Appendix A
Table A1
Energy conservation, exergy balance and exergy efficiency equations used in modeling of configuration A (LFRC/RO) shown in Fig. 2 [39,40].
I.B. Askari et al.
Parameter Description
Solar field
Q USF = ṁ SF × (h1 − h11) = ηsf × Qs (a1) Solar field useful thermal energy ηsf (solar field thermal
efficiency)
Qs = Afield ∙ DNI (a2) Solar field incident thermal energy, Afield: solar field
aperture area
̇
0 = (E11 − E1) + Ein,SF − Idestroyed (a3) Solar field exergy balance equation
4 (a4) The exergy, i.e. maximum available power output in W/m2
4 T T
⎜ ⎟
Ein,SF = Qs × ⎜⎛1 − ⎛ 0 ⎞ + ⎛ 0 ⎞ ⎟⎞ ⎜ ⎟
of the collector's total mirror area, for an LF at a certain
⎝ 3 T T
⎝ sun ⎠ ⎝ sun ⎠ ⎠
hour of the day
̇
Idestroyed (E1 − E11) (a5) Solar field exergy efficiency
ηII = 1 − =
Ein,SF Ein,SF
63
ZReheater × (e1 − e11) ZReheater × (e1 − e11)
High pressure turbine
WH. P. T. = (h1 − ht8) + (1 − y8) × (ht8 − h2) (a9) High pressure turbine energy conservation
̇
WH.P.T. = (e1 − et8) + (1 − y8) × (et8 − e2) − Idestroyed (a10) High pressure turbine exergy balance
̇
Idestroyed WH.P.T. (a11) High pressure turbine exergy efficiency
ηII = 1 − =
(e1 − et8) + (1 − y8) × (et8 − e2 ) (e1 − et8) + (1 − y8) × (et8 − e2 )
Reheat turbine
WR. H. T. = (1 − y8 − y6) × (h3 − ht5) + (1 − y8 − y6 − y5) × (ht5 − ht4) + (1 − y8 − y6 − y5 − y4) × (ht4 − ht3) (a12) Reheat turbine energy conservation
+ (1 − y8 − y6 − y5 − y4 − y3) × (ht3 − ht2) + (1 − y8 − y6 − y5 − y4 − y3 − y2) × (ht2 − h4)
WR. H. T. = (1 − y8 − y6) × (e3 − et5) + (1 − y8 − y6 − y5) × (et5 − et4) + (1 − y8 − y6 − y5 − y4) × (et4 − et3) (a13) Reheat turbine exergy balance
+ (1 − y8 − y6 − y5 − y4 − y3) × (et3 − et2) + (1 − y8 − y6 − y5 − y4 − y3 − y2) × (et2 − e4) − T0 ∙ Sgen
̇
Idestroyed = T0 ∙Sgen = T0 × [(1 − y8 − y6) × (st5 − s3) + (1 − y8 − y6 − y5) × (st4 − st5) + (1 − y8 − y6 − y5 − y4) × (st3 − st4) (a14) Exergy destruction
+ (1 − y8 − y6 − y5 − y4 − y3) × (st2 − st3) + (1 − y8 − y6 − y5 − y4 − y3 − y2) × (s4 − st2)]
WR.H.T. (a15) Exergy efficiency
ηII =
̇
WR.H.T. + Idestroyed
Pump#1
WPump # 1 = zf × v6 × (P7 − P6) (a16) Energy balance
zf = 1 − (y5 + y6 + y8)
− WPump # 1 = zf × (e6 − e7) − T0 × Sgen (a17) Exergy balance
̇
Idestroyed z × (e7 − e6 ) (a18) Exergy efficiency
ηII = 1 − = f
WPump#1 WPump#1
Desalination 425 (2018) 37–67
Pump#2
WPump # 2 = (h10 − h9) (a19) Energy balance
− WPump # 2 = (e9 − e10) − T0 ∙ Sgen (a20) Exergy balance
̇
Idestroyed (e − e9 ) (a21) Exergy efficiency
I.B. Askari et al.
ηII = 1 − = 10
WPump#2 WPump#2
Mixing chamber
z1 × h5 + (y2 + y3 + y4) × hd2 = zf × h6 (a22) Energy balance
z1 = 1 − (y2 + y3 + y4 + y5 + y6 + y8)
0 = z1 × e5 + (y2 + y3 + y4) × ed2 − z × e6 − T0 ∙ Sgen (a23) Exergy balance
z × e6 (a24) Exergy efficiency
ηII = z1 × e5 + (y2 + y3 + y4) × ed2
64
y4 = (zf × (h8 − hf3))/(ht4 − hd4) (a31) Energy balance
0 = y4 × (et4 − ed4) − zf × (e8 − ef3) − T0 ∙ Sgen (a32) Exergy balance
z f × e8 + y4 × ed4 (a33) Exergy efficiency
ηII =
z f × e f3 + y4 × et4
De-aerator
y5 = ((h9 − h8) − (y6 + y8) × (hd6 − h8))/(ht5 − h8) (a40) Energy balance
0 = y5 × (et5 − e8) + (y6 + y8) × (ed6 − e8) − (e9 − e8) − T0 ∙ Sgen (a41) Exergy balance
e9 (a42) Exergy efficiency
ηII =
z f × e8 + y5 × et5 + (y6 + y8) × ed6
Condenser
Qout = z1 × (h5 − h4) (a43) Energy balance
Desalination 425 (2018) 37–67
T (a44) Exergy balance
⎜ ⎟
= z1 × (e4 − e5) + Qout × ⎛1 − 0 ⎞ − T0 ∙Sgen
⎝ T12 ⎠
⎝ T12 ⎠
̇
Idestroyed (a46) Exergy efficiency
ηII = 1 −
z1 × (e4 − e5 )
RO
0 = ṁ 14 × h14 + WRO − (1 − Wrr) × ṁ 15 × h15 − Wrr × ṁ 14 × h16 (a47) Energy balance, Wrr (Water Recovery Ratio = 45%, [33]),
WRO (RO electricity consumption)
0 = ṁ 14 × e14 + WRO − (1 − Wrr) × ṁ 14 × e15 − Wrr × ṁ 14 × e16 − T0 ∙Sgen (a48) Exergy balance
ṁ 16 × e fresh (a49) Exergy efficiency, ṁ 16 × e fresh (Eq. (7))
ηII =
ṁ 14 × e14 + WRO
Table A2
Energy conservation, exergy balance and exergy efficiency equations used in modeling of MED unit in Configuration B1 (LFRC/MED) (Fig. 3).
MED
0 = z1 × (h5 − h 4) + ṁ 12 × h12 + WMED − ṁ 14 × h14 − ṁ 13 × h13 − ṁ 15 × h15 (a50) Energy balance, WMED (MED electricity consumption)
0 = z1 × (e4 − e5) + ṁ 12 × e12 − ṁ 14 × e14 − ṁ 13 × e13 − ṁ 15 × e15 + WMED − T0 ∙Sgen (a51) Exergy balance
ṁ 15 × e fresh (a52) Exergy efficiency, ṁ 15 × e fresh (Eq. (7))
ηII =
65
z1 × (e4 − e5) + Wdes + M12 × e12
Table A3
Some of the parameters of the MED/TVC system [3,9,11,36].
Parameter Description
λ1 ⎝ λ1 ⎠
k−2 (a66) The vapor generated in the second effect to i − 1th effect (TVC location, Fig. 8):
⎡⎛ ⎛ ⎞ ⎞⎤ λ T − Tfk ⎞ C∙ΔT
Dk = ⎢ Dk − 1 + ⎜ ∑ Dk + Dr ⎟ ∙y − (k − 1) ∙Fk ∙y ⎥ ∙ k − 1 − Fk ∙C∙ ⎛ k + Bk − 1∙ ⎜ ⎟ (k = 2 to i − 1)
⎜ ⎟ λk λk
⎢
⎣⎝ ⎝ k = 1 ⎠ ⎠⎦⎥ ⎝ λk ⎠
λ i−1 T − Tfi ⎞ C∙ΔT (a67) The vapor generated in the first effect after TVC location (i)
Di = Df ∙ − Fi ∙C∙ ⎛ i ⎜ + Bi − 1∙⎟
λi ⎝ λi ⎠ λi
j−2 (a68) The vapor generated in the other effects after TVC location (i + 1 to n)
⎡⎛ ⎞ ⎤ λ j−1 Tj − Tfj ⎞ C∙ΔT
Dj = ⎢ Dj − 1 + − Fj∙C∙ ⎜⎛ ⎟ + Bj ∙
⎜ ∑ Dj∙y − (j − 1) ∙Fj∙y⎟ ⎥ ∙ λj λ j λj
⎢
⎣⎝ j=1 ⎠⎦⎥ ⎝ ⎠
[(Ds + Dr ) ∙ (h d − hfd )] (a69) The heat transfer area of first effect
A e1 = Ue1 ∙ (Td − T1)
3 (a70) The heat transfer area of the second effect to i − 1th effect (TVC location, Fig. 8)
[ (Dk − 2 + (∑kk −
= 1 Dk + Dr ) ∙ y − (k − 2) ∙ F k ∙ y) ] ∙ λk − 2
A ek − 1 = Uek − 1 ∙ (Tvk − 2 − T k − 1)
Df ∙λ i − 1 (a71) The heat transfer area of the first effect after TVC location (i)
A ei =
Uei ∙ (Tvi − 1 − Ti )
j−2 (a72) The heat transfer area for the other effects after TVC location (i + 1 to n)
⎡ Dj − 1 + ∑j = 1 Dj ∙y − (j − 1) ∙Fj∙y ⎤ ∙λ j − 1
( )
A ej = ⎣ ⎦
Uej∙ (Tvj − 1 − Tj)
1939.4 + 1.40562 ∙ Ti − 0.0207525 ∙ (Ti)2 + 0.0023186 ∙ (Ti)3 (a73) overall heat transfer coefficient of the effect
66
Uen = 1000
C ∙ ΔTfi ∙ ∑ik = 1 F k Tvi − Tfi + 1 (a74) Feed water preheater heat transfer areas i = 1,2, …, n − 1 (with the exception of the i − 1th
Afi = Uf ∙ (Tfi − Tfi + 1)
∙ln ⎡ ⎤
⎣ Tvi − Tfi ⎦ preheater)
Dn ∙ λ n (a75) Condenser heat transfer area
Ac = Uc ∙ (LMTD)c
(Tvn − Tf ) − (Tvn − Tc) (a76) Condenser logarithmic mean temperature difference
(LMTD)c = T −T
vn f⎤
ln ⎡
⎣ Tvn − Tc ⎦
Uc = 1.7194 + 3.2063 ∙ 10− 2 ∙ Tvn − 1.5971 ∙ 10− 5 ∙ (Tvn)2 + 1.9918 ∙ 10− 7 ∙ (Tvn)3 (a77) Overall heat transfer coefficient of the condenser
Dn ∙ λ n (a78) The cooling seawater flow rate
Mc = C ∙ (Tn − Tc)
λ = 2501.897149 − 2.407064037 × T + 1.192217 × 10− 3 × T2 − 1.5863 × 10− 5 × T3 (a79) Latent heat of evaporation (kJ/kg)
Pd (a80) The ratio of discharged pressure to entrained pressure (TVC unit)
Cr = Pr
Ps (a81) The ratio of the motive pressure to entrained pressure (TVC unit)
Er = Pr
Ds a3 a5 C a8 Cr C2 (a82) Entrained ratio (TVC unit). ai values are shown in Table A4
Ra = Dr
= a1 + a2∙Cr + Er
+ a 4∙Cr 2 + + a 6∙ Er + a7∙Cr 3 + + a 9∙ + a10∙ Er
Er 2 r Er 3 Er 2 r
D (a83) Gain output ratio of the desalination unit
GOR = Ds
i=n i=n−1 (a84) The specific heat transfer area
(∑i = 1 A e + A c + ∑i = 1 Afi)
SA = D
Desalination 425 (2018) 37–67
I.B. Askari et al. Desalination 425 (2018) 37–67
Table A4
Constants of the polynomial model adopted for TVC performance [38].
a1 − 3.20842211 −1.93422581
a2 3.933353 2.152524
a3 27.236 113.4909
a4 − 1.19206949 −0.52222106
a5 − 141.42328825 −14,735.96533618
a6 − 22.54551842 −31.85197010
a7 0.125813 0.047507
a8 348.5066 900,786
a9 41.7961 −495.58154134
a10 4.439929 10.02513
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