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YOUR EXPERT

IN ALTERNATIVE
FUELS
PRESENTS

Legal framework • Guidelines of the cement &


limeindustry • Calculation basis for alternative fuels
• Types of alternative fuels (biomass, waste-based
The most
fuels, solids/liquids) • Influences on the clinker
comprehensive
production process • Treatment technologies:
crushing,
compendium screening, of classifying, removal of pollutants
• Reception,
alternative fuels dosing, storage, sampling techniques •
Flame control, burner technologies, fire protection •
and raw
Impact onmaterials
CO2 emissions • Purchase management
for the cement
• Logistics • Quality control/quality management •
Trials
andorganization
lime industry • Analysis procedures • Information
about origin, composition and availability • Chemical
and physical parameters, such as bulk density, flow
behavior and burning behavior • Specific influences
on the clinker production process • Economic and
technical conditions for treatment, storage and
dosage possibilities • Specific legal requirements
• Safety at work • Environmental aspects • Country-
specific information Legal framework • Guidelines
of the cement & limeindustry • Calculation basis for
alternative fuels • Types of alternative fuels (biomass,
waste-based fuels, solids/liquids) • Influences on the
clinker production process • Treatment technologies:
crushing, screening, classifying, removal of pollutants
• Reception, dosing, storage, sampling techniques •
Dammstraße 11a, 47119 Duisburg, Germany
Flame control,
Tel: +49 burner
(0) 203 34 65 16 – 25 technologies,
Fax: +49 (0) 203 34 fire
65 16 – 50 sales@lechtenberg-partner.de protection •
www.lechtenberg-partner.de

Impact on CO2 emissions • Purchase management


Alternative Fuels and Raw Materials Handbook

Content
Preface 5 Fact Sheet:
Alternative fuel and raw material (AFR)
List of Abbreviations 21 review “Bamboo”
1 Classification according to European Waste
List of Chemical Formulae 33 Catalogue EWC 69
1.1 AFR description 69
1.2 AFR pictures 70
Fact Sheet:
Alternative fuel and raw material (AFR) 2 AFR source and composition 71
2.1 Source 71
review “Agriculture films”
2.2 Quantity and availability 72
1 Classification according to European Waste
2.3 Flow chart of AFR production 74
Catalogue EWC 37
2.4 AFR composition 75
1.1 AFR description 37
2.5 AFR analysis 75
1.2 AFR pictures 39
2.6 AFR ash composition 76
2 AFR source and composition 39
3 Harmful substances and hazardous characteristics 76
2.1 Source 39
4 Collection, recycling and disposal of the AFR 77
2.2 Quantity and availability 41
4.1 Collection and transport 77
2.3 Flow chart of AFR production 43
4.2 Recycling, current use and disposal 77
2.4 AFR composition 43 4.3 Use as alternative fuel in a cement or lime plant 79
2.5 AFR analysis 44
5 Recommendations 82
2.6 AFR ash composition 44
6 References 82
3 Harmful substances and hazardous characteristics 45
4 Collection, recycling and disposal of the AFR 45 Fact Sheet:
4.1 Collection and transport 45 Alternative fuel and raw material (AFR)
4.2 Recycling, current use and disposal of the AFR 46 review “Calcium fluoride sludge”
4.3 Use as alternative fuel in a cement or lime plant 47 1 Classification according to European Waste
5 Recommendations 50 Catalogue EWC 85
6 References 51 1.1 AFR description 85
1.2 AFR pictures 86
Fact Sheet: 2 AFR source and composition 86
Alternative fuel and raw material (AFR) 2.1 Source 86
review “Bagasse” 2.2 Quantity and availability 91
2.3 Flow chart of AFR production 92
1 Classification according to European Waste
Catalogue EWC 55 2.4 AFR composition and analysis 93
1.1 AFR description 55 3 Harmful substances and hazardous characteristics 94
1.2 AFR pictures 56 4 Collection, recycling and disposal of the AFR 94
2 AFR source and composition 56 4.1 Collection and transport 94
4.2 Recycling, current use and disposal 94
2.1 Source 56
4.3 Use as alternative raw material in
2.2 Quantity and availability 57
a cement plant 96
2.3 Flow chart of AFR production 58
5 Recommendations 99
2.4 AFR composition 59
6 References 99
2.5 AFR analysis 60
2.6 AFR ash composition 61
Fact Sheet:
3 Harmful substances and hazardous characteristics 61
Alternative fuel and raw material (AFR)
4 Collection, recycling and disposal of the AFR 62 review “Carpets and rugs”
4.1 Collection and transport 62 1 Classification according to European Waste
4.2 Recycling, current use and disposal 62 Catalogue EWC 103
4.3 Use as alternative fuel in a cement or lime plant 63 1.1 AFR description 103
5 Recommendations 65 1.2 AFR pictures 104
6 References 65 2 AFR source and composition 105
Alternative Fuels and Raw Materials Handbook

2.1 Source 105 4.2 Recycling, current use and disposal 153
2.2 Quantity and availability 107 4.3 Use as alternative fuel in a cement or lime
2.3 Flow chart of AFR production 108 plant 154
2.4 AFR composition 109 5 Recommendations 155
2.5 AFR analysis 111 6 References 156
2.6 AFR ash composition 112
3 Harmful substances and hazardous characteristics 112 Fact Sheet:
4 Collection, recycling and disposal of the AFR 113
Alternative fuel and raw material (AFR)
4.1 Collection and transport 113
review “Foams”
4.2 Recycling, current use and disposal 114
4.3 Use as alternative fuel in a cement or lime 1 Classification according to European Waste
plant 115 Catalogue EWC 159
5 Recommendations 120 1.1 AFR description 160
6 References 121 1.2 AFR pictures 160
2 AFR source and composition 161
Fact Sheet: 2.1 Source 161
Alternative fuel and raw material (AFR) 2.2 Quantity and availability 163
review “Coconut shells” 2.3 Flow chart of AFR production 164
1 Classification according to European Waste 2.4 AFR composition 165
Catalogue EWC 2.5 AFR analysis 165
127
2.6 AFR ash composition 166
1.1 AFR description 127
1.2 AFR pictures 128 3 Harmful substances and hazardous characteristics 166
2 AFR source and composition 129 4 Collection, recycling and disposal of the AFR 166
2.1 Source 129 4.1 Collection and transport 166
2.2 Quantity and availability 129 4.2 Recycling, current use and disposal 168
2.3 Flow chart of AFR production 133 4.3 Use as alternative fuel in a cement or lime
2.4 AFR composition 133 plant 169
2.5 AFR analysis 134 5 Recommendations 172
2.6 AFR ash composition 135 6 References 172
3 Harmful substances and hazardous characteristics 135
4 Collection, recycling and disposal of the AFR 136 Fact Sheet:
4.1 Collection and transport 136
Alternative fuel and raw material (AFR)
4.2 Recycling, current use and disposal 136
review “Glycerine from biodiesel
4.3 Use as alternative fuel in a cement or lime
plant 137 production”
5 Recommendations 140 1 Classification according to European Waste
6 References 140 Catalogue EWC 175
1.1 AFR description 175
Fact Sheet: 1.2 AFR pictures 176
Alternative fuel and raw material (AFR) 2 AFR source and composition 176
review “Coffee bean husks” 2.1 Source 176
1 Classification according to European Waste 2.2 Quantity and availability 177
Catalogue EWC 143 2.3 Flow chart of AFR production 181
1.1 AFR description 143 2.4 AFR composition 181
1.2 AFR pictures 144
2.5 AFR analysis 182
2 AFR source and composition 145
2.6 AFR ash composition 183
2.1 Source 145
3 Harmful substances and hazardous characteristics 183
2.2 Quantity and availability 146
2.3 Flow chart of AFR production 151 4 Collection, recycling and disposal of the AFR 184
2.4 AFR composition 151 4.1 Collection and transport 184
2.5 AFR analysis 152 4.2 Recycling, current use and disposal 184
2.6 AFR ash composition 152 4.3 Use as alternative fuel in a cement or lime
3 Harmful substances and hazardous characteristics 153 plant 185
4 Collection, recycling and disposal of the AFR 153 5 Recommendations 188
4.1 Collection and transport 153 6 References 188
Alternative Fuels and Raw Materials Handbook

Fact Sheet: 2.5 AFR analysis 247


Alternative fuel and raw material (AFR) 2.6 AFR ash composition 248
review “Labels” 3 Harmful substances and hazardous characteristics 248
1 Classification according to European Waste 4 Collection, recycling and disposal of the AFR 248
Catalogue EWC 191 4.1 Collection and transport 248
1.1 AFR description 191 4.2 Recycling, current use and disposal 249
1.2 AFR pictures 192 4.3 Use as alternative fuel in a cement or lime
2 AFR source and composition 193 plant 250
2.1 Source 193 5 Recommendations 253
2.2 Quantity and availability 194 6 References 254
2.3 Flow chart of AFR production 195
2.4 AFR composition 196 Fact Sheet:
2.5 AFR analysis 196 Alternative fuel and raw material (AFR)
2.6 AFR ash composition 197 review “Municipal solid waste”
3 Harmful substances and hazardous characteristics 198 1 Classification according to European Waste
4 Collection, recycling and disposal of the AFR 198 Catalogue EWC 259
4.1 Collection and transport 198 1.1 AFR description 259
4.2 Recycling, current use and disposal 198 1.2 AFR pictures 260
4.3 Use as alternative fuel in a cement or lime 2 AFR source and composition 260
plant 199 2.1 Source 260
5 Recommendations 202 2.2 Quantity and availability 261
6 References 202 2.3 Flow chart of AFR production 263
2.4 AFR composition 263
Fact Sheet: 2.5 AFR analysis 266
Alternative fuel and raw material (AFR) 2.6 AFR ash composition 268
review “Lime residues” 3 Harmful substances and hazardous characteristics 268
1 Classification according to European Waste 4 Collection, recycling and disposal of the AFR 269
Catalogue EWC 205 4.1 Collection and transport 269
1.1 AFR description 206 4.2 Recycling, current use and disposal 270
1.2 AFR pictures 206 4.3 Use as alternative fuel in a cement or lime
2 AFR source and composition 207 plant 272
2.1 Source 207 5 Recommendations 280
2.2 Quantity and availability 215 6 References 280
2.3 Flow chart of AFR production 219
2.4 AFR composition and analysis 220 Fact Sheet:
3 Harmful substances and hazardous characteristics 224 Alternative fuel and raw material (AFR)
4 Collection, recycling and disposal of the AFR 225 review “Nappies”
4.1 Collection and transport 225 1 Classification according to European Waste
4.2 Recycling, current use and disposal 225 Catalogue EWC 283
4.3 Use as alternative raw material in a 1.1 AFR description 283
cement or lime plant 227 1.2 AFR pictures 284
5 Recommendations 233 2 AFR source and composition 284
6 References 233 2.1 Source 284
2.2 Quantity and availability 284
Fact Sheet: 2.3 Flow chart of AFR production 290
Alternative fuel and raw material (AFR) 2.4 AFR composition 290
review “Meat and bone meal” 2.5 AFR analysis 292
1 Classification according to European Waste 2.6 AFR ash composition 293
Catalogue EWC 239 3 Harmful substances and hazardous characteristics 293
1.1 AFR description 239 4 Collection, recycling and disposal of the AFR 293
1.2 AFR pictures 240 4.1 Collection and transport 293
2 AFR source and composition 240 4.2 Recycling, current use and disposal 294
2.1 Source 240 4.3 Use as alternative fuel in a cement or lime
2.2 Quantity and availability 243 plant 294
2.3 Flow chart of AFR production 246 5 Recommendations 297
2.4 AFR composition 246 6 References 297
Alternative Fuels and Raw Materials Handbook

Fact Sheet: 2.3 Flow chart of AFR production 347


Alternative fuel and raw material (AFR) 2.4 AFR composition 348
review “Oil mud drillings” 3 Harmful substances and hazardous characteristics 349
1 Classification according to European Waste 4 Collection, recycling and disposal of the AFR 349
Catalogue EWC 303 4.1 Collection and transport 349
1.1 AFR description 303 4.2 Recycling, current use and disposal 349
1.2 AFR pictures 304 4.3 Use as alternative raw material in a
2 AFR source and composition 304 cement plant 349
2.1 Source 304 5 Recommendations 352
2.2 Quantity and availability 306 6 References 352
2.3 Flow chart of AFR production 308
2.4 AFR composition 309
Fact Sheet:
2.5 AFR analysis 310
Alternative fuel and raw material (AFR)
2.6 AFR ash composition 312
review “Plastics”
3 Harmful substances and hazardous characteristics 313
1 Classification according to European Waste
4 Collection, recycling and disposal of the AFR 315
Catalogue EWC 355
4.1 Collection and transport 315
1.1 AFR description 356
4.2 Recycling, current use and disposal 316
1.2 AFR pictures 358
4.3 Use as alternative raw material in a
cement plant 316 2 AFR source and composition 359
5 Recommendations 320 2.1 Source 359
6 References 320 2.2 Quantity and availability 360
2.3 Flow chart of AFR production 366
Fact Sheet: 2.4 AFR composition 367
Alternative fuel and raw material (AFR) 2.5 AFR analysis 368
review “Packaging materials” 2.6 AFR ash composition 368
1 Classification according to European Waste 3 Harmful substances and hazardous characteristics 369
Catalogue EWC 323 4 Collection, recycling and disposal of the AFR 372
1.1 AFR description 323 4.1 Collection and transport 372
1.2 AFR pictures 324 4.2 Recycling, current use and disposal 373
2 AFR source and composition 325 4.3 Use as alternative fuel in a cement or lime
2.1 Source 325 plant 375
2.2 Quantity and availability 326 5 Recommendations 381
2.3 Flow chart of AFR production 331 6 References 382
2.4 AFR composition 332
2.5 AFR analysis 333 Fact Sheet:
2.6 AFR ash composition 335
Alternative fuel and raw material (AFR)
3 Harmful substances and hazardous characteristics 336
review “Power plant ashes”
4 Collection, recycling and disposal of the AFR 336
1 Classification according to European Waste
4.1 Collection and transport 336 Catalogue EWC 385
4.2 Recycling, current use and disposal 336
1.1 AFR description 385
4.3 Use as alternative fuel in a cement or lime
1.2 AFR pictures 386
plant 338
5 Recommendations 340 2 AFR source and composition 387
2.1 Sources 387
6 References 340
2.2 Quantity and availability 390
2.3 Flow chart of AFR production 391
Fact Sheet:
2.4 AFR composition 391
Alternative fuel and raw material (AFR)
review “Paper fly ashes” 3 Harmful substances and hazardous characteristics 394
1 Classification according to European Waste 4 Collection, recycling and disposal of the AFR 394
Catalogue EWC 343 4.1 Collection and transport 394
1.1 AFR description 343 4.2 Recycling, current use and disposal 395
1.2 AFR pictures 343 4.3 Use as alternative raw material in cement
2 AFR source and composition 344 plants 396
2.1 Source 344 5 Recommendations 402
2.2 Quantity and availability 344 6 References 402
Alternative Fuels and Raw Materials Handbook

Fact Sheet: 2.3 Flow chart of AFR production 454


Alternative fuel and raw material (AFR) 2.4 AFR composition 454
review “Rice husk” 2.5 AFR analysis 455
1 Classification according to European Waste 2.6 AFR ash composition 456
Catalogue EWC 405 3 Harmful substances and hazardous characteristics 456
1.1 AFR description 405 4 Collection, recycling and disposal of the AFR 457
1.2 AFR pictures 406 4.1 Collection and transport 457
2 AFR source and composition 407 4.2 Recycling, current use and disposal 457
2.1 Source 407 4.3 Use as alternative fuel in a cement plant 458
2.2 Quantity and availability 407 5 Recommendations 464
2.3 Flow chart of AFR production 412 6 References 464
2.4 AFR composition 413
2.5 AFR analysis 413
Fact Sheet:
2.6 AFR ash composition 414
Alternative fuel and raw material (AFR)
3 Harmful substances and hazardous characteristics 414
review “Spent solvents”
4 Collection, recycling and disposal of the AFR 414
1 Classification according to European Waste
4.1 Collection and transport 414
Catalogue EWC 467
4.2 Recycling, current use and disposal 415
1.1 AFR description 468
4.3 Use as alternative fuel in a cement or lime
1.2 AFR picture 469
plant 416
5 Recommendations 420 2 AFR source and composition 469
2.1 Sources 469
6 References 421
2.2 Quantity and availability 471
2.3 Flow chart of AFR production 473
Fact Sheet:
2.4 AFR composition 473
Alternative fuel and raw material (AFR)
2.5 AFR analysis 473
review “Roofing felt”
2.6 AFR ash composition 478
1 Classification according to European Waste
Catalogue EWC 423 3 Harmful substances and hazardous characteristics 478
1.1 AFR description 423 4 Collection, recycling and disposal of the AFR 482
1.2 AFR pictures 424 4.1 Collection and transport 482
2 AFR source and composition 425 4.2 Recycling, current use and disposal 483
2.1 Source 425 4.3 Use as alternative fuel in a cement or lime
plant 484
2.2 Quantity and availability 426
2.3 Flow chart of AFR production 427 5 Recommendations 488
2.4 AFR composition 427 6 References 489
2.5 AFR analysis 429
2.6 AFR ash composition 430 Fact Sheet:
3 Harmful substances and hazardous characteristics 430 Alternative fuel and raw material (AFR)
4 Collection, recycling and disposal of the AFR 431 review “Synthetic gypsum”
4.1 Collection and transport 431 1 Classification according to European Waste
4.2 Recycling, current use and disposal 432 Catalogue EWC 491
4.3 Use as alternative fuel in a cement plant 432 1.1 AFR description 492
5 Recommendations 437 1.2 AFR pictures 492
6 References 437 2 AFR source and composition 493
2.1 Source 493
Fact Sheet: 2.2 Quantity and availability 499
Alternative fuel and raw material (AFR) 2.3 Flow chart of AFR production 500
review “Spent cell linings” 2.4 AFR composition and analysis 501
also known as “Spent pot linings” 3 Harmful substances and hazardous characteristics 502
1 Classification according to European Waste 4 Collection, recycling and disposal of the AFR 503
Catalogue EWC 441 4.1 Collection and transport 503
1.1 AFR description 441 4.2 Recycling, current use and disposal 503
1.2 AFR pictures 442 4.3 Use as alternative raw material in cement
2 AFR source and composition 442 plants 504
2.1 Source 442 5 Recommendations 508
2.2 Quantity and availability 443 6 References 509
Alternative Fuels and Raw Materials Handbook

Fact Sheet: 2.3 Flow chart of AFR production 556


Alternative fuel and raw material (AFR) 2.4 AFR composition 556
review “Textiles” 2.5 AFR analysis 557
1 Classification according to European Waste 2.6 AFR ash composition 558
Catalogue EWC 515 3 Harmful substances and hazardous characteristics 559
1.1 AFR description 516 4 Collection, recycling and disposal of the AFR 561
1.2 AFR pictures 516 4.1 Collection and transport 561
2 AFR source and composition 516 4.2 Recycling, current use and disposal 562
2.1 Source 516 4.3 Use as alternative fuel in a cement or lime
2.2 Quantity and availability 517 plant 564
2.3 Flow chart of AFR production 519 5 Recommendations 570
2.4 AFR composition 519 6 References 570
2.5 AFR analysis 520
2.6 AFR ash composition 521 Table of Figures 573
3 Harmful substances and hazardous characteristics 521
4 Collection, recycling and disposal of the AFR 522 Table of Pictures 578
4.1 Collection and transport 522
4.2 Recycling, current use and disposal 522 Table of Tables 584
4.3 Use as alternative fuel in a cement or lime
plant 523 Advertisement Index 590
5 Recommendations 526
6 References 526

Fact Sheet:
Alternative fuel and raw material (AFR)
review “Tobacco waste”
1 Classification according to European Waste
Catalogue EWC 531
1.1 AFR description 531
1.2 AFR pictures 532
2 AFR source and composition 532
2.1 Source 532
2.2 Quantity and availability 534
2.3 Flow chart of AFR production 536
2.4 AFR composition 537
2.5 AFR analysis 538
2.6 AFR ash composition 539
3 Harmful substances and hazardous characteristics 539
4 Collection, recycling and disposal of the AFR 540
4.1 Collection and transport 540
4.2 Recycling, current use and disposal 540
4.3 Use as alternative fuel in a cement plant 540
5 Recommendations 542
6 References 543

Fact Sheet:
Alternative fuel and raw material (AFR)
review “Used wood”
1 Classification according to European Waste
Catalogue EWC 547
1.1 AFR description 548
1.2 AFR pictures 549
2 AFR source and composition 549
2.1 Source 549
2.2 Quantity and availability 555

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