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Sln pH Corrección pHmetro [H+] Abs

1 1 0.4 0.1 0.502


2 3 2.66 0.001 0.493
3 5 3.28 0.00001 0.447
4 7 3.25 N/A 0.441
Sin corregir pH corregido

Sin corregir pH
0.51 0.51
0.5 0.5
0.49 0.49
0.48 0.48
0.47 Sin corregir pH 0.47
0.46 0.46
0.45 0.45
0.44 0.44
0.43 0.43
0.42 0.42
0.41 0.41
0 1 2 3 4 5 6 7 8 0 0.5 1 1.
0.4 0.502
2.66 0.493
3.28 0.447
3.25 0.441

pH corregido
0.51
0.5
0.49
0.48
0.47 pH corregido
0.46
0.45
0.44
0.43
0.42
0.41
0 0.5 1 1.5 2 2.5 3 3.5
ml SCN ppm (?) Abs abs-blanco
0 0 0.005 0
5 0.414 0.409
10 0.476 0.471
15 0.507 0.502
20 0.539 0.534
30 0.554 0.549

ml SCN vs Abs
0.6

0.55

0.5 ml SCN vs Abs

0.45

0.4

0.35
0 5 10 15 20 25 30 35
0 0
5 0.409
10 0.471
15 0.502
20 0.534
30 0.549
blanco
1 0.007
2 0.006
3 0.008
4 0.007
5 0.009
Promedio 0.0074
sd 0.00114018
sd*3 0.00342053
sd*10 0.01140175 Blancos iupac Error
LOD 0.01082053 0.00657694 0.01307541 49.70%
LOQ 0.01880175 0.03708622 0.04358469 14.91%
M 0.2616
A -0.0091

Blancos
LOD 0.00657694
LOQ 0.03708622
iupac Error en abs
0.01307541 49.70% 0.01082053
0.04358469 14.91% 0.01880175
Abs
Muestra Problema 0.025 0.06077982
Tiocianato sin tratar 0.022 0.04931193
(2 ppm) 0.572 0.572 2.15175841
Muestra Grifo 0.017 0.03019878

M 0.2616
A -0.0091
0.3 0.2 0.1 Muestra grifo
0.05213867 0.03432551 0.01608887 0.0049182
[] 0.16452091 0.09642779 0.02671586 -0.01598547
error 82.35% 107.41% 274.31%
mayor lod 1 1 1 0
mayor loq 1 1 0 0

Blancos iupac Error en abs


LOD 0.00657694 0.01307541 49.70% 0.01082053
LOQ 0.03708622 0.04358469 14.91% 0.01880175
Muestra problemaMuestra sin tratar
0.00574316 0.01276563
-0.0128319572 0.0140123471

0 1
0 0
[Fe] ppm log[Fe] Abs %T 100-%T dt tlogt Error
0.1 -1 0.026 94.1889597 5.81104035 0 185.929006 0
0.2 -0.69897 0.047 89.7428795 10.2571205 4.4460802 175.267844 0.02536735
0.3 -0.5228787 0.062 86.6961876 13.3038124 3.04669187 168.017212 0.01813321
0.9
0.5 -0.30103 0.104 78.704579 21.295421 7.99160861 149.223882- 0.0090945634
f(x) = 0.2616474465x 0.05355449
0.7 -0.154902 R² = 0.9985471879
0.185 65.3130553 34.6869447 13.3915237 118.543195 0.11296746
1 0 0.247 56.6239289 43.3760711 8.68912636 99.2617474 0.08753751
1.4 0.14612804 0.8 12.6697674 72.2166874 0.17544099
0.357 43.9541615 56.0458385
1.8 0.25527251 0.477 33.3426413 66.6573587 10.6115203 50.7808427 0.208967
2.5 0.39794001 0.637 23.0674719 76.9325281 10.2751694 31.4409642 0.32680834
3 0.47712125 0.776 16.7494288 83.2505712
0.7
6.31804313 20.5013008 0.30817767
4.5 0.65321251 1.048 8.95364766 91.0463523 7.7957811 8.52387257 0.91458208
6 0.77815125 1.542 2.87078058 97.1292194 6.08286707 1.31481751 4.62639647
8 0.90308999 1.91 1.23026877 98.7697312 1.64051181 0.11072419 14.8162007
0.6

0.5

Log[Fe] vs 100-%T
0.4

120

100 0.3

80
Log[Fe] vs 100-%T
60
0.2
40

20
0.1
0
-1.5 -1 -0.5 0 0.5 1 1.5

0
0 0.5 1 1
Concentración vs Abs

.0090945634

Column C
Linear (Colum

0.1 0
0.2 0.02536735
0.3 0.01813321
0.5 0.05355449
0.7 0.11296746 0.1 0.026 0.1 0.026
1 0.08753751 0.2 0.047 0.2 0.047
1.4 0.17544099 0.3 0.062 0.3 0.062
1.8 0.208967 0.5 0.104 0.5 0.104
2.5 0.32680834 0.7 0.185 0.7 0.185
3 0.30817767 1 0.247 1 0.247
4.5 0.91458208 1.4 0.357 1.4 0.357
6 4.62639647 1.8 0.477 1.8 0.477
8 14.8162007 2.5 0.637 2.5 0.637
3 0.776
4.5 1.048
6 1.542
1 1.5 2 2.5 3 3.5
8 1.91
0.1 0.026
0.2 0.047
0.3 0.062
0.5 0.104
0.7 0.185
1 0.247

Column C
Linear (Column C)

3.5
0.02

0.015

0.01

0.005
Residuos

0
0 0.5 1 1.5 2 2.5 3

-0.005

-0.01

-0.015

-0.02 Concentración mg/l


Resumen

Estadísticas de la regresión
Coeficiente de correlación múltip 0.9987526324
Coeficiente de determinación R^ 0.9975068207
R^2 ajustado 0.9971506523
Error típico 0.0113819663
Observaciones 9

ANÁLISIS DE VARIANZA
Grados de libertad Suma de cuadradosPromedio de los cuadrados F
Regresión 1 0.3628231559 0.3628231559 2800.660133
Residuos 7 0.0009068441 0.0001295492
Total 8 0.36373

Coeficientes Error típico Estadístico t Probabilidad


Intercepción -0.0090557418 0.0060156443 -1.5053652335 0.175948332
Variable X 1 0.2615884325 0.0049429741 52.9212635261 2.254192E-10

Análisis de los residuales

Observación Pronóstico para Y Residuos


1 0.0171031014 0.0088968986 0.8896898575
2 0.0432619447 0.0037380553 0.3738055323
3 0.0694207879 -0.0074207879 0.742078793
4 0.1217384744 -0.0177384744 1.7738474434
5 0.1740561609 0.0109438391 1.0943839061
6 0.2525326907 -0.0055326907 0.5532690696
7 0.3571680637 -0.0001680637 0.0168063705
8 0.4618034367 0.0151965633 1.5196563286
9 0.6449153395 -0.0079153395 0.791533948

0.1 0.0088968986
0.2 0.0037380553
0.3 -0.0074207879
0.5 -0.0177384744
0.7 0.0109438391
1 -0.0055326907
1.4 -0.0001680637
1.8 0.0151965633
2.5 -0.0079153395
Valor crítico de F
2.2541917E-10

Inferior 95% Superior 95%Inferior 95.0%


Superior 95.0%
-0.0232804803 0.005169 -0.0232805 0.005169
0.2499001562 0.27327671 0.24990016 0.27327671