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Article history: Application of structured packing in separation processes like natural gas dehydration has been
Received 27 June 2013 increased since last few years. Replacement of the existing trayed column with that of structured packing
Received in revised form can enhance the capacity and performance of the natural gas dehydration process. In this work, the
28 February 2014
natural gas dehydration plant of Farashband gas processing plant has been simulated. The profile of
Accepted 3 March 2014
Available online
concentration, temperature and pressure in absorption column was obtained. A computer program,
prepared with Visual Basic, has been proposed to calculate the height equivalent to a theoretical plate
(HETP) of structured packing. The effect of some important parameters of inlet Tri-ethylene glycol (TEG)
Keywords:
Farashband gas processing plant
and natural gas on the performance of absorption column have been analyzed. Results show that revamp
Dehydration unit of trays with structured packing, can reduce outlet natural gas dew point and improve the positive effect
Replacing trays with structured packing of other parameters on the performance of dehydration unit. Moreover, the most significant factors
Cost evaluation affecting the HETP were investigated which were less than 15% effective. Finally, the cost of the modi-
fication project for the absorption column in the Farashband gas processing plant was calculated. The
cost is evaluated 202,909 $ in this case and replacing was found economically justifiable.
Ó 2014 Elsevier B.V. All rights reserved.
http://dx.doi.org/10.1016/j.jngse.2014.03.005
1875-5100/Ó 2014 Elsevier B.V. All rights reserved.
S.M. Jokar et al. / Journal of Natural Gas Science and Engineering 18 (2014) 336e350 337
Glycol has been used for dehydration since the first of the 20th properties of an efficient packing seem to be a high effective area,
century (Kohl and Nielsen, 1997; Wieninger, 1991; Pearce et al., good liquid distribution, good gas liquid mixing, low pressure drop,
1972; Paymooni et al., 2011; Smith, 1993) but, limited researches and a structure composed of a material of small thickness (Kohl and
have been conducted to improve absorber trays yields and inves- Nielsen, 1997).
tigate the equations of state to predict thermodynamic behavior of The general tendency of chemical engineering is to achieve high
water-glycol system (Scauzillo, 1961; Twu et al., 2005; Erik, 2003). efficiency and capacity of separation units at a minimal possible
In 2009, Khosravanipour Mostafazadeh et al. (2009) investigated cost. A novel generation of column internals is introduced to
Vapor-Liquid Equilibria of Water þ Triethylene Glycol (TEG) and improve the mass transfer operation in this regard. The structured
Water þ TEG þ Toluene at 85 kPa. In 1999, Koch-Glitsch studied packing is made of corrugated sheets which have gained wide
improvement of TEG and natural gas contact in packed towers acceptance (Sperandio et al., 1965; Sakata and February 15, 1972;
(Koch, 1999). Also, in 2011 Paymooni et al. (2011) investigated the Spiegel and Meier, 2003; Chen et al., 1982). The structured packing
Enhancement in Triethylene Glycol (TEG) Purity via Hydrocarbon has been widely applied for mass transfer processes, and its ap-
Solvent Injection to a TEG þ Water System in a Batch Distillation plications in separation process have been developed during the
Column. past few years.
The absorption column of a natural gas dehydration unit has
been simulated by H. Pirzade and absorber charts were plotted
1.4. Replacing the tray column with the packed bed column
(Pirzadeh, 2003). The desorption system of the Farashband gas
processing plant dehydration unit was simulated by M. Jooshghani
The Contactor is the most important mass transfer equipment in
in 2004 (Joshghani, 2004). Natural gas dehydration in packed
TEG dehydration since its performance has crucial impact on
towers has been investigated by S. Khayami; he also studied the
downstream processes. The typical contactor is equipped with in-
influence of various factors on absorption rate (Khayami, 2004).
ternals like Vane Inlet Device (VID) for gas distribution, chimney
In recent years, most research has been done in response to the
tray for collection of liquid, trays/packing for mass transfer and
environmental debate. Today prevention of light and volatile
demister to minimize TEG losses. Mass transfer in contactor can be
compounds (benzene, toluene, Ethyl Benzene and xylene (BTEX))
achieved by using bubble cap, valve trays, sieve trays or the
emission is highly regarded (Break, 2000; Darwish, 2004). On the
structured packing.
other hand, from the economic viewpoint, glycol waste and hy-
Usually, the column with the structured packing has shown
drocarbon emission have been studied (Choi et al., 1992; Gupta,
better performance than tray column (Baniadam et al., 2009).
1996; Grizzle, 1993).
Specific surface area of structured packing is between 100 and
750 m2/m3, and its void fraction is higher than 90% (Olujic et al.,
1.2. Methods of reducing dew point of exhaust gas from the
1999).
absorption column
High capacity, high mass transfer surface area, high turn down
ratio, low pressure drop, and low liquid hold up are the advantages
There are some methods for the TEG regeneration process to
of the structured packing in comparison with trays or a random
achieve reduced water content specifications and/or BTEX emis-
packing. Other benefits of the packed columns are shorter column
sions, including: 1) Using stripping gas 2) Vacuum regeneration 3)
height, mechanical simplicity, ease of installation and ability to be
Regeneration using solvent 4) Cold finger method (Reid, 1975; Erik
fabricated cost-effectively from corrosion-resistant materials,
and Tyvand, 2002) 5) Increasing the height of absorption column 6)
including plastics, ceramics and other nonmetals.
Replacing the tray column with packed bed column:
One of the constraints on the selection of the structured
One way to reduce dew point of output gas leads from the ab-
packing is the high cost per unit volume, which causes the capital
sorption column is replacing existing contactors (tray) by con-
investment to be more than that of random packing or tray
tactors with higher efficiency (Structured packing) which is the
(Rahimpour and Kashkooli, 2004). Moreover, sometimes trays are
subject of this paper and will be discussed afterward.
easier to clean compared to packing. But, the column capacity
can increase at least 30e50% by replacing the existing tray col-
1.3. Structured packing
umns with structured packing columns. In earlier days, bubble
cap trays were commonly used in contactor. But in recent decade,
During the last two decades, the application of the structured
due to the proven performance of the structured packing, TEG
packing in mass transfer processes has been increasing (Wang
contactors are now designed or replaced with high capacity
et al., 2006). The first generation of the structured packing was
structured packing.
manufactured from wire gauze. This type of packing was quite
expensive compared to random packing. It was mainly used in the
vacuum distillation where a large number of theoretical stages 1.5. Farashband gas processing plant
were required combined with an extremely low pressure drop.
The development of sheet metal structured packing by Sulzer in Farashband gas processing plant is one of the oldest and
the late 1970’s revolutionized the packing industry. He made the important refineries in the southern part of Iran. It has been planted
structured packing more affordable and it became competitive to dehydrate the produced gas and stabilize the accompanied
with conventional internals (trays, random packing) (Erasmus, condensate from Aghar and Dalan gas reservoirs. Every day around
2004). 1400 million standard cubic feet (MMscf) of gas is fed to this plant.
The structured packing was made commercially available in the The gas field of Aghar contains sour gas and the gas field of Dalan
1980’s. Its distinct performance advantages became clear very contains sweet gas. In summer, all of the gases from the Farashband
quickly, which conduce to the modification of the mass transfer processing plant are injected into the oil wells for recovery
market over the succeeding 10 years. It is now considered as the enhancement and in winter, the gas from Dalan (sweet gas) is used
most preferred packing for many applications. for general consumption and the gas from Aghar (sour gas) is
In absorption processes, the best performance is usually ob- injected to the oil wells. Also, the gas condensate of the gas pro-
tained by packing techniques involving low pressure drop, good cessing plant (about 15,000 barrels/day) is sent to the Taheri harbor
mass transfer efficiency, and high capacity. The important for exporting (Rahimpour and Jokar, 2012).
338 S.M. Jokar et al. / Journal of Natural Gas Science and Engineering 18 (2014) 336e350
2. Objectives Table 1
Operating conditions of the absorption tray column of dehydration unit.
The aim of this study is to investigate the utilization of the Streams Summer Winter
structured packing instead of existing trays in absorption column of Flow rate Temp. Pres. Flow rate Temp. ( C) Pres.
dehydration unit of Farashband gas processing plant. In this regard (kg/h) ( C) (bar) (kg/h) (bar)
the TEG dehydration unit of Farashband gas processing plant was
Input wet gas 248418 51 127.80 246749 33 127.48
simulated. Furthermore the effects of various parameters on an Input lean glycol 5540 60 127.48 5401 42 127.48
absorption column of the Farashband processing plant were Output dry gas 248105 53 126.86 246600 34 126.86
investigated and the conditions for the best performance of ab- Output rich glycol 5546 53 127.48 5546 34 127.48
sorption column are specified. Finally, the costs of replacing the
trays with structured packing are calculated. water from glycol. The rich glycol (99 wt%) leaving the surge drum
enters to a pump where its pressure is elevated to that of the ab-
sorption column. Glycol solution is heated after pumping, in a
3. Simulation of the dehydration unit of the Farashband gas
glycoleglycol heat exchanger and fed to the absorption column.
processing plant
There are some differences between the operating conditions and
feed characteristics in winter and summer. So, the dehydration
3.1. Process description
process is simulated in both summer and winter operating
conditions.
The Dehydration unit of the Farashband refinery contains six
thoroughly distinct units. The dew point of gas before the dehy-
dration unit is 5 C in summertime and 15 C in winter which 3.2. Simulation of conventional absorption column
should reach to 35 C after the unit.
Fig. 1 presents the schematic diagram of the dehydration unit of The operating conditions and feed compositions are presented
Farashband gas processing plant. Wet gas enters from the bottom of in Tables 1 and 2, respectively. Also, the design parameters of
the absorption column with 127 bar g pressure and lean glycol desorption and absorption towers of the Farashband gas processing
enters from the top of the absorber. After passing demisters, a large plant are reported in Table 3.
amount of water content existing in the wet gas is absorbed in TEG The lack of a demister pad in steady state simulation causes to
solution. Dry gas exits from the top of the column. The existing use small separator at the entrance of the column as a demister pad.
absorber in the Farashband processing plant is a tray column. The tray efficiency is calculated by two methods: O0 Connell and
The rich glycol after preheating and flash separation enters a AICHE methods (O’Connell, 1946; AIChE, 1958). On the other hand,
glycoleglycol heat exchanger which is placed before the regener- Cohl and Nielson suggested the efficiency of 33% for valve trays in
ation unit. Then, it introduces into a high pressure filter for elimi- gas dehydration units (Kohl and Nielsen, 1997). The results of the
nating solid particles and run to the stripper (regenerator). The previous methods and the tray efficiency, which is calculated from
glycol stripper consists of a column and a reboiler. The output glycol experimental data are shown in Table 4.
from the reboiler with a temperature of 200 C and 99% glycol The efficiency which is calculated from experimental data (43%)
concentration goes to surge drum. The stripping gas is injected is used for simulation of absorption column.
from the bottom of the surge drum. This gas causes a relative For validation the simulation results were checked against the
pressure decrease in the gas phase and helps the separation of experimental data obtained from Farashband gas processing plant
Still Vent
Off-Gas
Stripping
Dry Natural Gas Gas Burner
Exhust
absorber
Inlet Reboiler
Separator
Moist Natural
Natural Gas Gas
Gas/Glycol Flash Gas to Surge
Vent, Fuel or Tank
Heat
Exchanger Stripping Gas
Lean
Glycol
Phase separator
Hydrocarbon Rich
Liquid to Tank Glycol Filter Glycol
Rich Glycol
Circulation
pump
Figure 1. Schematic diagram of the dehydration unit of Farashband gas processing plant.
S.M. Jokar et al. / Journal of Natural Gas Science and Engineering 18 (2014) 336e350 339
Table 2 Table 4
Feed composition of the absorption tray column of dehydration unit. Efficiency of absorption column trays by different methods
and the efficiency which had calculated by experimental data
Components Mass fraction (%) Components Mass fraction (%) of Farashband gas processing plant.
CO2 1.91 i-Pentane 0.28
Method Efficiency
N2 11.12 n-Pentane 0.24
H2O 0.07 n-Hexane 0.28 O’Connell 27%
Methane 80.26 n-Heptane 0.33 AICHE 65%
Ethane 2.58 Benzene 0.04 Kohl & Nielsen 33%
Propane 0.87 Toluene 0.05 Experimental data 43%
i-Butane 0.04 Ethyl benzene 1.00
n-Butane 0.48 o-Xylene 0.45
Figure 2. Replacing tray column absorber with structured packing packed bed column.
structured packing and tray absorption column, 2) the sensitive instead of trays the height of the absorption column could reduce
analysis of the packed bed absorption column, and 3) the effective from 3.8 m to 3.3 m.
parameters on HETP. In Fig. 7, it seems that, in the first 1.5 m from the top of the
structured packing case, the water concentration has been
4.1. The comparison of trayed and packed bed absorption columns decreased while water has been actually absorbing. It is because of
simultaneous absorption of high density hydrocarbons at the top of
Figs. 6 and 7 show the comparison of gas and liquid concen- the column.
tration of water in conventional trayed and structured packed bed Fig. 8 shows the concentration profile of TEG along the height of
absorption columns. packed and trayed absorption column. It can be detectable struc-
Fig. 6 reveals that using the structured packing in the absorption tured packing can be used instead of trays to improve separation in
column can lower the amount of water in the gas phase. In case of column. Because, trayed columns provide stepwise contact be-
structured packing, the concentration of water in the gas phase tween the vapor and liquid phases packed columns provide
reaches its lower limit before the end of the column (3.3 m continuous contact of the vapor and liquid between the top and
approximately). This means that by using structured packing bottom of the packed bed. Structured packing provides more sur-
face area and higher separation efficiency.
In Fig. 9, the concentration of TEG in liquid phase is decreasing
from the top to the bottom of the column. This trend becomes more
abrupt in the packing column because of more water absorption. In
fact, desorption of high density hydrocarbons coupling with ab-
sorption of water at the bottom of the column caused the TEG
concentration to be decreased dramatically.
Table 6
MELLAPAK 250Y (structured packing) properties.
Properties Value
Table 7
Comparison of various models for calculating HETP.
SRP 0.33
Delft 0.36
Gualito 0.34
Wang et al. 1.5
Vendor proposed value 0.38
Figure 6. Comparison of mass concentration of water in the gas phase in absorption
Modified Delft 0.44
column including packing and tray.
342 S.M. Jokar et al. / Journal of Natural Gas Science and Engineering 18 (2014) 336e350
Fig. 13. Effect of temperature of inlet gas on outlet water content of gas.
Fig. 11. Effect of mass concentration of water in inlet TEG on outlet water content of
gas.
5.2.2. Cost index
The preceding equation indicates that a logelog plot of capacity Costs change over time. The most important factor in cost
versus equipment cost for a given type of equipment should be a changes is devaluation affected by inflation. The information con-
straight line with a slope equal to n. The application of the 0.6 rule tent of prices is related to different years. We have to convert these
of thumb for most purchased equipment is an oversimplification of prices to the prices of current year. The following equation is used
a valuable cost concept since the actual values of the cost capacity to update prices.
factor typically vary from less than 0.2 to greater than 1.0. Because
of this, the 0.6 factor should only be used in the absence of other
information. The value of “n” can be obtained from various re-
sources. The recommended value is 1 for the towers (Perry and C2 I
Green, 1984). ¼ 2 (7)
C1 I1
Smith suggested an exact value of 0.85 for “n” exclusively in
structured packing (Smith, 1995). Also, He suggested that the cost Which “I”, “C”, “1” and “2” are cost index, purchased cost, base time
of structured packing depends on the column diameter (D) and when cost is known and time when cost is desired. The Cost index
packing height (H) instead of capacity (Cap). So, he suggested the is a relative number compares the prices of each year with the other
following correlation (Smith, 1995): years. Our references for cost index are:
Fig. 12. Effect of mass flow rate of inlet TEG on outlet water content of gas. Fig. 14. Effect of mass flow rate of water in inlet gas on outlet water content of gas.
344 S.M. Jokar et al. / Journal of Natural Gas Science and Engineering 18 (2014) 336e350
5.2.4. Location factor The results of cost evaluation with and without bank interest are
Production and installation costs of structured packing are presented in Table 11.
different all around the world. As indicated in Table 9 the location The Life cycle of the unit and bank interest is considered 25
factor for the Middle East is 0.84. years and 6 percent respectively. The third column shows the
annual profit. The annual profits for four cases are investigated: 1-
increasing capacity 2- decreasing dew point 3- decreasing stripping
5.2.5. Transport factor
gas and 4-decreasing reboiler load. The last two cases result from
The other factor is transportation cost of the equipment.
decreasing gas consumption. The fourth column shows the annual
Transportation cost is a function of the distance between the origin
cost of TEG consumption. In this column the negative values in two
and destination. Usually increasing in cost because of trans-
first rows refer to increasing TEG consumption and consequently
portation covers the decreasing in cost because of location. We can
Fig. 16. Effect of mass flow rate of inlet gas on HETP. Fig. 18. Effect of mass flow rate of inlet liquid on HETP.
S.M. Jokar et al. / Journal of Natural Gas Science and Engineering 18 (2014) 336e350 345
Mist Lean
Mist Eliminator
Eliminator Lean TEG
TEG
Tray No. 1 Liquid Distributor
Tray No. 2
Structured Packing
Wet
Insert Type Diffuser
Gas
Condensate Condensate
Table 9
Location factors for chemical plants of similar functions.
Australia 1.04
Austria 0.85
Belgium 0.70
Canada 1.14
Central Africa 1.51
Central America 1.20
Denmark 0.85
Finland 0.88
France 0.73
Germany 0.76
Greece 0.80
Imported element 0.80
Indigenous element 0.25
Ireland 0.70
Italy 0.79
Japan 1.46
Malaysia 0.42
Middle east 0.84
New Zealand 1.27
Fig. 20. Comparison of the four references for cost index.
Imported element 0.65
Indigenous element 0.44
increasing cost of TEG. The fifth column shows annual net profit
Norway 0.92
(sum of the values in column 3 and 4). Also, the last three columns Portugal 1.00
indicate the rate of return, payout time and total net profit South Africa 0.90
respectively. South America 1.36
Spain 0.83
Rate of return on investment is ordinarily expressed on an
Sweden 0.75
annual percentage basis. The yearly profit divided by the total initial Switzerland 0.94
investment necessary represents the fractional return, and this Turkey 0.80
fraction times 100 is the standard percent return on investment United Kingdom 0.76
(Smith, 1995). The negative values in the last column show the United States 1.00
Table 11
Cost evaluation with and without bank interest.
Life cycle Annual profit Annual cost Annual net profit Rate of return (%) Payout time (year) Total net profit (US $)
of unit (year) (US $) of TEG consumption (from project) (US $)
With Without With Without With Without
(US $)
interest interest interest interest interest interest
Increasing capacity 25 58320 5627 52693 25.97 12.81 3.85 7.81 1,114,416 446,852
Decreasing dew point 25 54000 271 53729 26.48 12.89 3.78 7.76 1,140,316 451,050
Decreasing stripping gas 25 12410 þ1472 13892 6.48 3.39 14.62 29.47 144,391 30,772
Decreasing reboiler load 25 1241 þ552 1793 0.88 0.44 113.64 228.30 158.84 180,692
Fig. 21. Cash flow with time for the case (a) increasing capacity (b) decreasing dew point (c) decreasing stripping gas (d) decreasing reboiler load.
Fig. 21 (aed) shows cash flow with time for the four mentioned process and lowering the dew point, but is not economical. The
cases for Farashband gas processing plant with and without bank water content of inlet gas has a negative effect on dew point and it
interest. The cases 1 and 2 have approximately the same cash flow seems to be necessary to use a demister pad under a good condi-
as shown before in Table 11. tion. Increase of inlet gas mass flow rate up to 30% can be acceptable
Results show that if the entire goal is considered increasing in case of using 3.8 m structured packing bed. Also the replacing
capacity and decreasing dew point the replacement of structured was investigated in an economical point of view and the cost ob-
packing instead of tray in absorption column of Farashband gas tains 202,909 $ for this case. Results show that if the entire goal is
processing plant is profitable. considered increasing capacity and decreasing dew point, it is
worth to use structured packings instead of trays.
6. Conclusion
Appendix A
In this research, the effect of various parameters on the per-
formance of the dehydration unit of Farashband gas processing The proceeding visual basic code is applied for HETP calculation
plant were analyzed and compared. The replacement of tray with based on the modified delft model (Rahimpour et al., 2011). The
structured packing in an absorption column not only chooses to proposed model was added in the steady state simulation software
lower the dew point of outlet gas, but also improve the positive and could be run by the software. This program designed to receive
effect of other parameters on the performance of dehydration unit operation variables, fluid intake and output data from the user. The
and is economically justifiable. data of the structured packing is in the databank of the program
The TEG parameters, except for inlet concentration, have no and the conditions of the streams report from simulation software
remarkable effect on the outlet gas water content. The inlet tem- to the program automatically. The calculated HETP and NTU reports
perature of gas has a significant effect on the performance of the to an Excel file. The NTU number can be estimated from the Eq. (2).
S.M. Jokar et al. / Journal of Natural Gas Science and Engineering 18 (2014) 336e350 347
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