k´= (�_���−1 )/([�]^(

1)
Π/c x 10^4
c (g/100 ml) Π (cm solvente) ηr (viscosidad relativa) [η]
a) (atm/g/100 ml)
0.275 0.457 1.17 0.6182 1.6618
0.338 0.592 1.7515
0.344 0.609 1.215 0.6250 1.7703
0.486 0.867 1.7840
0.896 1.756 1.629 0.7020 1.9598
1.006 2.098 2.0855
1.199 2.71 1.892 0.7440 2.2602
1.535 3.725 2.4267
1.604 3.978 2.33 0.8292 2.4800
2.108 5.919 2.995 0.9464 2.8079
2.878 9.713 3.3749

Ordenada 1/M 1.482

Pendiente A2 0.632

M 67476.383265857
A2 0.632

[𝜂]=𝐾𝑀^� [𝜂]_𝜃=0,00048𝑀^0,5 𝐾= Φ((𝑟_0^2 )  ̅/𝑀)^(3/2)

b)

〖 [𝜂] 〗 _𝜃 16.194
Φ 2.5E+021
K 0.00048
�_0^2=(𝐾/Φ)^(2/3) * M
8.2914979757085E-46

(�_0^2 )  ̅^(1/2)/2 2.87949613226142E-23

2)

3) cx10^3 [g/ml] R(ϴ) x 10^5 [1/cm]

 0.5034 0.239
1.0068 0.44
1.512 0.606
2.0136 0.79
2.517 0.902

𝐻𝑐/(�𝜃 −�𝑠𝑡𝑒)=1/(𝑀𝑤 𝑃(𝜃))+ 〖 2A 〗 _2 c

𝐻=(2�^2 �_�^2 (��/��)^2)/(𝑁_𝐴 𝜆^4 )

no 1.4199
dn/dc 6.297E-02 cm3 g^-1
λ 6328 Ǻ
�_𝑔^2=(3𝜆^2)/(16𝜋^2 )
P 1
H
Rg

𝐻𝑐/(�(𝜃))=1/𝑀_𝑊 [ 1+1/3 (4π/𝜆)^2 Rg^2 sen^2 𝜃/2]

 k´= (�_���−1 )/([�]^(2 )�=√(3&([𝜂])/
𝑐^2 )−[𝜂]
([𝜂]𝜃))

4.00
k´(Huggins) α
3.50
5.2642 0.013
f(x) = 0.6361630436x + 1.4821018682
3.00 R² = 0.9915973121
4.0262 0.013 2.50

0.8878 0.014 2.00

Π/c 1.50
0.3771 0.015
1.00
-0.0773 0.017 0.50
-0.4451 0.019
0.00
0 0.5 1 1.5 2 2.5 3 3.5

c (g/100ml)

^2 )  ̅/𝑀)^(3/2)
3 3.5