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ANSWER &
SOLUTION
1. k(rate constant) = Ae-Ea/RT
K E Ea
K
R T T
ln or ln k ln k
R T T
Now, T1=318 K, Ea=37.3 kJ mol-1 and T2=308 K
log
k log ×
× ×
× × ×
= -2.9208 - 0.1989
= k2 = 7.6×10-4s-1
2.
KHC2O4. 3NaHC2O4
v.f = 2×3 = 6
v.f = 2
over all v.f = 6+2 = 8
M M
E
v f
3. Root mean square velocity (urms) = RT
M
Also p M = dRT
Substituting for RT/M in urms expression gives,
p
rms ⇒ rms ∝
d
d
5. nFEFe
Fe
nEFFe
Fe
nEFFe
Fe
× × EFe
Fe
×
EFe
Fe
×
6. R and R
∞
∴ and ∴
R
11.
6
5
4
3
2
n=1
Maximum number of lines produced = = 15 out of these 15 lines,
5 lines belong to ultra violet region and 4 lines are in visible region and rest are in
infrared region.
14. Ozone layer acts as a shield and does not allow ultraviolet radiation from sun to reach
earth. It does not prevent infra-read radiation from sun to reach earth, thus option (4)
is wrong statement and so it is the correct answer.
O
O O
15.
N N
N
where, O = given mass of O N = given mass of N O = molecular mass of
O N = molecular mass of N N = molecular mass of N O = number of
moles O N = number of moles of N2
O
×
N
17.
∧m
∧∞ b
c
∧m = Molar conductivity at conc. c
∧∞ = Molar conductivity at infinite dilution
c = concentration
b = constant
23.
O O
|| ||
C C
KOH ClCH2COOEt
N-H N-K+
C C
|| ||
O O
O
|| COOH
C
H2O NH2–CH2–COOH +
N–CH2COOEt.
C COOH
||
O
24.
O O
Br2 (1.0 mol)
CH3COONa + CHBr3 +
Na+OH-
CH3 CH3 CH3
CH3
Reaction I: (Unreacted)
(1.0 mol)
(In basic medium complete haloform reaction takes place since the rate of reaction
increases with each α-halogenation)
O O
Br2 (1.0 mol)
CH3COOH
CH3 CH3 CH3
CH3
Reaction II:
(1.0 mol)
(In acidic medium monohalogenation takes place with 1-mol of halogen)
C–CH3
O
26.
O
PBr3 CH2-CH2
CH3-CH-CH3 CH3-CH-Br Mg/ether CH3-CH-MgBr C
OH CH3 CH3
H2 O CH3-CH-CH2CH2OH
CH3-CH-CH2CH2OMgBr
CH3 CH3
27.
(a) Gas dispersed in liquid (p) Foam
(b) Liquid dispersed in gas (q) Aerosol
(c) Liquid dispersed in solid (r) Gel
(d) Liquid dispersed in liquid (s) Emulsion
5 3 1
6 Cl 4 2
29.
H+/Hg2+
CH3-C≡ CH + H2O CH3-C = CH2 CH3-C = CH3
OH O
enol keto
H+ RCH2OH
-H+
O + O
O Acetal
OCH2R
H